Chapter : 2 Gaseous State

Standard MCQ
Q 1. a
K 92 . 1047
0821 . 0 0638 . 0
489 . 5
bR
a
e Temperatur s ' Boyle
=

=
=
Q 7. b
Daltons Law is not applicable to the mixture of
reacting gases like HCl & NH
3
or HBr.
Q 8. d
62 . 0 38 . 0
45 . 1
90 . 0
45 . 1
55 . 0
fraction Mole fraction Mole
90 . 0 ) 45 . 0 1 (
0 1
Cl 2 Cl
2
= =
= =

Average Mol. Mass = ( ) ( ) 5 . 35 62 . 0 71 38 . 0 +

. 49 99 . 48
01 . 22 98 . 26
~ =
+ =
Density P =
1
g 596 . 0
1500 0821 . 0
49 5 . 1
RT
PM

=

=
Q 10. c
Apply p =
RT
PM
Q 14.
The value of b depends upon the size of the
molecules.
6 2 2
H C CO CO He < < <
is the correct order.
Q 15. b
m 10 61 . 3 r
10
=
V 4 b =
Excluded volume per molecule is equal to 4 times
the volume of the molecule.
Excluded volume per mole is equal to 4N times
the volume of the molecule.
=
3
r
3
4
N 4 t
= ( ) ( )
3
10 23
10 61 . 3 14 . 3
3
4
10 023 . 6 4


= 4749.60
7
10

3
m
= 0.48 dm
3
Q 17. c
The value of a is greater for a gas having higher
intermolecular forces of attraction. So
2
CO with
maximum value of a can be most easily liquefied.
SOLUTIONS
2
Q 22. a
Pressure constant, volume constant,
So
( )
K 500
8 . 0
400
T
400 T 8 . 0
400 T 2 . 3 T 4
125 T 2 . 3 T 0 . 4
T w T w
T
M
w
T
M
w
T n T n
2 2 1 1
2
2
1
1
2 2 1 1
= =
=
=
+ =
=
= =
=
Q 25. a
Pressure of escaped gas = 4 2.36 = 1.64 atm
PV = nRT
. app g 7 . 18 w
300 0821 . 0
28
w
10 64 . 1
=
=
Q 26.
Vapor density of 36 means average molecular
mass = 72.
( ) ( )
( )
% 47 . 43
46
2000
2000 n 46
7200 9200 n 46 n 92
n 92 9200 n 46 7200
100
n 100 92 n 46
72
100
92 O N of % 46 NO of %
72
4 2 2
= =
=
=
+ =
+
=
+
=
43.47%
2
NO by moles
56.53 %
4 2
O N by moles.
( )
% 7 . 27
100
38 . 7200
62 . 1999
100
76 . 5200 62 . 1999
62 . 1999
mass by NO of %
g 76 . 520 92 53 . 56 O N of mass
g 62 . 1999 46 47 . 43 NO of mass
2
4 2
2
=
=

+
=
= =
= =
Q 30. c
6
P
P
M 2
M
P
P
P
P 3
M
M
P
P
P
P
RT
M P
P
RT
M P
P
y
x
x
x
y
x
y
y
y
x
y
x
y
x
y y
y
x x
x
=
=
=
=
=
Q 35. a
Case of open container
1 2
1
2
2 1
2 2 1 1
n
4
3
n ,
4
3
n
n
n 400 n 300
T n T n
= =
=
=
Q 36. a
300 0821 . 0
M
10 0012 . 0
1 1
nRT PV
3

=
=
On solving, M = 29.55 g
3
Q 38. d
C 207 or K 480 T
T n
8
5
300 n
T n T n
n
8
5
n
8
3
1 n
? T
K 300 C 27 T
2
2 1 1
2 2 1 1
1
1 2
2
1
=
=
=
=
|
.
|

\
|
=
=
= =
Q 40. a
( )
( )
( )
K 250 T
T 4 . 0 100
T 4 . 100 100 T 100
T 4 . 100 100 1 T
1 T
4 . 100
T
100
T
P
T
P
1 T T , T T
4 . 100 P , 100 P
2
2
1
1
2 1
2 1
=
=
= +
= +
+
=
=
+ = =
= =
Q 42.
KE per mol = RT
2
3
KE of 0.3 mol He = T R
2
3
3 . 0
KE of 0.4 mol Ar = 400 R
2
3
4 . 0
Equating 400 4 . 0 T 3 . 0 =
K 33 . 533 T =
Q 44. b
Let 16g of both are mixed.
9
8
8 1
8
H of fraction Mole
1
16
16
CH of Moles
8
2
16
H of Moles
2
4
2
=
+
=
= =
= =
Which is also the fraction of total pressure
executed by . H
2
Q 46. c
( ) ( )
torr 400 P
2000 P 800 500 600 1000
PV V P V P
2 2 1 1
=
= +
= +
Q 52. c
% decrease in volume means 100
V
V V
1
1 2

