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Ýë„ìS ¿¶æÑ™èl VýS$Æý‡$ÐéÆý‡… 15 H{í³ÌŒæ, 2010

GUIDANCE AND ANALYSIS- MATHEMATICS

TIME MANAGEMENT IS IMPORTANT

Prepared by students in wrong way . So student should be DONT'S
very careful while attempting that type of
M.N. RAO questions.
Last minute studies are not good
Sr. Faculty,
Maintain good health by taking liquid, fruit
Sri Chaitanya Educational Important topics in Mathematics
Institutions, Hyderabd.
juices along with food
More number of Questions are expected from
Avoid taking calculator, cell phones, log
Quadratic Equations, Conics, Inverse Trigno- tables to exam hall.
AIEEE Mathematics question paper va-ries metry + General solutions, Functions &
Try to reach the center one hour ahead of
year to year including number of questions, Calculus time of exam
so student should be careful before Six additional topics when compared to
Don't spend more time for one or two hard
attempting the questions. A.P. Inter Syllabus are problem. Better to skip that type of

Many questions may consists combination 1) Mathematic Reasoning 2)Sets & Relation problems
of one or more concepts 3) Stastics 4) 3D lines 5) Progressions
Attempt 70-90% of problems only

Previous year analysis of AIEEE papers 6) Mean value theorem perfectly depending upon your ability
indicates around 70% easy questions and Even though these Extra topics are easy it is
Sleep more time,on exam day student
30% difficult level. If student is able to do expected that 3 or 4 questions may come in should be cool with out any unnecessary
that 70% easy questions perfectly he will coming AIEEE exam.
In Complex numbers, Modulous , Amp- arguments so that mind will be fresh
get a seat in good college litude, Cube root of unity, Fourth root of
To increase self confidence attempt easy
Success Tips unity related problems are important question first.
AIEEE 2009 Analysis
To get more marks in Mathematics, solving
Inter Related problem of Trigonometric
Last year students had it quite an easy AIEEE more number of problems is necessary equation, Quadratic equation are important 2009 Marks and Rank Trend
paper in maths. The format of a single paper
Accuracy and time management is very
Max, min number of roots problems are Marks (Max Marks 432) Rank
test was retained. The number of questions important important > 375 1 - 10
was reduced per section to 30 from 35 last
Where ever necessary use Tips and
While solving Binomial theorem proble 375 - 330 10 - 500
year. This made it a paper of 90 questions to Shortcuts ms, logic and assumption can be used 300 - 255 1000 - 5000
be attempted in 3 hours. The marking scheme
After attaing command over concepts time easily 255 - 225 5000 - 10000
was changed this year. Each section of the bounded working is needed
Attempting more number of questions is 225 - 195 10000 - 20000
paper was of 144 marks means a total of 432
More number of questions may come in not important, but accurusy is important
marks. Out of 30 questions in each section 24 Calculus & Algebra.
questions carried 4 marks with negative ma- Preparation Tips
Number of Questions and Marks alloted
rks and 6 question of 8 marks with negative Trend of Competition
More emphasis should be given to 2006 40 (Q) 120 (M)
marking. 2005 3,97,000 additional AIEEE Topics 2007 35 (Q) 105 (M)
2009 Mathematics paper termed 2006 5,24,000
Geometrical methods involving complex 2008 35 (Q) 105 (M)
moderate in level of difficulty. The 2007 6,00000 numbers and vector algebra are very 2009 30 (Q) 144 (M)
significant time pressure that one witnessed important This indicates every year number of qu-
2008 8,20,000
in the past years has been dramatically
Complete synopsis of all chapters should estions marks allotted to them are changing
reduced. But never-theless, the strategy to ace
2009 10,30,000 be revised one day before exam so student should go through instr-uction
this test depended on keeping one's cool and 2010 (Around 13,00000)
One week before AIEEE solving model carefully before attempting.
identifying the simpler questions to attempt papers will be useful
first before mo-ving to the more difficult
Matrix, Determinants , Mathematical indu-
Better to relax by watching T.V or spe-
questions, which weren't many. As usual, ction, 3D Geometry problem should be sol- nding time with parents 12 hours before
better utilization of time would result in ved in Systamatic way exam.
better marks. So, the constraining factor was
once again time, and not level of difficulty. . Last Five Years topic wise weightage analysis
Topic 2005 2006 2007 2008 2009
Swing towards Second year Syllabus Sets, Relations and Functions 2 1 2 2 2
Limits, Continuity & Differentiability 5 2 2 1 1
Last few years Maths AIEEE paper indicates
Application of Derivatives 5 3 2 2 3
more number of questions are accruing from Indefinite integrals, Definite Integrals& Area under the Curve 5 4 4 3 2
Second Year Inter Syllabus compared to First Cartesian coordinates & Straight line 2 2 2 1 1
Year Inter Syllabus Circles - 1 - 1 1
Conics 3 2 2 2 3
2007 2008 2009 Quadratic Equations, Inequalities , Progressions 3 2 2 3 3
I st year(no.questions) 17 9 12 Complex Number 3 2 2 1 1
IInd year 20 19 14 Binomial theorem, Exponential & Logarithmic Series 4 2 3 1 1
Additional Syllabus 3 7 4 Permutation & Combination 2 1 1 2 1
Probability 3 1 2 2 2
Vectors 1 1 2 2 2
Type of Questions
3-D Coordinate Geometry - 1 2 2 1
In AIEEE number of new model questions Differential Equations 2 1 2 2 1
Trigonometric Ratios, Equations, & Inverse Circular Function 1 1 1 1 1
like, Assertion-Reason, Statement problems
Heights and Distances - 1 1 1 -
will be given and their number is increasing Matrices & Determinants 5 2 2 3 2
every year .All these question are conceptual Mathematical Logic - - 1 - -
oriented that to mixed concept question will Statics & Dynamics - - - - -
Statistics - - - 1 1
occur more same statement will drive

IMPROVE APPLICATION SKILLS
Prepared by
V. Kumar
Dean,
Sri Chaitanya Educational
Institutions, Hyderabd.
After IIT's, National Institute of Techno-
logies (NIT) are the second choice for every
serious aspirant. And the rate at which NIT's
are progressing, that day is not far off when,
NIT's would be comparable to IIT's. In such a
situation you can't afford to take your AIEEE
preparation lightly.
In all M.P.C. related competitive exams
like EAMCET (Engineering), AIEEE and IIT
- JEE, Chemistry plays very important role in
getting better rank. Because questions in che-
mistry can be answered in less time and is bit
easy when compared to Physics and Maths.
But, now-a-days students throughout the
nation are feeling toughness with Chemistry
not because of its conceptual toughness but of
its voluminous. In general we can say that
"Tho-se who gets better rank in AIEEE are
those who does well in Chemistry".
Analysis of AIEEE - 2007, 2008 and 2009
Papers
Out of 30 questions given in AIEEE - 2009,
12 questions are very easy (40%), 15
questions are moderate (50%) and the
remaining 3 questions are bit difficult (10%)
In this circumstances to get good score in
Chemistry and to make it simpler, a scientific
approach is needed towards its preparation
i.e, different strategies are to be adopted to
study different branches of Chemistry i.e,
Physical, Organic and Inorganic Chemistry.
Physical Chemistry :
● It is a conceptual based branch of
Chemistry. Hence spend enough time in
understanding concepts
● Practice good number of numericals
involving usage of different formulaes
● Prepare formulae profile and go through it
regularly
● Generally students feel comfortable in
solving questions pertaining to Physical
Chemistry because the things to be
remembered in it are very few.
The concepts from which questions will be
asked frequently from Physical Chemistry
are :
Solubility Product, Colligative Properties,
Problems, Molar Conductivities, Buffer
Solutions, Equilibrium Constant related
problems, Bohr's theory applications,
Heisenberg's Principle, deBroglie's
3
Ýë„ìS ¿¶æÑ™èl VýS$Æý‡$ÐéÆý‡… 15 H{í³ÌŒæ, 2010
GUIDANCE AND ANALYSIS- CHEMISTRY
wavelength, Gibbs Helm holtz equation, Organic compounds.
Nernst equation, Faraday's laws, Solid State
(Lattice positions, holes, density, crystal Inorganic Chemistry :
defects), Order determination, Gold number, 1) Most of the students will face difficulty
Equivalent Weight determination, Daltons with inorganic chemistry because they
law of partial pressures, Graham's law of need to remember and byheart so many
diffusion, Vander waal's equations. Types of points and which they forget very easily.
molecular velocities, Hess's law, Thermo 2) Inorganic Chemistry can be made
chemical calculations, etc. interesting with some scientific approach
towards its study i.e, compare the general
Organic Chemistry : properties of elements of all groups. Most
● It is the most volatile branch of Chemistry of the properties are common in all groups
but at the same time it is easy and very with some exceptions.
important in view of time saving in 3) Make tabular forms consisting of
exams. preparatory methods of elements and
● Treat Organic Chemistry just like Maths compounds, electrodes and electrolytes
i.e, Read and Write used and electrodic reactions, etc.
● Practice it in the form of sequence of
reactions, flow charts and inter Inorganic Chemistry is not only difficult
conversions consisting of preparatory for you but is also difficult to all students. Hydrogen Peroxide, Hypo, etc.
methods and properties of several Difficulty is not because of toughness, but
compounds because of its vastness. Instead of thinking Improving application skills
● After making inter conversion charts, go that I am forgetting, better think that why I For this, students first read the topic
through them frequently, so that you can will forget and do work accordingly. thoroughly and spend enough time in
retain and recollect at faster rate understanding it and then apply the concept
The topics from which question will be in solving different types of questions.
The topics from which questions will be asked frequently in inorganic chemistry Application skills can be developed by
asked frequently are : are : applying concept to various types of
Stability and reactivity orders of Carbonium, Molecular Orbital theory, Dipole moment, questions. And also by thorough reading of
Carbanion, Free radicals, Inductive, Types of bonds, Gold number Calculations, problem.. they can able to understand
Mesomeric effect, Hyper conjugation, Nomenclature and Isomerism in Complexes, whether problem needs application or not.
Resonance, Stereo isomerism, Nomenclature, Polymers (Nylon, Bakelite, Synthetic rubber, Most of the questions given in AIEEE are
Named reactions, Mechanisms, Acidic Vulcanization), Biomolecules (Elementary moderate. In very few are tough questions. In
strengths of Phenols, Carboxylic acids and treatment), Diborane, Silicons, f-block this type of questions concept is easy but
Factors affecting it, Basic strength of amines element, Hydrides, Group study, Practical application may be bit difficult.
and factors affecting it and Diazonium Salt Chemistry, compounds of Xenon, , EAN,
Reactions, Electrophilic substitution Periodic properties, Hydrides, Oxides, Memory tips:
reactions of benzene and Benzenoids, Oxyacids of VA, VIA, VIIA group elements, Improving memory techniques definitely
Preparatory methods and Properties of preparatory methods and properties of gives possible outcome to students. But to
improve these memory techniques they
Previous Aieee Chemistry Paper Analysis should do good exercise. In case of organic
chemistry related questions, as it is more
Topic 2009 2008 2007 2006
volatile it requires many times of revision.
Atomic Structure and Classifications 3 1 1 5
Hence they are advised to prepare inter
Chemical Bonding 1 2 3 5 conversations consisting of preparatory
States of Matter 1 1 1 1 methods and properties of almost all the
Stiochiometry - 1 2 2 compounds within the syllabus. With this
Chemical and Ionic Equilibrium 1 4 3 3 they can revise several times in less time. As
Chemical Kinetics &NuclearChemistry 1 1 3 3 exam is going to held soon, hope every
Chemical Thermodynamics 2 2 3 4 student might complete their preparation and
Solutions 2 2 2 2 they are doing practice tests. Taking more
Electro Chemistry 1 1 2 3 number of practice tests definitely increases
G.O.C. + Functional Group I 5 9 9 10 the chances to get good rank.
Organic Chemistry- Functional Group II 2 1 1 3
Organic Chemistry Functional Group III 1 0 1 4 Approximate weightage of marks in
Transition Elements 2 1 3 1 AIEEE in previous exams
Coordination Compounds 2 2 1 4
Chemistry of representative elements 3 5 4 4 Physical chemistry: 30-36%
Surface Chemistry 1 1 0 1 Inorganic chemistry: 25-32%
Biomolicular 2 1 1 - Organic chemistry: 25-29%
TOTAL 30 35 40 55 General chemistry: 20-24%
 4
Ýë„ìS ¿¶æÑ™èl VýS$Æý‡$ÐéÆý‡… 15 H{í³ÌŒæ, 2010

