You are on page 1of 33

HOCHSCHULE ZITTAU/GÖRLITZ

( FH) - Univer sit y of Appl ied Sciences

Faculty of
MECHANICAL ENGINEERING

Department of
TECHNICAL THERMODYNAMICS

Property Software for


Humid Air

FluidTI
for TI 89, TI 92, and
TI Voyage 200

Prof. Hans-Joachim Kretzschmar


Dr. Ines Stoecker
D. Seibt
R. Krause
Property Software for Humid Air

FluidTI
Student’s version

Contents
1. Property Functions of Humid Air
2. Application of FluidTI for Calculating Humid Air
2.1 Installation on the calculators TI 89, TI 92, TI 92Plus, and TI Voyage 200
2.2 Example: Calculation of hl = f(p,t,xw)
2.3 Removing FluidTI
3. Software Documentation of Humid Air
4. References

________________________________________________________________________
© Zittau/Goerlitz University of Applied Sciences (FH)
Faculty of Mechanical Engineering
Department of Technical Thermodynamics
Prof. Dr.-Ing. habil. H.-J. Kretzschmar
Dr.-Ing. I. Stoecker
Tel.: +49 3583-61-1846 or -1881
Fax: 03583-61-1847
E-mail: hj.kretzschmar@hs-zigr.de
Internet: www.thermodynamics-zittau.de

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
1/1

1. Property Functions of Humid Air

Function Name Property Functional Unit


Dependence of the result
Phi_ptxw Relative humidity ϕ = f( p, t , x w ) %
Humidity ratio (absolute humidity) from x w = f( p, t ,ϕ ) kg/kg(air)
xw_ptPhi
temperature and relative humidity
Xiw_xw Mass fraction of water ξ w = f( x w ) kg/kg
Psiw_xw Mole fraction of water ψ w = f( x w ) kmol/kmol
pd_ptxw Partial pressure of steam pd = f( p, t , x w ) MPa
Humidity ratio (absolute humidity) from x w = f( p, t , pd ) kg/kg(air)
xw_ptpd
Partial pressure of steam
xws_pt Saturation humidity ratio x ws = f( p, t ) kg/kg(air)
pds_pt Saturation vapor pressure of water pds = f( p, t ) MPa
tτ_pxw Dew point temperature t τ = f( p, x w ) °C

xw_ptτ Humidity ratio (absolute humidity) from x w = f( p, t τ ) kg/kg(air)


dew point temperature
tf_ptxw Wet bulb temperature t f = f( p, t , x w ) °C
Humidity ratio (absolute humidity) from x w = f( p, t , t f ) kg/kg(air)
xw_pttf
temperature and wet bulb temperature
cp_ptxw Specific isobaric heat capacity c p = f( p, t , x w ) kJ/(kg ⋅ K)

vl_ptxw Air-mass specific volume v l = f( p, t , x w ) m 3 /kg (air)


hl_ptxw Air-mass specific enthalpy hl = f( p, t , x w ) kJ/kg (air)

sl_ptxw Air-mass specific entropy sl = f( p, t , x w ) kJ/(kg(air) ⋅ K)

λ_ptxw Thermal conductivity λ = f( p, t , x w ) W/(m ⋅ K )

Eta_ptxw Dynamic viscosity η = f( p, t , x w ) Pa ⋅ s


Backward function: Temperature from
t_phlxw air-mass specific enthalpy and t = f( p, hl, x w ) °C
humidity ratio (absolute humidity)
Backward function: Temperature from
t_pslxw air-mass specific entropy and humidity t = f( p, sl, x w ) °C
ratio (absolute humidity)

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
1/2

Parameters
p - Overall pressure in MPa
t - Temperature in °C
xw - Absolute humidity in kg steam/kg(air) dry air

ϕ - Relative humidity (only defined for unsaturated humid air)


xls - Liquid fraction in kg liquid droplets / kg liquid droplets and
ice crystals
Input only when calculating fog with a temperature of t = 0.01 °C (mixture of liquid
fog and ice fog at t = 0.01 °C exactly)
xls = 1 when calculating liquid fog
xls = 0 when calculating ice fog
0 < xls < 1 when calculating a mixture of liquid fog and ice fog

Range of validity

Temperature t = -30 °C ... 800 °C


Pressure p = 0.0006112 MPa ... 2 MPa

Calculation algorithms

Unsaturated and saturated humid air ( x w ≤ x ws )


- ideal gas mixture of dry air and steam
- vl according to an ideal equation of mixture of gases
- hl, sl corresponding to the cp=const model
- λ, η corresponding to mixture model of Brandt [15]

Liquid mist ( x w > x ws ) and t ≥ 0.01 °C


- ideal mixture of saturated humid air and water liquid
- v, h, s of liquid droplets from IAPWS-IF97 [1], [2], [3], [4]
- cp of liquid droplets as constant value
- λ, η of liquid drops from IAPWS-85 [6], [7] - Mixture of volume fractions