P 01 . 1
P 01 . 0 P P than P P Let
2 1
=
+ = =
%
101
100
%
01 . 1
1
100
01 . 1
01 . 0
decrease %
01 . 1
01 . 0
01 . 1
1 01 . 1
V
V V
01 . 1
1
1
V
V
1
01 . 1
1
V
V
V P 01 . 1 V P
V P V P
1
2 1
1
2
1
2
2 1
2 2 1 1
=
= =
=

=
=
=
=
4
Q 57. a
( )
( )
( )
. cc 150
4 . 0
60
V
60 V 4 . 0
V 4 . 0 40 100
V 100 P 4 . 0 100 P
% 60 by down fell P 4 . 0 P
V V P V P
2
2
2
2 1 1
1 2
2 1 2 1 1
= =
=
+ =
+ =
=
+ =
Q 61. b
( )
2 4 C
on dissociati
2
M
M & T r T
M
RT 3
c
2
1
2 1 2
= =
= =
=
Q 62. b
Pressure constant, volume constant,
So
( )
K 500
8 . 0
400
T
400 T 8 . 0
400 T 2 . 3 T 4
125 T 2 . 3 T 0 . 4
T w T w
T
M
w
T
M
w
T n T n
2 2 1 1
2
2
1
1
2 2 1 1
= =
=
=
+ =
=
= =
=
. atm 41 . 0 P
500 0821 . 0
40
4
10 P
nRT PV
=
=
=
Q 64. b
( )
( )
( )
. K 200 T
16 T 32 . 0 T 4 . 0
50 T 32 . 0 T 4 . 0
50 T
M
008 .. 0
T
M
4 . 0
T n T n
t tan cons volume , t tan cons essure Pr
nRT PV
2 2 1 1
=
+ =
+ =
+ =
=
=
Q 68. c
If volume diffused is same, time taken t o M .
5
Q 75. a
The gas in case of open end manometer is having
greater pressure, because in this case the
atmospheric pressure is also acting against the
pressure of the gas.
Q 78. c
At high pressure, be can
V
a
2
neglected.
( )
( )
. Pb RT PV
RT Pb PV
RT b V P
RT b V
V
a
P
2
+ =
=
=
=
|
|
.
|

\
|
+
Q 82. d
Because CO & N
2
have the same molar mass.
Q 85. a
g 32 Let of each be present moles of 1
32
32
O
2
= =
3
1
2 1
1
O of fraction Mole
2
16
32
CH of Moles
2
4
=
+
=
= =
same as fraction of pressure.
Q 86.
V V
B A 1.2 atm
313 K
For bulb A :
313 R n V 2 . 1 =
V V
B A P atm
313 K 423 K
n-x n+x
For bulb A :
( ) 423 R x n V P =
For bulb B :
( ) 313 R x n V P + =
Dividing :
110n = 736 x
x = 0.15 n
again :
( ) 313 R x n V P + =
313 R n V 2 . 1 =
Dividing and putting the value x = 0.15n,
Pressure can be calculated.
6
Archives MCQ
Q 4.
KE = RT
2
3
When temperature changes from 20C (293 K) to
40C (313 K),
1 2
KE
293
313
KE =
Q 10. b
Let 16g of both are mixed.
9
8
8 1
8
H of fraction Mole
1
16
16
CH of Moles
8
2
16
H of Moles
2
4
2
=
+
=
= =
= =
Which is also the fraction of total pressure
executed by . H
2
Q 14. c
3
NH has maximum value of a, so it would have
maximum intermolecular forces of attraction and
is most easily liquefied.
Q 18. d
g 32 Let of each be present moles of 1
32
32
O
2
= =
3
1
2 1
1
O of fraction Mole
2
16
32
CH of Moles
2
4
=
+
=
= =
same as fraction of pressure.
Q 21. b
RT
PM
P Density =
for maximum density,
T
P
be maximum which is
for option b.
Q 24. b
Cl NH HCl NH
4 3
+
The ring of Cl NH
4
will be formed near the HCl
end because
3
NH diffuses faster due to its smaller
molecular mass.
Q 25. c
g 6 . 0 0006 . 0 1000 mass
1000
mass
volume
mass
0006 . 0
. cc / g 0006 . 0 P , vapors water For
= =
= =
=
Density of liquid water = 1g / cc
Volume occupied by water
= cc 6 . 0
1
6 . 0
density
mass
= =
Q 40. b
nRT
PV
Z = = compressibility factor for ideal gases,
V = 22.4 and z = 1 for 1 mole for z > 1, at NTP,
V < 22.1 only then the equations is satisfied.
Q 46. a
7
s / m 6 . 0
3 . 0
300
1200
V
T
T
V
s / m 3 . 0 V
K 1200 C 927 T
K 300 C 27 T
T
T
v
v
1
1
2
2
1
2
1
2
1
2
1
=
=
=
=
= =
= =
=
Q 58. a
g 32 Let of each be present moles of 1
32
32
O
2
= =
3
1
2 1
1
O of fraction Mole
2
16
32
CH of Moles
2
4
=
+
=
= =
same as fraction of pressure.
Q 18. d
g 32 Let of each be present moles of 1
32
32
O
2
= =
3
1
2 1
1
O of fraction Mole
2
16
32
CH of Moles
2
4
=
+
=
= =
same as fraction of pressure.
Q 63. d
d
P 3
velocity rms =

