P(bar) T(K) R (cc-bar/mol-K)

50 400 83.14

COMPONENTE yi Pc (bar) Tc(K) ωi

Etano (1) 0.150 48.320 305.300 0.100
Propano (2) 0.350 42.480 369.800 0.152
n-butano (3) 0.500 37.960 425.100 0.200

(a) Correlación de Pitzer/Abbot

Tri Pri �_𝒊�^� �_𝒊�^� �_𝒊
1.310 1.035 -0.1909 0.0837 0.8658
1.082 1.177 -0.2892 0.0153 0.7319
0.941 1.317 -0.3822 -0.0831 0.5722
 �_𝑖�^𝑜=0.083−0.422/( 〖��〗 _𝑖�^1.6 )

�_𝒊=𝒆𝒙�[𝑷𝒓𝒊/𝑻𝒓𝒊 (�_𝒊^�−�_𝒊 �_𝒊^� )]

�_𝑖�^1=0.139−0.172/( 〖��〗 _𝑖�^4.2 )

PROBLEMA DE FUGACIDAD DE MEZCLA

En el sistema etano(1)/propano(2)/n-butano(3), a una P, T y com

Determine el coeficiente de fugacidad de cada componente, us
(a). La correlacion de Pitzer/Abbott.
(b). La ecuación del virial truncado en dos términos.
(c). La ecuación de Redlich-Kwong-Soave (RKS)
A DE FUGACIDAD DE MEZCLA

2)/n-butano(3), a una P, T y composición dada.

cidad de cada componente, usando:
ott.
do en dos términos.
g-Soave (RKS)
 P(bar) T(K) R (cc/bar-K)
50 400 83.14

ij yi Pc (bar) Tc(K) ωi Zc Vc(cc/mol)

11 0.150 48.320 305.300 0.100 0.279 145.50
22 0.350 42.480 369.800 0.152 0.276 200.00
33 0.500 37.960 425.100 0.200 0.274 255.00

(b) Ecuacion del Virial truncado en dos términos

ij yi Pc (bar) Tc(K) ωi Zc Vc(cc/mol)
11 0.150 48.320 305.300 0.100 0.279 145.50
22 0.350 42.480 369.800 0.152 0.276 200.00
33 0.500 37.960 425.100 0.200 0.274 255.00
12 45.2525128 336.01 0.126 0.278 171.308
13 42.4349764 360.25 0.150 0.2765 195.160
23 40.0422866 396.49 0.176 0.275 226.388

ij Trij Prij �_𝒊�^� �_𝒊�^� �_𝒊� �_𝒊�

11 1.310 1.03476821 -0.1909 0.0837 -95.8794
22 1.082 1.17702448 -0.2892 0.0153 -207.6182
33 0.941 1.31717597 -0.3822 -0.0831 -371.2847
12 1.190 1.10491102 -0.2363 0.0563 -141.4828 20.5321
13 1.110 1.17827331 -0.2739 0.0282 -190.3672 86.4298
23 1.009 1.24867994 -0.3331 -0.0267 -278.0805 22.7420

ij �  ̅_ 𝒊 �  ̂_ 𝒊
11 -57.0183 0.9178
22 -204.7074 0.7351
33 -361.9006 0.5804
 �𝑖�=𝑅𝑇𝑐𝑖�/𝑃𝑐𝑖� (�_𝑖�^𝑜−�_𝑖� �_𝑖�^1 )

�_𝑖�^1=0.139−0.172/( 〖��〗
�_𝑖�^𝑜=0.083−0.422/(
_𝑖�^4.2 ) 〖��〗 _𝑖�^1.6 )
𝛿𝑖�=2�𝑖�−�𝑖𝑖−���

�  ̅_1=[𝜕(𝑛�)/(𝜕𝑛_1 )]_(𝑛2,𝑛3)=�_11+�_2 (1−�_1 ) 𝛿_

�  ̅_2=[𝜕(𝑛�)/(𝜕𝑛_2 )]_(𝑛1,𝑛3)=�_22+�_1 (1
(1−�_2 ) 𝛿_23−�_1 �_3 𝛿_13

�  ̅_3=[𝜕(𝑛�)/(𝜕𝑛_3 )]_(𝑛1,𝑛2)=�_33+�_1 (1−�_3 ) 𝛿_13+�_2

𝑛3)=�_11+�_2 (1−�_1 ) 𝛿_12+�_3 (1−�_1 ) 𝛿_13−�_2 �_3 𝛿_23

𝑛_2 )]_(𝑛1,𝑛3)=�_22+�_1 (1−�_2 ) 𝛿_12+�_3

_1 �_3 𝛿_13

_33+�_1 (1−�_3 ) 𝛿_13+�_2 (1−�_3 ) 𝛿_23−�_1 �_2 𝛿_12

 P(bar) T(K) R (cc.bar/mol.K)
50 400 83.14

ij yi Pc (bar) Tc(K) ωi Zc Vc(cc/mol)

