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COLLEGE OF ENGINEERING
DEPARTMENT OF CIVIL ENGINEERING
TE 41 – CONCRETE TECHNOLOGY
CHAPTER 4
MIXING WATER
FOR CONCRETE
BSCE – 4D
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1. Mixing Water
Water is a key ingredient in concrete, that when mixed with portland cement,
forms a paste that binds the aggregates together. Water causes the hardening of concrete
through hydration. Hydration is a chemical reaction between cement and water to form
cementitious hydration products. Water needs to be of suitable quality for use in concrete
as to not adversely impact the potential properties of concrete. Almost any water that is
drinkable and has no pronounced taste or odor, also known as potable water, can be used
as mixing water in concrete.
2. Quality of Water
The quality of the water plays an important role in the preparation of concrete.
Impurities in water may interfere with the setting of the cement and may adversely
affect the strength and durability of the concrete
The chemical constituents present in water may actively participate in the chemical
reactions and thus affect the setting, hardening and strength development of concrete.
3. Testing of Water
Testing of water play an important role in controlling the quality of cement
concrete work. Systematic testing of the water helps to achieve higher efficiency of cement
concrete and greater assurance of the performance in regard to both strength and
durability.
Some waters that are not fit for drinking may be suitable for concrete making
provided that they satisfy the acceptance criteria laid by ASTM C 94 (Tables 3.1)
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3.1 Tests required for quality of water for Concrete construction purpose:
1. pH Value Test
2. Limits of acidity Test
3. Limits of Alkalinity Test
4. Percentage of Solids
5. Chlorides
6. Suspended Matter
7. Sulphates
8. Inorganic Solids
9. Organic Solids
The pH value of water shall not be less than the following concentrations
represent the maximum permissible values (of deleterious materials in water):
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Table 2. Limits in each type of solids found in Mixing Water
Types of solids Limits
Organic solids 200 mg/liter
Inorganic solids 3000 mg/liter
Sulphates 400 mg/liter
2000 mg/liter for concrete not containing
Chlorides embedded steel, and
500 mg/liter for reinforced concrete work
Suspended matter 2000 mg/liter
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Municipal Reclaimed Water
Reclaimed water is wastewater treated to remove solids and certain impurities. It is
typically used for nonpotable applications uses such as irrigation, dust control, fire
suppression, concrete production, and construction.
Site-Sourced Water
Many large concrete paving projects and remote construction sites use site source
water either from shallow wells, ponds, or rivers. These natural sources of water are typically
not a concern. When they contain significant amounts of suspended particles such as silt and
contain organic impurities and algae, additional testing is warranted.
6. Organic Impurities
Sugar
Small amount of sucrose, as little as 0.03% to 0.15% by mass of cement, usually retard
the setting of cement. The upper limit of this range varies with the different cements.
Allowable amount of Sugar should be <500 ppm.
Oils
Various kinds of oil are occasionally present in mixing water. Mineral oil (petroleum)
not mixed with animal or vegetable oils probably has less effect on strength development that
other oils. However, mineral oil in concentrations greater than 2.5% by mass of cement may
reduce strength by more than 20%.
Algae
Water containing algae is unsuited for making concrete because the algae can cause
an excessive reduction in strength. Algae in water leads to lower strengths either by
influencing cement hydration or by causing a large amount of air to be entrained in the
concrete.
Carbonates and Bicarbonates of sodium and potassium have different effects on the
setting times of different cements.
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Sodium carbonate can cause very rapid setting, bicarbonates can either accelerate or
retard the set.
Chloride
Concern over a high chloride content in mixing water is chiefly due to the possible
adverse effect of chloride ions on the corrosion of reinforcing steel or prestressing
strands.
An acceptable limit of chloride in the concrete depends primarily upon the type of
structure and the environment to which it is exposed during its service life.