Ice fog ( x w > x ws ) and t ≤ 0.01 °C


- ideal mixture of saturated humid air and water ice
- v, cp of ice crystals as constant values
- λ, η of saturated humid air

Mixture of liquid fog and ice fog ( x w > x ws ) at (x w > x ws ) t = 0.01 °C exactly
- ideal mixture of saturated humid air, water liquid and water ice

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
2/1

2. Application of FluidTI for Calculating


Humid Air
2.1 Installation of FluidTI on the calculators TI 89, TI 92, TI 92 Plus,
and TI Voyage 200
The "FluidTI" program will be copied onto the pocket calculator with the help of a link
program and the appropriate link cord.
You can acquire the software needed on buying the TI calculator or in the Internet at the
address http://www.ti.com/calc/docs/link.htm. The link cord necessary can be bought as
accessory e. g. from Böttcher Datentechnik GmbH
http://www.boettcher-datentechnik.de/.
The following description applies to the link programs
TI-Graph-Link® and TI-Connect®,
whereas the particular program must be installed. If you are using other link programs you
have to take the steps for data transfer from the appropriate instructions manual or online
help.
1. Insert the FluidTI floppy disk in the floppy drive of your computer. It contains the group
files listed in the following table:
TI-Model TI 89 TI 92 TI 92Plus TI Voyage 200
with memory
extension
File HuAir89.89g HuAir92E.92g HuAir92P.9xg HuAirVoyage200.9xg
2. For the installation and working with the program it is necessary that the language of the
TI-calculator is set to English. If this is not the case, you can change the language
corresponding to the following description:
- Press the <MODE> key
- Press the <F3> key
The language currently set is displayed next to "Language".
- Open the "Language" menu by pressing the right direction key
You will now see all available languages on your TI-calculator
- Select the language "English" with the help of the direction keys
- Confirm your selected language by pressing the <ENTER> key
- Confirm your selection again by pressing the <ENTER> key
3. Connect your TI-calculator to your computer by plugging the link cord in a free serial
interface (mostly COM2 or USB) and the phono connector in the pocket calculator.
If you wish to use the TI-Connect® link program for data transfer, please follow subsection 5.

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
2/2

4. Data Transfer using the TI-Graph-Link® Program


a) Run the TI-Graph-Link® program on your computer.
Click on "Link" in the upper menu bar and then select "Send…".
Search and click the letter of your floppy disk drive in the "Drives:" window.
The group file belonging to your TI model appears in the "File name:" window.
Considering the table above click on the file belonging to your model and afterwards
click the "Add" button. The group file and the drive letter will be shown in the "Selected
files:" window.
Highlight the square "Retain folder" by clicking on it.
Click the "OK" button.
Now, the data transfer from the computer to your pocket calculator begins. You will
now see the files which have been copied. The directory FLUIDTI will be created on
your TI and afterwards the appropriate program files of the group file will be copied into
it.
b) Click the "OK" button to confirm the "Finished" notification which appears on your
computer screen. You have now finished installation of FluidTI on your pocket
calculator.
If the copying process has failed, the following errors are possible:
- TI has not been connected or switched on when the TI-Graph-Link program had
been started
- The TI cursor was not placed in the command line
- A wrong cord has been used
- The connectors are not plugged in properly
- A wrong interface is set (menu item "Link")
c) In order to run the program, navigate into the "fluidti" directory by pressing <MODE>
and select the entry "fluidti" in the field "Current Folder" by pressing the right direction
key. Confirm your selection by pressing the <ENTER> key. Now, "fluidti" flashes in the
"Current Folder" field.
Confirm again by pressing <ENTER>. In the lower left edge of the screen you will now
see "FLUIDTI".
Now, type "huair()" and confirm your entry by pressing the <ENTER> key.
Now, proceed as described in section "2.2 Example: …".

5. Data Transfer Using the TI-Connect® Program


a) Run the TI-Connect® program on your computer.
Click on "DeviceExplorer".
In some cases, the "TI Communication Settings" menu will be opened. You will see the
name of your TI calculator, the name of the cord and the port which will be used for the
cord. Check if everything is correct and confirm by clicking the "OK" button.
In the following window you will see the directory tree with the programs of the
connected TI calculator.

