SULIT 4541/1

4541/1
KIMIA
Kertas 1
Jun
2010
1¼ hrs

SMK SULTAN SULAIMAN SHAH

45600 BESTARI JAYA

____________________________________________________

PEPERIKSAAN PERTENGAHAN TAHUN 2010

TINGKATAN 4
______________________________________________________

KIMIA
Kertas 1
Satu jam lima belas minit

___________________________________________________________________________
JANGAN BUKA KERTAS SOALAN INI HINGGA DIBERITAHU

1. Kertas soalan ini mengandungi 50 soalan.

2. Jawab semua soalan
3. Jawab dengan menghitamkan ruangan yang betul pada kertas jawapan
4. Bagi setiap soalan hitamkan satu ruangan sahaja
5. Sekiranya anda hendak menukar jawapan, padamkan tanda yang telah dibuat.
Kemudian hitamkan jawapan yang baru.
6. Rajah yang mengiringi soalan tidak dilukiskan mengikut skala.
7. Anda dibenarkan menggunakan kalkulator saintifik yang tidak boleh
diprogramkan.
1 Which of the following substances contain molecules, except?

A Zinc
B Ethanol
C Sodium chloride
D Magnesium oxide

2 Which of the following is the correct formula for barium hydroxide?

A BaOH
B Ba2OH
C Ba(OH)2
D BaOH2
3 Which of the following set of elements consist of all non metals?
A Chlorine, Nitrogen and Sulphur
B Oxygen, Hydrogen and Lithium
C Phosphorus, Lead and Carbon
D Carbon, Iodine and calcium

4 Which of the following compounds will produce the most number of ions when 1 mol of the
compound is dissolved in water?
A KNO3
B FeCl2
C CuSO4
D H3PO4

5 Which of the following is true about similar properties of isotopes of an element?

A chemical properties
B physical properties
C Number of nucleons
D Number of electrons

6 Element V and W each have proton number 11 and 19. Which of the statement is true about V
and W?
A The atomic radius of atom V is larger than that of atom W
B Elements V is more reactive than element W
C Element W is more electropositive than element V
D The number of electrons of V is more than that of W

7 Four elements J, L, M, and Q have 1,8,11, and 17 electrons respectively. Which of the
following pairs of elements will form covalent compound.
A J and L
B L and M
C M and Q
D L and Q
8

Element R S T U
Number of protons 8 17 13 12
Ionic formula R2- S- T3+ U2+
Table 1

Table 1 shows ion formed from four elements, R,S, T and U. Which ion has the same number of
electrons as one calcium ion?
A R2-
B S-
C T3+
D U2+

9 An enclosed cylinder is filled with helium atoms. Which diagram shows the arrangement
of the helium atoms ?

10 The formula of a substance is written as FeSO4. What is the name of the compound
according to the IUPAC system?

A Iron sulphate
B Iron(II) sulphate
C Iron(III) sulphate
D Iron(II) sulphite

11 The element which does not form compound with other elements is likely to have proton
number of
A4
B8
C 10
D 16
12 Which of the following represents the electron arrangement for sodium chloride, NaCl?
[Proton number; Na, 11; Cl, 17]

13 Which of the following is NOT an element ?

A Silver
B Nitric Acid
C Chlorine
D Sulphur

14 Which of the following is a mixture ?

A Air
B Copper
C Sodium Chloride
D Ammonia
15 Which of the following scientific attitudes and values should NOT be practiced?
A Honesty
B Cooperative
C Selfish
D Responsible

16 Which of the following is NOT a reason to incorporate scientific attitudes and values in
carrying out investigation?
A To prevent accident
B To minimize pollution
C To clean workplace
D To exploit natural resources

17 The atoms
31
P and
32
s have the same
15 16
A number of protons
B number of neutrons
C number of electrons
D nucleon number

18 The ion of a newly discovered metal M has the symbol M3+ . What will be the formula of
its chloride?

A MCl
B M2Cl3
C MCl3
D M3Cl

19 The property of an element which cannot be predicted from the position of an element in
the Periodic Table of Elements is

A the charge of its ion.

