Professional Documents
Culture Documents
Abstract. The disposal and treatment of hazardous industrial waste is very costly affairs for the
industries, it has been a dormant issue. The new millennium brings challenges for the civil and
environmental engineers and opportunities for research on the utilization of the solid waste and
by-products and basic properties of concrete and its materials. The recycling of waste and by-
products attracts an increasing interest worldwide due to the high environmental impact of the
cement and concrete industries. Normal concrete is manufactured using sand and stones, but
lightweight concrete can be made by using industrial by-products and hazardous solid wastes
such as expanded fly ash, slag, sludge, etc. The Best Demonstrated Available Technology (BDAT)
stabilization/solidification (S/S) can be used for treatment of concrete contaminated solid hazard-
ous wastes and by-products. The performance of concrete is measured in terms of physical, engi-
neering, and chemical properties.
The review describes how chemical and mineral admixtures help in the improvement of the light-
weight concrete properties. Cement is replaced by the 15-35% fly ash in the concrete mix. Fly ash
increases concrete strength, improves sulfate resistance, decreases permeability, reduces the
water ratio required, and improves the workability of the concrete. Partial substitution solid hazard-
ous waste does not strongly affect the strength of concrete and other properties. This mixed light-
weight concrete is safe enough to be used in sustainable environmental applications, like road-
beds, filling materials, etc.
Fig. 1. Relationship of mix proportion with strength & W/C ratio, workability & water, cost &cement. Data
from [25].
able disposal methods. The industries are trying to The extensive use of fly ash, which is abundant
reuse solid waste material on the construction sites in India, to meet the current construction demands
[6,7]. and to decrease the environmental damage. In the
In recent years, the utilization of solid waste is past decades concrete vastly used in mega con-
the challenge for the civil and environmental engi- struction project in the country. [11]
neers to utilize economic friendly supplementary
cementitious materials produce at reasonable cost Objective of review
with the low possible environmental impact. The
use of Supplementary Cementitious Materials Review focused on utilization of industrial solid
(SCM) for e.g. Fly Ash (FA), Granulated Blast Fur- wastes and by–products (heavy metals bearing)
nace Slag (GBFS), Silica Fume (SF), Activated as concrete ingredients and also discussed the
Metakaolin (AM), etc. which can improve various mechanical and chemical properties of concrete
properties in fresh and hardened state of concrete through solidification/stabilization process.
and also increase the cost of construction. It is now
the global concern to making economic friendly ma- 2. CONCRETE
terial product at lower cost with less harmful effect Concrete is an artificial conglomerate stone made
on environment [8]. Addition of cost saving materi- essentially of Portland cement, water, sand, and
als by the replacement of considerable amount of aggregates. The mixing of all the materials is placed
cement reduces CO2 emission during the manu- into a plastic form; a chemical reaction called hy-
facturer of Portland cement [9,10]. dration takes place between the water and cement,
In India around 960 millions tonnes of solid and concrete normally changes from a plastic to a
waste is being generated annually as by-products solid state in about 2 hours. Theoretically, if kept in
during industrial, mining, municipal, agricultural, a moist environment, concrete will gain strength in
and other processes. It is important to use develop practical terms (about 90%) in the first 28 days.
technologies for the utilization of solid waste con- The product cannot be treated as concrete unless
sumption in concrete. Concrete preferred for con- all these steps are realized [14 -21].
struction, which is very durable require little or no
maintains. The assumption is largely true except
2.1. Chemistry of concrete
when it is subjected to highly aggressive environ-
ment. We build concrete structure in high polluted Concrete industry is particularly important, since it
urban and many other hostile conditions where is not only responsible for consuming natural re-
other construction materials are found to be non- sources and energy, but also for its capacity of
durable. Recently the uses of sludge in concrete absorbing other industrial waste and by-products.
have spread it to highly harsh and hostile condition
Ordinary Portland Cement + H2O + Sand + Aggre-
[11-13].
gates → Hardened Concrete + Energy (Heat)
44 Smita Badur and Rubina Chaudhary
sand, and shale. Minimum cement content in con- Table 1. Color and water absorption in different
crete is 1 m3 [21]. type sands.
of cement, 2 parts of sand, and 4 parts of aggre- secondary Calcium Silicate Hydrated (CSH) gel
gate by volume. The problem is that the quality of [45].
sand and aggregate vary greatly from one place to Placing of concrete is also very important pro-
another. Therefore, the same ratio of 1:2:4 can’t cess. It is the process of transferring of fresh con-
be expected to give a good quality of concrete with crete from the mixing or conveying device to its
different types of sand and aggregate. The materi- final place in the forms. The method of placing
als should always be measured by weight to pre- should be such that segregation, displacement of
pare concrete. A richer concrete, that is, a con- forms avoided. Prior to placing loose rust must be
crete with a higher cement ratio is stronger and removed, forms must be cleaned, and hardened
more durable [20,36-40]. surfaces of previous concrete lifts must be cleaned
K. Srinivasa Rao et al. [41] showed that a High and treated appropriately [20,31,36-40].
Strength Concrete (HSC) which was develop by The strength of concrete is strongly dependent
ACI mix design method was used to achieve a mix upon the hydration reaction just discussed. Water
with a compressive strength of 60 MPa. Mix pro- plays a critical role, particularly the amount used.
portion used was 1:0.94:1.35 and W/C ratio 0.25, The strength of concrete increases when less wa-
the size and shape of concrete were cube ter is used to make concrete (Fig. 3). The hydra-
(150x15x150 and 100x100x100 mm) and cylinder tion reaction itself consumes a specific amount of
(300x150 mm). This concrete was tested by differ- water [23].
ent parameters on different ages (1, 3, 7, 28, 56,
91 Days). Small change in compressive strength 2.5.2. Durability [freezing thawing
after 28 days and no change in compressive resistance].
strength after 56 days were reported.