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
2/3

Click on "Tools" in the upper menu bar and then select "GroupExplorer".
Search the letter of your floppy drive in the main window and click on the "+" next to the
drive name.
Below the name of the floppy drive you will now see the group files.
Considering the table above, left click the file belonging to your model.
Now, right-click the item in order to open the pop-up menu. Within the menu click on
"Send To Device".
Now, the data transfer from the computer to your pocket calculator begins. You will
now see the files which have been copied on your computer screen.
The directory FLUIDTI will be created on your TI and afterwards the appropriate
program files of the group file will be copied into it.
You have now finished installation of FluidTI on your TI-pocket calculator.
b) If the copying process has failed, the following errors are possible:
- TI has not been connected or switched on when the TI-Graph-Link program had
been started
- The TI cursor was not placed in the command line
- A wrong cord has been used
- The connectors are not plugged in properly
- A wrong interface is set (menu item "Link")

c) In order to run the program, navigate into the "fluidti" directory by pressing <MODE>
and select the entry "fluidti" in the field "Current Folder" by pressing the right direction
key. Confirm your selection by pressing the <ENTER> key. Now, "fluidti" flashes in the
"Current Folder" field.
Confirm again by pressing <ENTER>. In the lower left edge of the screen you will now
see "FLUIDTI".
Now, type "huair()" and confirm your entry by pressing the <ENTER> key.
Now, proceed as described in section "2.2 Example: …". ..."

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
2/4

2.2 Example Calculation of hl = f(p,t,xw)

We will now calculate, step by step, the air-mass specific enthalpy hl as a function of given
mixture pressure p, given temperature t and given absolute humidity xw for humid air.

Please carry out the following instructions:


- For the installation and working with the program it is necessary that the language of the
TI-calculator is set to English. If this is not the case, you can change the language
corresponding to the description in section "2.1 Installation of FluidTI...".
- In order to run the program, navigate into the "fluidti" directory by pressing <MODE> and
select the entry "fluidti" in the field "Current Folder" by pressing the right direction key.
Confirm your selection by pressing the <ENTER> key. Now, "fluidti" flashes in the
"Current Folder" field. Confirm again by pressing <ENTER>. In the lower left edge of the
screen you will now see "FLUIDTI".
Now, type "huair()" and confirm your entry by pressing the <ENTER> key.
- Leave the start screen by pressing <ENTER>.
You will see the main menu:

Press the right direction key to open the "Function" menu which contains the calculable
property functions. You will see the following menu:

- Select the menu item "hl_ptxw" with the help of the direction keys and confirm your
selection by pressing the <ENTER> key.
- The chosen function "hl_ptxw" flashes next to "Function". Confirm again by pressing
<ENTER>. The following menu appears, in which you can enter the given values.

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
2/5

- Enter the value for p in MPa into the appropriate window. Please consider the range of
validity:
p = 0.0006112 MPa ... 2 MPa
Æ e. g.: Enter the value 0.1 using the point as decimal point and move the cursor into
the field below with the help of the direction keys.
- Enter the value for t in °C into the appropriate window. Please consider the range of
validity:
t = - 30 °C ... 800 °C
Æ e. g.: Enter the value 25 and move the cursor into the field below with the help of the
direction keys.
- You now have to enter the value for the absolute humidity xw in kg steam / kg dry air into
the appropriate window.
Æ e. g.: Enter the value 0.01 and press the <ENTER> key.
- Confirm all your inputs again by pressing <ENTER>.
While calculation is carried out, you will see the BUSY-sign.
- After the calculation is finished, the result for hl in kJ/kg(air) relating to the mass of dry air
will be shown on the screen.

Æ The result in our sample calculation here is: hl = 50.7137 kJ/kg(air).


The calculation of hl = f(p,t,xw) has thus been completed.

It is now possible to save the calculated value for hl in a variable. Afterwards you can
calculate with this variable in other calculations within or outside FluidTI.

Æ e. g.: Enter the name "hl" within the "save as:" window and confirm it by pressing the
<ENTER> key twice.
Now, the calculated value is saved within the variable hl and is available in the FLUIDTI
directory.

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
2/6

Note: You can arbitrarily choose the name of the variable. It should merely not begin with
the sign ω (omega) and it should not bear the name of a system variable (cp. TI
manual). Generally, variables used within the FLUIDTI directory should not begin
with the sign ω.
Your calculator will now show the main menu again.
Close FluidTI by pressing the <ESC> key.

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
2/7

2.3 Removing FluidTI

Please carry out the following instructions for the pocket calculators TI 89, TI 92, TI 92 Plus,
and TI Voyage 200.
1. Open the "Var-Link-Menu" by pressing the <2nd> key and then the < - > key (but not <(-
)> ). You will see the following menu:

2. Locate the FluidTI directory with the cursor. The following files belong to this directory.
Move the cursor to the "airdat1" file and highlight it by pressing the <F4> key. A check
mark will appear in front of the file.

Repeat this highlight procedure for the files "airdat2", "airdat3", and "huair".
3. Press the <F1> key. The "Manage" menu appears. Select "UnLock Variable" with the
cursor and confirm this selection by pressing <ENTER>.

