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Finally, we find the modified dipole and quadrupole moments which include phase and
also time-dependency.
(a) Using the information that the HO length is approximately 1 Å and the HOH angle is
105◦ , find the partial charges on the H and O atoms.
(Solution)
Due to symmetry, the total dipole moment of an H2 O molecule
is twice that of single H − O system:
(b) Suppose that a water molecule is placed in a region of uniform E field of E = 1 kV/m
at an angle 90◦ to the field. How much work is required to rotate the dipole 180◦ about
an axis perpendicular to the dipole moment vector p~?
(Solution)
92 CHAPTER 7. INTERPRETATION IN MULTIPOLES
~ = −pE cos θ
U = −~p · E
W = U(final) − U(initial) = 0 .
(c) The phenomenon of hydration can be modelled by the force of attraction between a
water molecule as an electric dipole and an ion in a solution as a point charge. Esti-
mate the energy required to separate an ion carrying a single charge |e| from a water
molecule. Assume that initially the ion is located 2 Å from the effective center of the
water molecule along the axis of the dipole moment.
(Solution)
The electric potential due to dipole moment is
1 p cos θ
V =
4πǫ0 r2
And the potential energy (Ep ) is defined as following
−1 5.94 × 10−30
Ep = |e|V = eV ≈ 1.34 eV
4πǫ0 (2Å)2
In the limit when b → ∞ we may remove (a/b) and (r/b) terms. Removing
the latter corresponds to having only inverse powers of r surviving, which is the
expected case for an exterior solution. The result is
V V 3 a 2 7 a 4
Φ(r, θ) → + P1 (cos θ) − P3 (cos θ) + · · ·
2 2 2 r 8 r
which agrees with the exterior solution for a sphere with oppositely charged hemi-
spheres (except that here we have the average potential V /2 and that the potential
difference between northern and southern hemispheres is only half as large).
Similarly, when a → 0 we remove (a/b). But this time we get rid of the inverse
powers (a/r) instead. The result is the interior solution
V V 3 r 7 r 3
Φ(r, θ) → − P1 (cos θ) − P3 (cos θ) + · · ·
2 2 2 b 8 b
which is again a reasonable result (this time with the hemispheres oppositely
charged from the previous case).
3.2 A spherical surface of radius R has charge uniformly distributed over its surface with
a density Q/4πR2 , except for a spherical cap at the north pole, defined by the cone
θ = α.
a) Show that the potential inside the spherical surface can be expressed as
∞
Q X 1 rl
Φ= [Pl+1 (cos α) − Pl−1 (cos α)] l+1 Pl (cos θ)
8π0 2l + 1 R
l=0
Q
R σ=
4π R
2
We are thus interested in obtaining the potential Φ(r, θ) given a charge distri-
bution. This may be done using Coulomb’s law (or, equivalently, integrating
the Green’s function with the charge density). Alternatively, in this problem,
the surface charge density specifies an appropriate jump condition on the normal
component of the electric field
1
Er out = Er in + σ (4)
r=R r=R 0
This condition allows us to solve for the electrostatic potential Φ(r, θ).
In particular, because of the azimuthal symmetry of this problem, we may perform
an expansion in Legendre polynomials
∞
X r l
Φin = αl Pl (cos θ)
R
l=0
∞ l+1 (5)
X R
Φout = αl Pl (cos θ)
r
l=0
Note that the expansion coefficients αl are identical for the inside and outside
expansion. This holds because we demand that Φ is continuous at r = R. In this
case, the radial components of the interior and exterior electric fields are given
by
∞
X lαl r l−1
Er in = −
Pl (cos θ)
R R
∂
l=1
Er = − Φ ⇒ ∞ l+2 (6)
∂r X (l + 1)αl R
Er out = Pl (cos θ)
R r
l=0
or Z 1
R
αl = σ(cos θ)Pl (cos θ)d(cos θ)
20 −1
Using
Q n
0 cos θ > cos α
σ(cos θ) = 2
×
4πR 1 cos θ < cos α
gives Z cos α
Q
αl = Pl (cos θ)d(cos θ)
8π0 R −1
the inside and outside expressions (5) may be combined into a compact form
∞ l
X r<
Φ= αl R l+1 Pl (cos θ)
l=0
r>
∞
(8)
l
Q X 1 r<
= [Pl+1 (cos α) − Pl−1 (cos α)] l+1 Pl (cos θ)
8π0 2l + 1 r>
l=0
~ Q sin2 α
E= ẑ (9)
16π0 R2
Note that, had we chosen to look along the −ẑ axis (θ = π), we would have
gotten an identical result since P1 (cos π) = −1 would give an extra minus sign to
compensate for the −ẑ direction.
c) Discuss the limiting forms of the potential (part a) and electric field (part b) as
the spherical cap becomes (1) very small, and (2) so large that the area with
charge on it becomes a very small cap at the south pole.
We first consider the case α → 0, when the spherical cap becomes very small.