Durability is the ability of concrete to resist weath-
ering action, chemical attack, abrasion and/or any
2.5. ENGINEERING PROPERTIES OF
other process of deterioration. Durable concrete
CONCRETE will retain its original form, quality, and serviceabil-
2.5.1. Unconfined compressive ity when exposed to its environment. Factors re-
strength (ucs) sponsible for aggravating or deterioration of con-
crete are: freezing and thawing, aggressive chemi-
Unconfined compressive strength depends upon cal exposure, abrasion, corrosion of metals and
many factors, including the quality and proportions other materials embedded in concrete, alkali ag-
of the ingredients and the curing environment. The gregate reaction, high temperature and poor work-
most important indicator of strength is the ratio of manship [21].
the water used compared to the amount of cement. The durability of concrete refers to the extent to
Basically, the lower this ratio is, the higher the final which the material is capable of resisting deterio-
concrete strength will be. (This concept was de- ration caused by exposure to service conditions.
veloped by Duff Abrams of The Portland Cement Concrete is also strong and fireproof. Ordinary
Association in the early 1920s and is in worldwide structural concrete that is to be exposed to the el-
use today). A minimum W/C ratio (water to cement ements must be watertight and weather resistant.
ratio) of about 0.3 by weight is necessary to en- Concrete that is subject to wear, such as floor slabs
sure that the water comes into contact with all ce- and pavements, must be capable of resisting abra-
ment particles (thus assuring complete hydration). sion. The major factor that controls the durability
In practical terms, typical values are in the 0.4 to of concrete is its strength. The stronger is the con-
0.6 ranges in order to achieve a workable consis- crete, the more durable it is. The chief factor con-
tency so that fresh concrete can be placed in the trolling the strength of concrete is the water-cement
forms and around closely spaced reinforcing bars ratio. However, the character, size, and grading
[21,25]. Compressive strength depends on the (distribution of particle sizes between the largest
curing time [42,43]. Concrete showed small change permissible coarse and the smallest permissible
in compressive strength after 28 days and no fine) of the aggregate also have important effects
change after 56 days [41]. Strength enhancement on both strength and durability [25]. Both time and
of gravel reaches 97% at the 2.8% volumetric ra- temperature to bulk transport properties, which di-
tio. The roundness of aggregate assists to distrib- rectly influence concrete durability. For pavements,
ute the lateral confinement and helps the concrete permeability and durability are intimately connected
element to experience higher stress [44]. The [46].
strength is increases because the formation of
48 Smita Badur and Rubina Chaudhary
Fig. 3. Concrete strength as a function of the water to cement ratio. Data from [23].
sorption ratio increases too, while compression sign of 2:1 with 15% fly ash was found to be the
strength and freeze–thaw resistance decreases. intermediate condition to have satisfactory com-
However, these losses are under limit values; so, pressive strength [2,62].
the standards allow up to 30% replacement ratio The addition of pozzolans or slag modified the
[50]. microstructure. The outer CSH appeared less fibril-
Heavy metals like Pb, Cd, and Cu leachate con- lar and the cement matrix was less porous at ear-
centrations were below the analytical detection limit lier ages with use of silica fume or metakaolin. The
of atomic absorption spectrophotometer (AAS). effect of this was a reduced rate of leaching of the
Higher concentrations were measured for Cr, Zn, alkali hydroxide from the pore fluid, with which the
and Fe. The quantity of Cr, Zn, and Fe leached silica fume specimen appeared to slow the expan-
tended to increase when the initial concentration sion process, but did not prevent expansion [63].
