You are on page 1of 30

Vidyamandir Classes

Joint Entrance Exam | Mains-2018


Paper Code - B
th
8 April 2018 | 9.30 AM – 12.30 PM
CHMISTRY, MATHEMATICS & PHYSICS

Important Instructions:
1. Immediately fill in the particulars on this page of the Test Booklet with only Black Ball Point Pen
provided in the examination hall.
2. The Answer Sheet is kept inside this Test Booklet. When you are directed to open the Test Booklet,
take out the Answer Sheet and fill in the particulars carefully.
3. The test is of 3 hours duration.
4. The Test Booklet consists of 90 questions. The maximum marks are 360.
5. There are three parts in the question paper A, B, C consisting of Physics, Mathematics and Chemistry
having 30 questions in each part of equal weightage. Each question is allotted 4 (four) marks for
correct response.
6. Candidate will be awarded marks as stated above in instruction No. 5 for correct response of each
question. 1 4 (one-fourth) marks of the total marks allotted to the questions (i.e. 1 mark) will be
deducted for indicating incorrect response of each question. No deduction from the total score will be
made if no response is indicated for an item in the answer sheet.
7. There is only one correct response for each question. Filling up more than one response in any
question will be treated as wrong response and marks for wrong response will be deducted
accordingly as per instruction 6 above.
8. For writing particulars/marking responses on Side-1 and Side-2 of the Answer Sheet use only Black Ball
Point Pen provided in the examination hall.
9. No candidate is allowed to carry any textual material, printed or written, bits of papers, pager, mobile
phone, any electronic device, etc. except the Admit Card inside the examination room/hall.
10. Rough work is to be done on the space provided for this purpose in the Test Booklet only. This space is
given at the bottom of each page and in four pages (Page 20-23) at the end of the booklet.
11. On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator on duty in
the Room/Hall. However, the candidates are allowed to take away this Test Booklet with them.
12. The CODE for this Booklet is B. Make sure that the CODE printed on Side-2 of the Answer Sheet is same
as that on this Booklet. Also tally the serial number of the Test Booklet and Answer Sheet are the same
as that on this booklet. In case of discrepancy, the candidate should immediately report the matter to
the Invigilator for replacement of both the Test Booklet and the Answer Sheet.
13. Do not fold or make any stray mark on the Answer Sheet.

VMC/JEE Mains-2018 1 JEE Entrance Examination


Vidyamandir Classes

Joint Entrance Exam/IITJEE-2018

PART-A PHYSICS

1. It is found that if a neutron suffers an elastic collinear collision with deuterium at rest, fractional loss of its
energy is pd ; while for its similar collision with carbon nucleus at rest, fractional loss of energy is pc . The
values of pd and pc are respectively.
(1) (0, 0) (2) (0, 1) (2) ( 89,  28) (3) (28,  89)
1.(3) For collision with deuterium:

mv  o  mv1  2mv2 (Conservation of momentum ) ......... (1)


v2  v1  v ( e  1 ) ......... (2)
v
By (1) and (2) v1  
3
1 2 1 2
mv  mv1
8
Pd  2 2   0.89
1 2 9
mv
2
For collision with carbon Nucleus

mv  0  mv1  12mv2 (Conservation of momentum ) ......... (1)


v  v2  v1 ( e  1 ) ......... (2)
By (1) and (2)
11
v1   v
13
2
1 2 1  11 
mv  m  v 
2 2  13  48
Pc    0.28
1 2 169
mv
2

2. The mass of a hydrogen molecule is 3.32 1027 kg. If 1023 hydrogen molecules strike, per second, a fixed wall
of area 2 cm2 at an angle of 45° to the normal, and rebound elastically with a speed of 103 m/s, then the pressure
on the wall is nearly:
(1) 2.35  102 N / m 2 (2) 4.70 10 2 N / m2
(3) 2.35  103 N / m 2 (4) 4.70  103 N / m2
2.(3) Change in momentum of a single molecule.
u
P0  m0 2
2
Total change in momentum per second
P  nP0  n.m0u 2
F nm0 u 2
Pressure  
A A
Substituting values: P  2.35  103 N / m 2 .

VMC/JEE Mains-2018 2 JEE Entrance Examination


Vidyamandir Classes

3. A solid sphere of radius r made of a soft material of bulk modulus K is surrounded by a liquid in a cylindrical
container. A massless piston of area a floats on the surface of the liquid, covering entire cross section of
cylindrical container. When a mass m is placed on the surface of the piston to compress the liquid, the fractional
 dr 
decrement in the radius of the sphere,   , is:
 r 
mg mg Ka Ka
(1) (2) (3) (4)
3 Ka Ka mg 3mg

P
3.(1) B
V
V
V P
 
V B
V r
Also, 3 (As V  4r 2 r )
V r
r  P  mg
   
r  3 B  3Ka
4. Two batteries with e.m.f. 12 V and 13 V are connected in parallel across a load resistor of 10. The internal
resistances of the two batteries are 1  and 2  respectively. The voltage across the load lies between :
(1) 11.4 V and 11.5 V (2) 11.7 V and 11.8 V
(3) 11.6 V and 11.7 V (4) 11.5 V and 11.6 V
4.(4)

Equivalent circuit is

Where,
1 2 2
req  
1 2 3
 V1 V2 
  
r r2 
veq  1  12.33
1 1

r1 r2
10
 V AB  Veq = 11.55 volts
10  req
k
5. A particle is moving in a circular path of radius a under the action of an attractive potential U   . Its total
2r 2
energy is :
3 k k k
(1) Zero (2)  (3)  (4)
2 a2 4a 2
2a 2
K
5.(1) U 
2r 2
dU  K
F  r   3 r
dr r
VMC/JEE Mains-2018 3 JEE Entrance Examination
Vidyamandir Classes

 K mv 2 mv 2
 (As Force towards center  )
r3 r r
1 K
 K. E. = mV 2  2
2 2r
K K
Total energy = KE + PE   = Zero
2r 2 2r 2

6. Two masses m1  5 kg and m2  10 kg, connected by an inextensible string over a frictionless pulley, are
moving as shown in the figure. The coefficient of friction of horizontal surface is 0.15. The minimum weight m
that should be put on top of m2 to stop the motion is :

(1) 43.3 kg (2) 10.3 kg (3) 18.3 kg (4) 27.3 kg


6.(4) For m1 to be at rest
T  5g
For m & m2 to be at rest
f  T  5g
f  ( N )
 f  0.15(m  m2 ) g
 m  23.33 kg
Amongst the options minimum mass that can be kept for no motion is 27.3 kg