B the formula of its oxide
C the number of isotopes it has.
D the acidic or basic nature of its oxide.
20 Table 1 shows the proton number of elements M and N.

Element Proton number

M 3

N 17

TABLE 1

Which of the following is true of the compound formed between elements M and N?
A MN Ionic bond
B MN Covalent bond
C M2N3 Ionic bond
D M3N2 Covalent bond

21 What do isotopes of oxygen have in common ?

A Number of neutrons
B Nucleon number
C Physical properties
D Proton number

22
 The particle can move freely and are not held in fixed positions.
 The particle are loosely arranged but still in contact with one another

Table

Which of the following statements describe the above arrangement of particles ?

A Solids
B Liquid
C Gas
D Plasma

23 Phosphorus has to isotopes. If Phosphorus-31 has 15 protons, what is the number of neutrons
for Phosphorus-32
A 15
B 16
C 17
D 31
24 Which of the following gases sublime when cooled?

I Iodine vapour
II Ammonium Chloride
III Carbon Dioxide
IV Steam

A I and II only
B II and III only
C I, II and IV only
D I, II, and III only

25 Which of the following diagram represents magnesium oxide?

26 How many molecules of bromine are there in 0.045 mol of bromine?

[Avogadro Constant ; 6.02 X 1023 ]

A 2.7 X 1022
B 3.3 X 1023
C 7.9 X 1024
D 1.2 X 1025
27 An element X requires two electrons to form a stable negative ion. Which group is X
located in the Periodic Table of Elements?

A2
B 16
C 17
D 18
28 The electron arrangement of atoms P and Q are 2.8.4 and 2.6 respectively.
Which of the following statement is true about the formation of a compound between P
and Q ?

A Each atom Q receives an electron from one atom P

B Each atom P receives four electrons from one atom Q
C Each atom P combines with two atoms Q by sharing of electrons
D Each atom P combines with one atom Q by transfer of electron

29 Element V forms a compound with the empirical formula of VH2 . The compound contains
95% of V, by mass. What is the relative atomic mass of element V [ relative atomic mass of
H=1]

A 28
B 38
C 59
D 80
30 The empirical formula of a compound is given as CH2. What other information is needed to
determine its molecular formula?
A Density
B Relative molecular mass
C Melting point
D Boiling point

31 The following equation represents the reaction between copper(II) oxide and nitric acid.
CuO + 2HNO3 → Cu(NO3)2 + H2O
Calculate the mass of copper(II)nitrate formed when 6.4g of copper (II) oxide powder
reacts with excess nitric acid.
[ Relative atomic mass: Cu,64; N,14; O,16]

A 4.96g
B 5.04g
C 7.52g
D 15.04g

32 Which of the following compounds has the same empirical formula as heptene, C7H14
A C4H10
B C4H9OH
C C6H12
D C2H6
33 An element represented by the symbol

8 atoms of element Z have the same mass as in 1 atom of tellurium, Te.

A has three valence electrons

B forms a positively charged ion.
C is located in Group 17 of the Periodic Table.
D has 3 protons and 7 neutrons.

34 8 atoms of element Z have the same mass as in 1 atom of tellurium, Te.

Based on the statement above, what is the relative atomic mass of element Z?
[Relative atomic mass : Te, 128 ]

A8
B 16
C 32
D 64

35. Which of the following locations are correct of an element with a proton number of 7 in
the Periodic Table of Elements?