of these metals and leachate pHs were growing. Another study was performed to assess whether
For higher loading percentages, the Cr leached was the Stabilization/Solidification (S/S) technology can
above U.S. EPA limits [45]. be applied for treatment of “real” refinery oily sludge
Partial substitution (15% or 30% by mass) of contaminated by heavy metals. The performance
cement by Sewage Sludge Ash (SSA) does not of stabilized wastes is generally measured in terms
strongly affect the strength of mortars cured at 40 of leaching and extraction tests. The samples were
°C for 3- to 28-day curing periods. High sulfur con- cured at approximately 24 °C in the laboratory for
tent in SSA does not have a decisive influence on 28 days [64]. As a result, the effects of replace-
strength development. Fineness of SSA is an im- ment of cement (by mass) with three percentages
portant parameter for strength development of of fly ash and the effects of addition of natural san
SSA/cement mortars: the coarsest fraction yields fibers on the different parameters and impact
the lowest strength values. SSA showed a greater strength of fly ash concrete. San fibers belong to
or similar contribution to mechanical development the category of ‘‘natural bast fibers.’’ It is also known
than fly ashes at early ages, but they become less as “sunn hemp”. A control mixture of proportions
efficient for longer term curing. CSGr and FSGr 1:1.4:2.19 with W/Cm of 0.47. Cement was re-
increased remarkably with increasing SSA replace- placed with three percentages (35%, 45%, and
ment [60]. 55%) of class F fly ash. Three percentages of san
In this study sewage sludge was used as an fibers (0.25%, 0.50%, and 0.75%) having 25-mm
additive in order to develop new construction ma- length were used. Addition of san fibers reduced
terials. For this purpose, several mixtures of sludge the workability; did not significantly affect the com-
cement calcium chloride and calcium hydroxide pressive strength; increased the splitting tensile
were prepared and Stabilized/Solidified (S/S). Cal- strength and flexural strength, and tremendously
cium chloride and calcium hydroxide were used enhanced the impact strength of fly ash concrete
as accelerating additives. XRD and SEM studies as the percentage of fibers increased [65].
were performed to determine the hydration prod- This study also investigated the possibilities of
ucts. The specimens were tested in order to deter- plain concrete containing dry sludge. The S/S
mine their setting time and compressive strength mechanisms for sludge from treatment plants in a
after 28 days. Furthermore, in order to investigate Portland cement matrix have previously been
the environmental compatibility of these new ma- evaluated in [1, 5-7,66].
terials, Toxicity Characteristics Leaching Procedure
(TCLP) and CEN/TS 14405 tests were carried out 3.3. Admixtures
for the determination of heavy metals leaching [61].
Jarosite released from zinc metal extraction Industrial waste works with Mineral admixtures in
process is hazardous in nature. Statistically de- concrete are summarized in [67].
signed experiments on S/S sintered jarosite CCRs Mineral admixtures used in concrete were fly
products confirmed that the compressive strength ash, metakaolin, GGBS, and silica fume since
of jarosite bricks reached as high as 140 kg/cm2 many important structures built with silica fume in
with 14.5% water absorption capacity at the com- concrete are used for durability aspects [68].
bination of 3:1 ratio of jarosite and clay, respec- S. Asavapisit and D. Chotklang [45] investigated
tively, but, concentrations of all the toxic elements the potential for utilization of alkali activated (Pul-
recommended by U.S.EPA TCLP standard are not verized Fuel Ash) PFA as solidified binder to treat
within the permissible limits. The optimum mix de- electroplating sludge. The early strength develop-
Utilization of hazardous wastes and by-products as a green concrete material through... 51
Concrete is one of the most important construc- results indicating that the strength decreased ap-
tion materials. It is comparatively economical, easy preciably as the proportion of sludge increased. For
to make, offers continuity and solidity, and can be all the different mixtures, the compressive strength
effectively bonded with other materials. The keys after 28 days increased in comparison with that of
to good quality concrete are the raw materials re- the previous period, but not uniformly. After 90 days,
quired to make concrete and the mix design as the compressive strength had recovered and, for
specified [24]. The test results indicated that the example, the specimens containing 10% sludge
replacement of cement with fly ash increased the reached 58% of the compressive strength of the
workability (Slump and Vebe time), decreased com- reference concrete, and those containing 2.5%
pressive strength of plain (control) concrete [65]. sludge reached 78% of the reference value [66].
rous material obtained by solidification of PbO and of the S/S wastes depends mainly on the type of
CdO with Portland cement. In order to determine waste and, to a lesser degree, on the type of binder
the influence of laboratory leaching conditions on agent, since cement types for each S/S waste re-
the release of different chemical species (NaC, KC, veal similar behavior to each other. The pH of the
Ca2C, Pb2C, Cd2C, and SO2K4) contained in a po- leachate produced from a S/S waste is directly af-
rous reference material obtained by solidification fected by the ANC of the waste. Since heavy metal
of PbO and CdO with Portland cement. This ap- leaching is pH dependent, the ANC test might con-
proach allowed assessing the pH influence on the stitute a rapid qualitative prediction method for po-
dissolution of pollutants and the initial pore solu- tential leaching of metals contained in the waste
tion composition were assessed by applying a [64].
methodology consisting of two equilibrium leach- The author performed time dependent diffusion
ing tests, the ANC and the Pore Water (PW) tests test. The diffusion coefficients (m) values for the
and geochemical modeling. The influence of the concretes with various replacement levels of silica
sample shape (monolithic) and elute hydrodynam- fume and slag. The results for the time dependent
ics on the leaching of the target elements was also diffusion coefficients based on total time, or mtotal
assessed. The comparison criteria were the elute values. The total time method yields the lowest m
saturation state, the cumulative release, and the value, while the effective time approach of Stanish
released flux. It would conduct that evaluate a par- and Thomas yields the highest. The initial diffu-
ticular concrete formulation before predicting its sion coefficients (28 day) are equal, but the sec-
performance in a special acid environment is nec- ondary hydration effect in concrete containing blast
essary. At least, under certain circumstances, the furnace slag leads to a greater reduction in diffu-
addition of FA, SF, or MK can improve the acid re- sion with time. The determination of diffusion coef-
sistance of concrete [74]. ficients and their time dependant behavior has an
The solidified refinery oily sludge waste sample evident effect on the estimated time to corrosion
was ground to pass a 150 mm sieve. Each sample [80,81].
