Datos:

P 286 atm
Fracción mol
H2 0.6548
N2 0.2182
NH3 0.05
He 0.077
Tref 298.15 K

Cp/R a b c
H2 2.883 3.68E-03 -7.72E-06
N2 3.539 -2.61E-04 7.00E-08
NH3 4.238 -4.22E-03 2.04E-05
He 2.5 0 0

H2 N2 NH3
∆Hf°(kJ/mol) 0 0.00 -45.94
∆Gf°(kJ/mol) 0 0.00 -16.41
∆Sf°(kJ/mol-K) 0 0 -0.0990441053

Calculos:
∆a ∆b ∆c ∆d

Δ𝐻_𝑅°=∑▒ 〖� _� Δ𝐻_𝑓° 〗 𝛥𝐻_𝑅=��_�°+𝑅(Δ𝑎(𝑇−𝑇_𝑟𝑒𝑓 )+1/2 Δ𝑏(�^2−�_���^2 )+

∆HR°(kJ/mol)
Δ𝑆_𝑅°=∑▒ 〖� _� Δ𝑆_𝑓° 〗
∆SR°(kJ/mol-K)
δ 𝛥𝑆_𝑅=�𝑆_�°+𝑅(Δ𝑎 𝑙𝑛(𝑇/𝑇_𝑟𝑒𝑓 )+Δ𝑏(�−�_��� )+1/2 Δ
FT0(kmol/h)
yN20
�=𝛿𝑦_𝑁20
ε
ΘH2
Θ_𝐻2=𝐹_𝑖0/𝐹_𝑁20
ΘNH3
ΘHe

T(°C) T(K) ∆HR(kJ/mol) ∆SR(kJ/mol-K)

200 473.15
220 493.15
240 513.15
260 533.15
280 553.15
300 573.15
320 593.15
340 613.15
360 633.15
380 653.15
400 673.15
420 693.15
440 713.15
460 733.15
480 753.15
500 773.15
520 793.15
540 813.15
560 833.15
580 853.15
600 873.15
 𝑁_2+3𝐻_2⇌𝑁𝐻_3

d e
6.92E-09 -2.13E-12
1.57E-09 -9.90E-13
-2.13E-08 7.61E-12
0 0

He
0.00
0.00Δ𝑆°_𝑓=(Δ𝐻°_�−Δ�°_�)/𝑇_𝑟𝑒𝑓
0

Δ𝑎=∑▒ 〖� _𝑖 𝑎_𝑖Δ𝑏=∑▒
〗 〖� _𝑖 𝑏_𝑖 〗 〗�=∑▒ 〖� _𝑖 �_𝑖 Δ
Δ�=∑▒ 〖� _𝑖 �_𝑖 Δ 〗𝑒=∑▒ 〖� _𝑖 𝑒_𝑖 〗
∆e

𝑇_𝑟𝑒𝑓 )+1/2 Δ𝑏(�^2−�_���^2 )+1/3 Δ�(�^3−�_���^3 )+1/4 Δ�(�^4−�_���^4 )+1/5 Δ𝑒(�^5−�_���^5 ))

(𝑇/𝑇_𝑟𝑒𝑓 )+Δ𝑏(�−�_��� )+1/2 Δ�(�^2−�_���^2 )+1/3 Δ�(�^3−�_���^3 )+1/4 Δ𝑒(�^4−�_���^4 ))

𝑦_𝑁2=(𝑦_𝑁20 (1−𝑋))/((1+�𝑋))
�_𝑝^((1))=𝑒^(−(Δ�_𝑅)/𝑅𝑇) 𝑦_𝑁𝐻3=(𝑦_𝑁20 (Θ_𝑁𝐻
𝑦_𝐻2=(𝑦_𝑁20 (Θ_𝐻2−3𝑋))/((1+�𝑋))
Δ�_𝑅=Δ𝐻_𝑅−𝑇Δ𝑆_𝑅

∆GR(kJ/mol) Kp(1) Xeq yN2 yH2 yNH3 yHe

 𝑦_𝑁𝐻3=(𝑦_𝑁20 (Θ_𝑁𝐻3+2𝑋))/((1+�𝑋))
𝑋))/((1+�𝑋)) �_𝑝^((2))=(𝑦_𝑁𝐻3^2)/(𝑦_𝑁2 𝑦_𝐻2^3 ) 𝑃^(−2)
𝑦_𝐻𝑒=1−(𝑦_𝑁2+𝑦_𝐻2+𝑦_𝑁𝐻3)

Kp(2) Error 𝐸𝑟𝑟𝑜𝑟=|ln(�_𝑝^((1) ))−ln(�_𝑝^((2) ))|

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