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WATER TECHNOLOGY
INTRODUCTION
Water is the most important compound for the existence of human beings, animals & plants.
Among the various sources of water surface & underground water are normally used for
domestic & industrial purposes. Such water must be free from undesirable impurities. The
process of removing all types of impurities from water & making it fit for domestic or industrial
purpose is called water treatment.
HARD WATER
Water which does not produce lather freely with soap is called hard water. This is due to the
formation of insoluble soaps of calcium & magnesium.
Calcium stearate
SOFT WATER
Water which produce lather freely with so soft water. Hardness is the property of water which
does not produce lather with soap.
TYPES OF HARDNESS
Depending on the type of dissolved salts present in water, hardness can be classified in two types
1) Temporary hardness
2) Permanent hardness
TEMPORARY HARDNESS
The hardness which is removed by boiling of water is called temporary hardness. This is due to
the presence of bicarbonates of calcium & magnesium.
The hardness which is not removed even after boiling of water is called permanent hardness.
This is due to the presence of chlorides and sulphates of Ca & Mg.
(i) Its molecular weight (100) & equivalent weight (50) is a whole number, so tee calculations
can be simplified.
Amount equivalent to CaCO3 = Amount of hardness producing salt x molecular weight of CaCO3
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PROBLEM 1:
A sample of water is found to contain the following analytical data in mg/lt. Mg (HCO3)2 = 14.6;
MgCl2 = 9.5; MgSO4 = 6.0; Ca (HCO3)2 =16.2 . Calculate the temporary & permanent hardness
of the sample of water.
SOLUTION:
=10 + 10 = 20 mgs/lt.
=10 + 5 = 15 mgs/lt.
PROBLEM 2:
A sample of water is found to contain the following analytical data in mg/lt. Mg (HCO3)2 = 16.8;
MgCl2 = 12; MgSO4 = 29.6; NaCl=5 . Calculate the temporary & permanent hardness of the
sample of water & express it in ppm. (Atomic weight of Mg =24; H = 1 ; C =12 ; O =16; Cl =
35.5; Na = 23; S = 32)
SOLUTION:
NaCl does not contribute any hardness to water & hence it is ignored
Alkalinity is due to presence of soluble hydroxide (OH-), carbonate (CO32-) & bicarbonate
(HCO3-) ions. These can be determined by titrimetry using standard acid, phenolphthalein &
methyl orange as indicators. The determination is based on the following reactions
Alkalinity is classified into three types based upon the anion present in the water
EXPERIMENTAL PROCEDURE
Pipette out 100 ml of the given water sample a clean conical flask. Add 2 to 3 drops of a
phenolphthalein indicator & titrate it against N/50 H2SO4 taken in the burette. The end point is
the disappearance of pink colour.Let the volume of acid consumed be V1.
To the same solution add 2 to 3 drops of methyl orange indicator and continue the titration
against the N/50 H2SO4 .The end point is appearance reddish orange. Let the volume of acid
consumed be V2.
CALCULATION
V1N1 = V2N2
N2 = V1N1/ V2
N2 = VI/100 X 1/50
=V1 X 50 X 1000
________________
100 X50
P = 100 V1 PPM
V1N1 = V2N2
N2 = V1N1/ V2
N2 =( VI+V2)/100 X 1/50
=(V1+V2) X 50 X 1000
________________
100 X50
(i) When P=O, both OH- & CO32- are absent & alkalinity is due to HCO3- only.
(ii) When P = ½ M, only is CO32- present, half of carbonate neutralization reaction takes place
with phenolphthalein indicator. Complete carbonate neutralization reaction occurs when methyl
orange indicator is used.
(iv) When P > ½ M, besides CO32- , OH- ions are also present.
(v) When P < ½ M, besides CO32- , HCO3- ions are also present.
PROBLEM 1:
A water sample is not alkaline to phenolphthalein. But 100 ml of the sample on titration with
N/50 HCl required 16.7 ml to methyl orange end point. What are the types & amounts of
alkalinity present in the sample.
SOLUTION:
Since P = O, the alkalinity of the water sample is only due to HCO3- ions.
V1N1 = V2N2
N2 = V1N1/ V2
N2 = 16.7/100 X 1/50
N2 = 0.00334 N
= 0.00334 x 50 x 100
= 167 PPM.
100 ml of a water sample on titration with N/50 HCl gave a titre value of 6.8 ml to
phenolphthalein end point & 13.6 ml to methyl orange end point. Calculate the alkalinity of the
water sample & comment on the type alkalinity present.
SOLUTION:
Since P = ½ M, the alkalinity of the water sample is only due to CO32- ions.
V1N1 = V2N2
N2 = V1N1/ V2
N2 = 13.6/100 X 1/50
N2 = 0.00276 N
= 0.00276 x 50 x 100
= 136 PPM.
This method is based on complexometric titration method. EDTA is Ethylene diamine tetra acetic
acid. The structure of EDTA is
HOOCH2C CH2COOH
N--CH2—CH2—N
HOOCH2C CH2COOH
PRINCIPLE
The amount of hardness causing ions can be estimated by titrating the water sample against
EDTA using Erichrome Black- T indicator at a PH of 8 to 10. In order to maintain the PH buffer
solution is added.
When the EBT indicator is added to the water sample it forms wine red coloured weak complex
with Ca2+ & Mg2+ ions.
Ca2+ PH 8 – 10 Ca
Mg2+ Mg
When this solution is titrated against EDTA, it replaces the indicator from tee weak complex &
form stable EDTA complex. The colour of the free indicator is steel blue.