was subdivided into 11 sub samples, each of 3 g in
weight. Each sub sample was placed in increasing 3.6.2. Porosity and permeability
amount of nitric acid (2N). Then the samples were
tumbled strongly at room temperature for 48 h to Permeability is closely related with strength and W/
reach equilibrium. The acid neutralizing capacity C ratio. Micro cracks in the initial stage are so small
that they may not increase the permeability. But
Table 2. Factors influencing developed concrete with differrent wastes and by-productes.
54
S. No. Type of waste Waste or Curing days Admixture Admixture % Water/Cement Waste/Binder Compressive References No.
or by-products by-products % Ratio Ratio Strength (MPa)
1. Fly ash 20 7,28 Silica fume, Metakaolin 10, 30 0.33 0.2 108-127 82 (HSC)
2. Fly ash 20 7,28 Metakaolin 20 0.40 0.2 58.4 (NSC)
3. - - 7,28 CaCl22H2O 10-30 0.36-0.40 - 1100 (kPa) 60
Ca(OH)2
4. Fly ash 16.5 g 7,28 Silica fume, Metakaolin 16.5 g 0.4,0.45 0.6,1.6 72-90 73
5. RHA, PA 10 - 30 1,3,7,28, Cr(OH)3, Fe(OH)3, >25 0.45-0.70 0.1-0.3 89.37 106
51,90,180 Zn(OH)3
6. SA, SMW 20 3,5,7,21,28, Ca(OH)2,lime stone 80 0.38 0.2-1 70-100 93
28,51,90
7. PFyA 70 1,3,5,7,21, Lime, Na2SiO3, Na2CO3 30, 4, 8 0.5 0.1-0.5 67–200 79
28.51,91
8. Fly ash 40 - 60 7,28 Superplasticizer 4.5-5.1 0.32-0.42 0.68,1,1.5 41 54 (HSC)
liters/cu.yd
9. Fly ash, Slag 57, 8 - 35 13,5,7,21,28, Silica fume 7, 8, 12 0.30±0.01 1.3,0.4,0.5, 0.08 87.5-112.3 10
51,91,151,
265-3650
10. GBFS, Fly ash 15 - 60 7,14,28 - - 0.3-0.4 0.42 15.91-51.48 51
11. GBFS, BA 20 - 50 28 Silica fume, waste glass 2.08,2.04 0.5,0.32,0.47 4.1-4.8 42.5 50
12. Electroplating 25 7, 28 Lime 10 1 0.5 35 108
sludge
13. - - 3 - 28 NaCl, Al2O3 3, 10 0.6 - 36.67 43
14. Hazardous 10, 25 28 Clay 25, 40, .45 - .65 0.1, 0.25 250 Kg/m2 104
Wastes, Fly ash 50, 90
Captions: HSC = High Strength Concrete, NSC = Normal Strength Concrete, EAF = Electrical Arc Furnace, BFS = Blast Furnace Slag, SA = Sludge Ash, RHA = Rice
Husk Ash, PFyA = Pulverize Fly Ash, SMW = Steel Making Waste, PA = Plating Sludge, BA = Bottom Ash, GBFS = Granulated Blast Furnace Slag, PFuA = Pulverized
Fuel Ash, GFA = Ground fly Ashes
Utilization of hazardous wastes and by-products as a green concrete material through... 55
propagation of micro cracks with time due to dry- concrete durability. ASHTO T-227 Concrete and
ing shrinkage and externally applied load will in- stripped mortar samples are taken from concrete
crease the permeability of the system [21]. Some mixtures cured for 28 days. A mortar shows higher
of the wastes and by-products also participate in chloride permeability in addition at constant cement
the structure of concrete. BA and GBFS increase content; the charges passed increase with decreas-
workability and carbonation depth and decreases ing the volume of sand in the mortar. At constant
chloride permeability [50]. cement content, there is a direct correlation be-
A model has been developed for relating po- tween the charge passed through concrete and the
rosity to permeability. It was determined that a lin- fine sand to coarse aggregate ratio. Higher W/C
ear combination of lognormal distributions can be ratio gives higher charge passage through both
used to describe pore structure. One of these dis- concretes and mortars. Chloride permeability takes
tributions describes small pores, while the remain- place primarily through the cement matrix [46]. The
ing two describe porosity through which bulk trans- effects of various pozzolans and water to cement-
port. The pore structure is very important for the ing materials ratios are clearly seen in the chloride
prediction of permeability. The results show that diffusion values presented. Initial chloride diffusion
permeability increases with temperature [70]. The values are higher in concrete mixtures at the higher
basic trend concerning the increase of porosity with water to cement ratio of 0.40 without the addition
temperature was confirmed and the values of po- of pozzolans. The chloride diffusion coefficient re-
rosity determined by both methods were closer to duces more dramatically in concrete mixtures con-
each other with an increase of temperature. The taining pozzolans showing their long-term hydra-
most dramatic increase in porosity was observed tion properties [80].
