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Design and Fabrication of Nano Antenna for Carbon

Nanotube Infrared Detector


Carmen Kar Man Fung*, Ning Xi, Balasubramaniam Shanker, King Wai Chiu Lai, Jiangbo Zhang, Hongzhi Chen and Yilun Luo
Electrical and Computer Engineering,
Michigan State University, USA
E-mail: carmen@egr.msu.edu

Abstract-This paper reports on fabrication of a novel simplicity and special features. Recently, antennas in nano
nanoscale antenna with carbon nanotubes (CNTs) based sensor scale have been investigated theoretically [2] and explored in
for sensitive infrared detection. CNTs are used as sensing element various applications such as optoelectronics and nanophotonics
for detecting both near and middle wave infrared. By using the
nanoassembly of CNTs and standard photolithography processes, [3]. However, the experimental realization of practical nano
a nanosized antenna is designed and integrated to enhance the antenna for quantum infrared detector has not been reported.
electric field intensity at the position of the sensing element In this paper, the fabrication of the ultra-small and sensitive
creating a very sensitive infrared nanosensor. The efficiency of CNT based IR detector with the nano antenna will be
nano antenna was studied experimentally by measuring and presented. To investigate the electric field enhancement effect
comparing the photocurrent response of the sensor to one without of the antenna, experiments have been performed to measure
the antenna. The photocurrent was increased 10 fold after
the photocurrent response of the sensor with and without the
integrating the nano antenna. This implies that the electric field in
the vicinity of the detector is enhanced by the nano antenna. The nano antenna. Preliminary results showed the photocurrent was
proposed fabrication process enables easy and direct integration increased by 10 times, and the I-V characteristic of the device
of the nano antenna into the manufacturing of infrared devices. has also been obtained. Several issues such as the conductivity
Therefore, this opens the possibility of developing high fidelity of the nano sized antenna and factors to affect the antenna gain
infrared sensors with a wide sensing range. Moreover, a novel will also be discussed. The novelty of our work includes the
approach was employed to consider and include quantum effects analysis of the near field and quantum effect of the nano
in the analysis and design for the nano antenna, which uses the
Green’s function for finding the near field effect from the antenna.
antenna, by applying Schrödinger’s equation and Green’s
As a result, these effects were verified and demonstrated function to find the maximum field intensity near the antenna,
experimentally in this paper. where the classical Maxwell’s method cannot be fully applied
for the antenna in nano environment. In addition, our
I. INTRODUCTION experimental results show the nano antenna is efficient in near
The development of infrared (IR) detectors using field. These main contributions will be presented in this paper.
nanostructural materials has attracted increasing interest in II. DESIGN AND WORKING PRINCIPLE
recent years. CNTs have been found to be promising
candidates for photodetection due to their low thermal noise. It To design a nano antenna with maximum electric field
is well known that the electronic properties of CNTs are enhancement effect, the location of the maximum field
different and they can exist in two forms, conducting and semi- intensity is first estimated by the following integral equation
conducting. Semi-conducting CNTs are natural candidates for for current density [2]:
IR detector as they have a bandgap in the IR range. Our group ∂2
L ' 2
e − jk ( z − z ) + a
2
1 (1)
2 ∫
has already developed a single CNT based nano infrared (k 2 + ) I ( z ' )dz ' = j 4πωε ( I ( z ) − Ei ( z ))
∂z − L ( z − z ) + a
' 2 2 2π aσ
detector [1], which exhibited IR response and small dark
current. However, the photocurrent response of CNT sensors where I(z), a and L are the current, radius, and length of the
has been relatively low because of the small sensing area. antenna, respectively, k is the wave vector, ω is the frequency
Thus, an enhancement technology is developed in this paper to of the incident electric field Ei(z), ε is the permittivity and σ is
increase the electric field at the sensing area. Since the size of the bulk conductivity of the metal. In nano environment, it was
the CNT is in nano scale, the technique to enhance the electric predicted that the antenna with nanometer radius is more
field that is incident on such small sensing element is efficient because the conductivity of the nano-sized antenna
challenging. In this paper, a nano antenna is used to increase plays an important role. When the radius of the antenna is in
the response of the sensor. These are not antennas in the nano scale, the electronic property is different when compared
traditional sense, in that we are not interested in the radiated with the macroscopic antenna. In the analysis for macroscopic
field. However, this terminology has been used extensively in antennas, it considers the antenna is a prefect conductor and so
the optics literature to refer to metallic field enhancement
the conductivity is a constant. However, when the radius of the
structures in the near field, especially in development of
antenna decreases to nanoscale, the conductivity should be
plasmonic devices. On the other hand, dipole antennas have
taken into account. Therefore, the classical Maxwell’s method
been widely used in electromagnetics because of their
cannot be fully applied to the antenna at nanoscale. On the

978-1-4244-2104-6/08/$25.00 ©2008 IEEE. 205


infrared source, a standing-wave current pattern is generated
along two metal wires. The field in the vicinity of the
electrically conducting object is enhanced; the structure can be
Re (σ) S

found from equation (1). The CNT sensing element is then


aligned to the position of the maximum estimated field near the
antenna. As discussed before, the maximum radiation occurs at
the point that is perpendicular to the antenna axis.
Im (σ) S

Frequency (THz)

Fig. 1. Plot of the conductivity of the antenna (titanium is chosen as the


material of the antenna) against the frequency of the incident wave.

other hand, the quantum conductivity was considered in


equation (1) and can be found by applying Schrödinger’s
equation [2]:
e 2 EF
σ (ω ) = − j (2)
π = 2 (ω − jυ )
where e, υ, and = are electron’s charge, relaxation frequency
and Planck’s constant, respectively. EF is the Fermi energy of
the metal (material of the antenna) and can be found from the
following equation [2][4]: Fig. 2. Illustration showing the setup of the infrared detection system with the
nano antenna.
N π=2d 2
EF = e
(3) III. FABRICATION PROCESS
me
After designing the antenna, the fabrication process of the
where N e2d and me are the number of electrons per m2, and CNT based IR detector with the nano antenna was developed
the mass of an electron, respectively. and the schematic structure is shown in Fig. 3.
Spin on photoresist on
quartz substrate Quartz

As a result, the conductivity on the antenna based on the Photoresist


Pattern and develop PR
incident electric field was calculated and plotted in Fig. 1. Titanium
Based on the current obtained from equation (1), the field in
Deposit Titanium and Gold Gold
the vicinity of the nano antenna can then be calculated [5]:
1 Parylene-C
E S (r ) = (k 2 + ∇∇⋅) ∫ g (r , r ') J (r ')dV ' (4)
jωε V
Remove photoresist CNT

where V is the volume over the entire space, r is the position CNT formation by
nanoassembly
vector from the source point to the observation point, J(r’) is
the current density and g(r,r’) is the electric dyadic Green’s
Parylene-C coated on the
function: chip

'e− jkR ⎧ 1 1 ⎫
g (r , r ) = ⎨ + 2 + "⎬ (5)
4π ⎩ R R ⎭ Deposit Titanium to form
the antenna

(a)
where R = r−r'
By using the above dyadic Green’s function for the electric
field and the Method of Moment, the electric field intensity
near the antenna can be calculated so that the position of the
maximum field is found. The nano antenna was then designed
for our system as depicted in Fig. 2. It consists of two
symmetric thin metal wires which are separated by a (b)
Fig. 3. (a) Fabrication process and (b) schematic structure of a CNT based IR
nanometric gap. When the antenna is illuminated with an detector with a nanoscale antenna.

206
antenna contamination. The IR sensing ability of the CNT detector after
packing by parylene has been report by our group in [6]. The
parylene separation distance between the antenna and the sensor was
determined by the thickness of the parylene layer. In principle,
the field enhancement effect is larger when the sensor is closer
microelectrode
to the antenna. The thickness of the parylene layer is 500nm.
quartz
Since the position of the sensing region (CNT-metal contact)
CNT
was estimated by the AFM, the antenna was then patterned and
(a) aligned to the sensing region by using e-beam lithography.
During this process, a layer of 950PMMA
CNT covered by (polymethylmethacrylate with molecular weight of 950) resist
parylene was spin-coated on the substrate. After the bakeout curing of
the PMMA, the nano antenna design pattern was written
directly on the resist by an electron beam writer. As mentioned
before, the position of the maximum field output is at the
center of the antenna. By using the above processes, the
position of the antenna can be precisely controlled and the
nano antenna structure can be fabricated. Finally, a pair of thin
metal wires was deposited on top of the parylene C layer by
1μm
parylene thermal evaporation and the nano antenna was formed after the
lift-off process. The fabricated device is shown in Fig. 4. As
(b) antenna seen from Fig. 4, two nano antennas were fabricated on the
Fig. 4. (a) Schematic drawing and (b) AFM images of the fabricated CNT IR CNT-metal contacts respectively. The total length, width and
detector with the nano antenna. Parylene thin film was coated between the thickness of each antenna are 5μm, 1μm and 300nm,
antenna and CNT. respectively. Titanium was used as the material of the antenna.
Detailed experimental results will be presented in the next
The single CNT sensor was first fabricated by using section.
nanoassembly to form the CNT across micro electrodes. A pair
of micro electrodes was evaporated on the quartz substrate by
using thermal evaporation. Titanium was used to improve the
IV. EXPERIMENTAL RESULTS
adhesion of gold to the substrate. The gap distance between the
micro electrodes is from 1 to 3μm. Then a drop of CNT An IR sensing experiment was performed to validate the
suspension was dispersed on the substrate and an ac voltage field enhancement effect on the CNT sensor with the nano
was applied. CNTs were then formed between the pair of antenna. The experiment was performed at room temperature.
micro electrodes by the dielectrophoresis force. CNT’s ON
responsibility to IR has been proposed as the Schottky barrier
effect at the CNT-metal contact and reported previously by our IR light OFF
group in [1]. When the IR irradiates the CNT, electrons and
holes inside the CNT are excited by the photons and results in
the generation of current. As a result, the current from the 1.80E-08
No antenna
CNT-metal contact is affected by the concentration of the 1.60E-08 Antenna