4. Deletion is carried out by opening the "Manage" menu again pressing <F1>, then select
the option "Delete" with the cursor and confirm by pressing <ENTER>. Confirm the
following query by pressing <ENTER> again.
Now FluidTI for humid air has been removed.
5. Leave the Var-Link menu by pressing the <ESC> key.

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
3/1

3. Software Documentation of Humid Air


Relative humidity ϕ = f(p,t,xw)

Name in FluidTI:
Phi_ptxw

Input Values:
p - Overall pressure p in MPa
t - Temperature t in °C
xw - Humidity ratio (Absolute humidity) xw in kgwater / kgair

Result:
Phi_ptxw - relative humidity

Range of validity:
Temperature t: from - 30°C to tcrit = 373.946°C (critical temperature of water)
Pressure p: from 0.0006112 MPa to 2 MPa
Humdity ratio (Absolute humidity) xw: from 0 kg/kg to x ws (p,t)

Comments:
xw p
Relative humidity ϕ =
Rl pds (t )
+ xw
Rw

with pds = ps ( t) for t ≥ 0.01°C - Vapor pressure of water


pds = psub ( t) for t < 0.01°C - Sublimation pressure of water

Results for wrong input values:


Phi_ptxw = - 1

References:
ps (t) corresponding to IAPWS-IF97 [1], [2], [3], [4] ]

psub (t) corresponding to IAPWS -93 [5]

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
3/2

Humidity ratio (Absolute humidity) from Temperature and


Relative Humidity xw = f(p,t,ϕ)

Name in FluidTI:
xw_ptPhi

Input Values:
p - Overall pressure p in MPa
t - Temperature t in °C
Phi - relative humidity in %

Result:
xw_ptPhi - Humidity ratio (Absolute humidity) in kgwater / kgair

Range of validity:
Temperature t: from - 30°C to tcrit = 373.946°C (critical temperature of water)
Pressure p: from 0.0006112 MPa to 2 MPa
relative humidity ϕ from 0 to 100 %

Comments:
Rl ϕ pds (t )
Humidity ratio (Absolute humidity) xw =
Rw p − ϕ pds (t )
with pds (t) = ps (t) for t ≥ 0.01°C - Vapor pressure of water
pds (t) = psub (t) for t < 0.01°C - Sublimation pressure of water

Results for wrong input values:


xw_ptPhi = - 1

References:
ps (t) corresponding to IAPWS-IF97 [1], [2], [3], [4] ]

psub (t) corresponding to IAPWS -93 [5]

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
3/3

Mass fraction of water ξw = f(xw)

Name in FluidTI:
Xiw_xw

Input Values:
xw - Humidity ratio (Absolute humidity) xw in kgwater / kgair

Result:
Xiw_xw - Mass fraction of water in kgwater/ kg

Range of validity:
Humdity ratio (Absolute humidity) xw: greater than or equal to 0 kgwater/kgair

Comments:
xw
Mass fraction of water ξ w =
1 + xw

Results for wrong input values:


Xiw_xw = - 1

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
3/4

Mole fraction of water ψw = f(xw)

Name in FluidTI:
Psiw_xw

Input Values:
xw - Humidity ratio (Absolute humidity) xw in kgwater / kgair

Result:
Psiw_xw - Mole fraction of water in kmolwater / kmol

Range of validity:
Humdity ratio (Absolute humidity) xw: greater as or equal to 0 kgwater/kgair

Comments:
Rw x w
Mole fraction of water ψ w =
R (1 + x w )

Results for wrong input values:


Psiw_xw = - 1

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
3/5

Partial pressure of steam pd = f(p,t,xw)

Name in FluidTI:
pd_ptxw

Input Values:
p - Overall pressure p in MPa
t - Temperature t in °C
xw - Humidity ratio (Absolute humidity) xw in kgwater / kgair

Result:
pd_ptxw - Partial pressure of steam in MPa

Range of validity:
Temperature t: from -30°C to 800°C
Pressure p: from 0.0006112 MPa to 2 MPa
Humdity ratio (Absolute humidity) xw: from 0 kg/kg to x ws (p,t)

Comments:
xw
Partial pressure of steam pd = p for x w ≤ x ws (p,t)
Rl
+ xw
Rw

for x w > x ws (p,t ) result pd = pds (t )

Results for wrong input values:


pd_ptxw = -1

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
3/6

Humidity ratio (Absolute humidity) from Partial Pressure of


Steam xw = f(p,t,pd)

Name in FluidTI:
xw_ptpd

Input Values:
p - Overall pressure p in MPa
t - Temperature t in °C
pd - Partial pressure of steam in MPa

Result:
xw_ptpd - Humidity ratio (Absolute humidity) in kgwater / kgair

Range of validity:
Temperature t: from -30°C to 800°C
Pressure p: from 0.0006112 MPa to 2 MPa
Partial pressure of water vapor pd : from 0.0006112 MPa to pds (t)