at 600 °C in mercury porosimetric measurements. The experimental work included in the current
The values of porosity at 1200 °C were the same program was directed towards assessment of re-
for the water vacuum saturation method and mer- sistance of concrete to chloride permeability. The
cury porosimetry. This indicates a significant results are expected to be useful in connection with
change of structure and disappearance of major water permeability. The technique is similar to that
cracks not detectable by mercury porosimetry [82]. described in method for measuring the chloride
According to Sandrolini and Franzoni [81], fine permeability under the effect of electric field [84].
filler effects and actual W/C ratio reduction due to
fine solids contents in sludge water leads to the 3.6.3. Sulphate corrosion
reduction of concrete capillary water absorption and
porosity, and possibly improves the durability of The S/Ca (Sulphate/Calcium) ratios are much
concrete. The porosity increased with an increase higher than those of 0.01–0.04 commonly found in
of sludge content and tends to decrease as the pastes cured at ordinary temperatures [85,86].
age of the concrete increased from 7 to 90 days. Most of the Al3+ present in the CSH appears to
The hardening of concrete has an effect of binding be primarily substituted for Si4+, [87,88] whereas
the particles, which over time, decreases the num- the sulphate incorporated into the CSH adsorbed
ber of pores [66,84]. [89]. With moist storage, sulphate can be desorbed
Poor dispersion and inhomogeneity during mix- from the CSH. The mean S/Ca ratio of the CSH
ing and placing may cause the cement particles to formed during the heat curing typically decreases
coagulate and cluster in the mix water, resulting in to values of about 0.02–0.03 during storage
alternating regions of dense and high porosity hard- [87,90,91] which is similar to that of the CSH that
ened paste, even in instances where the use of a forms later. A significant amount of sulphate was
low W/C ratio was intended to provide an ultimately taken up by the CSH during heat curing, both with
high density microstructure [85]. The water not con- mixtures containing only Portland cement as the
sumed in the hydration reaction will remain in the binder and with partial amounts of SF, MK, BFS,
microstructure pore space. These pores make the and FS. The CSH acts like a cache and this sul-
concrete weaker due to the lack of strength form- phate was later released when the specimens were
ing CSH bonds [23]. exposed to moisture at ambient temperature [92].
Higher percentages of metakaolin decrease the
corrosion resistance [73]. Sodium sulfate attack
3.6.2.1. Chloride permeability
of portland cement paste (15 mmol/l) has been
The resistance to chloride ion penetration and presented by the author. Surface abrasion is an
transport of concretes is an important feature for
56 Smita Badur and Rubina Chaudhary
important durability characteristic for paving blocks strength of the concrete is related to the water to
[50]. cement mass ratio and curing conditions. A high
The author discussed that calcium leaching in water to cement mass ratio yields a low strength
sulfate environment presents similar kinetics with concrete. This is due to the increase in porosity
respect to calcium leaching in pure de-ionized wa- (space between particles) that is created with the
ter. The precipitation of significant quantities of hydration process. Most concrete is made with
ettringite and gypsum resulted in, the breakdown water to cement mass ratio ranging from 0.35 to
of samples in presence of sulfates. Cracks were 0.6. Time is also an important factor in determin-
found predominantly in zone 2, perpendicular and ing concrete strength. Concrete hardens as time
parallel to the attacked surface, and partly filled passes. Remember that the hydration reactions get
with gypsum. The initiation of cracking and failure slower and slower as the tricalcium silicate hydrate
of the samples was found to depend significantly forms. It takes a great deal of time (even years) for
on their thickness. The proper estimation of the all of the bonds to form, which determines
service life of concrete structures to sulfate attack concrete’s strength. It is common to use a 28-day
must therefore account for these marked scale test to determine the relative strength of concrete
effects [93]. [23].
G. Appa Rao [94] in discussed the water/ce- out the need to determine the degree of cement
ment ratio negative effect on compressive strength. hydration of concrete under investigation [34].
Adopted cement/sand ratios were 1:2, 1:2.5, 1:3
and the water/cement ratio was from 0.30 to 0.65. 5. DISCUSSION
The compressive strength was measured at the
age of 3, 7, 28 days. Mainly W/C ratio is influenced Landfilling is not a desirable option for the disposal
the strength of concrete. The W/C ratio described of solid hazardous waste materials. It is not a li-
the strength of concrete described by the “Abram’s able method because of future environmental costs
W/C ratio law”. Compressive strength decreases and problems associated with landfilling regulations
as the C/S ratio and the w/c ratio increases. [99]. This method increases load of toxic metals
and other contaminants in the landfill, potentially
increasing the threat to ground water contamina-
4.3. Water absorption percentage tion. Increasing economic and financial factors also
Water absorption percentage is an effective pa- dictate that industry should look forward to recy-
rameter for pure and mixed concrete. In the mixed cling and reuse of waste material as a better op-
concrete it is very important. Waste absorption tion to landfilling [100].