I Period 2
II Period 5
III Group 15
IV Group 2
A I and III only
B II and IV only
C I and IV only
D II and III only

36 Which of the following careers does NOT require knowledge in chemistry?

A Farmer
B Nurse
C Accountant
D Pharmacists
37 From which Arabic word did the word ‘chemistry’ originate from?
A Khaemia
B Al-Kimiya
C Psysikos
D Chymist

38 Which of the following factors determines the size of empty spaces between particles in a
matter?
A Particle size
B Particle volume
C Energy content
D Particle mass

39 Zn + 2HCl → ZnCl2 + H2
Based on the equation above, calculate the volume of hydrogen gas released at room
conditions when 1.3 g of zinc powder reacts with excess hydrochloric acid.
[ Molar volume : 24 dm3mol-1 at room conditions, Relative atomic mass: H,1; Cl, 35.5;
Zn, 65]
A 120 cm3
B 240 cm3
C 360 cm3
D 480 cm3
40 The boiling point and freezing point of X is 1560 oC and 265 oC respectively. X will probably
exists as liquid at?
A 1570oC
B 264 oC
C 300 oC
D Room temperature
41 Which of the following graphs shows the temperature (T) against time (t) when a mixture
of pentane (boiling point 36oC) and hexane (boiling point 70oC) is distilled?

42 A hydrocarbon has the empirical formula of CH3 with a molar mass of 30 g mol-1. Which
of the following is the molecular formula of the hydrocarbon?
[Relative atomic mass : H, 1; C,12 ]

A CH3
B C2H6
C C3H9
D C4H12

43 Element X reacts with cold water to form alkaline solution while element Y reacts with
water to form acidic solution. Which of the following is the correct group of X and Y in
the Periodic Table of Elements?

X Y
A 1 14
B 2 15
C 1 17
D 3 17
44 Table 3 shows the proton number of three elements X, Y and Z.

Element X Y Z
Proton Number 12 8 17
TABLE 3

What is the formula of the substance and the type of bond formed between X, Y and Z?

Formula Type of Bond

I XY Covalent
II YZ2 Covalent
III XZ2 Ionic
IV Z2 Covalent

A IV only
B III and IV only
C II, III and IV only
D I, II, III and IV

45 A tiny piece of sodium is placed in an evaporating dish. Several drop of water and litmus
solution are added to the dish. Which of the following will occur?
I Sodium will dissolved in the water
II Heat is released
III A gas is released
IV The solution turns blue
A I, II and III only
B I, II and IV only
C I, III and IV only
D I, II, III and IV only

46 Choose the correct statements about astatine (At).

I Astatine can react with sodium to form a compound with formula NaAt
II Astatine does not dissolve in aqueous sodium hydroxide solution
III Astatine has bigger atomic size than iodine
IV Astatine is solid at room temperature
A I, II and III only
B I, II and IV only
C I,III and IV only
D II, III and IV onlt
47 When we travel across a period from left to right, elements
I Will have more valence electrons
II Will become more electropositive
III Will have higher melting points
IV Will have bigger relative atomic masses
A I and II only
B I and IV only
C II,and III only
D I, II and IV only

48 Which of the following properties of ceramics are correctly matched to the ceramic
articles?
Ceramic articles Properties of ceramic
I Tiles Resistant to chemical reactions
II Spark plug High melting point
III Superconductor Low electrical resistance
IV Electrical cable holder Good conductor of electricity
A I and II only
B II and III only
C I, II and III only
D II, III and IV only

49 Elements P, Q and R are in the same group in the Periodic Table of Elements. Table 4
shows the observation for the reaction of the elements with chlorine and the formula of the
chloride formed.

Reaction with chlorine Formula of chloride

P Burns brightly PCl

Q Burns very brightly QCl

R Burns most brightly RCl

Table
Which of the following statements is correct?
A P, Q, R are earth metals
B The atomic radius increases from P to Q to R
C The elements form ion with univalent negative charge
D Their reactivity decreases down the group
50
Elements R S T U
Proton Number 6 8 12 17
Table

Table shows the proton numbers of four elements R, S, T and U. Which

A O2 H2
B Cl2 H2
C Cl2 Na
D O2 Cl2

END OF QUESTION PAPER

Nama: .................................................... Tingkatan: ..............................

SULIT
4541/2
Kimia
Kertas 2
Oktober
2008 SMK SULTAN SULAIMAN SHAH
45600 BESTARI JAYA
____________________________________________________

PEPERIKSAAN PERTENGAHAN TAHUN 2010

TINGKATAN 4
______________________________________________________

KIMIA
Kertas 2
Dua jam tiga puluh minit
2½
___________________________________________________________________________
JANGAN BUKA KERTAS SOALAN INI HINGGA DIBERITAHU

1. Tuliskan nama dan tingkatan pada ruang yang

disediakan. BAHAGIA SOALAN MARKAH MARKAH
N
2. Jawab semua soalan daripada Bahagian A. Tuliskan 1 10
jawapan anda dalam ruang yang disediakan
A 2 10
3. Jawab satu soalan daripada Bahagian B dan satu
3 10
soalan daripada Bahagian C. Jawapan kepada Bahagian
B dan Bahagian C hendaklah ditulis padakertas tulis. 4 10

4. Anda diminta menjawab dengan lebih terperinci 5 10

untuk Bahagian B dan Bahagian C. Jawapan mestilah
jelas dan logik. Persamaan, gambar rajah,jadual, graf 6 10
dan cara lain yang sesuai untuk menjelaskan jawapan
anda boleh digunakan. B 7 20

5. Anda hendaklah menyerahkan kertas tulis dan 8 20

kertas tambahan, jika digunakan bersama-sama
dengan kertas soalan. C 9 20

10 20
6. Penggunaan kalkulator saintifik yang tidak boleh
diprogramkan adalah dibenarkan.
 SULIT 4541/2

1. Diagram 1.1 shows the symbols for atoms of elements X, Y and Z.

24 28 19
X Y Z
12 14 9

DIAGRAM 1.1

(a) (i) Write the electron arrangement of atom Z.

………………………………………………………………………………………………
[1 mark]
(ii) What is the number of neutrons for atom Y?
………………………………………………………………………………………………
[1 mark]
(iii) What is the atomic mass of atom X?
………………………………………………………………………………………………
[1 mark]

(b) Diagram 1.2 shows the set up of the apparatus of an experiment where a drop of bromine
liquid is dropped into a gas jar and is left for a few minutes.

DIAGRAM 1.2

(i) State one observation in the gas jar after a few minutes.
…………………………………………………………………………………………………….
[1mark]

(ii) Name the process that occurred in the gas jar.

…………………………………………………………………………………………………..
[1mark]

(iii) Name the type of particles that exist in bromine.

…………………………………………………………………………………………………..
[1 mark]

[lihat sebelah
SULIT
 (iv) State the change of state of bromine that occurred in the gas jar.
…………………………………………………………………………………………………..
[1 mark]

(v) The change of state in (b) (iv) can occur at room temperature. Explain why
………………………………………………………………………………………………….
[1 mark]

(c) Substance X has a melting point of 79oC . Draw the particles arrangement of substance X at 60 oC and
o
at 80 C.

o
At 60oC At 80 C.
[2 marks]

2. An experiment was carried out in the school laboratory to determine the empirical formula of an
oxide of copper by flowing hydrogen gas over heated copper oxide. Table 2 shows the results
obtained.

Description Mass (g)

Combustion tube + asbestos paper 36.20

Combustion tube + asbestos paper + copper oxide 39.40

Combustion tube + asbestos paper + copper 38.76

TABLE 2

(a) What is meant by ‘empirical formula’ ?

……………………………………………………………………………………………………………..

………………………………………………………………………………………………
[1 mark]

[lihat sebelah
SULIT
 (b) Draw a labelled diagram to show the set up of the apparatus that can be used to carry out
the experiment above.
[2 marks]

(c) State one precautionary step to be taken when carrying out the experiment above.
……………………………………………………………………………………...............
[1 mark]

(d) Based on the results obtained,

(i) calculate the mass of copper and oxygen that have reacted.
[1 mark]

(ii) determine the ratio of moles of copper atom to oxygen atom.

