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Wood-plastic composite
Leandro Shiroma
School of Agricultural Engineering, State University of Campinas
Campinas, São Paulo, Brasil
Abstract
Wood is one of the most important raw materials in Brazil, mainly for the industry of
construction, packing, furniture among others. In the mechanic process of cutting wood,
large volumes of sawdust can eventually pollute the rivers and landfills. There is a great
deal for the society to find some rational use for such wastes, like as an energy source to
replace the coal, the diesel oil, and enhances its capability in exchange for carbon credits.
Following this trend, studies were developed at several countries looking for the reuse of
vegetable fibers as reinforcement in thermoplastics matrices, for several industry
applications.
The objective of this work was to develop a composite from Pinus sp residues and
recycled plastics, such as polypropylene (PP) and polyethylene (PE), seeking their use in
the manufacture of pallets components.
Paper WS-49 1 of 9
Proceedings of the 51st International Convention of Society of Wood Science and Technology
November 10-12, 2008 Concepción, CHILE
Bibliographic Review
One wood pallets company, located at the region of Campinas, Brazil, leads daily amount
of 100 ton of waste from sawdust. Currently this waste is used as a source of burning
energy in industries of this region. Pinus sp is the principal waste wood used as a load of
more thermoplastics in Brazil. Its bulk density is between 0.15 a 0.374 kg/m3. Its
chemical composition is 50.1% of cellulose, 30.3% of lignin, 9.7% of hemicelluloses and
10% of other substances (CAMARGO, 2006).
Thermoplastic composites with sawdust (WPC) have some advantages over the
conventional mineral material. They are lighter in compared to the fiber glass = 2.5
kg/m3, CaCO3 or talc = 2.8 kg/m3. Moreover, these materials are less abrasive and not
wear the equipment (CAMARGO, 2006). Consumption of composite is very significant
in the USA - about 1,170,000 ton of wood-profile extruded plastic was produced. In
Europe, consumption was approximately 1,200,000 ton each in 2007. The consumer
sectors are furniture, packaging (pallets) and construction (manufacture of terraces,
balconies, ceilings, etc.). In the other countries, like Brazil and Chile, consumption still
comes up in the cultural barrier that can be broken through an appeal of environmental
issues facing marketing (OMEGA, 2007).
Thermoplastics modified by vegetable fibers are recent and its melting point should be
below the point of degradation of the fibers, usually between 200 to 220 °C (FOREST
PRODUCTS LABORATORY, 1999). The polypropylene is a polymer of the same
family of polyethylene and differentiated by this one by the presence of radical methyl
(CH3) in monomeric unit. The position occupied by methyl radical determines the
classification of polypropylene in atatic, sindiotatic, isotatic. The configuration gives the
polymer isotatic a greater mechanical strength (SANTOS, 1998).
Paper WS-49 2 of 9
Proceedings of the 51st International Convention of Society of Wood Science and Technology
November 10-12, 2008 Concepción, CHILE
• Sawdust – vegetable waste obtained from Pinus trees, provided by the Industry
Woodpack. The material was obtained from a sawmill located at Limeira-SP.
Waste density at air dry condition was determined using a cylindrical glass container with
a volume of 11 L. The container was filled by the residues, launched from a height of 10
cm to 12 cm from the top of the container, to complete its total. The area was settled
through a metal ruler and then it was weighted the mass of waste contained in this
volume.
The residue of sawdust and recycled plastics PP and PE were initially dried in an oven for
80 °C for 24 h. The components of the mixture under appropriate proportions as showed
in tables 2.1 and 2.2, were homogenized manually in a plastic container.
Paper WS-49 3 of 9
Proceedings of the 51st International Convention of Society of Wood Science and Technology
November 10-12, 2008 Concepción, CHILE
The components were fed directly into the funnel of feeding the extruder, being merged,
homogenized in the cannon and pushed through the twin screw co-rotational forming
continuous yarns that are cooled in a tank with water in recirculation. The pellets are
formed in the chopper that pulls the wires into the tank and short form of granules.
Extruder parameters are showed in table 2.3.
The pellets were placed in an oven for 24 hours at 80 °C for drying before the injection to
produces the specimens. Data from the injector process are showed in table 2.4.
Traction
The traction test was performed at an universal test device EMIC DL 2000, at the
laboratory of Unesp - Botucatu, Campos Julio de Mesquita. The specimens followed
the standard ASTM D 638. Five specimens were tested for each ratio.
Flexure
The flexure test was performed at an universal test device EMIC DL 2000, at the
laboratory of Unesp - Botucatu, Campus Julio de Mesquita. The specimens followed
the standard ASTM D 790-02. Five specimens were tested for each ratio.
Paper WS-49 4 of 9
Proceedings of the 51st International Convention of Society of Wood Science and Technology
November 10-12, 2008 Concepción, CHILE
Impact
The impact test was conducted at a Tinius Olsen device, at the laboratory of Unesp -
Botucatu, Campos Julio de Mesquita. The specimens followed the standard ASTM
256-97. It was tested 10 specimens for each ratio.