For small α, we use cos α ≈ 1 − 12 α2 as well as the Taylor expansion
to write
0 0
Pl+1 (cos α) − Pl−1 (cos α) ≈ 2δl,0 − 12 α2 [Pl+1 (1) − Pl−1 (1)]
Note that the delta functions take care of the special case concerning P−1 (1) = −1
instead of the usual +1. Using (7) now gives
2l + 1 2 2l + 1 2
Pl+1 (cos α) − Pl−1 (cos α) ≈ 2δl,0 − α Pl (1) = 2δl,0 − α
2 2
Q 1 Qα2 /4 1
Φ≈ −
4π0 r> 4π0 |~r − Rẑ|
Physically, this expression corresponds to the limit where the spherical shell is
almost complete (Φ = Q/4π0 r> for a shell centered at the origin). By linear
superposition, the very small cap can be thought of effectively as an oppositely
charged particle located at Rẑ with charge given by
Q 2 Q 2 Qα2
q = −σdA = − (R dΩ) = − (πα ) = −
4πR2 4π 4
~ Qα2 /4 ẑ
E(0) ≈
4π0 R2
Again, this makes sense for the electric field of a particle of charge −Qα2 /4
located at Rẑ. Note that the full spherical shell does not contribute any electric
field, since we are inside the shell.
Finally, we consider the case α → π, when the spherical cap becomes very large.
In this case, let α = π − β where β is the angle of the south polar cap. The
Legendre polynomial expansion is now
Note that the l = −1 special case is covered without any additions to this expres-
sion. This gives us
0 0
Pl+1 (cos α) − Pl−1 (cos α) ≈ 12 β 2 [Pl+1 (−1) − Pl−1 (−1)]
2l + 1 2 2l + 1 2
= β Pl (−1) = β (−1)l
2 2
This is clearly the potential due to a point charge of strength Qβ 2 /4 at the south
pole (−Rẑ) of the spherical surface. For the electric field, we substitute α = π −β
into (9) to obtain
~ Qβ 2 /4 2
E(0) ≈ ẑR
4π0
This is the electric field of a particle of charge +Qβ 2 /4 located at −Rẑ.
l.14 (0) Verify that
p1 6(p-p') = [- kl.(kp)J.(Icp,) dk
(b) Obtaio the (ollowing expansioo:
_1_ . = f
Ix- a \ .-
1- dk e...· -·'I.(Icp)I.(Icp')e-"··-· ...
dc~
~~
("')~~~~ ~~~
g(l)= r:~f(f))7r(-lf)df
iff) =: (;1e9{~) Jfl(-lif}r/~
.::iItht
flf') = r;-&. r:r-f(f);utif) tit .;;n(~t0t1~
f{f') 1;0 r:
(:-fifJf ~nt (-if) ::T"t/0o!~ "t
aLu
1(//) c: (;fqo) d(f-rYJa'j
tntif' ~
cf(f-f/J r f' r:~(~f) ~cJ.fIjJ~
- '1 J. -
81 ~ ~·/~i
dcl-pf/):= ~f eAMCHJ
;M=~
~fte~~tM~
~-t.D.Jc.f:Jd.t(~)k{~/;e-(~tP-pI'~J~'2-~ o(~
~
4~ (1)~ )= - {: dCf-fY; cRp-p5/) d(r-~/)
d~A Il~ (c,:r:') _ ~'l:} a.,..,(~/~/) =-~ dC-{!-'Z:''')
de:L (/
~ ~ ~=2:/ Ad Xk. ~ f e:J:..d.e ~
::t4t ~tVtf ~
~(i!J"t;I) ::= { e- b > (~:>-r/)
e -I--6p:< ( t< "2/ )
tJik~~ ~~~~pd'
~ «'/;.;;;;. . ~ -
a;r~ (Y+e = (-I}~-/1~) = -m
~ r!:.. e
4-fC. :uc..
=9A ~ ~ = ~
tutti~
- 13 -
--.-:-/~.::. ~~ ~'#('-M (1-p5~ (/~) k (.I. d.Je~~>-~q~ <...tJ-n. z4.L .4
(t-)tll )0 ;:-6-'- "T. IC( ~
~~
f;,t1<~
- (~~~ eh~(~)k1(-i(,:)e-l!!~tI~
~~~rad~'t'C~
~(~ J~~~/~f' )~J4~~-~l~f):r~(~t)
-;:i:::; ~ ~ r ~ J~
..£d
- rf
(d) -'~ ~ ~~ 'Y e -<-¥ t:hwI' ;d{a
hu;t ~ ~~I'
)0
(~~ -(-kf~;/e~'~?tt'r' co
T ~c-1>o
Z. i"(~-t¥.
Joe
~"'Id1cI"<:r~(,1,£))
r 'I
l>4
-.::. Z .2.7C i""tFIl1tm(::Tm.. (~)
~t:-PO
~17'l .7'~
~~~,
If desired, the potential may be rearranged to read
X (2l + 1)V Nl a l a l+1
l+1
Φ(~x ) = 1 + (−1)
a 2l+1 b r
l 2 1− b
l+1 r l
l l+1 a
+ (−1) 1 + (−1) Pl (cos θ)
b b
∞
"
V X (−1)j+1 (4j − 1)Γ(j − 12 ) a 2j−1 a 2j
= +V √ 1+
2 a 4j−1 b r
j=1 4 πj! 1 − b
#
a 2j r 2j−1
− 1+ P2j−1 (cos θ)
b b
which agrees with the solution to Problem 3.1 that we have found earlier.