Comments:
Rl pd
Humidity ratio (Absolute humidity) x w =
Rw p − pd

Results for wrong input values:


xw_ptpd = - 1

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
3/7

Saturated humidity ratio xws = f(p,t)

Name in FluidTI:
xws_pt

Input Values:
p - Overall pressure p in MPa
t - Temperature t in °C

Result:
xws_pt - Saturated humidity ratio in kgwater / kgair

Range of validity:
Temperature t: from -30°C to tcrit= 373.946 °C (critical temperature of water)
Pressure p: from 0.0006112 MPa to 2 MPa

Comments:
Rl pds (t )
Humidity ratio (Absolute humidity) x w =
Rw p − pds (t )
with pds (t) = ps (t) for t ≥ 0.01°C - Vapor pressure of water
pds (t) = psub (t) for t < 0.01°C - Sublimation pressure of water

Results for wrong input values:


xws_pt = - 1

References:
ps (t) corresponding to IAPWS-IF97 [1], [2], [3], [4] ]

psub (t) corresponding to IAPWS -93 [5]

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
3/8

Saturation Vapor Pressure of Water pds = f(p,t)

Name in FluidTI:
pds_pt

Input Values:
p - Overall pressure p in MPa
t - Temperature t in °C

Result:
pds_pt - Saturation vapor pressure of water in MPa

Range of validity:
Temperature t: from -30°C to t s (p) (Boiling temperature of water)

Pressure p: from 0.0006112 MPa to 2 MPa

Comments:
Vapor pressure of water pds = ps (t) for t ≥ 0.01°C
Sublimation pressure of water pds = psub (t) for t < 0.01°C

Results for wrong input values:


pds_pt = -1

References:
p s ( t ) corresponding to IAPWS-IF97 [1], [2], [3], [4] ]

p sub ( t ) corresponding to IAPWS -93 [5]

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
3/9

Dew point temperature tτ = f(p,xw)

Name in FluidTI:
tτ_pxw

Input Values:
p - Overall pressure p in MPa
xw - Humidity ratio (Absolute humidity) xw in kgwater / kgair

Result:
tτ_pxw - Dew point temperature in °C

Range of validity:
Pressure p: from 0.0006112 MPa to 2 MPa
Humdity ratio (Absolute humidity) xw: greater than or equal to x ws (p, −30°C)

Comments:
Dew point temperature t τ = t s (pd ) for t ≥ 0.01°C (Boiling temperature of water)

t τ = t sub (pd ) for t < 0.01°C (Sublimation temperature of water)


xw
with pd = p
Rl
+ xw
Rw

Results for wrong input values:


tτ_pxw = - 1

References:
t s (pd ) corresponding to IAPWS-IF97 [1], [2], [3], [4] ]

t sub (pd ) corresponding to IAPWS -93 [5]

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
3/10

Humidity ratio (Absolute humidity) from Dew Point Temperature


xw = f(p,tτ)

Name in FluidTI:
xw_ptτ

Input Values:
p - Overall pressure p in MPa
tτ - Dew point temperature in °C

Result:
xw_ptτ - Humidity ratio (Absolute humidity) in kgwater / kgair

Range of validity:
Dew point temperature tτ: from -30°C to tcrit = 373.946°C (crit. temperature of water)
Pressure p: from 0.0006112 MPa to 2 MPa

Comments:
Rl pds (t τ )
Humidity ratio (Absolute humidity) x w =
Rw p − pds (t τ )
with pds (t τ ) = ps (t τ ) for t τ ≥ 0.01°C - Vapor pressure of water
pds (t τ ) = psub (t τ ) for t τ < 0.01°C - Sublimation pressure of water

Results for wrong input values:


xw_ ptτ = - 1

References:
ps (t τ ) corresponding to IAPWS-IF97 [1], [2], [3], [4] ]

psub (t τ ) corresponding to IAPWS -93 [5]

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
3/11

Wet Bulb Temperature tf = f(p,t,xw)

Name in FluidTI:
tf_ptxw

Input Values:
p - Overall pressure p in MPa
t - Temperature t in °C
xw - Humidity ratio (Absolute humidity) xw in kgwater / kgair

Result:
tf_ptxw - Wet bulb temperature in °C

Range of validity:
Temperature t: from -30°C to tcrit = 373.946 °C (critical temperature of water)
Pressure p: from 0.0006112 MPa to 2 MPa
Humdity ratio (Absolute humidity) xw: from 0 kg/kg to x ws (p,t)

Comments:
fog
Iteration of tf from hlunsaturated ( p, t , x w ) = hl ( p, t f , x w )

Results for wrong input values:


tf_ptxw = - 1

References:
Unsaturated and saturated humid air:
hl corresponding to Baehr [14]
Water droplets in fog:
h corresponding to IAPWS-IF97 [1], [2], [3], [4] ]