The software Statgraphics 4.1 was applied to perform analysis of variance (ANOVA).
Average values were compared by Tukey´s Test at 95%.
According to the standard Brazilian NBR 7217, the residue of pine can be classified as a
fine aggregate, table 3.1.
Impact results
According to ANOVA at Table 3.2, the p-value of polymers type (< 0.05) and p-value of
material ratios (<0.05) are highly significant. The interaction between the polymers and
ratios are also highly significant. Figure 3.1 shows the impact results. According to the
comparison of the polymers, there is a significant difference. For this property,
polyethylene showed a better performance than polypropylene. For ratio comparison, as
Paper WS-49 5 of 9
Proceedings of the 51st International Convention of Society of Wood Science and Technology
November 10-12, 2008 Concepción, CHILE
Table 3.2- Analysis of Variance for impact - Sum of square Type III.
Sum of Average Coefficient- P-
Font GL
square square F Value
EFECT
A:polymers 75102.3 1 75102.3 299.93 0.0000
B:ratios 99390.4 2 49695.2 198.46 0.0000
Interaction
AB 32460.7 2 16230.3 64.82 0.0000
Residue 13020.7 52 250.398
TOTAL (CORRECTED) 223367 57
Traction Results
According to ANOVA table 3.3, the p-value of polymers types (<0.05) and the p-value of
ratios (<0.05) are highly significant. The interaction between the polymers and ratio are
also highly significant. Figure 3.2 shows the traction results. According to the
comparison of polymer types, there is a significant difference, and the PP shows a better
performance than PE.
According to the comparison of the ratios, as shown in Figure 3.2, T1 (60% polymer/40%
sawdust), T2 (70% polymer/30% sawdust) and T3 (80% polymer/20% sawdust) are
significantly different. Ratio T3 shows a better performance.
Paper WS-49 6 of 9
Proceedings of the 51st International Convention of Society of Wood Science and Technology
November 10-12, 2008 Concepción, CHILE
Table 3.3 - Analysis of Variance for traction - Sum of square Type III.
Sum of Average Coefficient-
Font GL P-Valor
square square F
EFECT
A:polymers 1.27717E6 1 1.27717E6 32074.24 0.0000
B:ratios 10127.6 2 5063.81 127.17 0.0000
Interaction
AB 5267.59 2 2633.8 66.14 0.0000
Residue 955.661 24 39.8192
TOTAL
1.293527E6 29
(CORRECTED)
Flexure results
According to ANOVA, (table 3.4), the p-value polymers (<0.05) is highly significant, but
the p-value ratios (> 0.05) is not.
Figure 3.3 shows the flexure results. According to the comparison of polymers types,
there is a significantly difference. For this property PP shows a better performance.
According to the ratio comparison, as showed in Figure 3.3, T1 (60% polymer/40%
sawdust), T2 (70% polymer/30% sawdust) and T3 (80% polymer/20% sawdust) are not
significantly different.
Paper WS-49 7 of 9
Proceedings of the 51st International Convention of Society of Wood Science and Technology
November 10-12, 2008 Concepción, CHILE
Conclusions
With respect to the recycled plastic type it can be concluded that polypropylene (PP)
presented a better performance in relation to the polyethylene. The ratio T3 (80% of
recycled polymer and 20% of sawdust by weight) showed a better performance for
manufacturing pallets components. To manufacturing pallet boards, which is a piece that
needs to bear loads and presents some flexibility, can be concluded that the ratios studied
in this work did not interfere in the bending property. The recycled polypropylene (PP)
was more suitable for this application.
For the next steps, an assessment of accelerated aging and natural decay is necessary to
verify the composite performance in relation to conventional wood pieces.
Biodegradability test, mainly fungi resistance, is also an important point to consider.
The development and use of other types of recycled plastic is also an important point for
reducing the cost of products.
Paper WS-49 8 of 9
Proceedings of the 51st International Convention of Society of Wood Science and Technology
November 10-12, 2008 Concepción, CHILE
References
Camargo, A. S. 2006. Compósito de polipropileno reforçado com farinha de madeira para
aplicações em produtos moldados por injeção. Itatiba, SP.
Omega, C. 2007. Perfiles Extruídos de Madera Plástico. Santiago, Chile.
http://www.corfo.cl/rps_corfo_v57/OpenSite/Corfo/Centro%20de%20.
Documentación/Estudios/Estudios_doc/Estudio_Perfiles_Extruidos_Madera_Plástico01.p
df
Santos, D. G. 1998. Efeito do uso de compatibilizante no processamento e produção de
fios da blenda PET/PP.Campinas, SP.
Bolsoni, E.2001. Estuda da Reprocessabilidade do polietileno de baixa
densidade.Campinas, SP.
Forest Products Laboratory. 1999. Wood handbook—Wood as an engineering material.
Gen. Tech. Rep. FPL–GTR–113. Madison, WI: U.S. Department of Agriculture, Forest
Service,Forest Products Laboratory. 463 p.
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