3.17 The Dirichlet Green function for the unbounded space between the planes at z = 0
and z = L allows discussion of a point charge or a distribution of charge between
parallel conducting planes held at zero potential.
a) Using cylindrical coordinates show that one form of the Green function is
G(~x, ~x 0 )
∞ ∞ nπz nπz 0 nπ
4 X X im(φ−φ0 ) nπ
= e sin sin Im ρ< Km ρ>
L n=1 m=−∞ L L L L
In cylindrical coordinates, the polar direction φ is periodic with period 2π. This
suggests that the Green’s function could be expanded as a Fourier series in eimφ .
Similarly, the boundary conditions G = 0 at z = 0 and z = L motivates the use of
a Fourier sine series sin(nπz/L) in the z coordinate. More precisely, a complete
Fourier expansion in φ and z would give
X 0 0
nπz n0 πz
G(~x, ~x 0 ) = g(ρ, ρ0 )eimφ eim φ sin sin
L L
m,n,m0 ,n0
However, it turns out that m and m0 (and n and n0 ) do not need to be chosen
to be independent. This can be seen from the Green’s function equation (given
here as a differential equation in ~x )
1 ∂2 ∂2
1 ∂ ∂ 4π
ρ + 2 2 + 2 G(ρ, φ, z; ρ0 , φ0 , z 0 ) = − δ(ρ − ρ0 )δ(φ − φ0 )δ(z − z 0 )
ρ ∂ρ ∂ρ ρ ∂φ ∂z ρ
(3)
Using the completeness relations
∞
X 0
eim(φ−φ ) = 2πδ(φ − φ0 ) (4)
m=−∞
and
∞
X nπz nπz 0 L
sin sin = δ(z − z 0 )
n=1
L L 2
m2 nπ 2
1 d d 4
ρ − 2 − g(ρ, ρ0 ) = − δ(ρ, ρ0 )
ρ dρ dρ ρ L Lρ
d2 m2
1 d 4
2
+ − 1+ 2 g(x, x0 ) = − δ(x, x0 )
dx x dx x Lx
At this stage, the solution becomes standard. Noting that the modified Bessel
function Im (x) blows up as x → ∞ and the function Km (x) blows up as x → 0,
we are left with
AIm (x) x < x0
0
g(x, x ) =
BKm (x) x > x0
where the coefficients A and B are determined by the matching conditions
d d 4
g< = g> , g< = g> +
dx dx Lx0
4 Km (x0 )
A=
Lx0 Im
0 (x0 )K (x0 ) − I (x0 )K 0 (x0 )
m m m
0
4 Im (x )
B=
Lx0 Im
0 (x0 )K (x0 ) − I (x0 )K 0 (x0 )
m m m
Noting that the modified Bessel functions satisfy the Wronskian formula
1
Iν (x)Kν0 (x) − Iν0 (x)Kν (x) = −
x
finally gives
4 Im (x)Km (x0 ) x < x0
0
g(x, x ) =
L Im (x0 )Km (x) x > x0
4
= Im (x< )Km (x> )
L
where
x< = min(x, x0 ), x> = max(x, x0 )
Converting x back to ρ and substituting into (5) then gives the desired Dirichlet
Green’s function
∞ ∞ nπz nπz 0 nπρ
0 4 X X im(φ−φ0 ) <
nπρ
>
G(~x, ~x ) = e sin sin Im Km
L n=1 m=−∞ L L L L
d2 m2
1 d 2
+ + k − 2 Jm (kρ) = 0
dρ2 ρ dρ ρ
the substitution of (6) into the Greens’ function equation (3) gives
d2
− k gk (z, z 0 ) = −2δ(z − z 0 )
2
dz 2
Since gk (z, z 0 ) vanishes at z = 0 and z = L, this is a standard one-dimensional
Green’s function problem. Writing
z < z0
0 A sinh(kz)
gk (z, z ) =
B sinh[k(L − z)] z > z 0
3.26 Consider the Green function appropriate for Neumann boundary conditions for the
volume V between the concentric spherical surfaces defined by r = a and r = b, a < b.