GUIDANCE AND ANALYSIS - PHYSICS

UNDERSTAND BASIC CONCEPTS

Prepared by
AIEEE examination has come into existence Graphs showing percentage of marks scored against
and when we study the pattern and how it is
being evolved, one can say that it is made
rank in three consecutive years
K.V. Raghunath
Vice Chairman, easy and simpler year after year.
Narayana Institutions, In AIEEE the weightage for
Hyderabad.
MATHEMATICS, PHYSICS & CHE-
MISTRY is same. Time management is also
PREPARATION TIPS an important factor for the students to get
When we look at the last 3 years question good rank. Therefore, students must try to
papers, the weightage/ distribution for give at least 1 hour to solve PHYSICS paper.
different topics of PHYSICS is not uniform. Under any circumst-ances students should
However, it is desirable to concentrate more not try for a guess answer in case of 8 marks
on the following Chapters. questions.
Also it is observed that II year topics are
Most Important Topics more important than I year topics. There will
● Modern Physics be 13 questions from I year topics and 17
● Electrostatics questions from II year topics but marks wise
● Magnetic Effects of Current And Earth's II year topics are having more weightage.
Magnetism Strangely there may be 1 question from each
● Heat & Thermo Dynamics of the chapters
● SHM and Oscillations From the above graphs it is clear that paper is made easy year after year and that
● Current Electricity ● UNITS & DIMENSIONS is the reason why students are able to score more percentage of marks even though
● DYNAMICS competition is increased.
Important Topics ● SURFACE TENSION
● Gravitation & Rotational Mechanics ● VISCOSITY & ELASTICITY
● EMI Physics Chapter wise Questions and Marks Analysis
● AC & EM Waves For no scientific reason questions were for Last Three Years
● Optics not asked from "FRICTION", but this time 2007 2008 2009
● Kinematics we can surely expect at least 1 question. Name of the Chapter 40 × 3 = 120 35 × 3 = 105 6 × 8 = 48
MARKS MARKS 24 × 4 = 96
Topics To Be Reviewed How difficult the questions? (144 MARKS)
Easy (direct & simple) 55% Measurements Units - 2 (6) -
● Friction Moderate questions 38% & Dimensions
● Dynamics Difficult questions 7% Vectors - - -
● Centre of Mass Kinematics 2 (6) 1 (3) 1 (4)
● Mechanical Wave & Sound Some other words: Dynamics 1 (3) 1 (3) -
It may be observed that atleast 1 to 2 In time of solving the problem students must Collisions - 1 (3) 1 (4)
questions are generally asked on read the clue in related question. For this.. Centre of Mass 1 (3) 1 (3) -
Practical/Experimental Physics. These careful keen reading needed. Solving the Friction 1 (3) - -
questions are more often not easy, simple and problem conventionally is advised. In last Rotatory Motion 3 (9) 1 (3) 1 (8)
scoring. Students must know what they few years exam it is observed that questions Gravitation 1 (3) 2 (6) 1 (4)
confidently learnt Or otherwise negative based on intermediate second year syllabus Simple Harmonic Motion 3 (9) - 1 (8)
marks are going to take heavy toll on wild have been giving high rather than first year Elasticity - - 1 (4)
guess. Therefore, students should take fresh syllabus. Surface Tension - 1 (3) -
guard for every question they try to attempt. Keeping it in mind it is better to Fluid Mechanics - 2 (6) -
But at the same time they should not bog understand the basic concepts thorou-ghly Thermal Expansion of Materials - - -
down over the pressure of mistakes. and should understand the formula involved Thermo Dynamics 3 (9) 1 (3) 4 (16)
Students must read the instructions concepts. Then only they can able to solve Transmission of Heat 1 (3) - 1 (4)
carefully before starting the examination. the problems. Finally every student should Wave Motion 2 (6) 3 (9) 2 (8)
Since, there has been change in the number of know that basic fundamentals, accuracy and Ray Optics 1 (3) 1 (3) 2 (4 +8)
questions and marks. It is 8 years since speed will give the best rank. Physical Optics 1 (3) 3 (9) 1 (4)
Magnetism - 1 (3) -
Electrostatics 5 (15) 2 (6) 4 ( 12 + 8)
Total Marks and Ranks Obtained Current Electricity 1 (3) 5 (15) 2 (8)
Thermo Electricity - - -
RANK 2007 2008 2009 Electro Magnetics + 5 + 1 + 1 (21) 2 (6) 2 (8)
100 316 / 360 255 / 315 373 / 432 EMI + AC Circuits
500 296 / 360 233 / 315 342 / 432 Atomic Physics 2 (6) 1 (3) 3 (12)
1000 284 / 360 221 / 315 325 / 432 Nuclear Physics 3 (9) 1 (3) -
Semi Conductor Devices 2 (6) 1 (3) 3 (4+16)
10000 211 / 360 166 / 315 238 / 432
Communication Systems - - -
Above table indicate that except in 2008 question papers are found to be scoring papers. Experimental Physics - 2 (6) -
 5
Ýë„ìS ¿¶æÑ™èl VýS$Æý‡$ÐéÆý‡… 15 H{í³ÌŒæ, 2010

AIEEE GRAND TEST

IF THE SUM OF SQUARES...

M AT H E M AT I C S then chance that their product is greater 11. Statement-1: The number of different Ans: 4
1. p, q are two positive integers such that than 3/4 times their greatest product ways child can buy 6 ice-creams is 10C3 Sol. x ≤ −1 ⇒ x < x ⇒ f ( x) = x for x ≤ −1
3

L.C.M. of p, q is 8100. The number of probability is -1 < x < 0 ⇒ x < x3 ⇒ f ( x) = x 3 for −1 < x < 0
ordered pairs (p, q) is 1) 51/99 2) 99/199 3) 1/2 4) 1/3 Statement-2: The number of different
Ans: 3 0 ≤ x < 1 ⇒ x3 < x ⇒ f ( x ) = x for 0 < x < 1
1) 225 2) 242 3) 224 4) 220 ways child can buy 6 ice creams is equal
Ans: 1 3 to the number of different ways of x ≥ 1 ⇒ x3 > x ⇒ f ( x) = x 3 for x ≥ 1
Sol. x (200 − x ) > × 100 × 100 ⇒ 50 < x < 150
Sol. We know 8100 = 22 × 34 × 52 4 arranging 6A's and 4B's in a row 16. For all complex numbers z1, z2 satisfying
α β γ 7. The distance between the line 1) statement 1 is false, statement 2 is true |z1| = 12 and |z2 – 3 – 4i| = 5, the
Let p = 2 3 5 and q = 2 3 5
a b c

r = 2i − 2 j + 3k + λ (i − j + 4 k ) 2) statement I is false, statement 2 is false minimum value of |z1 – z2| is

At least one a, α is '2' and other can take 3) statement 1 is true, statement 2 is false 1) 0 2) 2 3) 7 4) 17
0, 1, 2
and the plane r . (i + 5 j + k ) = 5 4) statement 1 is true, statement 2 is true Ans: 2
Number of ordered pairs = 32 − 22 = 5 for Statement 2 is not correct explanation of Sol. Clearly,
b, β = 52 − 42 = 9 , for c, γ = 32 − 22 = 5 1) 10 2) 10 3) 10 4) 3 statement 1
Total 5 × 9 × 5 = 225
3 3 9 3 10 Ans: 1
2. Let p and q be the roots of equation Ans: 1 Sol. Statement 1: x1 + x2 + x 3 + x 4 + x 5 = 6
a .n − d ⇒ 5+ 6 −1
C5 −1 = 10C 4 ⇒
x − 2 x + A = 0 and let 'r' and 's' be the
2 Sol. Distance = False
n |z1| = 12 ⇒ z1 is a variable point on the
roots of the equation x − 18 + B = 0 if
2 10
(2i + 2 j + 3k ) . (i + 5 j + k ) − 5 = 10 Statement 2:
6 4
= 10
C4 ⇒ True circle |z – (3 + 4i)| = 5.
p < q < r < s are in A.P, then value of 'A', = Circles |z| = 12 and |z – (3 + 4i)| = 5 are
12 + 5 2 + 12 3 3
'B' are ___ 12. ABCDEF is a regular hexagon in anticl-
8. Find the equation of the curve passing th- drawn as shown in figure.
1) A = 3, B = 77 2) A = 3, B = 7 ockwise with vertices A, B respectively at
rough (1,2) whose differential equation is 17. If the coordinates of two consecutive
3) A = - 3, B = 77 4) A = 3, B = - 7 1 + 2i, 1 + 3i in argand plane the vertex
= y(x + y3)dx = x(y3 – x)dy 'P' is vertices of a regular hexagon which lies
Ans: 3
1) xy = 1 2) x2 – y2 =1 completely above the x-axis, are (-2, 0)
2− 3 5
Sol. Let the roots be a − 3d , a − d , a + d , a + 3d 3) y + 2x − 5x y = 0 4) x2 – y + 3 = 0
3 2 1) (2, 3 ) 2)  ,  and (2, 0), then the equation of the circle,
p + q = 2, pq = A , r + s = 18, rs = B Ans: 3  2 2
circumscribing the hexagon, is
p + q + r + s = 4a = 20 ⇒ a = 5 xdy − ydx  1
1) x + y − 4 3 y − 4 = 0
2 2
Sol. − x y .
2 2
+ x (ydx + xdy ) = 0 3)  −1,  4) (2, 2)
x2  2
p + q = a − 3d + a − d ⇒ d = 2 2) x + y + 4 3 y − 4 = 0
2 2