7. If the series limit frequency of the Lyman series is vL , then the series limit frequency of the Pfund series is ;
(1) vL /16 (2) vL / 25 (3) 25vL (4) 16vL
7.(2) For Series limit of Lyman : n1  1 and n2  
1 1 
  P  RcZ 2   
1  
For Series limit of Pfund: n1  5 and n2  
 1 1 
  P  RcZ 2     L
 25   25
8. Unpolarized light of intensity I passes through an ideal polarizer A. Another identical polarizer B is placed
I
behind A. The intensity of light beyond B is found to be . Now another identical polarizer C is placed between
2
I
A and B. The intensity beyond B is now found to be . The angle between polarizer A and C is :
8
(1) 45° (2) 60° (3) 0° (4) 30°
I
8.(1) When an unpolarized light of intensity I passes through a polarizer for the 1st time, intensity of output is
2
(irrespective of orientation of polarizer)
So,

VMC/JEE Mains-2018 4 JEE Entrance Examination


Vidyamandir Classes

i.e., polarizers A and B have axes parallel to each other.


Now let the axis of C make an angle  with A, and   with B.

I I
cos4  
2 8
Solving,   45
9. An electron from various excited states of hydrogen atom emit radiation to come to the ground state. Let  n ,  g
be the de Broglie wavelength of the electron in the nth state and the ground state respectively. let  n be the
wavelength of the emitted photon in the transition from the nth state to the ground state. For large n, (A, B are
constants)
B
(1)  2n  A  Bn2 (2)  2n   (3) n  A  2 (4)  n  A  Bn
n
1 1 1 
9 (3).  RZ 2   
n  1 n2 
2

1
1  1 
n  1 
2
RZ  n2 
Since n is very large, using binomial
1  1 
n  1
2 
RZ  n 2 
1 1  1 
n    
2
RZ RZ 2  n 2 
B 2 r  n 2 h2  1
n  A  As  n   2   n
 2n n  42 mZe 2  n
 
10. The reading of the ammeter for a silicon
diode in the given circuit is:
(1) 11.5 mA
(2) 13.5 mA
(3) 0
(4) 15 mA
10 (1).

Voltage across Si diode in forward bias is 0.7 volts. Hence voltage across 200  resister is 3 – 0.7 = 2.3V
2.3
 I = 11.5 mA
200

VMC/JEE Mains-2018 5 JEE Entrance Examination


Vidyamandir Classes

11. An electron, a proton and an alpha particle having the same kinetic energy are moving in circular orbits of radii
re , rp , r respectively, in a uniform magnetic field B. The relation between re , rp , r is:
(1) re  rp  r (2) re  r  rp (3) re  rp  r (4) re  rp  r

mv 2mK
11.(4) r 
qB qB
2me K
re 
eB
2  4m p K
r 
2eB
2  mp K
rp 
eB
Comparing (1), (2) and (3)
re  r  rp
12. A parallel plate capacitor of capacitance 90 pF is connected to a battery of emf 20 V. If a dielectric material of
5
dielectric constant K  is inserted between the plates, the magnitude of the induced charge will be :
3
(1) 2.4 nC (2) 0.9 nC (3) 1.2 nC (4) 0.3 nC
12.(3) qi  CV
q f  KCV

5 
qinduced  q f  qi  ( K  1)CV    1   90  1012  20  1.2 nC
3 
1
13. For an RLC circuit driven with voltage of amplitude vm and frequency 0  the current exhibits
LC
resonance. The quality factor, Q is given by :
R CR 0 L 0 R
(1) (2) (3) (4)
(0 C ) 0 R L
0  L
13.(3) Quality factor Q   0
2 R
14. A telephonic communication service is working at carrier frequency of 10 GHz. Only 10% of it is utilized for
transmission. How many telephonic channels can be transmitted simultaneously if each channel requires a band
width of 5 kHz?
(1) 2  105 (2) 2  106 (3) 2  103 (4) 2  10 4
14.(1) Overall bandwidth use for transmission  10% of C
10
 10  109
Total bandwidth 100
Number of telephonic channel    2  105
Channel bandwidth 5  103
15. A granite rod of 60 cm length is clamped at its middle point and is set into longitudinal vibrations. The density
of granite is 2.7  103 kg / m3 and its Young’s modulus is 9.27  1010 Pa . What will be the fundamental
frequency of the longitudinal vibrations?

(1) 10kHz (2) 7.5kHz (3) 5kHz (4) 2.5 kHz

c 1 Y
15.(3) f  
 2l 

VMC/JEE Mains-2018 6 JEE Entrance Examination


Vidyamandir Classes

1 9.27  1010

2  0.6 2.7  103

1 9.27 107

1.2 2.7
 4.88 103 Hz
 5 kHz
16. Seven identical circular planar disks, each of mass M and radius R are welded symmetrically as shown.
The moment of inertia of the arrangement about the axis normal to the plane and passing through the point P
is:

73 181 19 55
(1) MR 2 (2) MR 2 (3) MR 2 (4) MR2
2 2 2 2

MR2  MR 2  1  55
16.(2) I0   6  M (2 R )2   MR 2   3  24   MR 2
2  2   2  2
O is the centre of mass of the system. Applying parallel axis theorem between O & P.
55 181
I P  I 0  7 M (3R)2  MR 2  63MR 2  MR 2
2 2
17. Three concentric metal shells A, B and C of respective radii a, b and c  a  b  c  have surface charge densities
,  and  respectively. The potential of shell B is:
  b2  c2    b2  c2    a2  b2    a 2  b2 
(1)   a  (2)   a  (3)   c  (4)   c
0  b  0  c  0  a  0  b 
kQA kQB kQC
17.(4) VB   
b b c
 ( )(4 a 2 ) ( )(4 b 2 ) ( )(4 c 2 ) 
k   
 b b c 

1  a 2 b2    a 2  b2 
  4    c     c
4 0  b b   0  b 
18. In a potentiometer experiment, it is found that no current passes through the galvanometer when the terminals of
the cell are connected across 52 cm of the potentiometer wire. If the cell is shunted by a resistance of 5  , a
balance is found when the cell is connected across 40 cm of the wire. Find the internal resistance of the cell.
(1) 2 (2) 2.5  (3) 1 (4) 1.5 
18.(4) Let potential difference per unit length of potentiometer wire be x.
In case-I
  (52)( x ) …(i)
In case-II

i
r 5
  ir  (40)( x)
    5 
   r  40 x     40 x …(ii)
r 5 r 5

VMC/JEE Mains-2018 7 JEE Entrance Examination


Vidyamandir Classes

From (i) & (ii)


 r 5
52 x  40 x  
 5 
52 r  13  15
 1  r  5   1   1.5
40 5  10  10
   z 
19. An EM wave from air enters a medium. The electric fields are E1  E01 xˆ cos  2v   t   in air and
  c 