To be able to use (1.46) for the potential, impose the simple constraint (1.45). Use
an expansion in spherical harmonics of the form
∞
X
0
G(~x, ~x ) = gl (r, r0 )Pl (cos γ)
l=0
l+1
where gl (r, r0 ) = r<
l
/r> + fl (r, r0 ).
a) Show that for l > 0, the radial Green function has the symmetric form
l
r<
gl (r, r0 ) = l+1
+
r>
l (ab)2l+1 r0l
l
1 l+1 0 l 2l+1 r
(rr ) + +a + l+1
(b2l+1 − a2l+1 ) l l + 1 (rr0 )l+1 r0l+1 r
There are several approaches to this problem. However, we first consider the
Neumann boundary condition (1.45)
∂G(~x ~x 0 )
4π
= −
∂n0 bndy S
5
R;,( ) Ry; R;,EW)( )(
$
R 3 y1 > R y1
) 1$6 1>Ld
h1> w{BR D ) ;$6 wn {BR1 dD L 333
( >)d ( n
l M
R d
) 0 d d ) R y1
1$6( d L wybD1 ;$6( n L 333
sR b$Y Y RZj BP w{D
-Φ
1 q
4πε0 a
1 2 3 4 5
r/a
qY }Bt$sj w$t Zt$R BP wRb;$6( yDD $t ? r }jst sR PZt{$BtR BP by qY IBI j$t $R Y s}}B-$8s$Bt PB8
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l M
d n N n n( ) d 8 n nI N +n&n wnI n D Q+ I ) d 8 nI
wnD ) ;$6 d N
+
n &
n wnI n D Q+ I
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;$6( ~ /n nI/ (
8 l M 8
d
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n & n wnI n D
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n
& w
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) 1$w6<L 6 D nn
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o
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h
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) w6 6( Don ) 1<$ 66 L 6 n (
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n
If we divide out by 1/r3 , the approximate and exact potentials are
0.8
0.6
0.4
0.2
where the straight line is the approximation of c) and the sloped line is the exact
result. The approximation improves as r a.
b) Determine the potential explicitly at any point in space, and show that near the
origin, correct to r2 inclusive,
r2
1 1
Φ(~r ) ' − P2 (cos θ)
4π0 4 120
We may use a Green’s function to obtain the potential at any point in space. In
general (since there are no boundaries, except at infinity)
1 X 4π rl
G(~x, ~x 0 ) = = <
Y ∗ (θ0 , φ0 )Ylm (θ, φ)
0
|~x − ~x | 2l + 1 r> lm
l+1
lm
Then
Z
1
Φ(~x ) = ρ(~x 0 )G(~x, ~x 0 ) d3 x0
4π0
1 2π 2 ∞ 04 −r0 r< l
Z
= r e l+1
dr0
4π0 64π 3 0 r>
Z 1
× [P0 (cos θ0 ) − P2 (cos θ0 )]Pl (cos θ0 )Pl (cos θ) d(cos θ0 )
−1
Z r Z ∞
1 1 1 0l+4 −r 0 0 l 03−l −r 0 0
= r e dr + r r e dr [2δl,0 − 52 δl,2 P2 (cos θ)]
4π0 48 rl+1 0 r
Obtaining the correct l = 2 term involves the cancellation of the first five terms
in the Taylor expansion. Note that the leading terms in the final expression have
the ‘correct’ powers of rl Pl (cos θ) in order to satisfy Laplace’s equation.
c) If there exists at the origin a nucleus with a quadrupole moment Q = 10−28 m2 ,
determine the magnitude of the interaction energy, assuming that the unit of
charge in ρ(~r ) above is the electronic charge and the unit of length is the hydrogen
Bohr radius a0 = 4π0 h̄2 /me2 = 0.529 × 10−10 m. Express your answer as a
frequency by dividing by Planck’s constant h.
The charge density in this problem is that for the m = ±1 states of the 2p level
in hydrogen, while the quadrupole interaction is of the same order as found in
molecules.
We first note that if we put the correct units of electronic charge e and Bohr
radius a0 into the charge distribution ρ, the potential near the origin (2) becomes
" 2 #
e 1 1 r
Φ=− − P2 (cos θ) + · · ·
4π0 a0 4 120 a0
where the overall minus sign is due to the negative charge of the electron. (We
take e > 0). The interaction energy is then
Z Z " 2 #
e 1 1 r
W = ρN Φ d3 x = − ρN − P2 (cos θ) + · · · d3 x
4π0 a0 4 120 a0
ρN d3 x = Ze gives the
R
where ρN is the charge density of the nucleus. Since
total charge of the nucleus, we write
e2
Z
Z 1 1 2 2 3
W =− − ρN r (3 cos θ − 1)d x + · · ·
4π0 a0 4 240a20 e
where we have used P2 (x) = 21 (3x2 − 1). Using z = r cos θ, this may be rewritten
as
e2
Z
Z 1 1 2 2 3
W =− − ρN (3z − r )d x + · · ·
4π0 a0 4 240a20 e
e2
Z Q
=− − + ···
4π0 a0 4 240a20
where we have used the (classical) definition of the nuclear quadrupole moment
Z
1
Q= ρN (3z 2 − r2 )d3 x
e
The first term is the electrostatic interaction energy. The quadrupole interaction
energy (expressed as a frequency) is
e2 Qc αQc
W/h = 3 = ≈ 1 MHz
4π0 h̄c 480πa0 480πa30
where α ≈ 1/137.036 is the fine structure constant, and where we have put in
the numerical value of Q. This nuclear quadrupole interaction with the electric
field of the electron cloud typically gives rise to radio frequency resonances (in
the low megahertz range) that may be detected using the process of nuclear
quadrupole resonance (NQR). Since NQR is sensitive to the electronic structure
(ie chemical bonds), it has seen some application towards explosives detection.