− y  y  dxy Ans: 2
Numbers are 1, 3, 7, 11 d + =0
3) x + y − 4 3 x − 4 = 0
2 2

pq = -3 = A
x  x  x2 y 2
Sol. A (Z1 ) = 1 + 2i, B ( Z 2 ) = 1 + 3i, P( Z 3)
π 4) x + y + 4 3 x − 4 = 0
2 2 2
B = rs = 77  y
  ∠ PAB =
−  −
3. Let a, b, c be positive real numbers. The x 1 3 Ans: 1
On integration =c passes
2 xy iπ Sol. Center is the 3rd vertex of the equilateral
following system of equations x, y, z in AP = AB e
3

2 2 2 2 2 2 through (1, 2) ⇒ c = −5 triangle having (-2, 0) and (2, 0) as two

x
+
y
−
z
=1
x
−
y
+
z
=1 3 iπ  2− 3 5  vertex.
Z 3 − Z1 = (Z 2 − Z 1 )e
3
a2 b2 c 2 a2 b2 c2 ⇒  , + i 
⇒ y3 + 2 x − 5 x 2 y = 0  2 2  18. Range of values K for which the point (k,
x2 y2 z 2 9. If x, y, z are real numbers satisfying the –1) is exterior to both the parabolas
+ + = 1 has 13. If f(x) is function such that
a2 b2 c2 equation
f (x + 5 ) + f ( x + 6) = 0 ∀ x ∈ R the period y2 = |x| is
1) no solution 2) unique solution 25 (9 x 2 + y 2 )+ 9 z 2 − 15 (5 xy + yz + 3 zx ) = 0
of function 1) (-1, 0) 2) (-1,1) 3) (0,1) 4) (0,-1)
3) infinite solutions 4) finite solutions then x, y, z are in
1) 1 2) 2 3) 3 4) 2π Ans: 2
Ans: 4 1) A.P 2) G.P 3) H.P 4) A.G.P
Ans: 1 Ans: 2 Sol. The two parabolas are y2=x and y2=-x
x2 y2 z2
Sol. Let 2
= X, 2 = Y, 2 = Z
Sol. (15x ) + (5 y ) + (3z ) − (15x )(5 y )− (5 y )(3z )− (3z )(15x )= 0
2 2 2
Sol. f (x + 5 ) + f ( x + 6) = 0 → (1) The point (k, -1) is an exterior point.
a b c if (–1)2 – k > 0 and (–1)2 + k > 0
Replace 'x' with
⇒ (15 x − 5 y ) + (5 y − 3z ) + (3z − 15x ) = 0
2 2 2
X+Y–Z= 1, X–Y+ Z=1, –X+Y+Z=1
x + 1 ⇒ f ( x + 6) + f ( x + 7) = 0 → (2) Hence Range of K is (-1, 1)
Determinant of coefficient ≠ 0 ⇒ 15 x − 5 y = 0, 5 y − 3 z = 0, 3 z − 15 x = 0 2 2
19. If the ellipse x + y = 1 meet the ellipse
1000 n
x y z (1)-(2) → f (x + 5 ) = f ( x + 7) of x + 5 = x 4 1
4. For all n ∈ N a n = ⇒ = = ⇒ A. P
n
is greatest, then
1 3 5 ⇒ f (x ) = f ( x + 2 ) ⇒ Period = 2 x 2
y 2
+ = 1 in four distinct points and
1) n = 997 2) n = 998 10. α , β , γ are the angles made by a line with  λ µ 
2x 1 a2
1 + + 2  = e then
2
3) n = 999 4) n = 996 x, y , z axes in positive direction then the 14. If x Lt
→∞  a = b2 – 10b + 25, then the value of b does
x x 
Ans: 3 range of cos α cos β + cos β cos γ + cos γ cos α is 1) λ = 1, µ = 2 2) λ = 2, µ = 1 not satisfy
a
Sol. n +1 =
1000
⇒ a n +1 > a n
 −1   −1 
1)  , 1 2)  , α  3) (1, α ) 4) (1, 2]
3) λ = 1, µ = any real constant 1) (−∞, 4] 2) (4,6) 3) [6, ∞ ) 4) [4,6]
an n +1 2  2  4) λ = µ = 1 Ans: 2
Ans: 1 Ans: 3 Sol. Now according to condition a > 1
for n=1, 2,.., 999 ⇒ n = 999
Sol.
= cos α , m = cos β , n = cos γ
2x
  b2 − 10b + 25 = a > 1
 
5. If the sum of squares of roots of equation
2 + m 2 + n 2 = 1 and (
+ m + n ) ≥ 0
2
1 + 1  ⇒ λ = 1, µ ∈ R ⇒ b 2 − 10b + 24 > 0
x2 – (sin α – 2)x – (1 + sin α) = 0 is least, Sol. xlim
→∞  x2 

+ m + n + 2 (
m + mn + n
) ≥ 0
2 2 2
  ⇒ (b − 4 )(b − 6 ) > 0 i.e. b < 4 & b > 6
then α =  λ x +µ 
−1  c
1) 90° 2) 70° 3) 20° 4) 60° ⇒
m + mn + n
≥ and 20. If normal to hyperbola xy = c2 at  ct1 , 
2
Ans: 1 15. f : R → R is defined by f(x)=max{x, x3}.  t1 

Sol. S = α + β = (α + β ) − 2αβ = sin α − 2sinα + 5

2 2 2 2 1 2
2
(

+ m 2 + n 2 −
m − mn −
n ≥ 0 ) The set of all points where f(x) is not
meet the curve again at
 c
 ct 2 ,  , then:
differentiable is
= (sin α − 1) 
2
+ 5 ⇒ α = 90° t2 
−1  −1  1) {-1, 1} 2) {-1, 0}
⇒
m + mn + n
≥ ⇒  , 1 2
6. The sum of two positive integers is 200 2 2  3) {0, 1} 4) {-1, 0, 1} 1) t1t2 = −1 2) t2 = −t1 −
t1
 6
Ýë„ìS ¿¶æÑ™èl VýS$Æý‡$ÐéÆý‡… 15 H{í³ÌŒæ, 2010

AIEEE GRAND TEST

THE RADIATION IS EMITTED

3) t1t1 = −1
3
4) t1 t 2 = −1
3 Ans: 4 1 1 4) N +2 becomes diamagnetic
+ =
3 (λ − 4 ) H − a H −b
Ans: 4 Sol. f 1
(x ) = 2
>0 Ans: 4
Sol. Hyperbola Equation of normal at (2 sin x + 3cos x ) 1)a 2) b 3)a+b 4)1/a+1/b Narration:
 c if λ > 4 Ans: 4 N 2+ becomes paramagnetic
 ct1 ,  is t1 x − t1 y − ct 1 + c = 0
3 4

2ab − a 2 − ab a (b − a ) N 2+ (13 electrons):

 t1 26 The equation of the tangent, to the curve 2ab 2ab
Sol. H = ⇒ H − a= − a= =
KK ó 2 s ó 2 s ð2 p x = ð2 p y ó2 p z
2 * 2 2 2 1
 c y =e
−x a+b a+b a+ b a+ b
at the point where the curve cuts
It passes through  ct2 , 
 t2  the line x = 1, is 2ab 2ab − ab − b 2 ab − b 2 b (a − b ) B.O =
7−2
= 2.5 , paramagnetic
Also H − b = −b= = =
c 1) x + y = e 2) e(x + y) = 1 a +b a +b a +b a +b 2
i.e t1 .ct2 − t1 − ct 14 + c = 0
3
3) y + ex = 1 4) x - ey = 0
t2 1 1 a +b a +b 5. The heats of neutralization of CH 3COOH ,
Ans: 1 + = =
H − a H − b a (b − a ) b (b − a )
⇒ (t1 − t 2 )( + 1)= 0 ⇒
t13t 2 = −1 t13t 2 HCOOH , HCN and H 2 S with a strong
  1
21. The function f whose graph passes Sol. Point of intersection is, 1,  and slope ab + b 2 − a 2 − ab b2−a 2 b +a 1 1 base are -13.2, -13.4, -2.9 and -3.8kcal
e   = = = = +
through (0, 7/3) and whose derivative is ab (b − a ) ab (b − a ) ab a b per equivalent respectively. The correct
= 1/e
x 1− x2
increasing order of acid strength is
is given by
CHEMISTRY
( )
27. The angles of elevation of a flying kite at 1) HCOOH<CH3COOH M<H2S<HCN
1) f (x ) = (1 / 3 ) (1 − x 2 ) + 7
3/ 2
three points A, B, C on a horizontal line 1. Equal masses of SO2, CH4 and O2 are 2) HCN<H2S<CH3COOH<HCOOH
(same vertical plane of kite) are in the mixed in an empty container at 298K, 3) HCOOH<CH3COOH<HCN<H2S
2) f (x ) = (3 / 2 )sin −1 x + 6  ratio 1 : 2 : 3. If AB = a, BC = b then the when total pressure is 2.1 atm. The partial 4) CH3COOH<H2S<HCN<HCOOH
height of the kite is pressure of CH4 in the mixture is Ans: 2
3) f (x ) = − (1 / 3 )(1 − x ) − 8 
2 3/ 2

  1) ab 2) a/b 3) a+b 1) 0.5 atm 2) 0.75 atm Narration:

