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TECHNOLOGICAL
UNIVERSITY
COMPOSITE MATERIAL
TECHNOLOGY
(ME 328)
GROUP MEMBERS
Rubber Composites
Short coir fibre reinforced natural rubber composites
were developed and investigated the effects of fibre
length, orientation, and alkali treatment on mechanical
properties and processability characteristics. They
pointed out that mechanical properties of the composites
were superior in the longitudinal direction than in the
transverse direction. It was concluded that the optimum
length of coir fibre was found to be 10 mm. The alkali
treated fibers showed better-reinforcing property
compared with the untreated one. SEM and anisotropic
swelling studies confirmed this. It was also studied
the dynamic mechanical behaviour of natural rubber and
its composites reinforced with short coir fibers. It
was observed that maxima in tan d, E00, and the middle
point of the E0 versus temperature curve of the gum-
natural rubber compound at 1 and 10 Hz almost coincided
with one another. However, in the case of composites,
the maxima in tan d and E00 did not coincide. In
addition, the values of E0, E00, and tan d of the gum
increase with fibre incorporation, indicate lower heat
dissipation in gum. They pointed out that a composite
with poor interfacial bonding tend to dissipate more
energy than the composite with good interfacial bonding.
Damping studies revealed that these composites are good
elastomeric compounds at higher temperatures. The
stress relaxation behaviour of natural rubber (NR) and
its composites reinforced with short coir fibers under
tension was analysed. It was noted that the relaxation
mechanisms of both the unfilled compound and the
composite were influenced by the strain rate, fibre
loading and fibre orientation. From the result, it was
found that fibre–rubber adhesion was best in the
composite containing alkali treated, toluene di-
isocyanate and NR solutions along with a hex resorcinol
system as a bonding agent.
Coir Fibre Reinforced Hybrid Composites
Natural fibers can be mixed with thermosetting or
thermoplastic polymer matrix to make composites.
Nowadays, hybrid composites are getting significant
attention due to their superior combination properties
and less expense. With respect to a single fibre
reinforced composites, hybrid composites showed a
synergistic property.
Chemical Modification
Chemical modification is effected through the chemical
reaction between some reactive constituents of the coir
fiber and a chemical reagent, with or without a
catalyst, resulting in a covalent bond between the fiber
and chemical reagent. At temperatures below 1508C, the
chemicals must be capable of reacting with
lignocellulosic hydroxyls under neutral, mild alkaline
or acid conditions. Alkaline Treatment. This is one of
the most widely used chemical treatments of natural
fibers. The modification formed due to the disruption
of hydrogen bonding in the three-dimensional structure
of fiber resulted in an increase in surface roughness.
The alkaline treatment helps to remove waxes, lignin,
etc. on the external surface of the fiber and
depolymerizing the cellulose . Addition of aqueous
sodium hydroxide (aq. NaOH) to natural fiber leads to
an ionization of the hydroxyl group to the alkoxide.
Maleated Coupling Agents
Maleated coupling agents are used with fillers and fiber
reinforcement to strengthen the composites . They also
help to achieve better interfacial bonding and
mechanical properties in composites .Nadir et al. used
MAPP as coupling agents for the surface modification of
coir fibers. It has been found that 60 wt% coir fiber,
37 wt% PP powder, and 3 wt% MAPP offered better
mechanical and flammability properties. The mechanism
of grafting of MAPP with coir fiber is as shown in
Scheme 2.