In particular, nitrogen is a common element in many explosives, and since 14 N
has a non-zero quadrupole moment, NQR can be used to detect what sorts of
nitrogen compounds may be present in a sample.
4.8 A very long, right circular, cylindrical shell of dielectric constant /0 and inner and
outer radii a and b, respectively, is placed in a previously uniform electric field E0
with its axis perpendicular to the field. The medium inside and outside the cylinder
has a dielectric constant of unity.
a) Determine the potential and electric field in the three regions, neglecting end
effects.
Since the cylinder is very long, we treat this as a two-dimensional problem. In
this case, the potential admits a general expansion
X
Φ= [αm ρm + βm ρ−m ] cos(mφ − δm )
m
Am = Bm = Cm = Dm = 0 m 6= 1
The matching at ρ = a is
0 Eρ3 = Eρ2 , Eφ3 = Eφ2
ρ=a ρ=a
or
(0 /)D − B + Ca−2 = 0, D − B − Ca−2 = 0
1 − 0 / 2 2
C= Ba , D= B (5)
1 + 0 / 1 + 0 /
or
(0 /)Ab−2 + B − Cb−2 = −(0 /)E0 , Ab−2 − B − Cb−2 = E0
Eliminating C using (5) gives rise to the simultaneous equations
1−0 / a 2
! ! !
b−2 −1 − 1+0 / b
A 1
1−0 / a 2
= E0
(0 /)b−2 1− B −0 /
1+0 / b
where 2 !
1 − 0 / a
∆ = (1 + 0 /) 1 −
1 + 0 / b
is b2 times the determinant of the above matrix. Substituting B into (5) then
gives the remaining coefficients
(1 − 0 /)20 / 2
C = −E0 ∆−1 a
1 + 0 /
40 /
D = −E0 ∆−1
1 + 0 /
The potential and electric field are obtained by substituting these coefficients into
(3) and (4). For the potential, we have
Note that we have actually plotted the electric displacement field D,~ as Gauss’
~ ~
law in vacuum ∇ · D = 0 ensures that the lines of electric displacement are
continuous and unbroken. The electric field lines themselves are discontinuous at
the interface between dielectrics.
c) Discuss the limiting forms of your solution appropriate for a solid dielectric cylin-
der in a uniform field, and a cylindrical cavity in a uniform dielectric.
where x = ρ cos φ. The potential Φ3 is irrelevant in this case. Here we see that the
potential Φ2 inside the cylinder is uniform (but corresponds to a reduced electric
field provided > 0 ). The potential outside is that of the original uniform electric
field combined with a two-dimensional dipole.
For the opposite limit, we obtain a cylindrical cavity of radius a by taking the
limit b → ∞. In this case, we end up with
20 / 2
x − E0 20(1+
/(1−0 /) a x
(
Φ2 = −E0 1+ 0 / 0 /)
2 ρ2 , ρ > a
Φ= 40 /
Φ3 = −E0 (1+0 /)
2 x, ρ<a
At first glance, this appears to be considerably different from (8). However, note
that the physical electric field we measure as ρ → ∞ is Ẽ0 = E0 (20 /)/(1+0 /).
In terms of Ẽ0 , we have
( 2
Φ2 = −Ẽ0 x − Ẽ0 1− 0 / a x
1+0 / ρ2 , ρ > a
Φ=
Φ3 = −Ẽ0 1+20 / x, ρ<a
This agrees with (8) after the replacement ↔ 0 (and a → b), as it must.
4.9 A point charge q is located in free space a distance d from the center of a dielectric
sphere of radius a (a < d) and dielectric constant /0 .
a) Find the potential at all points in space as an expansion in spherical harmonics.