4) f (x ) = − (2 / 3 )(1 − x ) − 8
 2  3/ 2 a
( a + b )(3b − a )
3) 1.2 atm 4) 0.6 atm More strong the acid, more will be heat of
4) 2b Ans: 4 Ans: 3 neutralization. Negative sign signifies
Ans: 3 Sol. as angles are in 1:2:3 ratio height is Narration: evolution of heat.
a
Sol. f ( x) = ∫x 1 − x 2 dx passes through (0,7/3) h= ( a + b )(3b − a ) Let w g of each SO2 , CH 4 and O2 are mixed 6. In a fuel cell methanol is used as fuel and
2b
∴ Mole fraction, w oxygen gas is used as an oxidizer. The
22. The area enclosed by the curve r2 = a2Sin 28. Let p be the statement: "x is an irrational nCH 4 16 4 reaction is
X CH 4 = = =
is given by number" nSO2 + nCH 4 + N O2 w w w 7
+ + 3
CH 3OH (
) + O2 (g ) 
→ CO 2( g) + 2H 2O(
)
1) a2 2) 2a2 3) 2a 4) none of these q be the statement: "y is a transcendental 64 16 32 2
Ans: 1 number" PCH 4 = mole fraction × Total pressure At 298K standard Gibb's energies of for-
Sol. The equation of the given curve is r be the statement: x is rational off y is a 4
× 2.1 = 1.2 atm mation for CH 3OH (
), H 2O(
) and CO2(g )
r2 = a2Sinθ transcendental number = 7 are -166.2, -237.2 and -394.4kj mol-1 res-
Required area=Area of OBACO Statement-1: r is equivalent to either q or p 2. Consider the following gases and their pectively. If standard enthalpy of combu-
= 2 x Area of OBAO Statement-2: r is equivalent to ∼ ( p ↔ ∼ q ) corresponding values of 'a' given in brac- stion of methanol is -726 kj mol-1, efficie-
1) Statement-1 is false, statement-2 is true kets. CH4(2.25), N2(1.35), O2(1.36) and ncy of the fuel cell will be
2) Statement-1 is true, statement-2 is true CO(1.46). Which of them will liquefy 1) 80% 2) 87% 3) 90% 4) 97%
π /2 1 2 Statement-2 is correct explanation for with great difficulty? Ans: 4
2∫ r dθ statement-1 1) CH4 2) N2 3) O2 4) CO Narration:
0 2 3) Statement-1 is true, statement-2 is true Ans: 2 For the given reaction,
Statement-2 is not correct explanation for Narration: 3
π /2
1 2 π /2 CH 3OH (
) + O2(g ) 
→ CO 2( g) + 2H 2O(
),
2∫ a Sinθ d θ =  −a 2 cos θ  = a 2 statement-1 Constant 'a' is a measure of 2
0 2 0

  4) Statement-1 is true, statement-2 is false intermolecular attractive forces. Greater , ∆H = −726 kj mol −1
23. If a and b are unit vectors, then the Ans: 1 the value of 'a' grea-ter are the
   
greatest value of a + b + a − b is Sol. Given statement r = ∼ p ↔ q intermolecular forces of attraction, hence
∆ G° f CH 3OH (
)  = −166.2 kj mol −1
more easily the gas is liquefied. Also,  
1) 2 2) 4 3) 2 2 4) 2 Statement-1: r1 = ( p ∧ ∼ q ) ∨ (∼ p ∧ q)
Ans: 3 3. The radiation is emitted when a hydrogen ∆ G° f  H 2O(
)  = −237.2 kj mol −1
Statement-2:  
 atom goes from a higher energy state to a and
Sol. a.b = cos θ r2 = ∼ ( p ↔∼ q ) = ( p ∧ q) ∨ (∼ q ∧ ∼ p) ⇒ r1 = r2
lower energy state. The wavelength of ∆ G° f CO2(g )  = −394.4 kj mol −1
  θ   θ ⇒ Statement 1 is true and statement-2 is
 
=| a + b |= 2 cos , | a − b |= 2sin one line in visible region of atomic spec-
2 2 −7
false trum of hydrogen is 6.63 × 10 m . Energy ∆ G° reaction = ∑ ∆ G° f products − ∑ ∆ G°
     θ θ freactants
=| a + b | + | a − b |= 2  cos + sin  ≤ 2 2 29. The interior angles of regular polygon difference between the two states is Now,
 2 2
 −394.4 + 2 × (−237.2 ) − (−166.2 )= −702.6 kj mol
−1

x − 2 y +1 z −1
measures 1500 each, the number of 1) 3.0 × 10–19 m 2) 1.0 × 10–18 m
24. The line = = intersects the diagonals of the polygon. 3) 5.0 × 10–10 m 4) 6.5 × 10–7 m ∆G − 702.6
3 2 −1 × 100 = × 100 = 96.77%
1)12 2)42 3)54 4)10 Ans:1 % Efficiency= ∆ H − 726
curve xy = c , z = 0 if c=
2
Ans: 4 Narration: ∴ Efficiency = 97%
1) ±1 2) ± 3 3) ± 5 4) ± 7
Sol: ⇒ Exterior angle = 180-150=30° Total hc 6.62 × 10−34 × 3 × 108
7. 8 moles of a gas AB3 are introduced into
Ans: 3 ∆E = = = 3.0 ×10−19 a 1.0 dm3 vessel. It dissociates as,
360
0
λ 6.63 × 10−7 2 AB3(g )  A 2( g ) + 3B 2( g)
Sol. P(3k+2,2k-1,-k+1) lie on z=0 angle = 360° Sides: = 12 . At equilibrium
300
k=1 and P=(5,1,0) lie on curve xy=c2 4. N2 and O2 are converted to mono cations 2 moles of A2 are found to be present. The
n( n − 3)
λ sin x + 6sin x N 2+ and O2+ respectively. Which is wrong? equilibrium constant of reaction is
25) Function f (x ) = Number of diagonals = 2 = 54 +
2sin x + 3cos x 1) In N 2 , the N - N bond weakens (in mol2L-2 )
+
is monotonically increasing if: 2) In O2 , the O - O bond order increases 1) 12 2) 3 3) 27 4) 36
1) λ > 1 2) λ < 1 3) λ < 4 4) λ > 4 30. If H is the H.M. between a and b, then +
3) In O2 , paramagnetism decreases Ans:3
 7
Ýë„ìS ¿¶æÑ™èl VýS$Æý‡$ÐéÆý‡… 15 H{í³ÌŒæ, 2010

AIEEE GRAND TEST

IN A MOLECULE OF DIBORANE
Narration: Narration: to the time taken for the reaction to be remove temporary hardness. A reacts with
2 AB3(g )  A 2( g ) + 3B 2( g) ∆ Tf = m × K f 90% complete ? sodium carbonate to generate caustic soda
Initial moles 8 0 0 = 0.011 ×1.86 = 0.021 1) There is no change When CO2 is bubbled through a solution of
At equilibrium (8 - 4) 2 2x3=6 ∆ T f (calculated) = 0.021oC 2) Time taken is double A, it turns cloudy. What is the chemical
=4 ∆ T f (observed)= 0.063°C (given) 3) Time taken is triple formula of A ?
[A2 ][B2 ]3 = (2 )(6 )3 = 27 Observed ∆ T f 0.063 4) The time required is half the initial 1) CaCO3 2) CaO
Kc = i= = =3
[AB3 ]2 (4 )
2
Calculated ∆ T f 0.021 value 3) Ca(OH)2 4) Ca(HCO3)2
8. The solubility product of AgI at 250C is Degree of dissociation, α = i − 1 Ans: 2 Ans: 3
1.0 × 10 −16 mol 2 L−2 . The solubility of AgI in n −1 Narration: Narration:
10 −4 N solution of KI at 250C is approxi- 3− 2.303 100 Ca(OH)2 is used for water softening
K 3  Fe (CN )6   3K + +  Fe (CN ) 6 t99% = log
mately (in mol L−1 ) k 100 − 99 .........(i)
Na2CO3 + Ca (OH )2 
→ 2NaOH + CaCO
1) 1.0 × 10−8 2) 1.0 × 10−16
3
thus n = 4 t90% =
2.303
log
100 Caustic soda
−12 −10
3) 1.0 × 10 4) 1.0 × 10 3 −1 k 100 − 90 .......(ii) Ca (OH )2 + CO 2 
→ CaCO 3(s )+ H 2O
á= = 0.67
Ans:3 4 −1 Dividing equation (i) by (ii), ( A) Cloudiness

Narration: Percent dissociation = 67% t99% log 100 ∴ t99% = 2 × t90% 20. In a molecule of diborane
= =2
AgI  Ag + + I − 12. The colour of K 2Cr2O7 changes from red t90% log10 1) 4 - bridged hydrogens and two
Let the solubility of AgI be 'x' then, orange to lemon yellow on treatment with terminal hydrogens are present
(Ag + )= x, (I − )= x + 10 −4 (from KI) aqueous KOH because of 16. 10-4 g of gelatin is required to be added to 2) 2 - bridged hydrogens and four
( )
1.0 × 10 −16 = x x + 10 −4 = x 2 + 10 −4. x 1) Reduction of Cr (VI) to Cr (III) 100cm3 of a standard gold sol to just terminal hydrogens are present
x2 can be neglected, then 10 −4 x = 0 −16 2) Formation of chromium ion to prevent its coagulation by the addition of 3) 3 - bridged hydrogens and three
10 −16 chromate 1cm3 of 10% NaCl solution to it. Hence terminal hydrogens are present
x= = 10 −12
10 −4 3) Conversion of dichromate ion to the gold number of gelatin is 4) None of the above
9. In a cubic packed structure of mixed oxi- chromate 1) 10 2) 1.0 3) 0.1 4) 0.01 Ans:2
des, the lattice is made up of oxide ions, 4) Oxidation of potassium hydroxide to Ans: 4 Narration:
one fifth of tetrahedral voids are occupied potassium peroxide Narration: A molecule of diborane consists of 2 -
by divalent (X++) ions, while one - half of Ans: 3 Gold number is given in terms of bridged hydrogens and four terminal
the octahedral voids are occupied by Narration: milligrams of protective colloid required to hydrogens
trivalent ions (Y+++) then the formula of In basic medium dichromate ion changes just prevent the coagulation of 10ml of 21. Which one of the following compounds
the oxide is to chromate ion standard gold sol by addition of 1ml of will not exhibit optical isomerism ?
1) XY2O4 2) X2YO4 K 2Cr2O7 + 2 KOH  2 K 2CrO 4 + H 2O 10% NaCl solution. 1) CH3CH(OH)Br 2) CH3CH(OH)CH3
3) X4Y5O10 4) X5Y4O10 13. If 3 Faradays of electricity is passed In the given case amount of gelatin 3) CH 3 4) CH3 − CH − CHCH 2OH
CH3 CH2 − CHBrCHCH3
Ans:3 through the solutions of AgNO3 , CuSO4 required to protect 10cm3 of gold sol OH Br

