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HYDROCARBON
ALKANES
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- How to name the alkanes ??
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- The naming is based on the IUPAC.
- The ending of the IUPAC name indicates the family of the compound.
- b) select the correct root name ( meth-, eth-, prop-, but-, etc.)
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Formula ; 1) molecular formula (shows the actual number of atoms)
- 3) Place the other bond around the carbon atom. (not more than 4 bonds)
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• Chemical Properties of Alkane
• 2) Combustion
- with sufficient oxygen, complete combustion will form carbon dioxide
and water.
- if insufficient, the alkane will produce carbon monoxide and water first
and react again to form CO2 and H2O
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• 3) Halogenation
ALKENES
• The functional group => determines the chemical properties of the organic molecule
• The naming method is similar except the ending of alkene must be –ene.
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a) identify the longest continuous carbon chain that contains the double bond.
c) number the carbon atoms in the longest chain and begin at the end near of the double
bond.
d) identify the location of the double bond by using the number of the 1st carbon atom in the
double bond.
e) place the number in front of the ending –ene (for molecules with more than than 3 carbon
atoms).
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- so,bromine solution can be used as the reagent for testing the presence
of carbon-carbon double bond
• Chemical Reactions of Alkenes
3) addition of hydrogen halides (HBr, HF , HCl)
• Alkenes are more reactive than alkanes.
4) addition of water (hydration)
• 1) Combustion (similar with alkane)
- will form alcohol
• 2) Addition Reactions
- the conditions are H3PO4 at 300oC and 60atm
• Small alkene molecules undergo an addition reaction with one another to form a long chain
called polymers.
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ISOMERISM
• A phenomenon whereby 2 or more molecules are found to have the same molecular
formula
• They are the same in terms of number and types of atoms but only differ in the
arrangement. (molecules which have different structures)
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• In alkanes group (e.g)
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• General steps of drawing isomers;
1) Draw all the possible carbon skeletons.
2) For each carbon skeleton, place a double bond at different location (only for
alkene group!!!!)
3) Place single bonds around each carbon atom ( each carbon has 4 bonds)
- In isomers, there are branches-chain structures and they are called as alkyl group ( CnH2n+1 )
- For this alkyl group naming, just replace the –ane for the name of corresponding alkane
with –yl . (place at the early name of the molecule)
4) Locate and name the attached alkyl groups.The position of each alkyl group is given
the number of the carbon atom to which it is attached on the chain.
5) Complete the name for the molecule by12combining the three component parts
together. Write the name as the single word. (e.g 2,2-dimethylbutane, 2-methylpropane)
6) For alkene group, do not forget to mention the position of its functional group as well.
(e.g 3-methylbut-1-ene )
ALCOHOLS
- Non-hydrocarbons ( contains C, H, O )
- The naming of alcohols are quiet similar with the previous naming steps of isomer. Just
replace the end of the name with –ol and mention the location of the hydroxyl group.
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- 1) Fermentation process
a) anaerobic process (it takes place in the absence of oxygen)
b)
c) temperature = 18 -20 o C
- 2) Hydration Process
- temperature = 300o C
- pressure = 60atm
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- 1) Combustion
- 2) Oxidation
- 3) Dehydration
- in lab testing = 1) alcohol vapour is passed through the heated catalyst (porcelain)
CARBOXYLIC ACIDS
- Containing elements of C, H, O.
- Just replace the end of the corresponding chain of alkane with –oic acid.
- e.g
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- By using the process of oxidation of alcohol = (refluxing ethanol with an oxidizing agent
such as acidified potassium dichromate (vi) solution!!!
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- What is esterification????
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- Carboxylic acid reacts with alcohol to produce a sweet-smelling compound called an
ester and water with condition of a few drops of concentrated sulphuric acid.
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ESTERS
- How to nameand
1) Identify esters????
name the alcohol part of the ester.
*(the alcohol part is named 1st followed by the acid part,the name of an ester consists
of two separate words)*
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