11 0.150 48.320 305.300 0.100 0.279 145.50
22 0.350 42.480 369.800 0.132 0.276 200.00
33 0.500 37.960 425.100 0.200 0.274 255.00

(c ) Ecuación de Redlich-Kwong-Soave
ij yi Pc (bar) Tc(K) ωi Zc Vc(cc/mol) Trij
11 0.150 48.32 305.30 0.100 0.279 145.50 1.310
22 0.350 42.48 369.80 0.132 0.276 200.00 1.082
33 0.500 37.96 425.10 0.200 0.274 255.00 0.941
12 45.25 336.01 0.116 0.278 171.31 1.190
13 42.43 360.25 0.150 0.2765 195.16 1.110
23 40.04 396.49 0.166 0.275 226.39 1.009

ij �_𝒊� aij bij �_𝒊� �  ̅_ 𝒊 �  ̂_

11 0.8246 4699983 45.512 3430565 𝒊
1.222
22 0.9459 8997980 62.706 8232334 0.803
33 1.0478 14738771 80.667 14442310 0.449
12 6503104 -691756
13 8322979 -2792796
23 11516039 -704672

SOLVER
a A B f(z) z b
10854581.2 0.490731 0.10390199 0.000 0.32674486 69.1072913 〖�  ̅_𝑖=[𝜕(𝑛�)/(𝜕𝑛

〖�  ̅_𝑖=[𝜕(𝑛�)/(𝜕

�_𝑖=0.42748 (𝑅^2 〖��〗

�=�_11 �_11+�_22 �_22+
 ├ �  ̅_1 ]_𝑛2𝑛3=�_11+�_2 (1−�_1 ) 𝛿_12+�_3 (1−�_1 ) 𝛿_13−�_2 �_3 𝛿_23
├ �  ̅_)]
〖�  ̅_𝑖=[𝜕(𝑛�)/(𝜕𝑛_𝑖 2 ]_𝑛1𝑛3=�_22+�_1
〗 _𝑛� (1−�_2 ) 𝛿_12+�_3 (1−�_2 ) 𝛿_13−�_1 �_3 𝛿_13
├ �  ̅_3 ]_𝑛1𝑛2=�_33+�_1 (1−�_3 ) 𝛿_13+�_2 (1−�_3 ) 𝛿_23−�_1 �_2 𝛿_12

〖�  ̅_𝑖=[𝜕(𝑛�)/(𝜕𝑛_𝑖 )] 〗 _𝑛�
�  ̅_𝑖=�_𝑖
�_𝑖=0.08664 (𝑅 〖��〗 _𝑖)/ 〖��〗 _𝑖
�_𝑖=0.42748 (𝑅^2 〖��〗 _𝑖^2)/ 〖��〗 _𝑖 �_𝑖 (𝑇𝑟𝑖, �𝑖)

�=�𝑃/(𝑅𝑇)^2
�_𝑖 (𝑇𝑟𝑖, �𝑖)=[1+(0.48+1.574�_𝑖−0.176�_𝑖^2 )(1− 〖��〗 _𝑖^0.5 )]^2

�  ̂_𝑖=𝑒𝑥�[�  ̅_𝑖/� (𝑧−1)−𝑙𝑛(𝑧−�)−�/� (1+�  ̅_𝑖/�−�  ̅_𝑖/�)𝑙𝑛((𝑧+�)/𝑧)]

�=�𝑃/𝑅𝑇

�_𝑖�=√(�_𝑖 �_� )
𝑧^3−𝑧^2+(�−�−�^2 )𝑧−�×�=0
�=�_11 �_11+�_22 �_22+�_33 �_33+�_1 〖� _2 𝛿 〗 _12+�_1 〖� _3 𝛿 〗 _13+�_2 〖� _3 𝛿 〗 _23

�=�_1 �_1+�_2 �_2+�_3 �_3

𝛿_𝑖�=2�_𝑖�−�_𝑖𝑖−�_��
 P(bar) T(K) R (cc.bar/mol.K) (d) Ecuación de Redlich-Kwong
50 400 83.14

ij yi Pc (bar) Tc(K) ωi Zc Vc(cc/mol) �_𝑖 (𝑇𝑟𝑖, �𝑖)=[1+(0.48+1

11 0.150 48.320 305.300 0.100 0.279 145.50
�_𝑖=0.42748 (𝑅^2 〖 � 〖� _𝑖^2.5)/(𝑇
〗
22 0.350 42.480 369.800 0.132 0.276 200.00
33 0.500 37.960 425.100 0.200 0.274 255.00 �  ̂_𝑖=𝑒𝑥�[�  ̅_𝑖/� (𝑧−1)−