The ACI 318 building code limits water soluble chloride ion content in reinforced concrete to
the following percentages by mass of cement:
Prestressed concrete 0.06 %
Reinforced concrete exposed to chloride in surface 0.15 %
Reinforced concrete that will be dry or protected from moisture in service 1.00 %
Other reinforced concrete construction 0.30 %
Sulfate
Concern over a high sulfate content in mix water is due to possible expansive reactions
and deterioration by sulfate attack, especially in areas where the concrete will be exposed to
high sulfate soils or water.
This are not very soluble in water and are seldom found in sufficient concentration to
affect the strength of concrete.
Concentrations up to 400 ppm of bicarbonates in these forms are not considered harmful.
Magnesium Sulfate
Magnesium Chloride
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Iron Salts
Natural ground waters seldom contain more than 20 to 30 ppm of iron; however, acid
mine waters may carry rather large quantities. Iron salts in concentration up to 40,000 ppm
do not usually affect concrete strengths adversely.
Sodium Sulfide
Even the presence of 100 ppm, warrants testing. Concern over a high sulfate content in mix
water is due to possible expansive reactions and deterioration by sulfate attack. Although
mixing waters containing 10,000 ppm of sodium sulfate have been used satisfactorily, the
limit in ASTM C1602, 3000 ppm, should be considered unless special precautions in the
composition of the concrete mixture are taken.
When evaluating waters for their effect on concrete properties, it is important to also test
the water with chemical admixtures that will be used in the job concrete. Certain compounds
in water can influence the performance and efficiency of certain admixtures.
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9. Use of Questionable Waters as Mixing Water
Sea Water
Seawater containing up to 35,000 parts per million of dissolved salts is generally
suitable as mixing water for concrete not containing reinforcing steel. Seawater is not
suitable for use in production of concrete with steel reinforcement and likewise, it should
not be used in prestressed concrete due to the risk of corrosion of the reinforcement.
Acid Waters
Acid waters may be accepted as mixing water on the basis of their pH values.
Use of acid waters with pH values less than 3.0 should be avoided.
Organic acids, such as tannic acid can have significant effect on strength at higher
concentrations.
In terms of pH value, the water that has a pH value greater than 6 can be employed
for the concrete construction.
Alkaline Waters
Waters with sodium hydroxide concentrations up to 0.5 % and potassium hydroxide
in concentrations up to 1.2 % by weight of cement has no significant effect on
strength.
Wastewaters from paint factories, coke plants, and chemical and galvanizing plants
may contain harmful impurities. Thus, such wastewaters should not be used as mixing
water without testing.
Sanitary Sewage
The sanitary sewage may be safely used as mixing water after treatment or dilution of
the organic matter.
Wash Water
Water carried on a truck mixer in a special tank for flushing the in interior of the mixer
after discharge of the concrete. It is common practice in the ready mixed concrete industry to
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thoroughly clean the inside of a concrete truck’s drum at the end of the day using
approximately 150 to 300 gallons of water and this water used for flushing the mixer is called
wash water.
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References
[1] Test for Water Quality for Concrete Construction and Recommended Limits. Retrieved
from:https://theconstructor.org/practical-guide/water-quality-tests-concrete-
construction/7357/
[2] Mixing Water for Concrete.pptx. Retrieved from: www2.cement.org/PW2015/EB001_15-
Presentations/EB001%20CH5%20-%20Mixing%20Water%20for%20Concrete.pptx
mixing water
[3] Chapter 3: Mixing Water for concrete. pdf. Retrieved from:
http://site.iugaza.edu.ps/malqedra/files/Lecture-42.pdf
[4] ACI 318M-08, ―Building Code Requirements for Structural Concrete and Commentary.
Retrieved from:
http://site.iugaza.edu.ps/sshihada/files/2010/02/ACI_318M08_Building_Code_Requirements
for_Structural_Concrete_(ACI_318M 08)_And_Commentary.pdf
[5] Test for Water Quality. Retrieved from: https://theconstructor.org/practical-guide/water
quality-tests-concrete-construction/7357/
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