E2  E02 xˆ cos  k  2 z  ct  in medium, where the wave number k and frequency v refer to their values in air.
The medium is non-magnetic. If r1 and r2 refer to relative permittivities of air and medium respectively, which of
the following options is correct?
r1 1 r1 1 r1 r1
(1)  (2)  (3) 4 (4) 2
r2 4 r2 2 r2 r2
19.(1) From wave equations :
2
In air:   2 , k 
c
In medium:   kc, k   2k
   2 c
k , k     c 
c c c c 2
1 1 1

0 r2 0 r2 0 r1 0 r1 2
 Medium and air are non-magnetic
r1  1 ;  r2  1

1 1 r1 1
   
r2 4 r1 r2 4

20. The angular width of the central maximum in a single slit diffraction pattern is 60°. The width of the slit is 1
m. The slit is illuminated by monochromatic plane waves. If another slit of same width is made near it, Young’s
fringes can be observed on a screen placed at a distance 50 cm from the slits. If the observed fringe width is 1
cm, what is slit separation distance? (i.e., distance between the centres of each slit.)
(1) 75 m (2) 100 m (3) 25 m (4) 50 m
2
20.(3) Angular width of central maxima  ; (where a is slit width and  is wavelength)
a
2 
 … (i)
a 3
In YDSE, fringe width
D
 [where d is slit separation and D is distance of screen from slits)
d
D  D a 1 3.14  106 100
  a  d  d    106  25 m
d 6 6 2 6  102 4
21. A silver atom in a solid oscillates in simple harmonic motion in some direction with a frequency of 1012/sec.
What is the force constant of the bonds connecting one atom with the other? (Mole wt. of silver = 108 and
Avagadro number = 6.02 × 1023 gm mole–1)
(1) 2.2 N/m (2) 5.5 N/m (3) 6.4 N/m (4) 7.1 N/m
1 
21.(4) 1012  f      2  1012
T 2

VMC/JEE Mains-2018 8 JEE Entrance Examination


Vidyamandir Classes

k  108  2
 2 
m
 k  m 2  
 6.023  1023 
 

  10 3  2  1012   7.1

22. From a uniform circular disc of radius R and mass 9 M, a small disc of
R
radius is removed as shown in the figure. The moment of inertia of the
3
remaining disc about an axis perpendicular to the plane of the disc and
passing through centre of disc is :
37
(1) 10 MR2 (2) MR2
9
40
(3) 4 MR2 (4) MR2
9
  R 2 
2M   2
 9M  R   3   2R  
22.(3) I   M   
2  2  3  
 
 
9 MR 2  MR2  MR 2  2
I     4MR
2  18 9 
23. In a collinear collision, a particle with an initial speed v0 strikes a stationary particle of the same mass. If the
final total kinetic energy is 50% greater than the original kinetic energy, the magnitude of the relative velocity
between the two particles, after collision, is:
v0 v0 v0
(1) (2) (3) (4) 2 v0
2 2 4
23.(4)

It is given that final total kinetic energy has increased, so some internal energy of the system must have been
converted into kinetic energy.
1 1 1 
mv12  mv 22  1.5  mv 20 
2 2 2 
 v12  v 22  1.5 v 02 ...... (i)
Since, there is no external force, momentum can be conserved
mv1  mv 2  mv0
 v1  v2  v0 ...... (ii)
From (i) & (ii)
2
v1   v 0  v1   1.5 v02

2v12  2v 0 v1  0.5v02  0

D
Relative velocity  v 2  v1  Difference of roots   2 v0
a
24. The dipole moment of a circular loop carrying a current I, is m and the magnetic field at the centre of the loop is
B1 . When the dipole moment is doubled by keeping the current constant, the magnetic field at the centre of the
B1
loop is B2 . The ratio is :
B2
1
(1) 2 (2) (3) 2 (4) 3
2

VMC/JEE Mains-2018 9 JEE Entrance Examination


Vidyamandir Classes

0 I
24 (1). B1 
2r1
; m1  I r12  
0 I
B2 
2r 2
; m2  I r 22  
2 2
m2 r 2 r  r2
  2 2   2
m1 r12  r1  r1

B1 r2
   2
B2 r1
25. The density of a material in the shape of a cube is determined by measuring three sides of the cube and its mass.
If the relative errors in measuring the mass and length are respectively 1.5% and 1%, the maximum error in
determining the density is:
(1) 4.5% (2) 6% (3) 2.5% (4) 3.5%
M M
25 (1).  
V L3
 M L
 3
 M L
 Maximum % error in density  1.5%  3 1%   4.5%

26. On interchanging the resistances, the balance point of a meter bridge shifts to the left by 10 cm. The resistance of
their series combination is 1 k. How much was the resistance on the left slot before interchanging the
resistances?
(1) 550 Ω (2) 910 Ω (3) 990 Ω (4) 505 Ω
26.(1) Let the resistances in left and right slot be r and 1000  r respectively
Initial: r (100  x)  (1000  r )( x ) ..................(1)
After interchanging: (1000  r )[100  ( x  10)]  r ( x  10)
(1000  r )(110  x )  r ( x  10) ..................(2)

From (1): 100r  rx  1000 x  rx  r  10 x


 r   r 
From (2): (1000  r ) 110    r   10 
 10   10 
 (1000  r )(1100  r )  r 2  100r
1000 1100
 1000 1100  2100r  r 2  r 2  100r  r  550 
2000
 
27. In an a.c. circuit, the instantaneous e.m.f. and current are given by e  100sin 30t i  20sin  30t   . In one
 4
cycle of a.c., the average power consumed by the circuit and the wattless current are, respectively:
50 1000
(1) ,0 (2) 50, 0 (3) 50, 10 (4) ,10
2 2

27.(4) P  Vrms I rms cos  ; 
4
100 20 1 1000
P    
2 2 2 2
20 1
Wattless current, I  I rms sin     10
2 2
28. All the graphs below are intended to represent the same motion. One of them does it incorrectly. Pick it up.

VMC/JEE Mains-2018 10 JEE Entrance Examination


Vidyamandir Classes

(1) (2)

(3) (4)
28.(4) The (1), (2) and (3) graphs can represent the motion of a ball that is thrown in vertically upward direction.
Initially speed decreases, becomes zero and then on the return trip, speed increases. Slope of graph in option (4)
does not explain it.