Narration: and AuCl3 , the molar ratio of the cations 10 −4 × 10 Ans: 2

= 10 −5 g = 10 −2 mg = 0.01mg
Oxide ion (O2-) forms the cubic lattice, deposited at the cathodes will be 100 Narration:
Number of O - atoms per unit cell = 4 1) 1 : 1 : 1 2) 1 : 2 : 3 17. Which one of the following arrangements CH3CH(OH)CH3 does not contain chiral
Number of tetrahedral voids = 4 x 2= 8 3) 3 : 2 : 1 4) 6 : 3 : 2 does not represent the property indicated carbon.
Number of X - atoms per unit cell = 8/5 Ans:4 against it ? 22. Consider the acidity of the carboxylic
Number of octahedral voids = 4 Narration: 1) Br2 < Cl2 < F2 : Electron negativity acids :
Number of Y - atoms per unit cell = 4/2=2 AgNO3 : Ag + + e − → Ag 2) Br2 < F2 < Cl2 : Electron affinity i) PhCOOH ii) o - NO2C6H4COOH
8 : 2:4 i.e., 8:10:20 = 4:5:10 3 Faradays of electricity deposit 3 mole of 3) Br2 < Cl2 < F2 : Bond energy iii) p - NO2C6H4COOH
X: Y : O =
5 Ag CuSO4: Cu2++2e− → Cu 4) Br2 < Cl2 < F2 : Oxidising energy iv) m - NO2C6H4COOH
Thus, formula is X4Y5O10 2F 1 mole Ans: 3 Which of the following order is correct ?
10. Schottky defect in crystals is observed 3 Faradays of electricity deposit 3/2 mole Narration: 1) i > ii > iii > iv 2) ii > iv > iii > i
when of Cu Au cl3 : Au3+ + 3e− → Au Br2 < Cl2 < F2 : Bond energy 3) ii > iv > i > iii 4) ii > iii > iv > i
1) Unequal number of cations and anions 3F 1 mole Due to smaller size of fluorine there are gr- Ans: 4
are missing from the lattice 3 Faradays of electricity deposit 1 mole eat interelectronic repulsions between lone 23. Tertiary alkyl halides are practically inert
2) Equal number of cations and anions of Au pair of electrons so that its bond energy to substitution by mechanism because of
are missing from the lattice Thus Ag : Cu : Au = 3 : 3/2 : 1 decreases and becomes less than that of Cl2 1) steric hinderance 2) inductive effect
3) Anion leaves its normal site and i.e., 6 : 3 : 2 18. Extraction of zinc from zinc blende is 3) instability 4) insolubility
occupies an interstitial site achieved by Ans :1
E° = 0.8V E° = −0.76V
4) Density of the crystal is increased 14. When Ag + Ag and Zn2 + Zn 1) Electrolytic reduction 24. OH O− Na+
Ans: 2 , which of the following is correct ? 2) Roasting followed by reduction with + CHCl 3 + NaOH
CHO
Narration: 1) Ag+ can be reduced by H2 carbon
In Schottky defect, equal number of 2) Ag can oxidize H2 to H+ 3) Roasting followed by reduction with The electrophile involved in the above
reaction is
cations and anions are missing from the 3) Zn2+ can be reduced by H2 another metal
⊕
lattice 4) Ag can reduce Zn+2 ion 4) Roasting followed by self - reduction  
1) dichloromethyl cation  CH Cl 2 
11. The percentage dissociation of a 0.011m Ans: 1 Ans:2  
2) dichlorocarbene (:CCl2)
aqueous solution of K3  Fe (CN )6  which Narration: Narration: −
freezes at −0.063°C is (Kf for water = Silver has higher reduction potential and 2 ZnS + 3O2 
→ 2ZnO + 2SO 2 3) trichloromethyl anion (C Cl3)
1.86) can be easily reduced by H2 ⊕
1400°C
ZnO + C  → Zn + CO 4) formly cation  CH O 
1) 75% 2) 67% 3) 33% 4) 50% 15. What is the time required for a first order  
Ans: 2 reaction to be 99% complete, compared 19. Chemical A is used for water softening to Ans: 2
 8
Ýë„ìS ¿¶æÑ™èl VýS$Æý‡$ÐéÆý‡… 15 H{í³ÌŒæ, 2010

AIEEE GRAND TEST

THE IONIZATION ENERGY..

25. In [SiO4]4– (tetrahedral structure) three 3) linkage isomerism, ionisation meridian when it shows an angle of dip θ
oxygen atoms are shared in which of the isomerism and optical isomerism. at a place. The dip circle is rotated
following 4) linkage isomerism, ionisation through an angle x in the horizontal plane
1) Sheet silicates isomerism and geometrical isomerism. and then it shows an angle of dip 'θ' Then
2) Three dimensional silicates
Ans: 4 tanθ'/tanθ is 1) 150 V 2) 70 V 3) 40√2V 4)50 V
3) Linear silicate 4) Pyro silicate
1 1
Ans:1 PHYSICS 1) 2) 3) 1 4) cosx Ans: 4
26. Prussian blue colouration is observed in cos x sin x tan x
Hint: V = (VL − VC ) 2 + VR2
the detection of nitrogen. The formula of 1) The main scale of vernier calipers is Ans: 1
the compound is divided into half millimeters and its least v v 12) Assertion (A): Two slits in young double
Hint: tan θ , tan θ ' =
1) Fe4[Fe(CN)5]3 2) Fe4[Fe(CN)6]3 count is to be 0.005cm. The number of H H cos x slit experiment are illuminated by two
3) Fe3[Fe(CN)5]4 4) Fe3[Fe(CN)6]4 vernier divisions is different sodium lamps emitting light of
Ans: 2 1)10 2) 20 3)30 4)40 7) A coil of self inductance 50 henry is same wavelength. No sustained inter-
CH 3 CH 2 CN 
L iAlH 4 , HC l
→ A 
N aNO 2 , HCl
→B
Ans: 1 joined to the terminals of battery of e.m.f. ference pattern is observed on screen.
27. H 2O
main scale division 2 volts through a resistance of 10 ohm Reason (R) : The sources are incoherent.
H 2O+
→ C 
LiAlH 4

→ D
Hint: Least count =
Hydrolysis ether
number of vernier division and a steady current is flowing through 1) Both A and R are true, R is the correct
the circuit. If the battery is now explanation of A
B and D respectively are 2) A potentiometer wire of length 100cm disconnected, the time in which the 2) Both A and R are true, R is not the
1) CH3CH2CH2OH, CH3CH2CH2CH2OH has a resistance of 10 Ω. It is connected current will decay to 1/e of its steady correct explanation of A
2) CH3CH2CHO, CH3CH2CH2OH in series with a resistance and an value is (in seconds) 3) A is true, R is false
3) CH3CH2CH2OH, CH3CH2CH2NH2 accumulator of emf 20V and negligible 1) 500 2) 50 3) 5 4) 0.5 4) A is false, R is true.
4) CH3CH2CH2OH, CH3CH2CH2OH resistance. A source of emf 1V is Ans: 3 Ans: 1
Ans:4 balanced against a length of 40cm of R Hint: Conceptual
− t
Narration: potentiometer wire. The value of external Hint: i = i 0 e L 13) An infinitely long straight conductor is
A = CH3CH2CH2NH2 resistance is uniformly charged with charge density λ
B = CH3CH2CH2OH 1) 420Ω 2) 570Ω 8) 10 gm of water at 50° and 10 gm of ice at per metre. The work done to bring a
C = CH3CH2COOH 3) 70Ω 4) 370Ω –20°c are mixed in a calorimeter of charge q0 at perpendicular distance b to a
D = CH3CH2CH2OH Ans: 3 negligible water equivalent. Then (Sp perpendicular distance a (a < b) from the
28. A colloidal solution is subjected to an heat of ice = 0.5cal/gm/°C) conductor is
electric field. The colloidal, particles Hint: V =  20  × 4 a) Resultant temp is 2°C q0λ
 10 + R  1) zero 2)
move towards the anode. Coagulation of b) 5 gm of ice is melted 2πε 0
the same colloidal solution is studied 3) The ionization energy of Hydrogen atom c) mass of water in the calorimeter 12 gm q0λ b q0 λ a
3) log e   4) log e  
using NaCl, BaCl2 and AlCl3 solution. is 13.6 eV. Following Bohrs theory of 1) a & b are wrong 2) b & c are wrong 2πε 0 a πε 0 b
Ans: 3
The coagulating power of :- hydrogen atom, the amount of energy 3) a & c are wrong 4) All are wrong λ
1) NaCl > BaCl2 > AlCl3 involved corresponding to a transition Ans: 3 Hint: dw = Eq o dr, E(r) =
2π ∈o r
2) AlCl3 > BaCl2 > NaCl between the 3rd and the 4th orbit is Hint: Apply the principle of mixtures.
3) NaCl>AlCl3>BaCl2 1) 3.40 eV 2) 1.51 eV 9) A block of mass M moving at a speed v 14) 12 cells each having the same emf are
4) BaCl2 > NaCl > AlCl3 3) 0.85 eV 4) 0.66 eV collides with another block of mass 2M at connected in series and are kept in a
Ans: 2 Ans: 4 rest. The lighter block comes to rest after closed box, to act like a battery. In this
136
Narration: As the particles are moving Hint: E n = ev the collision. The coefficient of battery some of the cells are wrongly
towards anode, they carry negative n2 restitution is connected. Similar two more cells are
charge. Hence cation of electrolyte is 4) A radio station is transmitting waves of 1) 1/3 2) 1/4 3) 1/2 4) 1 taken and connected in series. This two
useful for coagulation. Coagulating po- wavelength 300m. If the radiating power Ans: 3 cells combination, battery, a resistor and
wer of an ion increases with charge on it. of the transmitter is 10kW, then the v an ammeter are connected in series. The
rel vel of seperation
Hint: e = = 2 ;(mv = 2mv 1)
29. Match the following number of photons emitted per second rel vel of approach v current is 3A when the cells and the
LIST - I LIST - II will be nearly battery aid each other and is 2A when the
( polymer) (polymerizing unit ) 1) 1.5 × 1035 2) 1.5 × 1031 10) A copper wire is held at the two ends by cells and the battery oppose each other.
A) Bakelite I) Butadiene and Styrene 3) 1.5 × 1029 4) 1.5 × 1033 rigid supports. At 60°C the wire has just The number of cells that are connected
B) Nylon - 6 II)Phenol and methanal Ans: 2 negligible tension. The speed of wrongly, in the battery is
C) Nylon - 6,6 III) Caprolactam nhc transverse waves in this wire at 10°C is 1) 1 2) 2 3) 3 4) 4
Hint: P = (Y = 1.6 × 1011 Nm–2, α = 1.8×10–6/°C Ans: 1
D) Buna - S IV) Urea and methanal λt
V) Hexane1, 6-dioic 5) If E0 and B0 denote the electric field and and density, ρ = 9 × 103 kgm–3
acid and Hexane1, 6
the magnetic field respectively in a
1) 160ms–1 2) 80ms–1 Hint: (m − n)E + 2E = 3, (m − n)E − 2E = 2
-diamine 3) 40ms –1 4) 20ms–1 R R
propagating electromagnetic wave in free
A B C D A B C D E0 Ans: 3 15) A carpet of mass M made of inextensible
1) IV III V I 2) II III V I space then the quantity µ 0ε 0 is material is rolled along its length in the
B0 T yAα∆t
3) V II III I 4) II IV V III Hint: V = = form of a cylinder of radius R and is kept
1) C 2) C2 3) 1/C 4) 1 m A. ρ
Ans: 2 on a rough floor. The carpet starts
Ans: 4
30. [Co(NH3)4(NO2)2]Cl exhibits 11) In the given circuit, the effective voltages unrolling without sliding on the floor
E 1
1) ionisation isomerism, geometrical Hint: 0 = across inductor, capacitor & resistance when a negligibly small push in given to
isomerism and optical isomerism. B0 µ0 ε0 are 80V, 40V and 30V respectively. The it. The horizontal velocity of the axis of
2) linkage isomerism, geometrical effective value of emf of alternating cylindrical part of the carpet when its
isomerism and optical isomerism. 6) A dip needle lies initially in the magnetic current source will be radius reduces to R/2 is
 9
Ýë„ìS ¿¶æÑ™èl VýS$Æý‡$ÐéÆý‡… 15 H{í³ÌŒæ, 2010