percentage depends on the type of waste. Water Wastes and by-products can be used in addi-
adsorption percentage increases with the increase tion to concrete without the need for large changes
of waste (Table 1)[50,63]. Water absorption re- in its preparation. Its granulometric properties indi-
duces the fine solid content and improves durabil- cate that it can be used in fine sand in production.
ity [83]. Waste content of 10% or more cannot be used
because it significantly delays the setting of the
4.4. Temperature variations cement and reduces its mechanical properties,
especially in the short term. For all waste and by-
Changes in the temperature of concrete can cause products contents, the strengths increase as the
cracking. As the concrete gets hotter, it expands; curing time of the concrete increases [66]. Some
as concrete gets cooler, it contracts similarly to waste materials have 60-90% water holding capac-
many other materials. If the concrete tends to ex- ity, which is not beneficial for concrete [50,62]. In
pand or contract, it will most likely crack [97]. the worst case the compressive strength was 4.5
Elevated temperature affects the properties of Mpa. After 28 days the same concrete had reached
concrete such as change in moisture content, de- strength of 6 MPa and after 90 days, 18 MPa, which
gree of hydration, and other features [34]. The de- would allow it to be used for road bases and sub-
gree of hydration increases with time and tempera- bases, and as a filling material [7,9,10,12,14,28].
ture, but the degree of hydration was not increased In general, it would be suitable for any application
in significant amount after 28 day curing [98]. Fly that does not require high strengths, especially not
ash/cement cured at different temperatures (20 °C in the short term [32,42,45,50]. The porosity and
and 40 °C curing temperature) shows significant the absorption coefficient increase with an increase
increase in compressive strength (Rc) of concrete in waste content and decrease as the curing time
[34,42,57]. increased [52,53,56,62]. The deformability of con-
The concrete cured at 20 °C for 28 days had a crete also increases with the increase of waste
higher degree of cement hydration and lower cap- contents [61,62,67]. The density of the concrete
illary porosity than the concrete cured in water of decreases with an increase in waste content and
the same temperature for 7 days followed by ex- increases as the curing time increases [24,69,94].
posure to outdoor air for 21 days, but had opposite With reference to our previous study on con-
trend compared to the concrete cured in 35 °C crete M15 [101] and geopolymer [99] the mixed
water for 7 days followed by exposure to outdoor concrete is a desirable option to utilize or reuse of
air. However, the differences in the degree of ce- solid hazardous waste materials. Solidified mate-
ment hydration and capillary porosity for the con- rials are weak and contain significantly less
crete cured in these different conditions were not cementitious materials and more water, for example
significant. This suggests that the reference thin concrete. Due to waste addition, CSH hydration is
sections of concrete cured at 20 °C in moist condi- poisoned. In these situations, ettringite plays an
tion for 28 days may be used to estimate the W/C important role - it increases strength and durability
of concrete cured in a tropical environment for at characteristics. UCS increases with a decrease of
least 28 days, including 7 days moist curing with- crystalline phases [91,98].
58 Smita Badur and Rubina Chaudhary
[15] Cementitious properties, concrete [35] Method of making, curing and determine
properties, www.ce.memphis.edu. compressive strength of accelerated cured
[16] C. V. Nielsen and M. Glavind // Journal of concrete test specimens, Indian Standards
Advanced Concrete Technology 5 (2007) 3. (IS): 9013-1978.
[17] C. W. Condit, American Building: Materials [36] S. Mathur, U.K.G VittalGeotechnical,
and Techniques from the First Colonial Engineering Division Central Road Research
Settlements to the Present (University of Institute (2006) 1.
Chicago Press, Chicago, 1968) p. 90. [37] Code of Practice for Plain and Reinforced
[18] N. Shigeyoshi and H. Makoto // Concrete Concrete, Indian Standards (456 2000,
Journal 37(1999) 4. BIS, New Delhi).
[19] Schmidt Hammer Test, www.ce.ufl.edu. [38] Manual of Concrete Practice, yearly
[20] Note on Mix Design Method (Building publication (American Concrete Institute,
Research Establishment Laboratory, 2000).
Department of Environment (DOE), London, [39] ACI Committee 211.1 (1991); Standard
UK, 1975). Practice for Selecting Proportions for
[21] M.S.Shetty, Concrete Technology theory and Normal, Heavyweight and Mass Concrete,
practical (S. Chand, New Delhi, 2006). ACI Manual of Concrete Practice Part 1,
[22] J. Thomas Abraham and C. Richard Sloan, (2000, Michigan, USA).
Analysis and Repair of Cracking in TVAs [40] ACI Committee 211.4R (1993); Guide for
Fontana Dams Caused by Temperature and Selecting Proportions for High Strength
Concrete Growth, 13th ICOLD Proceedings, Concrete with Portland Cement and Fly Ash,
New Delhi, (1979). ACI Manual of Concrete Practice Part 1,
[23] http://matse1.mse.uiuc.edu. (2000, Michigan, USA).
[24] J.P. Won, Y.S. Lee, C.G. Park and H.G. Park [41] K.S. Rao, M.P. Raju and P.S.N. Raju //
// Magazine of Concrete Research 64 (2004) Journal of Structural Engineering 32 (2005)
429. 221.