29. Two moles of an ideal monoatomic gas occupies a volume V at 27°C. The gas expands adiabatically to a volume
2V. Calculate (a) the final temperature of the gas and (b) change in its internal energy.
(1) (a) 189 K (b) – 2.7 kJ
(2) (a) 195 K (b) 2.7 kJ
(3) (a) 189 K (b) 2.7 kJ
(4) (a) 195 K (b) –2.7 kJ
5
29.(1) For mono atomic gas  
3
Using TV 1  constant
2 2 300
(300)V 3  T  2V  3  T 2
 189 K
2 3

3 3 
U  n RT  2   8.314  189  300    2768  2.7 kJ
2 2 
30. A particle is moving with a uniform speed in a circular orbit of radius R in a central force inversely proportional
to the n th power of R. If the period of rotation of the particle is T, then:
T  R 
n 1 / 2
(1) (2) T  Rn / 2
n
1
(3) T  R3/ 2 for any n (4) T  R2
1
30.(1) F
Rn
(1 n )
k mV 2 k
F   V2   VR 2
Rn R mRn 1
n 1
2 R R
Now T   R 2
V (1 n)
R 2
H 22  (3) He 22  (4) He 2

VMC/JEE Mains-2018 11 JEE Entrance Examination


Vidyamandir Classes

PART-B MATHEMATICS

31. If the tangent at (1, 7) to the curve x 2  y  6 touches the circle x 2  y 2  16 x  12 y  c  0 then the value of
c is:
(1) 85 (2) 95 (3) 195 (4) 185

y7
31.(2) x 6  2 x  y  7  12  2x  y  5  2x  y  5  0
2
Also, centre of the circle is  8,  6  and the radius is 64  36  c

 16  6  5 
    100  c  5  100  c  c  95
 5 

32. If L1 is the line of intersection of the planes 2 x  2 y  3 z  2  0 , x  y  z  1  0 and L2 is the line of


intersection of the planes x  2 y  z  3  0 , 3 x  y  2 z  1  0 , then the distance of the origin from the
plane, containing the lines L1 and L2 is:
1 1 1 1
(1) (2) (3) (4)
2 2 2 4 2 3 2
32.(4)  2    x   2    y  3    z  2    0
1  3  x   2    y   2   1 z  3    0
2    2    3
     2  1  3  2   3  
1  3 2 2
So the equation of plane is 7 x  7 y  8 z  3  0

3 1
Now, distance from origin equal to 
7 2  7 2  82 3 2

33. If ,  C are the distinct roots, of the equation x 2  x  1  0 , then 101  107 is equal to:
(1) 1 (2) 2 (3) –1 (4) 0
1  3
33.(1) x2  x  1  0  x    ,   2 (where  and  2 are non-real cube roots of unity)
2
    and    2
107
   101    2    
  101   214    2    1 
34. Tangents are drawn to the hyperbola 4 x 2  y 2  36 at the points P and Q. If these tangents intersect at the
point T(0, 3) then the area (in sq. units) of PTQ is:

(1) 60 3 (2) 36 5 (3) 45 5 (4) 54 3


34.(3) Equation of PQ,
4 x   0   3 y  36

VMC/JEE Mains-2018 12 JEE Entrance Examination


Vidyamandir Classes

y  12
1
Area of TPQ   15  6 5  45 5
2
35. If the curves y 2  6 x , 9 x 2  by 2  16 intersect each other at right angles, then the value of b is:
9 7
(1) 4 (2) (3) 6 (4)
2 2
35.(2) 2 yy'  6
6 3
y'  
2 y y1
18 x1  2by1 y'  0
18 x1 9 x1 27 x1 27 x1
y'       1  b
2by1 by1 by12 y12
9
y12  6 x1  b
2
36. If the system of linear equations
x  ky  3 z  0
3 x  ky  2 z  0
2 x  4 y  3z  0
xz
has a non-zero solution ( x, y, z ) , then is equal to:
y2
(1) –30 (2) 30 (3) –10 (4) 10

1 k 3
36.(4) 3 k 2  0
2 4 3
7
 k
2
x  ky  3 z  0 …..(i)
3 x  ky  2 z  0 ….(ii)
2 x  4 y  3z  0 …..(iii)
On solving (i) and (ii)
2x  5z  0 …..(iv)
On solving (iii) and (iv)
4 y  2 z
5
z z
xz
2  10
y2 z2
4

VMC/JEE Mains-2018 13 JEE Entrance Examination


Vidyamandir Classes

37. 
Let S  x  R : x  0 and 2 x  3  x  x  6   6  0 . Then S:
(1) contains exactly two elements. (2) contains exactly four elements.
(3) is an empty set. (4) contains exactly one element.
37.(1) 2 x 3  x  
x 6  6  0

Case-I: x 3
 2  
x 3  x6 x 6  0  x4 x  0  x  0, 16
As x  9  x  16
Case-II: x 3  2 x 6 x6 x 6  0  x  8 x  12  0

  x 6  x2 0   x  36, 4

As, x 3  x4
 There are exactly two elements in the given set.
     1
38. If sum of all the solutions of the equation 8cos x.  cos   x  .cos   x     1 in [0, ] is k  , then k is
 6  6  2
equal to:
8 20 2 13
(1) (2) (3) (4)
9 9 3 9
   1
38.(4) 8 cos x ·  cos 2  sin 2 x     1
 6  2
3 1 
8 cos x    1  cos 2 x   1
4 2 
8 cos x
4

 4 cos 2 x 1  2  1 
cos 3 x  4 cos3 x  3cos x
2  cos3 x  1
1
cos3 x 
2
3 x  0, 3 
   13
3x  , 2  , 2   Sum = .
3 3 3 9
39. A bag contains 4 red and 6 black balls. A ball is drawn at random from the bag, its colour is observed and this
ball along with two additional balls of the same colour are returned to the bag. If now a ball is drawn at random
from the bag, then the probability that this drawn ball is red, is:
1 3 3 2
(1) (2) (3) (4)
5 4 10 5
39.(4)

VMC/JEE Mains-2018 14 JEE Entrance Examination


Vidyamandir Classes

1 1 f x
40. Let f  x   x2  and g  x   x  , x  R  1, 0,1 . If h  x   , then the local minimum value of
x 2 x g  x
h(x) is:
(1) 2 2 (2) 2 2 (3) 3 (4) 3
1
40.(2) Let g  x   x  t
x
1
g'  x   1  0
x2

 t  R  0 ; t 2   0 ,  
2
1  
 f  x   x2    x    2  t 2  2   2,  
2  x
x
f  x
 h  x 
g  x

f  x t2  2 2
  t
g  x t t
2
Let h  t   t 
t
2
h' t   1 
t2

 Local minimum value occurs at t  2


2
 Local minimum value  h  2  2
2
2 2

41. Two sets A and B are as under:


A   a, b   R  R : a  5  1 and b  5  1 ;