By symmetry, we may place the point charge on the z-axis at z = d. In this
case, the problem is azimuthally symmetric, and we may expand the potential
in Legendre polynomials instead of spherical harmonics. For the potential inside
the dielectric sphere, we take
q X r l
Φin = αl Pl (cos θ) (9)
4π a
l
where the q/4π prefactor is taken for convenience (but can be absorbed into a
redefinition of αl if so desired). Note that we do not need any source term, since
there are no charges inside the sphere. On the other hand, the solution outside
the sphere is given by
1 q
Φout = + Φ0
4π0 |~x − dẑ|
where Φ0 is a homogeneous solution to Laplace’s equation, ∇2 Φ0 = 0. Expanding
in Legendre polynomials allows us to write
l a l+1
q X r<
Φout = l+1
+ βl Pl (cos θ) (10)
4π0 r> r
l
Note that r< = min(r, d) and r> = max(r, d). Since we must match the parallel
electric field and perpendicular electric displacement at r = a, we may take r< = r
and r> = d when using Φout in the matching equations. For the parallel electric
field, we have
in 1 ∂Φin q X αl 0
Eθ = − = P (cos θ) sin θ
r ∂θ r=a 4π a l
l
q X al−1
1 ∂Φout βl
out
Pl0 (cos θ) sin θ
Eθ = − = +
r ∂θ r=a 4π0 dl+1 a
l
4.11 The (a llowing data on thc variation oC dielectric constant with pressure are taken
Cram the Smithsonian Physical Tabla, 9th ed., p. 424:
Air at 292"K
Pressure (atm)
20 1.0108 Relative density oC
40 1.0218 air as a function of
60 1.0333 pressure is given in
80 1.0439 AlP Handbook, 3rd
100 1.0548 ed.• 1972, p. 4-165.
Test the Clausiu's -Mossotti retatioo between dielectric eoostan( and density for air
and pentane in the ranges tabulated. OOC$ it bold exactly? Approximately? If
approximately, discuss fr actional variatiON in dcosiry and (£-1). For pentane,
compare the Clausius-Mossotti relation 10 the cruder relation, (£-1) oc density.
rm-J (tAtta,)
..l. .. ~19 X 10-Z.J
.1. .. / s:J..6 J( (0- 11
-0
~.0/2..1 )( 10
/ .. f'l4 6 )( 10-1*
~ A~ ea.-n ~ ~.
Pu ... .2 .01J' )((0
11 ~-~ .
- /J--/
Physics 505 Electricity and Magnetism Fall 2003
Prof. G. Raithel
Problem Set 7
Maximal score: 25 Points
I · ¸
4π (x − x0 )
B(x) · x̂i = x̂i · dl0 ×
µ0 I ∂S |x − x0 |
I · ¸
1
= x̂i · dl0 × ∇x0
∂S |x − x0 |
I · ¸
1
= dl0 · ∇x0 × x̂ i | Stokes0 law
∂S |x − x0 |
Z ½ · ¸¾
1
= da0 · ∇x0 × ∇x0 × x̂ i
S |x − x0 |
Z ½· ¸ · ¸
1 1
= da0 · ∇x0 (∇ x 0 · x̂i ) − x̂i ∇ 0
2
x
S |x − x0 | |x − x0 |
· ¸ · ¸ ¾
1 1
+(x̂i · ∇x0 ) ∇x0 − ( ∇ x 0 · ∇ x 0 )x̂i use x 6= x0 always
|x − x0 | |x − x0 |
Z ½ · ¸ ¾
1
= da0 · 0 − 0 + (x̂i · ∇x0 ) ∇x0 − 0
S |x − x0 |
Z ½ · ¸ ¾
1
= da0 · 0 − 0 + (x̂i · ∇x0 ) ∇x0 − 0
S |x − x0 |
Z ½ · ¸¾ Z ½ · ¸¾
0 ∂ 1 0 ∂ 1
= da · ∇x0 = − da · ∇x0
S ∂x0i |x − x0 | S ∂xi |x − x0 |
Z ½· ¸¾
∂ 1
= − da0 · ∇x0 | see Eqn. after 1.25 on page 33 of textbook
∂xi S |x − x0 |
Z
∂ ∂
= dΩ0 = Ω(x)
∂xi S ∂xi
µ0 I ∂
Thus, Bi = 4π ∂xi Ω(x), and
µ0 I
B(x) = ∇x Ω(x) q.e.d.
4π
1
PHY 5346
Homework Set 10 Solutions – Kimel
First consider a point at the axis of the solenoid at point z 0 . Using the results of problem 5.1,
μ0
dφ m = NIdzΩ
4π
From the figure,
⃗ ρdρ
∫ r̂ ⋅r 2dA ∫ dArcos θ = 2πz ∫
R
Ω= = = 2π − z +1
2 2 3/2
0 ρ + z
2
R + z 2
2
μ0 ∞ μ0
φm = NI ∫ z − 1 + 1z dz = NI −z 0 + R 2 + z 20
2 z0 R + z
2 2 2
μ0 μ0 −z 0 + R 2 + z 20
Br = − NI ∂ −z 0 + R 2 + z 20 = NI
2 ∂z 0 2 R 2 + z 20
In the limit z 0 → 0
μ0
Br = NI
2
By symmetry, thej loops to the left of z 0 give the same contribution, so
B = B l + B r = μ 0 NI
H = NI
⃗ is directed along the z axis, so
By symmetry, B
⃗ =0
⃗⋅B
δφ m = −δρ
⃗ is directed ⊥ to the z axis. Thus for a given z, φ m is independent of ρ, and consequently
if δρ
H = NI
everywhere within the solenoid.
