Professional Documents
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REACH Registration Number A registration number is not available for this substance as the
substance or its use are exempted from registration according to
Article 2 REACH Regulation (EC) No 1907/2006, the annual tonnage
does not require a registration or the registration is envisaged for a
later registration deadline.
CAS-No. 6032-29-7
1.2 Relevant identified uses of the substance or mixture and uses advised against
1.4 Emergency telephone Please contact the regional company representation in your country.
number
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 1 of 17
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
For the full text of the H-Statements mentioned in this Section, see Section 16.
Hazard pictograms
Signal word
Warning
Hazard statements
H226 Flammable liquid and vapour.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
EUH066 Repeated exposure may cause skin dryness or cracking.
Precautionary statements
Prevention
P210 Keep away from heat.
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 2 of 17
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Hazard pictograms
Signal word
Warning
Index-No. 603-006-00-7
3.1 Substance
Index-No. 603-006-00-7
EC-No. 227-907-6
*) A registration number is not available for this substance as the substance or its use are exempted from registration according to Article
2 REACH Regulation (EC) No 1907/2006, the annual tonnage does not require a registration or the registration is envisaged for a later
registration deadline.
For the full text of the H-Statements mentioned in this Section, see Section 16.
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 3 of 17
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
3.2 Mixture
Not applicable
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/
shower.
After eye contact: rinse out with plenty of water. Remove contact lenses.
After swallowing: immediately make victim drink water (two glasses at most). Subsequently
administer: activated charcoal (20 - 40 g in 10% slurry). Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
irritant effects, Cough, Shortness of breath, Dizziness, Unconsciousness, narcosis, Nausea,
Vomiting, Headache, muscular weakness, confusion, Coma, Repeated exposure may cause skin
dryness or cracking.
4.3 Indication of any immediate medical attention and special treatment needed
Laxative: Sodium sulfate (1 tablespoon/1/4 l water).
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 4 of 17
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Further information
Remove container from danger zone and cool with water. Prevent fire extinguishing water from
contaminating surface water or the ground water system.
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 5 of 17
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Hygiene measures
Change contaminated clothing. Preventive skin protection recommended. Wash hands after
working with substance.
Engineering measures
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Technical measures and appropriate working operations should be given priority over the use of
personal protective equipment.
Eye/face protection
Safety glasses
Hand protection
full contact:
Glove material: butyl-rubber
Glove thickness: 0,70 mm
Break through time: > 480 min
splash contact:
Glove material: Nitrile rubber
Glove thickness: 0,40 mm
Break through time: > 240 min
The protective gloves to be used must comply with the specifications of EC Directive
89/686/EEC and the related standard EN374, for example KCL 898 Butoject® (full contact), KCL
730 Camatril® -Velours (splash contact).
The breakthrough times stated above were determined by KCL in laboratory tests acc. to EN374
with samples of the recommended glove types.
This recommendation applies only to the product stated in the safety data sheet<(>,<)> supplied
by us and for the designated use. When dissolving in or mixing with other substances and under
conditions deviating from those stated in EN374 please contact the supplier of CE-approved
gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Respiratory protection
required when vapours/aerosols are generated.
Recommended Filter type: Filter A-(P3)
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective
devices are carried out according to the instructions of the producer. These measures have to be
properly documented.
Form liquid
Colour colourless
pH No information available.
Flash point 41 °C
Method: c.c.
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 8 of 17
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 9 of 17
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
10.1 Reactivity
Vapour/air-mixtures are explosive at intense warming.
Fluorine, Oxygen
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Skin irritation
Rabbit
Result: No irritation
(External MSDS)
Repeated exposure may cause skin dryness or cracking.
Eye irritation
Rabbit
Result: No eye irritation
(External MSDS)
Sensitisation
In animal experiments:
Result: negative
(External MSDS)
Carcinogenicity
This information is not available.
Reproductive toxicity
This information is not available.
Teratogenicity
This information is not available.
Aspiration hazard
This information is not available.
12.1 Toxicity
Toxicity to daphnia and other aquatic invertebrates
EC50 Tetrahymen pyriformis: 1,57 mg/l; 48 h
(ECOTOX Database)
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 12 of 17
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Ratio BOD/ThBOD
BOD28 90 %
(External MSDS)
(Lit.)
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
14.3 Class 3
Not relevant
14.3 Class 3
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
14.3 Class 3
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not relevant
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations
Major Accident Hazard SEVESO III
Legislation FLAMMABLE LIQUIDS
P5c
Quantity 1: 5.000 t
Quantity 2: 50.000 t
Occupational restrictions Take note of Dir 94/33/EC on the protection of young people at
work. Observe work restrictions regarding maternity protection in
accordance to Dir 92/85/EEC or stricter national regulations where
applicable.
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 15 of 17
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Substances of very high concern (SVHC) This product does not contain substances
of very high concern according to
Regulation (EC) No 1907/2006 (REACH),
Article 57 above the respective regulatory
concentration limit of ≥ 0.1 % (w/w).
National legislation
Storage class 3
For this product a chemical safety assessment was not carried out.
Training advice
Provide adequate information, instruction and training for operators.
Labelling
Hazard pictograms
Signal word
Warning
Hazard statements
H226 Flammable liquid and vapour.
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 16 of 17
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Precautionary statements
Prevention
P210 Keep away from heat.
Key or legend to abbreviations and acronyms used in the safety data sheet
Regional representation
This information is given on the authorised Safety Data Sheet for your country.
The information contained herein is based on the present state of our knowledge. It characterises the product with
regard to the appropriate safety precautions. It does not represent a guarantee of any properties of the product.
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
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