[25] History of Concrete Building Construction, [42] J. Paya, J. Monzo, M.V. Borrachero,
www.ce.memphis.edu. E. Peris-Mora and F. Amahjour // Cement
[26] M.C. Natarajan, N. Dhang and A.P.Gupta // and Concrete Research 30 (2000) 543.
The Indian Concrete Journal (1999) 111. [43] K. Thangavel, T.M. Balasubramanian and
[27] J.K. Desai, Suitability and Availability of N.S.Rengaswamy // The Indian Concrete
Sand Deposits in Gujarat State of India with Journal (2000) 203.
Reference to their Petrography Pancholi [44] D.P. Bentz and C.J. Haecker // Cement and
(Bulletin Of The International Association Of Concrete Research 29 (1999) 615.
Engineering Geology No 29, 1984). [45] S. Asavapisita, S. Naksrichumb and
[28] P. Lawrence, M. Cyr and E. Ringot // Cement N. Harnwajanawong // Cement and
and Concrete Research 35 (2005) 1092. Concrete Research 35 (2005) 1042.
[29] A.M. Neville, Properties of concrete [46] D.M. Roy, Concrete Microstructure
(Longman ELBS, fourth edition, Malayasia. (Materials Research Laboratory The
1997). Pennsylvania State University G.M. Idorn,
[30] ACI 221Rguide for use of normal weight and Consult A/S Strategic Highway Research
heavy weight aggregate in concrete Program National Research Council
(American concrete institute, Michigan, Washington, DC (1993) SHRP-C-340 ISBN:
USA, 1996). 0-309-05254-8).
[31] M. Cyr, P. Lawrence and E. Ringot //Cement [47] L. Bertolini, M. Carsana, D. Cassago, A.Q.
and Concrete Research 36 (2006) 264. Curzio and M. Collepardi // Cement and
[32] Q. Jueshi, S. Caijun and Z. Wang // Cement Concrete Research 34 (2004) 899.
and Concrete Research 31 (2001) 1121. [48] P.K. Mehta // Concrete International 23
[33] K. Ezziane, A. Bougara, A. Kadri, H. Khelafi (2001) 61.
and E. Kadri // Cement and Concrete [49] P.K. Mehta // Concrete International 21
Composites 29 (2007) 587. (1999) 27.
[34] S. Zhang and M. Zhang // Cement and [50] I.Y. Ksel and T. Bilir // Construction and
Concrete Research 36 (2006) 1947. Building Materials 21 (2007) 686.
60 Smita Badur and Rubina Chaudhary
[51] C. Natarajan // The Journal of Corrosion Grutzeck // Cement and Concrete Research
Science and Engineering 7 (2005) 1. 29 (1999) 997.
[52] F.J. Huyen and J.W. Meusel // Journal of [72] G. Batis, P. Pantazopoulou, S. Tsivilis and
cement concrete and aggregate 3 (1981) 40. E. Badogiannis // Cement and Concrete
[53] C. D. Ati // Journal of Material in Civil Composites 27 (2005) 125.
Engineering (2003) 153. [73] D.M. Roy, P. Arjunan and M.R. Silsbee //
[54] T.R. Naik, P.E. Vasanthy, S. Shiw and Cement and Concrete Research 31 (2001)
S. Singh, Use Of High-Volume Class F Fly 1809.
Ash For Structural Grade Concrete, [74] I. Demira and M. Orhanb // Building and
www.uwm.edu. Environment 38 (2003) 1451.
[55] K.G. Babu and G.S.N. Rao // Cement [75] P. Kumar and S.K. Kaushik // The Indian
Concrete Research 26 (1996) 465. Concrete Journal (2003) 1503.
[56] S.E. Hedegaard and T.C. Hansen // [76] K. S. Rebeiz // Cement and Concrete
Materials and Structures 25 (1992) 381. Composites 17 (1995) 119.
[57] G. Li and X. Zhao // Cement and Concrete [77] S. Asavapisit and D. Chotklang // Cement
Composite 25 (2003) 293. and Concrete Research 34 (2004) 349.
[58] K. G. Babu and D. S. Babu // Cement and [78] R. Barnaa, Z. Rethyb and, L.T. Barnac //
Concrete Composite 26 (2004) 605. Journal of Environmental Management 74
[59] J. Paya, J. Monzo, M.V. Borrachero and E.P. (2005) 141.
Mora // Cement and Concrete Research 29 [79] N.T Michelle, A. Boddy, R.D. Hooton and
(1999) 87. M.D.A. Thomas // Cement and Concrete
[60] O. Malliou, M. Katsioti, A. Georgiadis and Research 36 (2006) 200.
A. Katsiri // Cement and Concrete [80] K. Stanish and M.D.A. Thomas // Cement
Composites 29 (2007) 55. and Concrete Research 33 (2003) 55.
[61] P. Asokan, M. Saxena and S.R. Asolekar // [81] F. Sandrolini and E. Franzoni // Cement and
Journal of Hazardous Materials B137 (2006) Concrete Research 31 (2001) 485.
1589. [82] D.P. Bentz // Cement and Concrete
[62] T. Ramlochan, M.D.A. Thomas and R.D. Composites 28 (2006) 427.