If you are on the outside of the solenoid at position z 0 , by symmetry the magnetic field must be in
the z direction. Thus using the above argument, φ m must not depend on ρ. Set us take ρ far away
from the axis of the solenoid, so that we can replace the loops by elementary dipoles m ⃗ directed along
the z axis. Thus for any point z 0 we will have a contributions
⃗ ⋅ ⃗r 1
m ⃗ ⋅ ⃗r 2
m
φm 3
+
r1 r 32
⃗ ⋅ ⃗r 1 = −m
where m ⃗ ⋅ ⃗r 2 and r 1 = r 2 . Thus
H=0
or A = Q/2π( + 0 ). Hence
~ = Q r̂
E
2π( + 0 ) r2
Q
; dielectric side
0 2πa2
σ = + (1)
0
Q
; empty side
+ 0 2πa2
Note that the total charge obtained by integrating σ over the surface of the inner
sphere gives Q as expected.
c) Calculate the polarization-charge density induced on the surface of the dielectric
at r = a.
The polarization charge density is given by
ρpol = −∇ · P~
where P~ = 0 χe E~ = ( − 0 )E.
~ Since the surface of the dielectric at r = a is
against the inner sphere, we can take the polarization to be zero inside the metal
(‘outside’ the dielectric). Gauss’ law in this case gives
− 0 Q
σpol = −P ⊥ r=a = −( − 0 )E ⊥ r=a = −
+ 0 2πa2
Note that when this is combined with (1), the total (free and polarization) charge
density is
0 Q
σtot = σ + σpol =
+ 0 2πa2
on either half of the sphere. Since this is uniform, this is why the resulting electric
field is radially symmetric.
5.3 A right-circular solenoid of finite length L and radius a has N turns per unit length
and carries a current I. Show that the magnetic induction on the cylinder axis in the
limit N L → ∞ is
µ0 N I
Bz = (cos θ1 + cos θ2 )
2
where the angles are defined in the figure.
θ1 θ2
We start by computing the magnetic field on axis for a single loop of wire carrying
a current I. This may be done by an elementary application of the Biot-Savart
law.
dl
R
a B
α
z
[d~` × R
~ ]z µ0 Ia2
Z Z
µ0 I µ0 I d` R sin α µ0 I a
Bz = = = 2πa =
4π R3 4π R3 4π R3 2R3
Substituting in R2 = a2 + z 2 yields
µ0 Ia2
Bz = (2)
2(a2 + z 2 )3/2
We now use linear superposition to obtain the field of the solenoid. Defining z1
and z2 as follows
−z 1 z2
θ1 θ2
(where z1 + z2 = L) we have
z2
µ0 Ia2
Z
N dz
Bz =
2 −z1 (a2 + z 2 )3/2
~ = µ0 jr ẑ × r̂ = µ0 j ẑ × ~r
B
2 2
where ~r is the vector from the center of the conductor to the position where we
are measuring the field. We now use linear superposition to start with a solid
cylindrical conductor and then subtract the ‘missing’ current from the hole
~ = µ0 j ẑ × ~x − µ0 j ẑ × (~x − d~ ) = µ0 j ẑ × d~
B
2 2 2
Here d~ is the vector displacement of the hole from the center of the cylinder. This
somewhat remarkable result demonstrates that the magnetic induction is uniform
in the hole, and is in a direction given by the right hand rule.
If desired, we note that the total current carried by the wire is I = j(πa2 − πb2 ),
so we may express the magnetic induction in terms of I as
µ0 I
~ =
B ẑ × d~
2π(a2 − b2 )
5.7 A compact circular coil of radius a, carrying a current I (perhaps N turns, each with
current I/N ), lies in the x-y plane with its center at the origin.
a) By elementary means [Eq. (5.4)] find the magnetic induction at any point on the
z axis
~ x 0 )/|~x −~x 0 | we could find the magnetic induction
By appropriate integration of J(~
anywhere in space. However we have already computed the magnetic induction
when restricted to the z axis. The result is given by (2)
µ0 Ia2
Bz =
2(a2 + z 2 )3/2
4. Jackson, Problem 5.13 7 Points
There is an azimuthal surface current K(θ0 ) = φ̂0 σ sin θ0 aω. The corresponding three-dimensional current
density is
R −1 2 (l+m)!