B  a,b   R  R : 4  a  6  2 2
 9  b  5   36 
Then:
(1) A  B   (an empty set) (2) neither A  B nor B  A
(3) BA (4) AB

41.(4) Since Set A is, | a  5 | 1 4 < a < 6


and | b  5 | 1 4<b<6
Now B is
(a  6)2 (b  5)2
 1
9 4

VMC/JEE Mains-2018 15 JEE Entrance Examination


Vidyamandir Classes

It can be seen that all vertices of rectangle lie inside the ellipse, therefore A  B

42. The Boolean expression ~  p  q    ~ p  q  is equivalent to:


(1) q (2) ~q (3) ~p (4) p
42.(3)  ( p  q)  (  p  q)
p q  ( p  q)  p q ~ p
T F F F F
T F F F F
F T F T T
F F T F T

43. Tangent and normal are drawn at P(16, 16) on the parabola y 2  16 x , which intersect the axis of the parabola
at A and B, respectively. If C is the centre of the circle through the points P, A and B and CPB   , then a
value of tan  is:
4 1
(1) 3 (2) (3) (4) 2
3 2
43.(4) The equation of tangent at P
1
y  16  (x  16)  A  (16, 0)
2
The normal is y  16  2(x  16)
B  (24, 0)

Since APB 
2
 AB is the diameter.
Center of the circle C  (4, 0)
Slope of PB  2  m1

4 m  m1
Slope of CP   m 2  tan   2 2
3 1  m 2 m1
x  4 2x 2x
2
44. If 2 x x  4 2 x   A  Bx   x  A , then the ordered pair (A, B) is equal to:
2x 2x x  4
(1)  4, 5 (2)  4, 5 (3)  4 ,  5  (4)  4, 3
x  4 2x 2x
44.(1) 2x x  4 2x  (A  Bx)(x  A)2
2x 2x x  4
Put x = 0

VMC/JEE Mains-2018 16 JEE Entrance Examination


Vidyamandir Classes

4 0 0
0 4 0  A3
0 0 4

A  4
Put x = 1
3 2 2
2 3 2  (A  B)(1  A)2
2 2 3
3(9  4)  2(6  4)  2(4  6)
15  20  20  (4  B)25
1  (4  B)
B=5
5 5
45. The sum of the co-efficients of all odd degree terms in the expansion of  x  x3  1    x  x3  1  ,  x  1
   
is:
(1) 1 (2) 2 (3) 1 (4) 0
45.(2) Let x3  1  y

 x  y 5   x  y 5
  5 C0 x5  5C1x4 y  .......  5C5 y5    5 C0 x5  5C1x4  y  ........  5C5 y5 
 2 5C0 x5 5 C2 x3 y 2  5C4 xy 4   2 C0 x5  5C2 x 3 y 2  5C4 xy 4 
   
 2
    
 2  x5  10 x3 x 3  1  5 x x3  1   2  x5  10 x6  10 x3  5 x x 6  1  2 x 3 
    
 2  x5  10 x 6  10 x3  5 x 7  5 x  10 x 4   2 1  10  5  5  2
 
12
46. Let a1, a2, a3 , …, a49 be in A.P. such that a 4k  1  416 and a9  a43  66 . If a12  a22  .....  a17
2
 140 m ,
k 0

then mequal to :
(A) 34 (2) 33 (3) 66 (4) 68
46.(1) a1  a5  a9  ........a49  416  a  24d  32 ……(i)
a9  a43  66  a  25d  33 ….(ii)
From (i) and (ii) d  1 and a  8
Now, a12  a22  ......a17
2
 140m
17 2 17
  8   r  1   140m    7  r 2  140m  4760  140 m  m  34
r 1 r 1
47. A straight line through a fixed point (2, 3) intersects the coordinates axes at distinct points P and Q. If O is the
origin and the rectangle OPRQ is completed, then the locus of R is :
(A) 3 x  2 y  xy (2) 3x + 2y = 6xy
(3) 3x + 2y = 6 (4) 2x + 3y = xy
47.(1) Let, R  (h, k )
 P  (0, k )
Q  (h, 0)
 Equation of line would be,

VMC/JEE Mains-2018 17 JEE Entrance Examination


Vidyamandir Classes

x y
 1 . . . (i)
h k
2 3
  1
h k
2k  3h  hk
Locus of (h, k) is 2 y  3 x  xy

2
sin 2 x
48. The value of  1  2 x
dx is :

2

  
(1) 4 (2) (3) (4)
4 8 2
/ 2
sin 2 x
48.(2) Given  1  2x
dx
 / 2
/ 2 / 2
sin 2 x 2 x (sin 2 x) 
f ( x)  f (  x)    sin 2 x   sin 2 x dx   sin
2
x dx 
x x 4
1 2 1 2 0 0

49. Let g ( x)  cos x 2 , f ( x)  x , and  ,  (   ) be the roots of the quadratic equation 18 x 2  9 x   2  0 .


Then the area (in sq. units) bounded by the curve y  ( gof ) x and the lines x   , x   and y  0 , is :
1 1
(1)
2
 3 2  (2)
2
 2 1 
1 1
(3)
2
 3 1  (4)
2
 3 1 
49.(3) g ( x)  cos x 2
f ( x)  x
g ( f ( x) )  cos x
Given, 18 x 2  9 x  2  0  (6 x  ) (3x  )  0
 
 x ,
6 3
/3
3 1
Area =
 cos x dx  2
/6

1 2  15  
50. For each t  R , let [t] be the greatest integer less than or equal to t. Then lim x        .....    
x  0 x
    x  x 
(1) is equal to 120 (2) does not exist (in R)
(3) is equal to 0 (4) is equal to 15
1 2 15  
50.(1) lim x        ...........    
x 0   x x  x 
 1 1  2 2 15  15  
 lim x          .......   
x0 
 x  x  x  x  x  x 

 1 2 15  
= lim (1  2  3  ........  15)  lim x        ........    
x 0 
x0  x
    x  x 
Now 0   x  1  x  R  120

VMC/JEE Mains-2018 18 JEE Entrance Examination


Vidyamandir Classes

9 9
51. If 
i 1
( xi  5)  9 and  (x
i 1
i  5)2  45 , then the standard deviation of the 9 items x1, x2….. , x9 is :

