Professional Documents
Culture Documents
Timothy J. Strathmann
Department of Civil & Environmental Engineering
Center of Advanced Materials for Purification of Water with Systems
University of Illinois, Urbana-Champaign, IL
90683701-0
by MnO4-
N OH
H
O O O O CH3
N
HO H2N H
COOH
pharmaceutical fate O Cl
HO
Me
H H
NMe 2
OH F
O OH
N
during existing O
S S
N S S
S NH 2
N N N
O N
treatment processes O NH2 OH O OH
OH
O O
HN
Cl OH H2N
O
H MeO
H2 N S N O N
O MeO N NH2
N Cl Cl OMe
O
Sulfamethoxazole Triclosan Trimethoprim
(antibiotic) (antiseptic) (antibiotic)
10
measured (utility 1) ⎛ E (T - 298) ⎞
k 2,T = k 2,298K exp⎜ a ⎟
Carbamazepine (μg/L)
measured (utility 2)
8 Model prediction ⎝ 298RT ⎠
4 Ea = 21 kJ mol-1
Cinit = 10 μg/L
2 2 mg/L KMnO4
25 ºC, pH 8.0 Rate pH independent
0
0 5 10 15 20 25 30
Time (min) Hu et al., manuscript in prep
Goals:
1. Characterize kinetics and
mechanism of antibiotic oxidation
2. Identify strategies for improving
chemical selectivity
1.0
Ciprofloxacin, C/Co
0.8
hν O
S
O N O
Direct UV photolysis
N HCO3-, NH4+, Hombikat
UV + TiO UV 100
H 0.6 2
H2N
SO42-
O O
0.4
F
OH
- 0.2 N N
+ HN
Cipro
0.0
0 10 20 30 40 50 60
Time (minutes)
Nanophase TiO2
Strathmann Environmental Chemistry Group
O O
1.0 • Photocatalytic
degradation under
0.8
visible light?
Ciprofloxacin, C/C0
Dark Control
0.6 >450 nm
>420 nm
>400 nm
• Atypical behavior can
0.4
>324 nm be exploited for
selective treatment
0.2
within mixed waste
0.0 streams
0 10 20 30 40 50 60
Time (minutes)
Paul et al., ES&T (2007)
-OH
O2-• hν (visible)
H
Br-
-O
O
O
O HO
BrO3- e- N
O O N
O2 C.B.
N
-OH F NH
TiO2 F N
-OH N
H
stable
V.B. -O
H organic
byproducts
-O
H
-OH
20
filtered effluent
filtered + GAC-treated effluent
deionized water
[diatrizoate] (μM)
15
10
0.01 C/Co, UV
C/Co, Vis/TiO2
C/Co, UV/TiO2
PEQ, UV
PEQ, Vis/TiO2
PEQ, UV/TiO2
0.001
0 2 4 6 8 10 12 14 16
I * t (W.min/cm2)
I*t = fluence = photon energy
delivered to during treatment Dodd et al., in prep