AIEEE GRAND TEST

A PARTICLE IS PLACED..
7 8 14 F2 – F1 = F1 21) The PE of a particle of mass 1 Kg is in 27) Half life of a radioactive sample is T. If
1) gR 2) gR 3) gR 4) gR
3 3 3 motion along the x-axis is given by U = the radio activities of the sample are R1
Ans: 4 F2 = 2F1 4(1 – cos2x)J. Here x is in m. The period and R2 at times T1 and T2 respectively,
Hint: Decrease in PE = increase in KE of small oscillations (in sec) is then number of atoms distintegrated in
Gm 2 m Gm1m
16) A gas expands in a piston-cylinder device
2
=2 2
m2 = 2m1 1) 12π 2) π 3) π/2 4)√2π time (T2 – T1) is proportional to
from V1 to V2, the process being d d Ans: 3 1) (R1 + R2)T 2) (R1 – R2)T
   
described by P =
a
+ b where P is in 2 2 Hint: F = −du , T = 2 π sin θ ≈ θ  R −R2   R + R2 
V dx ω 3)  1  4)  1 
Also gravitational potential energy of the  T   T 
N/m2 and V is in cubic metre. The work body = its kinetic energy 22) A circular wire loop of radius r carries a
done in the process is :
Gmm1 Gmm 2 1 2Gm1 2Gm 2 total charge Q distributed uniformly on it. Ans: 2 Hint: R1 = N1 λ; R2 = N2λ ;
V  + + = mv c 2 + +
1) a log e  1  + b (V 2 − V1) d d 2 d d A small length dl is cut off. Electric field N1 − N2 (e− λT1 − e −λT2)
 V2  2 2 due to remaining wire at the centre is 28) A locomotive engine approaches a
 V2  v 2 2Gm 2G × 2m v c 2 Qdl Qdl railway station and whistles at a
= c + + =
2) −a log e   − b (V 2 − V1) 1) 2 3 2)
 V1 
2 d d 2 8π r ε o 8π 2 r 2 ε o frequency of 400 Hz. A stationary
2
2Gm1 4Gm1 v c observer on the platform observes a
  + = Qdl Qdl
3) −a log e  V1  − b (V 2 − V1) d d 2 3) 4) change of 40 Hz as the engine passes
 2
V 16 π2r 3εo 16 π 2r 2 ε o
6Gm1 v c 2 across him. If the velocity of sound is 330
V  = Ans: 1 m/s, the speed of the engine is (in m/s)
4) a log e  2  + b (V 2 − V1) d 2
 V1  dq 1) 33 2) 18 3) 16.5 4)24
Hint: E dq = E Q(at the centre) ; Edq =
Ans: 4 12Gm1 12G ×10 120G 4πε o r 2 Ans: 3
v0 2
= = =
a d 1 1 23) The distance time graph of a particle at
 V   V 
Hint: p = +b Hint: n ' = 
v time t makes an angle 45° with the time  n n" =  n
v e = 120G axis. After one second it makes an angle  V − Vs   V + Vs 
dw = p – dv 40 = n ' − n"
18) An object is placed in front of a convex of 60° with the time axis. What is the
a  acceleration of the particle
dw =  + b  dv mirror at a distance of 50cm. A plane 29) A ball rises to a surface with constant
v  mirror is introduced covering the lower 1) 3 − 1 2) 3 + 1 3) 3 4) 1 velocity in a liquid whose density is 5
v2 half of the convex mirror. If the distance times the density of material of the ball.
Hint: a = dv
w= ∫ pdv between the object and the plane mirror
Ans: 1
dt Then the viscous force is
v1 is 30cm, there is no parallax between the 24) A solid sphere of radius r and α = 2 × 1) less than the weight of ball
v2 v2 v images formed by the two mirrors. The 10–4/°C is spinning about its diameter as 2) equal to the weight of ball
a  a 2
= ∫  v + b  dv = ∫ v
dv + ∫ bdv radius of curvature of the convex mirror axis with an angular speed ω. If the 3) 4 times the weight of ball
v1 v1 v 1 (in cm) is temperature of the sphere is increased by 4) 5 times the weight of ball
v2
1
v2 1) 60 2) 50 3) 30 4) 25 100°C , the ratio of new angular speed to Ans: 3
=a∫ dv + b ∫ rdv Ans: 4 original speed is
v
v1 v 1 1 1 1 1) 26:25 2) 25:26 3) 12:13 4) 17:14
Hint: + = ; R = 2f Hint:
= a (log e V )v + b [v ]v2 v u f
v2 v
w2 1
1 1 Ans: 2 Hint: =
w1 1 + 2α∆t
= a [log e v 2 − log e v1 ]+ b (v 2 − v1 ) 19) In determination of velocity of sound by
resonance method the first successive 25) A transistor connected in common emitter As body is moving upwards net weight
v
w = a log e 2 + b (v 2 − v1 )
resonating lengths are 10 cm and 30 cm configuration has input resistance R1 = acts vertically upwards. Viscous force
v1 respectively. The frequency of tunning 2KΩ and load resistance of R0 = 5KΩ. If acts vertically downwards.
fork used is (velocity of sound is 330 m/s, β = 60 and an input signal 12 mV is w1 = Fv Fb – w = F b
17) A particle is placed at the centre of line end corrections are neglected) applied, then power gain is Fv = wl – w = wlg – mg
joining two spherical objects. The lesser 1) 825 Hz 2) 220 Hz 1) 150 2) 900 3) 9000 4) 1500 = vldlg – vsdsg = vsdlg – vsdsg
mass of spheres is 10 kg. The separation 3) 490 Hz 4)294 Hz
R0 d   5d 
between the centres of the spheres is 1 m. Ans: 1 Ans: 3 Hint: Power gain = β ×
2 = vs d s g  1 − 1 = mg  s − 1 = 4mg
R1  s 
d  s
d 
The net force experienced by the particle Hint: Vt = 2n(l2 – l1)
has same magnitude of force exerted by 26) The correct option for getting X=1 from 30) Assertion (A): When two charges of
the smaller sphere on the particle. The 20) An ideal gas is taken through a cyclic the given circuit is same nature are brought nearer to one
minimum speed of projection of the process ABCA as shown. The net work another, their mutual electrostatic
particle so that it escapes out of gravity of done by the gas is potential energy increases.
the two spheres is (G = universal Reason (R): When a charge is moved
gravitational constant) 1) A = C = 0 and B = 1 against Colombian electrostatic force,
120 G m / s 60 G m / s 2) A = B = 1 and C = 0 some work is to be done by the
1) 2)
3) A = C = 1 and B = 0 external agent.
3) 80 G m / s 4) 160 G m / s 4) A = B = C = 0 1) A is true, R is true; R is not a correct
Ans: 1 Ans: 2 explanation for A
1) 2P0V0 2) 3P0V0 2) A is true, R is false
AB = 0 and BC = 1 (or)
Hint: 9P0V0 3P0V0 Hint: 3) A is false, R is true
3) 4) AB = 1 and BC = 0 (or) 4) A is true, R is true; R is a correct
2 2
Ans: 2 AB = 0 and BC = 0 explanation for A
Net force acting on the body = F1 Hint: Work done is area of PV graph. Then output x = 1 Ans: 4 Hint: Conceptual
 10
Ýë„ìS ¿¶æÑ™èl VýS$Æý‡$ÐéÆý‡… 15 H{í³ÌŒæ, 2010

QUICK REVIEW

MATHEMATICS
TRIGNOMETRY A
2 cos = 1 + sin A − 1 − sin A
(
Cos −1 xy + 1 − x 2 1 − y 2 )
2
● Sin4θ + Cos4θ = 1–2sin2θCos2θ ● If 0 ≤ x ≤ 1, 0 ≤ y ≤ 1 Sin–1x + Sin–1y =
3π A 5π Sin −1 (x 1 − y2 + y 1 − x2 )for x2 + y2 ≤ 1
● Sin6θ + Cos6θ = 1–3Sin2θCos2θ If < <
4 2 4
x−y
● Cosθ + Cos(120° – θ) + Cos (120° + θ) = 0 A ● tan–1 x – tan–1y = tan
−1

2sin = − 1 + sin A + 1 − sin A 1 + xy

2
● Cos2θ + Cos2(120°– θ) + Cos2(120° + θ) = 3/2
A x≥0y≥0
● Sinθ + Sin(120 + θ)–Sin(120 – θ) = 0 2 cos = − 1 + sin A − 1 − sin A
2
 −1 x + y
● Sinθ.Sin(60 – θ).Sin(60 + θ) = 1/4 Sin3θ 5π A 7 π tan 1 − xy x ≥ 0, y ≥ 0, xy < 1
If < < then 
4 2 4  x+y
● Cosθ.Cos(60° – θ).Cos(60° + θ) = 1/4Cos3θ tan −1 x + tan −1 y = π + tan −1 , x > 0, y > 0, xy > 1
A  1 − xy
2sin = − 1 + sin A − 1 − sin A
● Tanθ.Tan(60° – θ).Tan(60° + θ) = Tan3θ π
2
 2 x > 0, y > 0, xy = 1
● Sin(A + B).Sin(A – B) = Sin2A – Sin2B A
2 cos = − 1 + sin A + 1 − sin A
2 1− x2 2x 2x
● Cos(A + B).Cos(A – B) = Cos2A – Sin2B ● 2 tan −1 x = cos −1 , x ≥ 0 2 tan −1 x = sin−1 = tan −1 , x <1
1+ x2 1+ x2 1 − x2
π A π
(1 + TanA)(1 + TanB) = 2 If − < < then
4 2 4 2x 2x
● 2 tan −1 = π − sin −1 x = π + tan −1 , x >1
● If A + B = 45° or 225° then (1 – CotA)(1 – CotB) = 2 1+ x2 1− x2
A
2sin = 1 + sin A − 1 − sin A ● If Tan 1 x + Tan 1y + Tan 1 z = π then x + y + z = xyz
_ _ _