(1) 2 (2) 3 (3) 9 (4) 4


45
51.(1) Variance =  (1)2  5 1  4
9
  Variance  2

sin 2 x cos 2 x
52. The integral  (sin 5
x  cos x sin 2 x  sin 3 x cos 2 x  cos5 x) 2
3
dx is equal to :

1 1
(1) C (2) C
1  cot 3 x 1  cot 3 x
1 1
(3) 3
C (4) C
3(1  tan x) 3(1  tan 3 x)
(where C is a constant of integration)
sin 2 x cos 2 x
52.(4)  (sin 5 x  cos3 x sin 2 x  sin3 x cos2 x  cos5x) 2 dx
tan 2 x sec6 x
 2
dx
 tan 5 x  tan 2 x  tan 3 x  1 
dt
Put tan x  t  sec2 x 
dx
2 2 2
t (1  t )
 (t 3  1)2 (t 2  1)2 dt
t3  1  y
dy
3t 2 
dt
1 dy 1 1
3 y2 

3(y)
C  
3
3(tan x  1)
C

53. Let S  {t  R : f ( x)  | x   | · (e| x|  1) sin | x | is not differentiable at t}. Then the set S is equal to :
(A)   (2) 0,   (3)  (an empty set) (4) {0}
53.(3) Doubtful points for differentiability are 0 and 
At x = 0
| h   |  (e|h|  1)  sin | h |  0
f (0 )  lim
h o  h

(  h)  (e h  1)  sin h
 lim
h o h
sinh
 lim  1 and lim e h  1  0
h  0 h h o 

 f (0 )    0  1  0

|  h   |  (e|h|  1)  sin |  h |  0
f (0 )  lim
h o h

VMC/JEE Mains-2018 19 JEE Entrance Examination


Vidyamandir Classes

(  h)  (eh  1)  sin h
 lim
h 0 h
sinh
 lim  1 and lim e h  1  0
h  0 h h o 

 f (0 )      0  1  0

 f  (0  )  f (0  )  0

Similarly f  ( )  f  (  )  0
Hence f ( x) is differentiable  x  R
dy  
54. Let y  y  x  be the solution of the differential equation sin x  y cos x  4 x, x   0,   . If y    0 , then
dx 2
 
y   is equal to :
6
8 4 4 8
(1)  2 (2)  2 (3) 2 (4) 2
9 9 9 3 9 3
dy
54.(1)  y cot x  4 x cosec x  d  y sin x   4 xdx
dx
Integrating both sides we get: y sin x  2 x 2  c

  2
Also, y    0  c
2 2
2   8 2
 y sin x  2 x 2  y   

2 6
  9
    
55. Let u be a vector coplanar with the vectors a  2iˆ  3 ˆj  kˆ and b  ˆj  kˆ . If u is perpendicular to a and
  2
u . b  24 , then u is equal to :
(1) 256 (2) 84 (3) 336 (4) 315
      
55.(3) u  (a  b )  0; u  a  0 and u  b  24.
  
Let b  (b  aˆ )aˆ  (b  uˆ )uˆ
  
| b |2  (b  aˆ )2  (b  uˆ ) 2

 2  2 (b  uˆ )2
| b |  (b  aˆ ) 
| uˆ |2
2 (24) 2 
2   | u |2  336
7 | uˆ |2

56. The length of the projection of the line segment joining the points  5, 1, 4  and  4, 1,3 on the plane,
x  y  z  7 is:

1 2 2 2
(1) (2) (3) (4)
3 3 3 3
x  5 y 1 z  4
56.(2)   
1 1 1
P    5,   1,   4 
P is foot of perpendicular from A to plane 3  8  7
1
 
3

VMC/JEE Mains-2018 20 JEE Entrance Examination


Vidyamandir Classes

 14 4 11 
P , , 
 3 3 3
x  4 y 1 z  3
 
1 1 1
Q    4,   1,   3 
Q is foot of perpendicular from B to plane
3  6  7
1

3
 13 2 10 
Q , , 
 3 3 3
1 4 1 6 2
 PQ   
3 3 3

57. PQR is a triangular park with PQ = PR = 200 m. A T.V. tower stands at the mid-point of QR. If the angles of
elevation of the top of the tower at P, Q and R are respectively 45°, 30° and 30°, then the height of the tower (in
m) is :
(1) 100 3 (2) 50 2 (3) 100 (4) 50
h 1
57.(3) 
x 3
x  3h
200  3h 2  h 2
4h 2  (200)2

4 h2  40000
h  100

58. From 6 different novels and 3 different dictionaries, 4 novels and 1 dictionary are to be selected and arranged in
a row on a shelf so that the dictionary is always in the middle. The number of such arrangements is:
(1) at least 500 but less than 750 (2) at least 750 but less than 1000
(3) at least 1000 (4) less than 500
6
58.(3) C4  3C1  1  4!
65
 3  24  45  24  1080
2

59. Let A be the sum of the first 20 terms and B be the sum of the first 40 terms of the series
12  2.22  32  2.4 2  52  2.62  ..... If B  2 A  100 , then  is equal to:
(1) 464 (2) 496 (3) 232 (4) 248
2 2 2 2 2 2
59.(4) A  1  2.2  3  2.4  ........  A  2.20

  
 12  2 2  32  42 .........  202  22  42  .......  202 
20  21  41 10  11  21
  4  2870  1540  4410  2870  1540  4410
6 6
40  41  81 4  20  21  41
B   540  41  41  280  41  820  33620
6 6
33620  8820  100
100  24800
  248

VMC/JEE Mains-2018 21 JEE Entrance Examination


Vidyamandir Classes

60. Let the orthocentre and centroid of a triangle be A  3,5 and B(3, 3) respectively. If C is the circumcentre of
this triangle, then the radius of the circle having line segment AC as diameter, is :
5 3 5
(1) 3 (2) (3) 10 (4) 2 10
2 2
60.(1)

2a  3
3  2a  12  a  6
3
2b  5
3  2b  4  b  2
3

AC  (6  3)2  32
Diameter  AC  81  9  90
3 10 3  10 5
Radius   3
2 2 2 2

PART-C CHEMISTRY

61. Total number of lone pair of electrons in I3 ion is :


(1) 9 (2) 12 (3) 3 (4) 6
61.(1) I3 3
is - sp d hybridised
- linear shape

62. Which of the following salts is the most basic in aqueous solution?
(1) FeCl3 (2) Pb(CH3COO) 2 (3) Al(CN)3 (4) CH3COOK

62.(4) CH3COOK is a salt of a weak acid and a strong base

 Most basic
63. Phenol reacts with methyl chloroformate in the presence of NaOH to form product A. A reacts with Br2 to form
product B. A and B are respectively:

(1)

(2)

VMC/JEE Mains-2018 22 JEE Entrance Examination


Vidyamandir Classes

(3)

(4)

63.(1)

64. The increasing order of basicity of the following compounds is:

(a) (b)

(c) (d)

(1) (b) < (a) < (d) < (c) (2) (d) < (b) < (a) < (c)
(3) (a) < (b) < (c) < (d) (4) (b) < (a) < (c) < (d)

64.(1) Amidines, are stronger organic bases.