Using Eq. 2 of the previous problem and −1
Plm (x)Plm
0 (x)dx =
2l+1 (l−m)! δl,l
0 and Pl1 = − sin θ, it is
Z
µ0 X 1 r<l
Aφ (r, θ) = Pl1 (cos θ) l+1
Pl1 (cos θ0 )Jφ (r0 , θ0 )d3 x0
4π l(l + 1) r >
l,m=1
X Z l
µ0 1 r<
= Pl1 (cos θ) l+1 l
P 1 (cos θ0 )σ sin θ0 δ(r0 − a) a ω r02 d cos θ0 dφ0
4π l(l + 1) r >
l,m=1
l Z
µ0 X 1 2πσa3 ωr<
= − Pl1 (cos θ) l+1
Pl1 (x)P11 (x)dx
4π l(l + 1) r >
l,m=1
µ0 σa3 ω 1 r< 4
= − Pl (cos θ) 2
4 r> 3
3
µ0 σa ω r<
= sin θ 2
3 r>
µ0 σa4 ω 1
Aexterior (r, θ) = φ̂ sin θ
3 r2
and inside
µ0 σaω
Ainterior (r, θ) = φ̂ r sin θ
3
1 1
Using that for azimuthal A it is B = ∇ × A = r̂ r sin θ ∂θ [sin θAφ ] − θ̂ r ∂r [rAφ ] it is found:
· ¸
µ0 σa4 ω 2 cos θ sin θ
Bexterior (r, θ) = r̂ 3 + θ̂ 3 ,
3 r r
4
which is the field of a magnetic dipole m = ẑ 4πσa
3
ω
, and
2µ0 σaω h i
Binterior (r, θ) = r̂ cos θ − θ̂ sin θ ,
3
6
~ 0 . The other two regions contain a dipole field in
along the same direction as B
addition a uniform component.
~ = −∇Φ
Since H ~ M = −δ x̂ for ρ < a, the ratio of B
~ on axis (ρ = 0) to B~ 0 is given
by
B 4
= 4∆−1 =
B0 (1 + µr )(1 + µr ) + (1 − µr )(1 − µ−1
−1
r )(a/b)
2
( a / b ) 2 = 0.5
0.8
0.6
0.4
0.2
1 2 3 4 5 6
( a / b ) 2 = 0.1 log 10 µ r
where any component of J~∗ is understood to have argument P ~x. For Hx and Hy
matching, we find
Since these equations hold for all values of (x, y), they separate into
~ ~x ) = µr − 1 P J(P
J~∗ (~x ) = (1 − λ)P J(P ~ ~x )
µr + 1
b) Show that for z < 0 the magnetic induction appears to be due to a current
distribution [2µr /(µr + 1)]J~ in a medium of unit relative permeability.
From the expression (4) for B ~ L , the magnetic induction appears to be due to a
current λJ~ = [2/(µr + 1)]J~ in a medium of permeability µ. This is equivalent
to having a current distribution [2µr /(µr + 1)]J~ in a medium of unit relative
permeability.
5.19 A magnetically “hard” material is in the shape of a right circular cylinder of length L
and radius a. The cylinder has a permanent magnetization M0 , uniform throughout
its volume and parallel to its axis.
a) Determine the magnetic field H ~ and magnetic induction B ~ at all points on the
axis of the cylinder, both inside and outside.
We use a magnetic scalar potential and the expression
1
Z ~ ·M
∇ ~ (~x 0 ) 1
I 0 ~ 0
n̂ · M (~x ) 0
3 0
ΦM =− d x + da
4π V |~x − ~x 0 | 4π S |~x − ~x 0 |
where ‘top’ and ‘bottom’ denote z = ±L/2, and the integrals are restricted to
ρ < a. On axis (ρ = 0) we have simply
Z !
M0 1 1
ΦM (z) = p −p ρ dρ dφ
4π ρ2 + (z − L/2)2 ρ2 + (z + L/2)2
a2
Z !
M0 1 1
= p −p dρ2
4 0 ρ2
+ (z − L/2)2
+ (z + ρ2 L/2)2
M0 h p p i
= a2 + (z − L/2)2 − a2 + (z + L/2)2 − |z − L/2| + |z + L/2|
2
Note that the last two terms cancel when |z| > L/2, but add up to 2 inside the
magnet. Thus we may write
M0 z − L/2 z + L/2
Hz = − p −p + 2 Θ(L/2 − |z|)
2 a2 + (z − L/2)2 a2 + (z + L/2)2
where Θ(ξ) denotes the unit step function, Θ = 1 for ξ > 0 (and 0 otherwise).
The magnetic induction is obtained by rewriting the relation H~ = B/µ
~ 0−M ~ as
~ = µ0 (H
B ~ +M ~ ). Since the magnetization is only nonzero inside the magnet [ie
Mz = M0 Θ(L/2 − |z|)], the addition H~ +M ~ simply removes the step function
term. We find
µ0 M0 z − L/2 z + L/2
Bz = µ0 (Hz + Mz ) = − p −p
2 a2 + (z − L/2)2 a2 + (z + L/2)2
~ 0 M0 and H/M
b) Plot the ratios B/µ ~ 0 on the axis as functions of z for L/a = 5.
0.2
-2 -1 1 2 z/ L
-0.2
-0.4
B / µ0M0
0.8
0.6
0.4
0.2
-2 -1 1 2 z/ L
Note that Bz is continuous, while Hz jumps at the ends of the magnet. This
jump may be thought of as arising from effective magnetic surface charge.