You are on page 1of 3

6/14/2019 The Iron Carbon Phase Diagram

The Iron Carbon Phase Diagram


There is more to the iron-carbon phase diagram than related in the backbone. In particular, there is some nomenclature that I avoided in the main text but that is important for
understanding other writings about iron and steel. So let's start with a phase diagram that contains maximal information:

Iron-carbon Phase Diagram

Source: Arabic Internet site

The important boundaries (the lines) separating phases have some universally used abbreviations:

A1: The upper limit of the ferrite / cementite phase field (horizontal line going through the eutectoid point).
A2: The temperature where iron looses its magnetism (so-called Curie temperature). Note that for pure iron this is still in the α-phase.
A3: The boundary between the γ austenite and the austenite/ ferrite field.
A4: The point in this case where α changes to δ at high temperatures.
ACM: The boundary between the γ austenite and the austenite / cementite field.

Why would anybody abbreviate a temperature with the letter "A"? Well, it stands for "arrest", something that happens in the slope of dilatometric or thermal curves recorded
phase diagrams where first measured.
Statements like "the addition of x lowers A3" are now clear.
The circular insets give a schematic idea of what the structure would like at the compositions and temperatures indicated.
The next thing to know is that the phase diagrams above is actually not the true iron-carbon phase diagram. I lied to you. Some mixture of cementite and iron is not the configura
allows the system to achieve total nirvana. That would be a iron - graphite mixture.
All the cementite forming is just a transient phase on the way to nirvana; it will decay into pure carbon (graphite) and iron in due time. Due time, however, means millennia an
at room temperature for plain carbon steel. Cementite, in other words, is a very long-lived metastable phase under normal conditions. It thus makes sense to use it for some
is not a true phase diagram for purists, but that sane normal folks will call "phase diagram" anyway.
We are also justified in doing this because the "real" iron - graphite phase diagram looks almost exactly like the iron - cementite "phase diagram". Here is the proof:

https://www.tf.uni-kiel.de/matwis/amat/iss/kap_6/illustr/s6_1_2.html 1/3
6/14/2019 The Iron Carbon Phase Diagram

Iron - carbon phase diagram in comparison to


the iron cementite phase diagram

Does that mean that we don't have to worry about graphite being formed? Yes and no. Like almost always, it depends:
For plain carbon steel with carbon concentrations below 2 %, you needn't worry, indeed. Graphite is never formed and the usual phase diagram covers everything nicely.
For cast-iron, with carbon concentrations up to a few percent you need to worry. Graphite might form, depending on conditions.
For alloy steel, the usual thing nowadays, you need to worry, too. Some alloying elements, in particular silicon (Si) but also nickel (Ni), promote graphite formation.

With frame

Science of Welding Steel

8.4.2 Multiculti in Steel

Science of Alloying

TTT Diagrams: 1. The Basic Idea

10.2.3 Smelting Wrought Iron, Steel and Cast Iron

11.5 Wootz Swords; 11.5.1 The Winner is....

11.5.2 Structure by Dendrites?

11.5.3 Forging a Wootz Sword

11.6.3 Making a Japanese Sword - Part 2

10.5.2 Making Steel up to 1870

Tricks of Smiths

TTT Diagrams

Cast Iron; 9.5.1 General Remarks

6.1.3 Reading Phase Diagrams: Mixed Phases and Boundaries

6.2.1 Creamy or Chunky?

Overview of Major Steels

Segregation at Room Temperature

Constitutional Supercooling and Interface Stability

10.4.2 Making Old-Fashioned Crucible Steel in Modern Times

https://www.tf.uni-kiel.de/matwis/amat/iss/kap_6/illustr/s6_1_2.html 2/3
6/14/2019 The Iron Carbon Phase Diagram
© H. Föll (Iron, Steel and Swords script)

https://www.tf.uni-kiel.de/matwis/amat/iss/kap_6/illustr/s6_1_2.html 3/3

You might also like