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
3/12

Humidity ratio (Absolute humidity) from Wet Bulb Temperature


xw = f(p,t,tf)

Name in FluidTI:
xw_pttf

Input Values:
p - Overall pressure p in MPa
t - Temperature t in °C
tf - Wet bulb temperature in °C

Result:
xw_pttf - Humidity ratio (Absolute humidity) in kgwater / kgair

Range of validity:
Temperature t: from 0.01°C to 800°C
Wet bulb temperature tf : from 0.01°C to the given temperature t
or to ts(p) (Boiling temperature of water)
Pressure p: from 0.0006112 MPa to 2 MPa

Comments:

Iteration of xw from hlunsaturated ( p, t, x w ) = hlfog ( p, t f , x w )

Results for wrong input values:


xw_pttf = - 1

References:
Unsaturated and saturated humid air:
hl corresponding to Baehr [14]
Water droplets in fog:
h corresponding to IAPWS-IF97 [1], [2], [3], [4] ]

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
3/13

Specific Isobaric Heat Capacity cp = f(p,t,xw)

Name in FluidTI:
cp_ptxw

Input Values:
p - Overall pressure p in MPa
t - Temperature t in °C
xw - Humidity ratio (Absolute humidity) xw in kgwater / kgair

xls - Liquid fraction in kgliquid / kgliquid and ice ( 0 ≤ x ls ≤ 1 )


! Specification only necessary if t = 0.01 °C when calculating a mixture of
liquid frog and ice fog

Result:
cp_pt_igas - Specific Isobaric Heat Capacity cp in kJ/(kg K)

Range of validity:
Temperature t: from -30°C to 800°C
Pressure p: from 0.0006112 MPa to 2 MPa
Humdity ratio (Absolute humidity) xw: greater than or equal to 0 kg/kg
Liquid fraction xls : from 0 kg/kg to 1 kg/kg

Comments:
Model of an ideal mixture

Results for wrong input values:


cp_ptxw = -1

References:

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
3/14

Air-Mass Specific Volume vl = f(p,t,xw)

Name in FluidTI:
vl_ptxw

Input Values:
p - Overall pressure p in MPa
t - Temperature t in °C
xw - Humidity ratio (Absolute humidity) xw in kgwater / kgair

xls - Liquid fraction in kgliquid / kgliquid and ice ( 0 ≤ x ls ≤ 1 )


! Specification only necessary if t = 0.01 °C when calculating a mixture of
liquid frog and ice fog

Result:
vl_ptxw - Air-mass specific volume in m3/kgair

Range of validity:
Temperature t: from -30°C to 800°C
Pressure p: from 0.0006112 MPa to 2 MPa
Humdity ratio (Absolute humidity) xw: greater than or equal to 0 kg/kg
Liquid fraction xls : from 0 kg/kg to 1 kg/kg

Comments:
Calculation:
- for unsaturated and saturated humid air ( x w ≤ x ws ) as ideal mixture of gases of
dry air and steam
- for fog ( x w > x ws ) as ideal mixture of saturated humid air and
water liquid or water ice

Results for wrong input values:


vl_ptxwxls = -1

References:
Specific volume of liquid water corresponding to IAPWS-IF97 [1], [2], [3], [4]

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
3/15

Air-Mass Specific Enthalpy hl = f(p,t,xw)

Name in FluidTI:
hl_ptxw

Input Values:
p - Overall pressure p in MPa
t - Temperature t in °C
xw - Humidity ratio (Absolute humidity) xw in kgwater / kgair

xls - Liquid fraction in kgliquid / kgliquid and ice ( 0 ≤ x ls ≤ 1 )


! Specification only necessary if t = 0.01 °C when calculating a mixture of
liquid frog and ice fog

Result:

hl_ptxw – air-mass specific enthalpy in kJ/kgair

Range of validity:
Temperature t: from -30°C to 800°C
Pressure p: from 0.0006112 MPa to 2 MPa
Humdity ratio (Absolute humidity) xw: greater than or equal to 0 kg/kgair
Liquid fraction xls : from 0 kg/kg to 1 kg/kg

Comments:
Calculation:
- for unsaturated and saturated humid air ( x w ≤ x ws ) as ideal mixture of gases of
dry air and steam
- for fog ( x w > x ws ) as ideal mixture of saturated humid air and
water liquid or water ice

Results for wrong input values:


hl_ptxw = -1000

References:
Unsaturated and saturated humid air:
hl corresponding to Baehr [14]
Water droplets in fog:
h corresponding to IAPWS-IF97 [1], [2], [3], [4] ]

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
3/16

Air-Mass Specific Entropy sl = f(p,t,xw)