photo generated carriers in CNT under the incident IR 1.40E-08


excitation. Therefore, if the CNT-metal contact is placed to the
1.20E-08
position of the maximum field output near the antenna, then
Current (A)

the current can be increased due to the increasing IR power at 1.00E-08

the sensing region. This alignment process can be performed 8.00E-09


by the following steps. Firstly, the CNT formation between the 6.00E-09
microelectrodes was observed by using an atomic force
4.00E-09
microscope (AFM) so that the position of the CNT-metal
electrode was known and estimated. Afterwards, a parylene C 2.00E-09

thin film layer was coated on the CNTs to act as an insulating 0.00E+00
layer for separating the antenna and the sensor. The advantage 0 5 10
Time (sec)
15

of using parylene C is that it can be deposited conformally at


Fig. 5. Comparison of the temporal photocurrent response plots of a CNT
room temperature and it can also cover CNTs from based IR detector with and without nano antenna.

207
During the experiment, the device was illuminated by the radiation [7]. Therefore, the antenna length effect on the field
incident IR laser source (power: 30 mW, wavelength: 830 nm, enchantment by the nano antenna has to be further studied.
World Star Tech). The current from the CNT based detector
was then measured with an Agilent analyzer. The photocurrent VI. CONCLUSION
response for multiple on/off IR illumination cycles was
obtained and plots of the detector with and without the nano The design and fabrication process of a novel CNT based IR
antenna were compared and shown in Fig. 5. The photocurrent detector with a nano antenna have been presented. By
was taken as the current change when IR is on. It has been seen integrating the nano antenna, the incident electric field at the
that the current was increased when the IR laser was on and it sensor was increased leading to an order of magnitude increase
dropped to its original value when IR was off. in the photocurrent of the sensor. The antenna in nano
environment is more efficient and can be incorporated into the
5.00E-05 manufacturing process of present day infrared detectors.
4.00E-05
Quantum effects were considered and included in the analysis
for finding the maximum field from the antenna in near field.
3.00E-05
The combination of Schrödinger’s equation and Green’s
2.00E-05
function for near field provides a novel approach to study the
Current (A)

1.00E-05 antenna in nano environment, and leads to the potential method


0.00E+00 for future complete analysis of nano scale structures and
-0.8 -0.6 -0.4 -0.2
-1.00E-05
0 0.2 0.4 0.6 0.8 devices where quantum effects cannot be ignored and
traditional Maxwell’s equation cannot be fully applied. Based
-2.00E-05
on the theoretical prediction, the practical nano antenna for
-3.00E-05
quantum infrared detector has been realized experimentally,
-4.00E-05 which successfully demonstrated and verified that the IR
-5.00E-05 response of the sensor can be greatly increased by the electric
Voltage (V) field enhancement in the vicinity of the nano antenna. This
Fig. 6. I-V characteristics of a CNT IR detector with nano antenna.
represents a major breakthrough in sensor research since this
will lead to a dramatic improvement in the performance of
infrared imaging systems, which are important for future
Moreover, the I-V characteristic of the CNT-metal
civilian and military applications.
electrodes was investigated and is shown in Fig. 6. Our
preliminary results showed the device exhibited fast response
to IR and the photocurrent change was increased by 10 times ACKNOWLEDGMENT
after adding the nano antenna. Before adding the antenna, the This research work is partially supported under NSF Grants
current change of the original CNT based IR detector was IIS-0713346 and DMI-0500372, and ONR Grants N00014-04-
small, which implied the low sensitivity of the sensor. On the 1-0799 and N00014-07-1-0935.
other hand, the results showed that the CNT based sensor with
the nano antenna was more sensitive to IR because the incident
power was enhanced by the antenna. REFERENCES
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