Premium MCQ
Q 2. d
According to the problem, 90g of the gas must
occupy volume of the cylinder after dent at 2 atm
& 27C.
70 . 27 V
300 0821 . 0
40
90
V 2
RT
M
W
PV
=
=
=
Q 3. b
Let there be 32 g of each gas
11
2
8 2 1
2
CH of fraction Mole
8
4
32
He of Moles
2
16
32
CH of Moles
1
32
32
O of Moles
4
4
2
=
+ +
=
= =
= =
= =
Q 5.
Let the total mass of gases be = 100 g
7
4
35
20
20 15
20
H of fraction Mole
15
4
60
He of Moles
g 60 He of Mass
20
2
40
H of Moles
g 40 H of Mass
2
2
2
=
=
+
=
= =
=
= =
=
7
4
is the fraction of pressure exerted by . H
2
8
Q 7. b
( )
1 2
2 1
2 2 1 1
2
1
n
3
1
n
900 n 300 n
vessel open T n T n
K 900 C 627 T
K 300 C 27 T
=
=
=
= =
= =
Q 10.
Number of molecules in 1 ml of a gas at NTP is
called Loschmidt number.
22400 cc of a gas at NTP = moles 10 023 . 6
23

1 cc of a gas at NTP =
22400
10 023 . 6
23

. 10 688 . 2
19
=
Q 11. b
atm 123 . 0
300 0821 . 0 025 . 0 5 P
RT n PV
=
=
=
Q 16. b
Let the total mass of gases be = 100 g
7
3
35
15
20 15
15
He of fraction Mole
15
4
60
He of Moles
g 60 He of Mass
20
2
40
H of Moles
g 40 H of Mass
2
2
=
=
+
=
= =
=
= =
=
7
4
is the fraction of pressure exerted by . H
2
Q 18. b
78 . 30
300 0821 . 0
40
100
V 2
RT
M
W
PV
=
=
=
Q 20. c
. atm 4926 . 0 P
300 0821 . 0 1 . 0 5 P
nRT PV
1 . 0 025 . 0 025 . 0 05 . 0 Moles Total
025 . 0
28
7 . 0
N of Moles
025 . 0
32
8 . 0
O of Moles
05 . 0
4
2 . 0
He of Moles
2
2
=
=
=
= + + =
= =
= =
= =
Q 22. c
2
c
2
c
b P 27 a So
b 27
a
P
=
=
Q 24. b
. P
3
2
' P
2
V
V ' P V P
=
|
.
|

\
|
+ =
9
Q 26. a
The gas in case of open end manometer is having
greater pressure, because in this case the
atmospheric pressure is also acting against the
pressure of the gas.
Q 28. b
. K 44 . 224
10 67 . 2 0821 . 0
246 . 0 2
Rb
a 2
e Temperatur Inversion
2
=

=
=