Name in FluidTI:
sl_ptxw

Input Values:
p - Overall pressure p in MPa
t - Temperature t in °C
xw - Humidity ratio (Absolute humidity) xw in kgwater / kgair

xls - Liquid fraction in kgliquid / kgliquid and ice ( 0 ≤ x ls ≤ 1 )


! Specification only necessary if t = 0.01 °C when calculating a mixture of
liquid frog and ice fog

Result:
sl_ptxw - air-mass specific entropy in kJ/(kgair K)

Range of validity:
Temperature t: from -30°C to 800°C
Pressure p: from 0.0006112 MPa to 2 MPa
Humdity ratio (Absolute humidity) xw: greater than or equal to 0 kg/kgair
Liquid fraction xls : from 0 kg/kg to 1 kg/kg

Comments:
Calculation:
- for unsaturated and saturated humid air ( x w ≤ x ws ) as ideal mixture of gases of
dry air and steam
- for fog ( x w > x ws ) as ideal mixture of saturated humid air and
water liquid or water ice

Results for wrong input values:


sl_ptxw = - 1000

References:
Unsaturated and saturated humid air:
sl corresponding to Baehr [14]
Water droplets in fog:
s corresponding to IAPWS-IF97 [1], [2], [3], [4] ]

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
3/17

Thermal Conductivity λ = f(p,t,xw)

Name in FluidTI:
λ_ptxw

Input Values:
p - Overall pressure p in MPa
t - Temperature t in °C
xw - Humidity ratio (Absolute humidity) xw in kgwater / kgair

Result:
λ_ptxw - Thermal Conductivity in W/(m K)

Range of validity:
Temperature t: from -30°C to 800°C
Pressure p: from 0.0006112 MPa to 2 MPa
Humdity ratio (Absolute humidity) xw: greater than or equal to 0 kg/kgair

Comments:
Calculations corresponding to Brandt – Model of ideal mixture

Results for wrong input values:


λ_ptxw = -1

References:
Unsaturated and saturated humid air:
λ corresponding to Brandt [15]
Water droplets in fog:
λ from IAPWS-85 [6]

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
3/18

Dynamic Viscosity η = f(p,t,xw)

Name in FluidTI:
Eta_ptxw

Input Values:
p - Overall pressure p in MPa
t - Temperature t in °C
xw - Humidity ratio (Absolute humidity) xw in kgwater / kgair

Result:
Eta_ptxw - Dynamic Viscosity in Pa s

Range of validity:
Temperature t: from -30°C to 800°C
Pressure p: from 0.0006112 MPa to 2 MPa
Humdity ratio (Absolute humidity) xw: greater than or equal to 0 kg/kgair

Comments:
Calculations corresponding to Brandt – Model of ideal mixture

Results for wrong input values:


Eta_ptxw = -1

References:
Unsaturated and saturated humid air:
η corresponding to Brandt [15]
Water droplets in fog:
η from IAPWS-85 [7]

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
3/19

Backward function: Temperature t = f(p,hl,xw)

Name in FluidTI:
t_phlxw

Input Values:
p - Overall pressure p in MPa
hl - air-mass specific enthalpy in kJ/kg
xw - Humidity ratio (Absolute humidity) xw in kgwater / kgair

Result:
t_phlxw - Temperature in °C

Range of validity:
Temperature t: from -30°C to 800°C
Pressure p: from 0.0006112 MPa to 2 MPa
Humdity ratio (Absolute humidity) xw: greater than or equal to 0 kg/kgair

Comments:
Iteration of t from hl ( p, t , x w )

Results for wrong input values:


t_phlxw = - 1

References:
Unsaturated and saturated humid air:
hl corresponding to Baehr [14]
Water droplets in fog:
h corresponding to IAPWS-IF97 [1], [2], [3], [4] ]

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
3/20

Backward function: t = f(p,sl,xw)

Name in FluidTI:
t_pslxw

Input Values:
p - Overall pressure p in MPa
sl - air-mass specific entropy in kJ/(kg K)
xw - Humidity ratio (Absolute humidity) xw in kgwater / kgair

Result:
t_pslxw - Temperature in °C

Range of validity:
Temperature t: from -30°C to 800°C
Pressure p: from 0.0006112 MPa to 2 MPa
Humdity ratio (Absolute humidity) xw: greater than or equal to 0 kg/kgair

Comments:
Iteration of t from sl ( p, t , x w )

Results for wrong input values:


t_pslxw = -1

References:
Unsaturated and saturated humid air:
sl corresponding to Baehr [14]
Water droplets in fog:
s corresponding to IAPWS-IF97 [1], [2], [3], [4] ]