LA ECUACIÓN DE REDLICH-KWOG
ij yi Pc (bar) Tc(K) ωi Zc Vc(cc/mol)
11 0.150 48.320 305.300 0.100 0.279 145.50
22 0.350 42.480 369.800 0.132 0.276 200.00
33 0.500 37.960 425.100 0.200 0.274 255.00
12 45.2525128 336.01 0.116 0.278 171.308
13 42.4349764 360.25 0.150 0.2765 195.160
23 40.0422866 396.49 0.166 0.275 226.388

�_𝒊� � _ ̅ 𝒊 �  ̂_ 𝒊

ij Trij aij bij
11 1.310 4979616.88 45.5122538 3843812.18 1.1686
22 1.082 9146156.00 62.7062548 8463500.54 0.7825
33 0.941 ### 80.6665281 14240386.3 0.4586
12 1.190 6748655.63 -628461.62
13 1.110 8497705.33 -2485521.81
23 1.009 ### -614339.403

a A B F(z) Z b
10871837.2 0.49151064 0.10390199 8.11471E-09 0.32275 69.1072913 〖
〖�  ̅_𝑖=[𝜕(𝑛�)

〖
〖�  ̅_𝑖=[𝜕(𝑛�

�=�_11 �_11+�_22
�_𝑖 (𝑇𝑟𝑖, �𝑖)=[1+(0.48+1.574�_𝑖−0.176�_𝑖^2 )(1− 〖 � 〖� _𝑖^0.5
〗 )]^2
(𝑅^2 〖 � 〖� _𝑖^2.5)/(𝑇^0.5
〗 〖 � 〖� ^𝑖
〗)(𝑅 〖 � 〖� _𝑖)/
�_𝑖=0.08664 〗 〖 � 〖� _𝑖
〗

�  ̂_𝑖=𝑒𝑥�[�  ̅_𝑖/� (𝑧−1)−𝑙𝑛(𝑧−�)−�/� (1+�  ̅_𝑖/�−�  ̅_𝑖/�)𝑙𝑛((𝑧+�)/𝑧)]

├ �  ̅_1 ]_𝑛2𝑛3=�_11+�_2 (1−�_1 ) 𝛿_12+�_3 (1−�_1 ) 𝛿_13−�_2 �_3 𝛿_23

〖�  ̅_𝑖=[𝜕(𝑛�)/(𝜕𝑛_𝑖├)]� 〗 ̅_2_𝑛�
〖 ]_𝑛1𝑛3=�_22+�_1 (1−�_2 ) 𝛿_12+�_3 (1−�_2 ) 𝛿_13−�_1 �_3 𝛿_13
├ �  ̅_3 ]_𝑛1𝑛2=�_33+�_1 (1−�_3 ) 𝛿_13+�_2 (1−�_3 ) 𝛿_23−�_1 �_2 𝛿_12

〖
〖�  ̅_𝑖=[𝜕(𝑛�)/(𝜕𝑛_𝑖 )] 〗 _𝑛� �  ̅_𝑖=�_𝑖 𝛿_𝑖�=2�_𝑖�−�_𝑖𝑖−�_��

�=�𝑃/(𝑅𝑇)^2
�=�𝑃/𝑅𝑇

�_𝑖�=√(�_𝑖 �_� )

�=�_11 �_11+�_22 �_22+�_33 �_33+�_1 〖� _2 𝛿 〗 _12+�_1 〖� _3 𝛿 〗 _13+�_2 〖� _3 𝛿 〗 _23

�=�_1 �_1+�_2 �_2+�_3 �_3
𝑧^3−𝑧^2+(�−�−�^2 )𝑧−�×�=0
𝑧^3−𝑧^2+(�−�−�^2 )𝑧−�×�=0

PROBLEMA DE FUGACIDAD DE MEZCLA

En el sistema metano(1)/etileno(2)/propano(3), a una P, T y composición dada.

Determine el coeficiente de fugacidad de cada componente, usando:
(a). La correlacion de Pitzer/Abbott.
(b). La ecuación del virial truncado en dos términos.
(c). La ecuación de Redlich-Kwong-Soave (RKS)
A

posición dada.
ando: