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General lea :cl9os;

1. All questions are compulsory.
·2. Questions 1-8 are of 1 marks each.
3. Questions ~20 are of 2 manes each.
4. Questions 21-26 are of 3 martcs each.
"
auestlons 1-a are of 1martcs each: ·:.:~_. V·'
Ql. Find out the wlume of o,a .-mole of ~ at s. T. P. .
Q2. How many quantum num!>ers are needed to designate an orbital ? Name them.
Q3.How would you Justify th<! presence of 18 elements in the fifth period of the periodic table ?
Q4. Predict the period and the group to which an element with atomic number 40 belong tQ ?
Q.S. Find the molarity of AICl3 If Its normality is o.2 N. ·
Q6. Draw the Lewis structure of CO, molecule. .✓
Q7. How many electrons •.n an atom may have the followlng quantum number-?
n•4, "'·••·M ·
08. What do you unde•·stand by limiting reagent? Give one use.

Questions 9-20 are of 2 marks each

09. Sulphur and a.cygen are known to form oxide.The sulphur content In one of these Is 50"
, 1,1{ while In the c,ther Is 40'6. Show that It Illustrates the law of multiple proportions.
O "\'1< Q10. Explain with the help of Helsenberrs Uncertalnlty Principle, why an electron cannot be
present I·,, the nucleus ?
Qll. The Ion/~ sue of 0·1 • Is greater than that of I( though tllt ·two tons are isoelectronlc .
Give r•~ason. . •
Q12. Nam,, the element which shows diagonal relationship with LI .Give reason , why It
sho~...s the diagonal relatlonshlp?
Q13. Chi orlne Is prepared according to the reaction:
4HCI (g) + MnO2 --> 2 HiO + MnCl1 + Cl2
1',ow manys,ams of HCI react with 5 sot manganese dioxide? (At. Mass of Mn• S5) ·
Q14. • rhe electron energy In hydrogen atom In the first orbit is given by -2 . 18 x10·1&J atom ·1• S.o,~••o"'l:
calculate the energy required to remove an electron _,,pl@tely from th• n ~ 2 orbit . ....... ,.qt,
What is the longest wavelength of light that can be used to cause this transition ?
Q1S. Would"°" expect the first lonl2atlon enthalpies of two Isotopes of the same element to
be same or different 7 Justify your statement . .
Q16 . Explain the pometry of HaO with the help of hybridization •
Q17 • Amnae the followJng In the Increasing order of their bond length with the help of M .
O. Theory:
0i,Oz,0t. ·
0:18.Althoua;h both CO2 and H2 O are triatomic molecules ,the shape of H20 molecule Is
bent while that of CO2 is linear .bplain this on the basis of dlpole moment .
Q19. Calculate molallty and molarity of 93 " H2SO, (W \V ) .The density of the solution Is
1.84 s \ml. .
Q20. In a hydl'Olln atom ,an electron Jumps from fourth orbit to first orbit .Find out the ·
frequency of the.spectral llne using Rydberg's formula.

Questions 21-26 are of 3 marks each.

Q21. What Is electron pin enthalpy ? Explain the factors responslble for it •
Q22. Accountforthefollowlna: ·
a) Amons hydrides ,,f aroup 16 etemenu ,which has the lowest bolllnl point? Give
reason.
b) Write the differences between BMO and ABMO .(Two I
• sl:Rrrtbe rwrn!Sfrfkftttt1ruaf Nlr1 , -~ -- -
023. 10 ml of HCl solution produced 0.1435 g of Agel when treated with excess of silver
; nitrate solution .What Is the molar:tty of the.acid solution. (At. Mass of Ag= 108) ·
Q24. ·aJ An atoml•; orbltal has n • 4.What ar~the possible values of I and m1 ? ,1
b) Ust the •,tuantum number$ ( I and m1 I of electrons for 4d orbital .
c) Which •Jf the following orbitals are possible?
2p , 2d , 3s ,lp •
Q25. Assign reasons for the following :
I
a)lonlc bonds are non - dlrectional •
b)lonlc compounds do not conduct electricity In solid state .
c) lor1lc compounds have high meltlng point •
Q26. The first and second Ionization enthalpies (Kl mo1e·1 •) of few elements are d-,neted
by alphabe~ are stven below : · · ·
First Ionization Enthalpy Second·-tonlzatlon Enthalpy ,.
.•
,; , A -. . .
B •
403
549
. 2640
1060
·-
(; 1142 ,. 2080
Identify the element which Is likely to be:
a) A non - metal.
b) An alkali metal .
c) An alkaline earth metal •