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
4/1

4. References
[1] Release on the IAPWS Industrial Formulation 1997 for the Thermodynamic Properties
of Water and Steam IAPWS-IF97.
IAPWS Sekretariat, Dooley, B, EPRI, Palo Alto CA (1997)
[2] Wagner, W.; Kruse, A.:
Zustandsgrößen von Wasser und Wasserdampf.
Springer-Verlag, Berlin (1998)
[3] Wagner, W.; Cooper, J.R.; Dittmann, A.; Kijima, J.; Kretzschmar, H.-J.; Kruse, A.;
Mares, R.; Oguchi, K.; Sato, H.; Stöcker, I.; Sifner, O.; Takaishi, Y.; Tanishita, I.;
Trübenbach, J.; Willkommen, Th.:
The IAPWS Industrial Formulation 1997 for the Thermodynamic Properties of Water
and Steam.
Journal of Eng. for Gasturbines and Power 122 (2000) Nr. 1, S. 150-182
[4] Wagner, W.; Rukes, B.:
IAPWS-IF97: Die neue Industrie-Formulation.
BWK 50 (1998) Nr. 3, S. 42-97
[5] Kretzschmar, H.-J.:
Mollier h,s-Diagramm.
Springer-Verlag, Berlin (1998)
[6] Revised Release on the IAPS Formulation 1985 for the Thermal Conductivity of
Ordinary Water Substance.
IAPWS Sekretariat, Dooley, B., EPRI, Palo Alto CA, (1997)
[7] Revised Release on the IAPS Formulation 1985 for the Viscosity of Ordinary Water
Substance.
IAPWS Secretariat, Dooley, B., EPRI, Palo Alto CA, (1997)
[8] IAPWS Release on Surface Tension of Ordinary Water Substance 1994.
IAPWS Sekretariat, Dooley, B., EPRI, Palo Alto CA, (1994)
[9] Kretzschmar, H.-J.; Stöcker, I.; Willkommen, Th.; Trübenbach, J.; Dittmann, A.:
Supplementary Equations v(p,T) for the Critical Region to the New Industrial
Formulation IAPWS-IF97 for Water and Steam.
in: Steam, Water and Hydrothermal Systems: Physics and Chemistry Meeting the
Needs of Industry, Proceedings of the 13th International Conference on the Properties
of Water and Steam, Eds. P.G. Hill et al., NRC Press, Ottawa, 2000
[10] Kretzschmar, H.-J.; Stöcker, I.; Knobloch, K.; Trübenbach, J.; Willkommen, Th.;
Dittmann, A.; Friend, D.:
Supplementary Backward Equations p(h,s) to the Industrial Formulation IAPWS-IF97
for Water and Steam.
Journal of Engineering for Gasturbines and Power - in Vorbereitung
[11] Release on the IAPWS Formulation 1995 for the Thermodynamic Properties of
Ordinary Water Substance for General and Scientific Use.
IAPWS Sekretariat, Dooley, B., EPRI, Palo Alto CA, (1995)
[12] Grigull, U.:
Properties of Water and Steam in SI Units.
Springer-Verlag, Berlin (1989)

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker
4/2

[13] Kretzschmar, H.-J.:


Zur Aufbereitung und Darbietung thermophysikalischer Stoffdaten für die
Energietechnik.
Habilitation, TU Dresden, Fakultät Maschinenwesen (1990)
[14] Baehr, H.D.; Diederichsen, Ch.:
Berechnungsgleichungen für Enthalpie und Entropie der Komponenten von Luft und
Verbrennungsgasen.
BWK 40 (1988) Nr. 1/2, S. 30-33
[15] Brandt, F.:
Wärmeübertragung in Dampferzeugern und Wärmetauschern.
FDBR-Fachbuchreihe, Bd. 2, Vulkan Verlag Essen (1985)
[16] Release on the IAPS Formulation 1985 for the Thermal Conductivity of Ordinary Water
Substance.
IAPWS Sekretariat, Dooley, B., EPRI, Palo Alto CA, (1985)
[17] Release on the IAPS Formulation 1985 for the Viscosity of Ordinary Water Substance.
IAPWS Secretariat, Dooley, B., EPRI, Palo Alto CA, (1985)
[18] Release on Surface Tension of Ordinary Water Substance 1975.
IAPWS Sekretariat, Dooley, B., EPRI, Palo Alto CA, (1975)
[19] VDI-Wärmeatlas, 7. Auflage.
VDI-Verlag, Düsseldorf (1995)
[20] Blanke,W.:
Thermophysikalische Stoffgrößen.
Springer-Verlag, Berlin (1989)
[21] VDI-Richtlinie 4670 - Thermodynamische Stoffwerte von feuchter Luft und
Verbrennungsgasen.
VDI-Handbuch Energietechnik, Düsseldorf (2000)

Zittau/Goerlitz University of Applied Sciences, Department of Technical Thermodynamics, Professor H.-J. Kretzschmar, Dr. I. Stoecker

You might also like