2
(1 – TanA)(1 – TanB) = 2
2 cos
A
= 1 + sin A + 1 − sin A _ _ _ π
● If A + B = 135° or 315° then (1 + CotA)(1 + CotB) = 2 2 ● If Tan 1 x + Tan 1y + Tan 1 z = then xy + y z + xz = 1
2
● If A + B + C = 180° then ΣTanA = Π TanA, π
INVERSE AND TRIGNOMETRIC SOLUTIONS ●
_ _
If Sin 1 x+Sin 1y + Sin 1 z=
_
then x2 + y2 + z2+2xyz = 1
ΣCotACotB = 1 2
If Cos 1 x+Cos 1y + Cos 1z=π then x2 + y2 + z2+2xyz = 1
_ _ _

● Principal value of value θ for function sinθ lies between ●

● If A + B + C = 90° then ΣTanATanB = 1, ΣCotA = Π CotA
 −π π  Example
● CotA + TanA = 2Cosec2A  2 ,2
  1.If a, b, c are + ve then
● CotA – TanA = 2Cot2A ● Principal value of value θ for function Tan θ lies between Tan−1
a(a + b + c)
+ Tan−1
b(a + b + c )
+ Tan−1
c (a + b + c)
=
3 bc ca ab
● If A ± B = 60° Cos 2 A + Cos2 B ∓ CosACosB =  −π π 
4  ,  Hint; put a=b=c=1 then
 2 2
π π π
3 Principal value of value θ for function Cosθ lies between Tan−1 3 + Tan −1 3 + Tan− 1 3 = + + =π
● If A ± B = 60° Sin 2A + Sin 2 B ∓ SinASinB = ●
3 3 3
4 [0, π]
● Cos3θ + Cos3(120° – θ) – Cos3(120° + θ) = 3/4Cos3θ ● General solution of Sinθ is nπ+(–1)nα if Principal value
is α 2. cos 2x + a sin x = 2a − 7 has a solution if 'a' belongs to
● Tanθ + Tan(60° + θ) + Tan(120° + θ) = 3Tan3θ
● General solution of Tanθ is nπ + α if Principal value is α Hint; 1 − 2sin2 x + a sin x = 2a − 7
● Sin(A + B + C) = ΣSinACosBCosC – SinASinBSinC ● General solution of Cosθ is 2nπ ± α if Principal value is ⇒ 2sin2 x + a sin x= 2a − 7
α
Cos(A + B + C) = CosACosBCosC – ΣSinASinBCosC General solution of θ if Sinθ = 0 is θ = nπ ⇒sin x = a ± a − 8 (2a − 8) But −1≤ sin x ≤ 1⇒ 2 ≤ a ≤ 6
● ●
2

π
aCosθ + bSinθ = C ⇒ aSinθ–bCosθ = ± a + b − c
2 2 2
● ● General solution of if θ Cosθ = 0 is (2n + 1) 22
2
Period of Sinx, Cosx, Secx and Cosecx is 2π tan 3x − tan 2x
●
● If Sin θ = Sin α
2 2
3. The set of values of x, for which = 1 is
1 + tan 3x tan 2x
● Period of Tanx, Cotx is π Cos2θ = Cos2α then general solution is θ = nπ ± α
Tan2θ = Tan2α Hint ; Because Tan(3x − 2x) = Tan x = 1 ⇒ x = 45°
● Period of x–[x] is '1' For aCosθ + bSinθ = c
●
x = 45° does not satisfies given , thus x = ∅
then solution exists if
● Period of ax–[ax] is 1/a
c ≤ a 2 + b2
4. The equation 3sin x + cos x = 4 has----solutions
● Range of Sinx are Cosx are ± 1
π
Range of aCosx + bsinx + c is c ± a 2 + b2
● sin −1 x + cos −1 x = ,
●
2 Hint : as C ≥ a 2 + b2 No solution exists
Minimum value of a2Sin2x + b2Cosec2x is 2ab −1 −1 π
●
tan x + cot x = ,
2
Minimum value of a2Tan2x + b2Cot2x is 2ab π 1 −1 a  π 1 −1 a 
●
π 5. tan  + Cos  + tan  − Cos =
sec −1 x + cosec −1x =  4 2 b   4 2 b
● Minimum value of a2Cos2x + b2Sec2x is 2ab 2
Tan–1x + Tan–1y + Tan–1z =
● Minimum value of a2Sec2x + b2Cosec2x is (a + b)2
1 a a
tan −1
x + y + z − xyz Hint : put Cos −1 = X ⇒ cos2x =
b
π A 3π 1 − xy − yz − zx 2 b
● If < < then
4 2 4 π π 2 2b
● sin–1(3x – 4x3) = 3sin–1x, cos–1(4x3 – 3x) = 3cos–1x
A
⇒ tan( + x ) + tan( − x ) = 2sec 2x = =
2sin = 1 + sin A + 1 − sin A ● If 0 ≤ x ≤ 1, 0 ≤ y ≤ 1 Cos–1x – Cos–1y = 4 4 cos 2 x a
2
 11
Ýë„ìS ¿¶æÑ™èl VýS$Æý‡$ÐéÆý‡… 15 H{í³ÌŒæ, 2010

QUICK REVIEW

PHYSICS
 
ATOMIC PHYSICS ● Electric Flux: φe = E.S = ES cos θ Wien's Law: λm ∝ orλ mT = b
1 1
● ● Kinetic Energy: mω 2 A2 cos 2 ω t
● e/m of Electron by Thomson method:  1  T 2
● Gauss Law: φe =  Q
e E  ∈0  e
= ●
λ
Kirchoff's Law: a = const = Eλ Total Energy: E = 1 mω 2 A 2
m B2r ● Applications of Gauss Theorem: Electric λ 2
Stefan's Law: E ∝ T ⇒ E = σ T
4 4
● The radius of the circular path in terms of field at a point due to a line charge: ●

Kinetic Energy is r =
2m × K .E E=
λ ● Stefan-Boltzman's Law: E = σ T − T0
4 4
( ) Current electricity
Bq 2π ∈0 r ● Newton's Law of Cooling: ● Current Density: J = i
● Millikan's Oil Drop Method: ● Electric field intensity at a point due to a dθ θ +θ  A
= K  1 2 − θs 
 9 η vg 
1/ 2
thin infinite charged sheet: dt  2  i
r= ● Drift Velocity (Vd) : Vd =
 q σ q
 2 (ρ − σ ) g  E= ;E = where σ = nAe
2 A ∈0 2 ∈0 A
THERMODYNAMICS ● Relation between Time & Drift Velocity:
● Photoelectric Effect: Einstein's photoele- ● Electric field due to a charged spherical W Vd=at
● Joule's Law: J =
ctric equation in terms of λ and λ0: 1 σ .4π R 2 H m l
shell: E = 4π ∈ ● Resistance (R) =
1 1  r2 First Law of Thermodynamics: ne 2t A
K .Emax = hv − w = hv − hv 0 = hc  −  0 ●

 λ λ0  Electric field due to a dipole at a point dQ = dU + dW m

Resistivity ρ = ne 2t
●
●
● Moseley's Law: lying on the axial line (end on position): ● Heat Capacity (or) Thermal Capacity:
vα Z v = a (Z − b ) Eaxial =
1 2 pr
∆Q ● Resistance & OHM'S Law V=iR
c=
(
4πε 0 r 2 − a 2
)
2
Compton Effect: Compton shift ∆T
●
● Specific Resistance S = RA
= λ ' − λ = ∆λ =
h
(1− Cosφ ) ε A 1 ∆Q l
m0C
● Parallel plate capacitor: C = 0 ● Specific Heat: s =
d m ∆T ● Variation of resistivity and resistance with
● de-Broglie Waves (or) Matter waves: If ● Law of mixtures (or) calorimetry Principle: temperature: ρ 2 = ρ1 1 + α (t 2 − t 1)
'm' is the mass and 'V' is the velocity of ELECTROMAGNETISM m1s1t1 + m2s 2t 2 + m 3s 3t 3 ● Variation of resistance of conductor with
t=
the material particle, then ●
µi
Ampere's Law: B = 0
m1s1 + m2s 2 + m3s 3 temperature: R2 = R1 1 + α (t 2 − t 1)
h 2π r Work done in Isothermal Process: Resistances in series and in parallel: If
p = mV λ= ● ●
mV µ0 idl sin θ V  resistors of resistances R1,R2,R3... are
● Biot - Savart's Law: dB = W = 2.303 RT log 10  2 
4π r2  V1  connected in series, the resultant resistance
NUCLEAR PHYSICS ● Filed due to a straight conductor: ● Work done in Adiabatic Process: R=R1+R2+R3+...
Size of the nucleus: R = R0 A
1/3
µ 0i nR
●
B= (Sin θ1 + Sin θ 2 ) W= (T1 − T2 ) ● If resistors of resistance R1,R2,R3... are co-
● Mass Defect: 4π r γ −1 nnected in parallel, the resultant resistance
  W 1 1 1 1
∆m   ZM p + ( A − Z )M n  − M nucleus  ● Tangent Galvanometer: I =  2rBH  tan θ ● Efficiency of Heat Engine: η = or R is given by = + + + ......
 µ0 n  Q1 R R1 R2 R3
Binding Energy: [∆m ]C
2
Force Experienced by a current carrying Q1 − Q2 Q T If resistances R1 and R2 are connected in
● ●
∴η = = 1 − 2 = 1− 2 ●

Packing Fraction of a nucleus: conductor placed in a magnetic field: Q1 Q1 T1 R1R2