Hooton // Cement and Concrete Research [83] L. Zuda, Z. Pavlýk, P. Rovnanýkov, P. Bayer
34 (2004) 1341. and R. Cerny // International Journal of
[63] A. K. Karamalidis and Evangelos Thermophysics 27 (4) 2006 1228.
A. Voudrias // Journal Of Environmental [84] A.M. Harrison, N.B. Winter and H.F.W.
Science And Health A39 (2004) 961. Taylor // 8th ICCC Brazil 4 (1986) 170.
[64] R. Siddique // Cement and Concrete [85] D. Bonen and S. Diamond // Journal of
Research 34 (2004) 37. American Ceramic Society 77 (1994) 1875.
[65] S. Valls, A. Yagüe, E. Vázquez and [86] C. Famy, Expansion of heat-cured mortars
C. Mariscal // Cement and Concrete (PhD thesis, Imperial College of Science,
Research 34 (2004) 2203. University of London, 1999).
[66] Extensive literature study for Petrographic [87] I.G. Richardson // Cement and Concreter
analysis of aggregate and concrete, Indian Research 29 (1999) 1131.
Standard (IS): 9103-1999. [88] I. Odler // 7th ICCC, Paris 1980 4 (1981)
[67] A. Buchwald and M. Sehulz // Cement and 493.
Concrete Research 35 (2005) 968. [89] C. Famy, K. L. Scrivener, A. Atkinson and
[68] N.P. Malivaganam // The Indian Concrete A. R. Brough // Cement and Concrete
Journal (1999) 55. Research 31 (2001) 795.
[69] C.S. Poon, S. Azhar, M. Anson and Y. Lung [90] M.C. Lewis and K.L. Serivener, A
// Cement and Concrete Research 25 (2003) microstructure and microanalytical study of
83. heat cured mortars and delayed ettringite
[70] V. Zvivica // Bulletin Material Sciences 27 formation,In: Proceedings International
(2004) 179. Congress on the Chemistry of Cement,
[71] A. Palomo, M.T. Blanco-Varela, M.L. 10th,Gothenburg, 4 (1997) 409.
Granizo, F. Puertas, T. Vazquez and M.W.
Utilization of hazardous wastes and by-products as a green concrete material through... 61
[91] A. Roy, E.C. Harvill, F.K. Carteledge and [102] J.R. Conner, Chemical fixation and
M.E. Tittlebaum // Journal Hazardous solidification of hazardous waste (Van
Material 30 (1992) 297. Nostrand Reinhold, New York, 1990).
[92] D. Planela, J. Sercombeb, P. Le Bescopb, [103] E. Barth, P. Percin, M. Arozarena,
F. Adenotc and J.M. Torrentid // Cement and J. Zieleinswski , M. Dosani, H. Maxey,
Concrete Research 36 (2006) 137. S. Hokanson, C. Pryately, T. Whipple,
[93] K.L. Lin and C.Y. Lin // Cement and Concrete R. Kravitz, M. Cullinane, L. Jones and
Research 35 (2005) 1999. P. Malone, Stabilization And Solidification
[94] G.A. Rao and B.K. Raghu Parad // Journal of Of Hazardous Wastes (Noyes Data
Structural Engineering 32 (2005) 207. Corporation, New Jersey, USA, 1989).
[95] I.C. Yeh // Cement and Concrete Research [104] A. Roy, E.C. Harvill, F.K. Carteledge and
36 (2006) 1865. M.E. Tittlebaum // Journal Hazardous
[96] F.A. Oluokun // ACI Material Journal 91 Material 30 (1992) 297.
(1994) 362. [105] I.B. Singh, K. Chaturvedi, R.K. Morchhale
[97] N.J. Bhal and J.P. Jain // The Indian and A.H. Yegneswaran // Journal of
Concrete Journal (1999) 503. Hazardous Materials 141 (2007) 215.
[98] R. Malviya and R. Chaudhary // Journal of [106] S. Asavapisit and N. Ruengrit // Cement
hazardous materials B137 (2006) 267. and Concrete Research 27 (2005) 782.
[99] D. Khale, Development of Fly Ash Based [107] P.H. Shih, J.E. Chang, H.C. Lu and L. C.
Geopolymer and its Utilization for Chiang // Cement and Concrete Research
Solidification/Stabilization of Hazardous 35 (2005) 2110.
Waste (Heavy Metals) (PhD Thesis, Devi [108] A.R. Silva, L. Mater, M.M. Souza-Sierra,
Ahilya university Indore, India, 2007). A.X.R. Correa, Rafael Sperb and C.M.
[100] D. Khale and R. Chaudhary // Journal of Radetski // Journal of Hazardous Materials
Material Sciences 42 (2007) 729. 147 (2007) 691.
[101] R. Malviya, The Performance Evaluation of [109] G.A. Rao // Cement and Concrete
Solidification/Stabilization Process for Research 31 (2001) 443.
Hazardous Waste (Heavy Metals) ( PhD [110] W. Tangchirapat, T. Seating,
thesis, Devi Ahilya university Indore, India, C. Jaturapitakkul, K. Kiattikolmol and
2005). A. Siripanichgorn // Waste Management
27 (2007) 81.