Chemistry Home Assignment ----------------2

1. The ion that isoelectronic with CO is a. CNb. O2+ c. O2d. N2+ 2. carbon tetrachloride has no net dipole moment because of a. its planar structure b. its regular tetrahedral structure c. similar sizes of carbon and chlorine atoms d. similar electron affinities of carbon and chlorine 3. which one among the following does not have the hydrogen bond? a. phenol b. liquid NH3 c. water d. liquid HCl 4. the types of bonds present in CuSO4.5H2O are only a. electrovalent and covalent b. electrovalent and coordinate covalent c. electrovalent, covalent and coordinate covalent d. covalent and coordinate covalent 5. On hybridization of one s and one p orbitals we get: a.two mutually perpendicular orbitals b. two orbital at 180 c. four orbitals directed tetrahedrally d. three orbital in a plane

6. the molecule having one unpaired electron is: a. NO b. CO c. CNd. O2 7. The bond between two identical non-metal atoms has a pair of electrons: a. unequally shared between the two. b.transferred fully from one atom to another c. with identical spins d. equally shared between them 8. the hydrogen bond is strongest in: a. O-HS b. S-HO c. F-HS d. F-H...O 9. The hybridization of sulphur dioxide is: a. sp b. sp c. dsp d. sp 10. The bonds present in N2O5 are ______ a. only ionic b. covalent and coordinate c. only covalent d. covalent and ionic 11. Any p-orbital can accommodate up to a. four electrons

b. two electrons in parallel groups c. six electrons d. two electrons with opposite spins 12. the principal quantum number of an atom is related to the a. size of the orbital b. spin angular momentum c. orbital angular momentum d. orientation of the orbital in space 13. The shape of [CH3] + is ------------------------. 14)Resonance structures for PF5 can be drawn so that each atom obeys the octet rule. Consider only resonance structures that are major contributors to the overall bonding in PF5. Which statement is correct? a)One resonance structure contains five PF covalent bonds. b)There are no resonance structures that involve ionic contributions. c)In each resonance structure, the P atom carries a positive charge. d)Only three resonance structures for PF5 can be drawn in which the P atom obeys the octet rule. 15) Which piece of evidence supports the delocalization of the negative charge in [NO3]? a)The NO bond lengths in [NO3] are not all equal. b)The NO bond lengths in [NO3] are equal. c)[NO3] is non-planar. d)[NO3] is planar 16)Match the hybridization scheme to the carbon atom in each molecule. Which pair is incorrect? a) b) c) d) sp2; sp2; sp3; sp3; H2CO CO2 CH2Cl2 CH4

17) Look at the structure of the platinum complex in Figure 6.21a. Which hybridization schemes are appropriate for the C atoms in this molecule? Click here to view Figure 6.21a a) b) c) d) Two of the C atoms are Two of the C atoms are Two of the C atoms are All the C atoms are sp3 sp3 hybridized, and the rest are sp hybridized. sp3 hybridized, and the rest are sp2 hybridized. sp2 hybridized, and the rest are sp3 hybridized. hybridized.

18) Which of the following compositions corresponds to an sp3 hybrid orbital? a) 25% s and 75% p character.

b) 50% s and 50% p character. c) 75% s and 25% p character. d) 33% s and 67% p character. 19) Match the shape to an appropriate hybridization scheme for the central atom. Which pair is incorrect a) b) c) d) NH3; sp3 ClF3; sp2 PF3; sp3 AlF3; sp2 20)For which one of the following molecules or ions would an sp2 hybridization scheme be appropriate for the central atom? a) [BO3] b) NI3 c) [H3O]+ d) [I3]+

20. Which response contains all of the characteristics listed that should apply to phosphorus trichloride, PCl3, and no other characteristics? (1) trigonal planar (2) one unshared pair of electrons on P (3) sp2 hybridized at P (4) polar molecule (5) polar bonds (a) 1, 4, 5 (b) 2, 3, 4 (c) 1, 2, 4 (d) 2, 4, 5 (e) another combination 21. Which molecule is nonpolar? (a) H2Se (b) BeH2 (c) PF3 (d) CHCl3 (e) SO2 22. The perchloric acid molecule contains: (a) 13 lone pairs, 1 bond, and 4 bonds. (b) 9 lone pairs, no bonds, and 6 bonds. (c) 8 lone pairs, 2 bonds, and 7 bonds.

(d) 2 lone pairs, 3 bonds, and 4 bonds. (e) 11 lone pairs, no bonds, and 5 bonds. 23. Draw a complete line-bond or electron-dot formula for acetic acid and then decide which statement is incorrect. (a) One carbon is described by sp2 hybridization. (b) The molecule contains only one bond. (c) The molecule contains four lone pairs of valence electrons. (d) One carbon is described by sp3 hybridization. (e) Both oxygens are described by sp3 hybridization.