[Relative atomic mass: Cu, 64; O, 16]
[1 mark]

[lihat sebelah
SULIT
 (iii) determine the empirical formula of the copper oxide
[1 mark]

(e) Write a balanced chemical equation for the reaction between copper oxide and hydrogen.
………………………………………………………………………………………………
[1 mark]

(f) Can the empirical formula of magnesium oxide be determined through the experiment
above? Give one reason for your answer.
………………………………………………………………………………………………
………………………………………………………………………………………………
[2 marks]

3. Diagram 3 shows the position of several elements in the Periodic Table of Elements.
The letters do not represent the actual symbols of the elements.

P U V
Q S T
R W

DIAGRAM 3

(a) Using the letters in Diagram 3, answer the following questions.

(i) Choose an element that is monoatomic.
……………………………………………………………………………………
[1 mark]

(ii) Which element forms an amphoteric oxide?

……………………………………………………………………………………
[1 mark]

(iii) Which element is a halogen?

……………………………………………………………………………………..
[1 mark]

[lihat sebelah
SULIT
(b) Write the formula for the ion formed from an atom of element P.
………………………………………………………………………………………………
[1 mark]

(c) Which element has the biggest atomic radius?

………………………………………………………………………………………………
[1 mark]

(d) (i) Why are elements Q and R placed in the same group?
………………………………………………………………………………………………
[1 mark]

(ii) When a small piece of element Q is put into water, a type of solution is formed.
Name the type of solution formed.
………………………………………………………………………………………………
[1 mark]

(iii) Compare the reactivity of the reaction towards water between elements Q and R.
……….……………………………………………………………………………………..
[1 mark]

(e) Arrange P, U, V and T according to the increase in size of atoms.

………………………………………………………………………………………………
[1 mark]

(f) State one special characteristic of element S.

………………………………………………………………………………………………
[1 mark]

4. Table shows five elements of Periodic Table, labeled as P,Q,R,S and T. The letters used do not
represent the actual symbols of the elements. The electron configuration of elements Q, R and S are as
shown in Table

Elements Proton Number Electron Configuration

P 3 ………………

Q 11 2.8.1

R 17 2.8.7

S 18 2.8.8

T 19 ………………

Table
a) What are the electron configuration of elements P and T ?

Element P: ___________________________________________________________________

Element T:___________________________________________________________________
[2 mark]

b) State TWO elements that is located in the same group as element P in the Periodic Table. Give your
explanation.
________________________________________________________________________________

________________________________________________________________________________

[2 mark]

c) In which group are the elements in 2(b) located in the Periodic Table? Explain your answer

________________________________________________________________________________

________________________________________________________________________________
[2 mark]

d) Elements Q, R, and S are located in the same period in Periodic Table.

i) Explain why are elements Q, R, and S located in the same period in the Periodic Table

_________________________________________________________________________________
[1 mark]

ii) State the period where these elements are located in the Periodic Table

__________________________________________________________________________________
[1 mark]
e) Which element is very stable and not reactive? Explain your answer.

__________________________________________________________________________________

___________________________________________________________________________________

___________________________________________________________________________________

___________________________________________________________________________________
[2 mark]
5. Table shows the electrical conductivity and melting points of substances K, L, M

Substance Electrical Conductivity Melting Points/oC

Solid Molten Aqueous
K No No No -158

L No No No 118

M No Yes Yes 850

Table

a) (i) state the type of structure and

6. The elements in Period 3 are shown in Table

Elements Symbol Proton Number

Sodium Na 11
Magnesium Mg 12
Aluminium Al 13
Silicon Si 14
Phosphorus P 15
Sulphur S 16
Chlorine Cl 17
Argon AR 18

a) Which elements is the

i) Most reactive
ii) Most inert
[2 mark]

b) How does the atomic radius change across the period? Explain your answer. [2 mark]

c) i) Which elements form an oxide that is amphoteric? [1 mark]

ii) State the elements which form oxides that are basic [1 mark]

d) i) State an element which reacts vigorously with cold water [1 mark]

ii) Write a chemical equation to show the reaction in d(i) [1 mark]

e) i) State an element which dissolves quickly in sodium hydroxide [1 mark]

 ii) Write a chemical equation to show the reaction in e(i)
[1 mark]

Section B ( 20 marks )
Answer any one question from this section.
The suggested time to answer section B is 30 minutes.

7. Diagram 7 shows the formulae of 4 types of gases released during the eruption of a volcano.

N2 CO2 H2S H2O

DIAGRAM 7

(a) Calculate the molar mass of each gas shown in Diagram 7.

[Relative atomic mass : H, 1; C, 12; O, 16; N, 14; S, 32 ]
[4 marks]

(b) Show that 0.9 g of water vapour contains the same number of molecules as in 2.2 g of
carbon dioxide. [Relative atomic mass: H, 1; C, 12; O, 16; Avogadro Constant, NA = 6.02 X
1023]
[4 marks]
(c) A sample contains 0.1 mol carbon dioxide gas at room temperature and pressure.[Relative
atomic mass : C, 12; O, 16; 1 mol of gas occupies a volume of 24 dm3 at room temperature and
pressure; Avogadro Constant,NA = 6.02 X 1023] Calculate:

(i) the volume,

(ii) the mass,
(iii) the number of molecules and
(iv) the number of atoms

of the 0.1 mol carbon dioxide gas in the sample.

[5 marks]

(d) At very high temperature, hydrogen sulphide gas released from the eruption of the
volcano will react with oxygen in the air to produce sulphur dioxide and water vapour.
Referring to the information above,
(i) write a balanced chemical equation to represent the reaction.
(ii) calculate the maximum mass of sulphur dioxide produced if 952 g of hydrogen
sulphide is released from the volcanic eruption.
[7 marks]
8. Table 8.1 shows the electron arrangement for atoms P, Q dan R.

Element Electron arrangement

P 2.8.1

Q 2.8.7

R 2.4

TABLE 8.1

(a) The reaction between atoms of P and Q form an ionic compound whereas the reaction
between atoms of Q and R forms a covalent compound. Based on the above statement, explain
how these ionic and covalent compounds are formed.
[12 marks]

(b) Table 8.2 shows the melting point and boiling point of two chemical compounds at room
temperature.

Compound Melting Point (OC) Boiling Point (OC)

M -23 76.8
N 2030 2970
TABLE 8.2

Explain the differences in the melting point and boiling point of compound M and N with respect
to the types of particles present and the types of bonding.
[8 marks]
 Section C ( 20 marks )
Answer any one question from this section.
The suggested time to answer section C is 30 minutes.

9. a) (i) State the meaning of matters. [1 mark]

(ii) How can matter change from solid state to liquid state and reverse the process?
[3 mark]

b) State three differences of physical properties of solids, liquids and gases. Briefly explain
their differences. [6 mark]

c) Explain what happens to the particles when a solid changes to liquid and vice versa
[10 mark]

10. Diagram shows two groups of elements which originate from the same group in Periodic
Table.

Group A Group B

Lithium Chlorine
Sodium Bromine
Potassium Iodine

a) (i) Identify group A and group B [2 mark]

(ii) By using one of the group as example, explain three similarities of the elements of the
group stated [6 mark]

b) Compare the chemical properties of elements of both groups [8 mark]

c) Elements of group A can react with elements of group B. using ONE of the elements of
each group, briefly explain the reaction of elements of group A and group B.
[4 mark]
END OF QUESTION PAPER