65. An alkali is titrated against an acid with methyl orange as indicator, which of the following is a correct
combination?
Base Acid End point
(1) Weak Strong Yellow to pinkish red
(2) Strong Strong Pink to colourless
(3) Weak Strong Colourless to pink
(4) Strong Strong Pinkish red to yellow
65.(1) Methyl orange is used for titration of strong acid and weak base.

66. The trans-alkenes are formed by the reduction of alkynes with:


(1) Na / liq. NH3 (2) Sn  HCl
(3) H2  Pd / C, BaSO4 (4) NaBH4

66.(1)

VMC/JEE Mains-2018 23 JEE Entrance Examination


Vidyamandir Classes

67. The ratio of mass percent of C and H of an organic compound (CX H Y O Z ) is 6 : 1. If one molecule of the above
compound (CX HY O Z ) contains half as much oxygen as required to burn one molecule of compound
CX H Y completely to CO 2 and H 2 O . The empirical formula of compound CX H Y O Z is:
(1) C3 H 4 O 2 (2) C2 H 4 O3 (3) C3 H6 O3 (4) C2 H 4 O
67.(2) Cx H y Oz has z oxygen atom

 y y
Cx H y   x   O2 
 x CO2  H 2O
 4 2
 y
O atoms required for combustion  2  x  
 4
1  y 
z 2  x  
2   4  
y
zx
4

68. Hydrogen peroxide oxidises [Fe(CN) 6 ]4 to [Fe(CN) 6 ]3 in acidic medium but reduces [Fe(CN) 6 ]3 to

[Fe(CN) 6 ]4 in alkaline medium. The other products formed are, respectively:

(1) H 2 O and (H 2 O  O2 ) (2) H 2 O and (H 2 O  OH  )

(3) (H 2 O  O2 ) and H 2 O (4) (H 2 O  O2 ) and (H 2 O  OH  )

68.(1) During reduction H 2O 2 


 H2O

During oxidation H 2 O2 
 O2

69. The major product formed in the following reaction is :

(1) (2) (3) (4)


69.(2)

Option (2) is correct [NCERT Class XII Part-II, Page No.-340]

70. How long (approximate) should water be electrolysed by passing through 100 amperes current so that the oxygen
released can completely burn 27.66 g of diborane ?
(Atomic weight of B  10.8 u)
(1) 3.2 hours (2) 1.6 hours (3) 6.4 hours (4) 0.8 hours

VMC/JEE Mains-2018 24 JEE Entrance Examination


Vidyamandir Classes

70.(1) B2 H 6  3O2 
 B2 O 3  3 H 2 O
27.66
nB2 H 6  1
27.66
n O2 required = 3

2H 2O 
 2 H 2  O2
n-factor for O2 = 4
 Number of equivalent = 3  4  12F  12  96500 C
i  t  12  96500
12  96500 12  96500
t s  h  3.2 hr
100 100  3600

71. Which of the following lines correctly show the temperature dependence of equilibrium constant, K, for an
exothermic reaction?

(1) C and D (2) A and D (3) A and B (4) B and C


71.(3) G  H  TS
 RTnk  H  TS
H S
nk  
RT R
H
Slope is
R
Since H is  ve
 Slope is positive.

72. At 518° C, the rate of decomposition of a sample of gaseous acetaldehyde, initially at a pressure of 363 Torr, was
1.00 Torr s–1 when 5% had reacted and 0.5 Torr s 1 when 33% had reacted. The order of the reaction is :
(1) 1 (2) 0 (3) 2 (4) 3
n
72.(3) r  k A 
n
1  k  363  0.95  ….(i)
n
0.5  k  363  0.67  ….(ii)
From (i) and (ii)
n2

73. Glucose on prolonged heating with HI gives :


(1) Hexanoic acid (2) 6-iodohexanal
(3) n-Hexane (4) 1-Hexene
73.(3)

Option (3) is correct [NCERT Class XII Part-II, Page No 405]

VMC/JEE Mains-2018 25 JEE Entrance Examination


Vidyamandir Classes

74. Consider the following reaction and statements :


[Co(NH3 ) 4 Br2 ]  Br   [Co(NH 3 )3 Br3 ]  NH 3
(A) Two isomers are produced if the reactant complex ion is a cis-isomer.
(B) Two isomers are produced if the reactant complex ion is a trans-isomer.
(C) Only one isomer is produced if the reactant complex ion is a trans-isomer.
(D) Only one isomer is produced if the reactant complex ion is a cis-isomer.
The correct statement are :
(1) C and D (2) B and D (3) A and B (4) A and C
74.(4) Case - I

Case - II

 Two isomers (fac and mer) are produced if reactant complex ion is a cis isomer.
Only one isomer (fac) is formed if reactant complex ion is a trans isomer.
75. The major product of the following reaction is :

(1) (2)

(3) (4)

75 (4).

VMC/JEE Mains-2018 26 JEE Entrance Examination


Vidyamandir Classes

76. Phenol on treatment with CO2 in the presence of NaOH followed by acidification produces compound X as the
major product. X on treatment with (CH 3CO)2 O in the presence of catalytic amount of H2SO4 produces :

(1) (2) (3) (4)

76 (3).
OH OH

COOH
NaOH H3O +
+ CO 2

(X)

OH OCOCH3

COOH COOH
H2SO4
+ (CO3CO)2O + CH3 COOH
Cat

(X) Aspirin
77. An aqueous solution contains an unknown concentration of Ba 2  . When 50 mL of a 1 M solution of Na 2SO4 is
added, BaSO4 just begins to precipitate. The final volume is 500 mL. The solubility product of BaSO4 is

1 1010. What is the original concentration of Ba 2  ?


