ARAB REPUBLIC OF EGYPT

Ministry of Education General Secondary Education Certificate Examination First Session 2010 CHEMISTRY ( For the First and Second Stages ) Time : 3 hours
-----------------------------------------------------------------------------------------------------------------------------: Answer five questions only from the following ( Write all the chemical equations balanced ) : Question One : A) Choose the correct answer from the following to complete the phrases) . The element of electronic configuration 6s2 5d3 4f14 is considered from .1

a) first transition series c) lanthanide series

b) third transition series d) actinide series

When lithium reacts with nitrogen of the air then adding water to the product , the gas .2 . evolved is a) oxygen b) hydrogen c) ammonia d) nitric oxide
Hydrogen

a) HF c) HCl

bonds are the strongest between the molecules of .3 b)HBr d) HI

The amount of electricity required to precipitate 32.5 g zinc ( Zn = 65 ) during the electrolysis .4 . of zinc chloride solution equals a) 0.2 Faraday b) 2 Faraday c) 0.5 Faraday d) 1 Faraday When the excited electrons in an atom fall back to their ground state energy levels , they .5 . generate a) alpha particles b) beta particles c) energy appears as spectral lines d) gamma rays
.. The pH value of

a) 3
: B)

0.001 molar hydrochloric acid equals .6 b) 1 c) zero

d) 11

Show by balanced chemical equations how can you obtain) Acetone from 2-bromopropane .1 Gamexane from carbolic acid .2

: Question Two : A) Write the chemical

name of the following compounds according to IUPAC system)

1. CH3CH2CHC==CH CH2CH2CH3 2. CH3CHCH3

3. CH3CHCHCOH CH3 CH3 O

4. CH3CH2CO O

(B) 1. Calculate the equilibrium constant KP for the following reaction : N2 (g) + 3H2 (g) 2NH3 (g) H = - 92 KJ

Knowing that the pressures of the gases are 2.3 atm for nitrogen , 7.1 atm for hydrogen and 0.6 atm for ammonia . Account for the value of KP 2. Arrange the following compounds according to the pH values of their aqueous solutions : NaCl -CH3COONa -- NH4Cl

(C) A,B,C,D are four elements , their atomic numbers are 1.6,17,19 respectively 1. 2. 1) 2) 3) 3. What is the type of groups to which C,D elements belong Using these elements , how can you obtain : Ionic compound Pure covalent compound Polar covalent compound Mention the name and the type of hybridization in the compound formed when two atoms Of element B overlap with four atoms of element A

(D) 1. Show the relation between the principal quantum number (n) and the number of orbitals in the same level . 2. ( The reduction cycle in Medrix furnace is a closed cycle ) . Explain Question Three : (1) In the following reaction , which is in equilibrium , : CH3COOH + H2O 1. 2. CH3COO - + H3O +

How the following changes affect the concentration of acetate ion giving your reasons : Addition of drops of hydrochloric acid Addition of drops of sodium hydroxide solution

(2) Give the scientific reason for each of the following : 1. The boiling point of carboxylic acids is greater than the boiling point of alcohols whih Have the same molecular masses 2. Iron in FeCl3 is paramagnetic while zinc in ZnCl2 is diamagnetic 3. Copper cant replace hydrogen of water or dilute acids while sodium replaces hydrogen Of water and acids 4. In oxygen atom 8O , two electrons are paired in an orbital of sublevel 2p although the Sublevel 3s is empty (3) 1. Three bottles containing : Ethanol Phenol Acetic acid

2. 12-

Show how can you identify each of them practically Mention one use for each of the following : Chromium Avogadros number

Question Four (1) Compounds (A) and (B) , both having the molecular formula C2H6O 1. Write the structural formula of each compound 2. If you know that compound (A) is easily oxidized while compound (B) is not oxidized. How can you convert compound (A) to a compound having the functional group of Compound (B) ? 3. How can you obtain hydrogen from one of them ? (2) 12(3) 1. 2. 1. Calculate the atomic radius of hydrogen atom if the bond length in water molecule is 1.96 A0 and the bond length in oxygen molecule is 1.36 A0 . 2. How can you differentiate experimently between each pair of the following : Ammonium thiocyanate and sodium hydroxide Methyl orange solution and phenolphthalein solution What is the role of each of the following : Ferromanganese alloy in steel industry Salt bridge in galvanic cells

Question Five (1) Show by balanced chemical equations and write the reaction conditions in each of the Following : 1. Conversion of carboxylic group into hydroxyl group in an organic compound 2. Conversion of aromatic acid into organic acid amide (2) 1. Draw the apparatus used in the laboratory preparation of ammonia .Write the balanced Equation of the reaction Then give reason : conc sulphuric acid cant be used in drying ammonia 225 ml of 0.5 molar hydrochloric acid solution is neutralized with 20 ml of calcium hydroxide solution . Calculate the concentration of calcium hydroxide ( mole/liter ) (3) What is meant by : 1Recharge of lead-storage battary 2Molecular orbital theory 3Sintering process

Question Six (1) Write the scientific term for each of the following statements :

1. 2. 3. 4. 5.

Group of elements characterized by their large volumes and greatest malleability Volumes of gasses involved in a reaction and the gasses produced exist in fixed ratios Used when an unsymmetrical reagent as HX is added to unsymmetrical alkene The electrode at which the oxidation process takes place in electrochemical cells The electron is a negatively charged particle associated with wave properties

(2) Compare between each of the following : 1. Substitutional alloys and intermetallic alloys 2. Subsidiary and magnetic quantum numbers (C) 1. Cr2O7-2 + 3H2S + 8H+ 2Cr+3 + 3S + 7H2O Show the type of change ( oxidation or reduction ) occurs to each of chromium and sulphur In the previous reaction . 2Show the electronic configuration of nitrogen atom according to Hunds rule then Mention the important uses of nitrogen in industry. *************************************************************************************** Questions end here