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2006
Indian sugarcane crop cultivation forms an important part of industry has been equally impressive. The distilleries
the Indian agricultural economy. Production of sugar has in their turn have led to the increased availability of
shown a phenomenal increase in the last 65 years. One of effluent, commonly termed as ‘spent wash’. The
the byproducts of sugar industry is pressmud, a solid residue,
major waste products from sugar processing and
obtained from sugarcane juice before crystallization of sugar.
alcohol manufacture are:
Generally pressmud is used as manure in India. The aim of
the present investigation is to recover protein, sugar and wax 1. Cane residues left in the field after cane
from pressmud. The amount of protein is estimated to be harvesting.
3.3%. The percentage of sugar is about 0.8%. Extraction of
2. Bagasse from the cane crushing operation.
wax by solvent has resulted in a recovery of about 12%.
3. Pressmud from the cane juice filtration.
4. Spent wash from distilleries.
T
he two main sources of sucrose are the Bagasse finds profitable use in the paper
sugarcane and the sugar beet. Sugarcane industry for the manufacture of wrapping and
is tall grass having a number of bamboo-like packing. Certain mills also manufacture paper by
stems, which grows to a height of 4 meters or more. employing suitable blends of conventional pulp with
The sugar content in sugarcane is about 10 to 15 per that obtained from bagasse. Its use is encouraged by
cent. As regards the sugar beet, the juice of the beet the government by providing subsidies to the
contains sugar identical to that found in cane. The manufacturers. Bagasse is also extensively used as a
sugar beet is found to contain 5 to 6 per cent of convenient source of fuel in mill boilers, often
sucrose. In improved varieties, a yield of 13 to 17 resulting in availability of excess energy. The other
percent is common and in this respect it compares cane residues could probably double the amount of
favourably with sugarcane. [1] energy availability. Table 2 describes the number of
factories in operation, their crushing capacity, area,
Indian Scenario
yield, cane and sugar production since the inception
Cane crop cultivation and production of sugar has
of sugar industry and their contribution to the Indian
shown a phenomenal increase in India over the last
economy.
60 years, since the industry started in an organized
manner [2]. The detailed figures are given in Table
1. Table 2 : Factories in Operation
The increase in sugarcane and sugar production
Sugarcane From 36 million tons in
has inevitably resulted in increased quantity of waste 1930 to 296 million
products. It is well known that molasses has found tonnes in 1999.
very useful applications in the manufacture of Yield per hectare From 31 tons in 1930 to
72.5 tonnes in1999.
ethanol and potable spirits. The growth of this
Area under cultivation From 1.2 million
Table 1 : Cane Crop Cultivation hectares in 1930 to 4.1
million hectares in
Sugarcane From 35M tonnes in 1930 to 1999.
296M tonnes in 1999. No. of sugar industries 550
Yield/hectare From 31 tonnes/hectare in 1930 Total cane production 220 million tonnes per
to 72.5 tonnes/hectare in 1999. year.
Area under cultivation From 1.2M hectares in 1930 to Total cane available fro crushing 135 million tonnes per
4.1M hectares in 1999. year.
Sugar production From 0.1M tonnes in 1930 to Total sugar production 13.5 million tonnes per
15.5M tonnes in 1999. year.
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Indian Chemical Engr. Section A, Vol. 48, No.3, July-Sept. 2006
Protein 3.3 %
Sugar 0.8 % 2
E (g)
Wax 12 %
0 . 1 m m p a r t i c le
pH %protein 0 . 5 m m p a r t i c le
5.5 2.59 0
0 100 200 300 400 500
6.0 2.62 Time (min)
7.0 3.00 Fig. 1 : Extraction of Wax by Solvent Toluene
8.0 3.13
2
8.5 3.30
E (g)
was recovered by evaporation. The percentage of 1
sugar was about 0.8% in pressmud.
Model for Wax Recovery 0.1 mm particle
The wax recovered from pressmud was about 12%. 0.5 mm particle
0
It had a melting point of 79°C and a density of 0.96.
0 100 200 300 400 500
The following mathematical expression was used to Time (min)
model the recovery of wax [5] : Fig. 2 : Extraction of Wax by Solvent
Toluene and Benzene
E=Emax θ/(θ+k) ... 1
4
2
recovery of wax in weight (g) as time proceeds using
the solvents toluene, toluene and benzene (50%) and
1
hexane, respectively. The maximum recovery of wax 0.1 mm particle
(0.1 mm particle size) was 2.7, 1.58 and 2.9 using 0.5 mm particle
0
toluene, toluene and benzene (50%) and hexane
0 100 200 300 400 500
respectively. The maximum recovery of wax (0.5 mm Time (min)
particle size) was 1.2, 1.64 and 2.78 using toluene,
Fig. 3 :Extraction of Wax by Solvent Hexane
toluene and benzene (50%) and hexane respectively.
The maximum quantity of wax was recovered by
Conclusion
using hexane as solvent. The results are reported in
Table 6. In conclusion, one could positively derive wealth from
the sugarcane and sugar industry wastes. Studies are
Table 6 : Emax and Values also done to model the Indian sugar industry with
precise mathematical approaches and to forecast its
SYSTEM Emax (g) K (min) performance in future. The amount of protein was
Toluene (0.1 mm) 6.67 0.17
estimated to be 3.3%. The percentage of sugar was
about 0.8%. Extraction of wax by solvent resulted in
Toluene (0.5 mm) 3.33 0.17
a recovery of about 12%.
Toluene + Benzene (0.1 mm) 4.00 0.56
Toluene + Benzene (0.5 mm) 2.50 0.25 Acknowledgement
Hexane (0.1 mm) 7.23 0.8 The authors acknowledge with thanks the South Indian Sugar
Research Foundation for providing pressmud and other sample
Hexane (0.5 mm) 3.87 0.79
materials for carrying out this investigation.
162
Indian Chemical Engr. Section A, Vol. 48, No.3, July-Sept. 2006
APPENDIX
163