(1) 1.1  10 9 M (2) 1.0  1010 M (3) 5  10 9 M (4) 2  109 M

77.(1)  Ba 2  (aq)  SO42  (aq)


BaSO 4 (s)  Ksp  1010

Na 2SO4  2Na   SO 42 
50  1
Conc. of SO 24  in final solution   0.1M
500
For final solution
  Ba 2  SO24    10 10   Ba 2   10 9 M
    
M i Vi  Mf Vf

C  450  109  500  C  1.1 109 M

78. Which of the following compounds will be suitable for Kjeldahl's method for nitrogen estimation ?

(1) (2) (3) (4)

78.(4) Kjeldahl method is not applicable to compounds containing nitrogen in nitro (NO2) and azo (N = N –) groups
and nitrogen present in the ring (pyridine) as nitrogen of these compounds does not change to ammonium sulphate.

VMC/JEE Mains-2018 27 JEE Entrance Examination


Vidyamandir Classes

[NCERT Class XI part II/Page No. 358]

79. When metal 'M' is treated with NaOH, a white gelatinous precipitate 'X' is obtained, which is soluble in excess of
NaOH. Compound 'X' when heated strongly gives and oxide which is used in chromatography as an adsorbent.
The metal 'M' is :
(1) Al (2) Fe (3) Zn (4) Ca
NaOH
79.(1)  Al  OH 3 
Al  NaOH   NaAlO2
(M)
white gel ppt
(X)

Al  OH 3  Al2 O3
Al2 O3 is used in chromatography as an absorbent. (Refer NCERT Class XIth/Part-II, Page-352)

80. An aqueous solution contains 0.10 M H 2S and 0.20 M HCl. If the equilibrium constants for the formation of

HS from H 2S is 1.0  107 and that S2 from HS ions is 1.2  1013 then the concentration of S2  ions in
aqueous solution is :
(1) 6  1021 (2) 5  10 19 (3) 5  108 (4) 3  1020
80.(4)  H   Cl 
HCl 
0.2M 0.2 M

 H   HS
H 2 S  K1  107

 H   S2 
HS  K 2  1.2  1013

 2H   S2 
H 2 S  K  K1  K 2
 1.2  1020
2
H   S2 
K     H    0.2M ,  H 2S  0.1
 H 2S  

 0.22 S2  
1.2  10 20   S2    3  10 20 M
0.1  
81. The recommended concentration of fluoride ion in drinking water is up to 1 ppm as fluoride ion is required to
make teeth enamel harder by converting 3Ca 3  PO4 2  Ca  OH 2  to :

(1) 3Ca 3  PO4   CaF2 


 2  (2)
  2 
3 Ca 3  OH   CaF2 

(3) CaF2  (4) 3  CaF2   Ca  OH  
 2
81.(1) (Refer NCERT Class XIth Part-II, Page-407)
The F ions make the enamel on teeth much harder by converting hydroxyapatite, 3Ca 3  PO4 2  Ca  OH 2  ,

into much harder fluorapatite i.e. 3Ca 3  PO4 2  CaF2 

82. The compound that does not produce nitrogen gas by the thermal decomposition is :
(1) NH 4 NO2 (2)  NH 4 2 SO4 (3) Ba  N3 2 (4)  NH 4 2 Cr2O7

82.(2) NH 4 NO 2  N 2  2H 2 O

 NH4 2 SO4   NH3  H 2SO 4

Ba  N3 2  Ba  3N 2

 NH 4 2 Cr2 O7   N 2  4H 2 O  Cr2 O3

VMC/JEE Mains-2018 28 JEE Entrance Examination


Vidyamandir Classes

83. The predominant form of histamine present in human blood is (pK a Histidine = 6.0) :

(1) (2)

(3) (4)

83.(3) NCERT Class XII/Part-II, Page No. 443

84. The oxidation state of Cr in Cr  H 2 O   Cl3 ,  Cr  C6 H 6   , and K 2 Cr  CN 2  O 2  O 2  NH3 
 6  2
respectively are:
(1)  3, 0, and  6 (2)  3, 0 and  4 (3)  3,  4 and  6 (4) 3,  2 and  4

84.(1) Cr  H 2 O   Cl3


 6
x 03  0
x  3
Cr  C6 H6  
 2
x0  0
x0

K 2 Cr  CN 2  O 2  O2  NH3 


2 x2420  0
x  6
85. Which type of 'defect' has the presence of cations in the interstitial sites ?
(1) Frenkel defect (2) Metal deficiency defect
(3) Schottky defect (4) Vacancy defect
85.(1) Pressure of cation in interstitial sites is ‘Frenkel’ defect.

86. The combustion of benzene () gives CO 2 (g) and H 2 O(). Given that heat of combustion of benzene at

constant volume is  3263.9 kJ mol 1 at 25°C, heat of combustion (in kJ mol 1 ) of benzene at constant pressure
will be :
(R  8.314 JK 1 mol1 )
(1) 3260 (2)  3267.6 (3) 4152.6 (4)  452.46

15
86.(2) C6 H6 ()   6CO2 (g)  3H 2 O ()
O 2 (g) 
2

3
n (g)  
2

H  U  n (g) RT

1.5  8.314  298


 3263.9   3267.6 kJ / mol
1000
87. Which of the following are Lewis acids?

VMC/JEE Mains-2018 29 JEE Entrance Examination


Vidyamandir Classes

(1) PH3 and SiCl4 (2) BCl3 and AlCl3


(3) PH3 and BCl3 (4) AlCl3 and SiCl4

87.(2) BCl3 and AlCl3 are e deficient and thus act as Lewis acid

88. Which of the following compounds contain(s) no covalent bond(s)?


KCl, PH3 , O2 , B2 H6 , H 2SO4
(1) KCl (2) KCl, B2H6 (3) KCl, B2H6, PH3 (4) KCl, H2SO4

88.(1) KCl exist as K and Cl

89. For 1 molal aqueous solution of the following compounds, which one will show the highest freezing point?
(1) [Co(H 2 O) 4 Cl2 ]Cl.2H 2 O (2) [Co(H 2 O)3 Cl3 ].3H 2 O
(3) [Co(H 2 O)6 ]Cl3 (4) [Co(H 2 O)5 Cl]Cl2 .H 2 O

89.(2) Depression in freezing pt

Tf  i K f m

Less the value of i,

Higher the value of freezing pt.

For (2) i = 1 (min)

90. According to molecular orbital theory, which of the following will not be a viable molecule?
(1) H 2 (2) H 22  (3) He 22  (4) He 2

90.(2) H 22  does not exist as Bond order is zero

Electronic configuration of H 22  : 1s


2 2
*1s

VMC/JEE Mains-2018 30 JEE Entrance Examination

You might also like