●
parallel, the resultant resistance R =
R1 + R2
Packing fraction = ∆m F = BiL
A ● Force Between two infinitely long SIMPLE HARMONIC MOTION ● If 'n' wires each of resistance 'r' are connec-
● For any radio active substance, radio parallel conductors carrying current: ● Displacement: y = A sin ωt ted to form a closed polygon, equivalent
active disintegration equation is µ0i1i2l A resistance across any two adjacent corners
F= ● Amplitude(A): y = A sin (ωt + φ ) y =
2π r
is R =  n − 1  r
2.303 N 2
λ= log 0
t N ● Current loop as a magnetic dipole: from mean position.  n 
● The half life period of a radio active µ0 nir 2 Velocity: v = ω A2 − y 2 ● 12 wires each of resistance 'r' are conne-
B= 3
●
substance is represented as cted to form a cube. Effective resistance
0.693 (
2 r + 2
x2 2) 4A across
t1/ 2 = ● Average Speed: Vavg =
λ ● Torque on a current carrying coil in a T ● Diagonally opposite corners = 5r/6
uniform magnetic field: ● Acceleration: a = −ω 2
y ⇒ a ∝ −y ● face diagonal = 3r/4
ELECTROSTATICS τ = nIAB cosθ = MB cosθ 2π ● two adjacent corners = 7r/12
● Time Period: T =
● Coulomb's Law & Force due to Multiple ● Shunt: Effective resistance of the circuit ω ● If two wires of resistivities S1 and S2,
1 q1q2 GS lengths l1 and l2 are connected in series, the
Charges: F = is, ● Frequency: n=
1 a
4π ∈0∈r d 2 G+S 2π y equivalent resistivity
● Coulomb's Law in Vector Form: Ammeter: S =
I gG ● Simple Pendulum: Time Period of a simple S1l1 + S 2l 2
● S=
1 q1q2 I − Ig l l1 + l 2
F= rˆ12 pendulum T = 2π
4π ∈0 r22 V g  E −V 
● Voltmeter: R = −G Internal resistance of a cell r =  R
 V 
●
1 Q Ig Spring Mass System: When the load is
● Electric Field: E0 = ●
4π ∈0 d 2 pulled down and released, it makes vertical nE
● Electric Cells Series : i =
Electric Potential: Potential at a point due HEAT R + nr
●
oscillations T = 2π M
1 Q Coefficient of Thermal conductivity: k .
to a point charge = ●
Electric Cells in parallel: i =
nE
4π ∈0 r KA (θ1 − θ 2 ) ● If the spring mass is considered
●
nR + r
Q= t
● Relation among E, V and d in a uniform l m V 2t
M+ ● Electrical Energy: =
v ● Effective conductivity: Series T = 2π 3 R
electric field is E = 2K1K 2 k
d combination: K = V2
K1 + K 2 ● Electric Power: P = watt (or) joule/ sec
● Potential Energy of System of ● Energy of a Simple Harmonic Oscillator - R
1 Q1Q2
Charges: U =
4π ∈0 d
● Parallel Combination: K = K1 + K 2 Potential Energy: P = 1 mω 2 A2 sin 2 ωt
● Wheatstone Bridge: When the bridge is
2 2 balanced, then P/Q = R/S
 12
Ýë„ìS ¿¶æÑ™èl VýS$Æý‡$ÐéÆý‡… 15 H{í³ÌŒæ, 2010

QUICK REVIEW

CHEMISTRY
● Since ∆p = m∆v where ∆v = error in ● Units a = atm.lit2.mol–2; b = lit.mol–1 a
ATOMIC STRUCTURE velocity. The above expression can be 'a' is a measure of intermolecular force of ● Boyle's temperature = TB =
● Angular momentum of an electron in an Rb
h attraction. Greater the value of 'a' stronger
written as ∆ x .m ∆ v ≥ The temperature below which a gas
●
h (or) are the intermolecular forces and greater is
orbit = n 2π the ease with which it can be liquified.
undergoes cooling and above which it
2π undergoes heating on expansion (Joule
h 'b' is measure of volume occupied by gas
● Angular momentum of an electron in an ∆x . ∆v ≥ molecules. Greater the value of 'b', smaller
Thomson effect) is called inversion
h 4πm temperature (Ti)
orbital =
(
+ 1). =
(
+ 1). is the compressible volume
2π 1) At high pressures, 2a
STATES OF MATTER Ti =
● Spin angular momentum ● Graham's law :  a  Rb
h  h  PV = RT + Pb  2 is negligible 
= s (s + 1). V  For Cubic crystal, a = b = c; α = β = γ = 90°
 = r1 M2 d V.D 2 ●
 = = 2 =
2π  2π 2) At moderate pressures,
r2 M1 d1 V.D1
a
● Bragg's law, nλ = 2d sin θ , the angle of
● de Broglie wavelength : PV = RT − (b can be neglected) diffraction = 2θ
h h P1 M2 n M2 V
λ= λ= = = 1 . ● Density of lattice matter
P2 M1 n2 M1 PV
2mE 2mQV ●
Compressibility factor = Z = Z× M
nRT (D) =
λ1 n1 N o .a 3
= 2πr = nλ w1 t1 M1
= .
1) For ideal gas : Z = 1
λ2 n 2 w 2 t2 M2 2) For real gas : Z ≠ 1 ● Z = number of atoms per unit cell
If Z > 1 → Positive deviation ● M = molecular mass, No = 6.023 × 1023, a
λ n = 3.3 × n Å ● Gases behave ideally at low pressure and If Z < 1 → Negative deviation = edge length
∈ = kinetic energy, Q = charge high temperature, while they deviate from
Critical Constants :
ideal behaviour at high pressure and low 8a a
(coulombs), V = potential difference, n = Atomic radius (r) :
principal quantum number of orbit
temperature. TC = ; PC = ; VC = 3b
27Rb 27b 2 a
Vander waal's equation Simple cubic cell = r =
●
●
● At critical state, the value of 2
HEISENBERG'S UNCERTAINITY  n2 
PRINCIPLE →  P + a 2  (V − nb ) = nRT compressibility factor (Z) for 1 mole of gas a
 V  is approximately constant ●
F.C.C = r =
h 2 2
● ∆ x . ∆p ≥ where ∆x = Error in .... for 'n' moles PC VC 3
4π Z= = = 0.375
'a' and 'b' are vanderwaal's constants. RTC 8 3
position, ∆p = error in momentum ● B.C.C = r = a
4
QUICK GLANCE OF INORGANIC PREPARATIONS ● Distance between nearest neighbours = 2 ×
Element or Process Chemicals used (Raw Principle Additional Information radius
compound materials)
1) Na2CO3 Leblanc NaCl, Conc. H2SO4 , Lime 2NaCl + H2 SO4 → Na2SO4 + 2HCl → Na2 CO3.10H2O is formed AB AB AB ..... hcp
stone Na2 SO4 + 4C → Na2 S + 4CO → Na2 CO3 + CaS is called black ash ABC ABC ABC .... ccp
Na2 S + CaCO3 → Na2 CO3 + CaS (Black ash) Coordination number in both hcp and ccp
2) Na2CO3 Ammonia-soda or Brine soln, Lime stone, NH3 + H2 O + CO2 → NH4HCO3 → By product is CaCl2 is '12' . In a close packed structure of 'N'
Solvay process Ammonia NaCl + NH4 HCO3 → NaHCO3 + NH4 Cl → NH3 & CO2 are recycled
(Carbonation tower) During ammonia regeneration spheres, there are '2N' tetrahedral holes and
2NaHCO3→ Na2 CO3 +H2 O + CO2 Ca(OH)2 + 2NH4 Cl → CaCl2 + 2NH3 + 2H2O 'N' octahedral holes.
3) Na2CO3 Electrolytic Brine solution, CO2 2NaOH + CO2 → Na2 CO3 + H2O Type of cell % of space
4) NaHCO3 1) Solvay process NaHCO3 is less soluble than Na2CO3 occupied
2) From Na2 CO3 Na2 CO3 + H2O + CO2 → 2NaHCO3
5) Mg Hansging MgO & Coke The Mg & CO thus formed are quenched in a 1) Simple cubic 52.4%
20000 C
MgO + C Mg(g) + CO(g) chamber maintained at 200°C by using H2 or unit cell
<20000C natural gas. Mg is solidified, and is purified 2) f.c.c. (c.c.p) 74% - efficient
by distillation in vaccum.
6) Mg Chemical reduction MgO + Si or FeSi or CaC2 2MgO + Si → 2Mg + SiO2
3) B.C.C. 68%
3MgO + FeSi → 3Mg + FeSiO3 NaCl structure
3MgO + CaC 2 → 3Mg + CaO + 2CO 
Pr essure
← →
6 : 6 Coordination number 760K
7) Mg From sea water Sea water + Ca(OH)2 MgCl2 + Ca(OH)2 → Mg(OH)2 ↓ + CaCl2 Mg present in sea water is precipitated as
MgSO4 + Ca(OH)2 → Mg(OH)2 ↓ + CaSO4 Mg(OH)2 by treating with slakedlime
(Ca(OH)2), then is treated with HCl to get CsCl
MgCl2 from this Mg is extracted by
electrolytic method (8 : 8Coordination number )
8) B2 H6 Industrial process → 2BF3 + 6LiH →B2 H6 + 6LiF
Lab method → 3LiAlH4 + 4BCl3 → 2B2H6 + 3AlCl3 + 3LiCl
Silent No.of unit cells in given weight (x) of
2BCl3 + 6H2 Electrical B2H6 + 6HCl
discharge substance
9) Graphite Acheson’s process Silica, Coke 3C + SiO2 → SiC + 2CO↑ SiC → Carborundum x
compound materials) SiC → Si + C (graphite) ● NaCl : ×N
10) Producer gas Coal and Air C + O2 → CO2 + 394kJ 33% CO + 64%N2 + 3%CO2 4 × Gmw of NaCl
CO2 + C → 2CO – 163kJ – endothermic It has low calorific value due to greater % of
x
2C + O2 → 2CO + 231kJ N2
It must be used immediately after preparation
● CsCl : ×N
Gmw of CsCl
11) Water gas Coal, air, steam C + H2 O → CO + H2 – 121.22kJ – Endothermic 40-50% CO + 45-50%H2
Blue gas, or synthesis gas x
The reaction to be avoided is ● ZnS : ×N
C + 2H2O → CO2 + 2H2 4 × Gmw of ZnS
12) Semi water Coal, air, steam By passing air & steam in proper proportion over red 10-12%H2 + 25-28% CO + 50-55%N2 +
gas hot coke 1-15%CH4 x
13) Carburetted Water gas + Hydrocarbons 30-40% H2, 15-20% saturated hydrocarbon ● CaF2 = ×N
water gas 10-15% unsaturated hydrocarbon 4 × Gmw of CaF2
18-20% CO, little CO2, N2
Ca(OH)2 + Cl2 → CaOCl2 + H2 O x
14) Bleaching Bachmanns Slaked lime & Chlorine It works on the principle of counter currents. ● Na 2 O = ×N
powder (CaOCl2) Bleaching powder is a mixed salt.
4 × Gmw of Na 2O