Ca PH 8 – 10 Ca
Mg Mg steel blue
Preparation of solutions
Standard hard water: 1 gm of calcium carbonate is dissolved in minimum amount of dil. HCl
& then made up to 1000 ml using distilled water.
Buffer: 67.5 gms of ammonium chloride & 570 ml of ammonia are dissolved & the solution is
made up to 1000 ml using distilled water.
Experimental procedure
Pipette out 20 ml of standard hard water into a clean conical flask. Add 10 ml of buffer solution
& 5 drops of EBT indicator & titrate it against EDTA.The end point is the change of colour from
wine red to steel blue.
Pipette out 20 ml of the given hard water sample into a clean conical flask & titrate it against as
before.
Take 100 ml of the same hard water sample in a 250 ml beaker.Boil it for 15 minutes.Cool &
filter the solution and make upto 100 ml in a standard flask by adding distilled water. Pipette out
20 ml of the made up solution into a clean conical flask & titrate it against EDTA as before.
Calculations
PROBLEM 1:
0.28 gm of CaCO3 was dissolved in HCl & the solution made up to 1 lt. with distilled water. 100
ml of the above solution required 28 ml of EDTA solution on titration. 100 ml of hard water
sample required 33 ml of same EDTA solution on titration. 100 ml of this water after boiling,
cooling & filtering required 10 ml of EDTA solution on titration. Calculate the temporary &
permanent hardness.
SOLUTION:
100 ml of the hard water after boiling cooling & filtering = 10 ml of EDTA
=330 – 100
CHARACTERISTICS OF WATER
As per the suggestion given by World Health Organization (WHO) & by Indian Council of
Medical Research (ICMR), the following are the important characteristics of potable water.
4. It should be free from dissolved gases like CO2, H2S etc & poisonous minerals like lead,
arsenic, manganese etc.
Rivers & lakes are the most common sources of water & this water should be free from colloidal
impurities, industrial effluents & disease producing bacteria’s.
1. Screening
2. Aeration
3. Sedimentation
4. Coagulation
5. Filtration
6. Sterilization
SCREENING
The raw water is allowed to pass through a screen which retains the floating materials like
leaves; wood pieces etc. & allow the water to pass.
AERATION
(i) to remove gases like CO2, H2S and other volatile impurities causing bad taste & odour to
water.
(ii) to remove ferrous & manganous salts s insoluble ferric & manganic salts.
SEDIMENTATION
It is a process of removing suspended impurities by allowing the water to stand undisturbed for 2
to 6 hours in a big tank. The suspended impurities settle down at the bottom due to force of
gravity & they are removed. This removes only 75% of the suspended impurities.
COAGULATION
Finely divided clay, silica etc. do not settle down & cannot be removed by sedimentation. Such
impurities are removed by coagulation method. Al2 (SO4)3 is added to water. It gets hydrolyzed to
form a gelatinous precipitate of Al (OH)3 which entraps the finely divided & colloidal
impurities ,settles to the bottom & can be removed easily.
FILTERATION
It is the process of removing bacteria, colour, taste, odour & suspended particles by passing
through filter beds containing fine sand, coarse sand & gravel. When the rate of filtration
becomes very slow, the filtration is stopped & the thick top layer is scrapped off & replaced with
clean sand.
STERILIZATION
1. Boiling
2. by ozonation
4. by chlorination
b) By adding chloramines
When bleaching powder is added to water, it produces HOCl which is a powerful germicide.
Bleaching powder
(Hypochlorous acid)
1. Intially the applied chlorine is used to kill bacteria & oxidizes all the reducing substance &
there is no free residual chlorine.
2. As the amount of chlorine increases, the amount of combined residual chlorine increases.
3. At one point on chlorination, the oxidation of chloramines & other impurities starts & there is
a fall in combined chlorine.
4. Thus the combined chlorine decreases to a point and free residual chlorine appears & this
point is known is known as” Break Point Chlorination”.
The water fed into the boiler for the production of steam is called boiler feed water.
BOILER TROUBLES
If hard water obtained from natural sources is fed directly into the boilers, the following troubles
may arise,
3. Caustic embrittlement
4. Boiler corrosion
When water is converted into steam in boilers the concentration of dissolved salts in water
increases.
Sludge
If the precipitate is loose & slimy is called sludge. Sludges are formed by substances like
MgSO4, MgCl2, and MgCO3 & CaCl2.
Disadvantages
Prevention
2. They can also be removed by blow down operation .It is a process of removing a portion of
concentrated water by fresh water from the boiler during steam production.
Scale
If the precipitate forms hard & adherent coating on the inner walls of the boiler, it is called
sacle.Scales area farmed by Ca (HCO3)2, CaSO4 & Mg (OH) 2
Disadvantages
Prevention
During production of steam in the boiler, due to rapid boiling, liquid droplets are carried along
with steam.Steam containing liquid droplets is called wet steam. These droplets carry with them
some dissolved salts & suspended impurities. This is called carry over.
Priming
Prevention
The formation of stable bubbles above the surface of water is called foaming.
Foaming is caused by
Prevention
Caustic embrittlement
This NaOH flows into minute hair cracks by capillary action & dissolves the surrounding area of
iron as sodium ferroate.
This causes brittlement of boiler parts causing even failure of the boiler.
Prevention
2. By adding tannin, lignin to the water which blocks the hair cracks.
Boiler corrosion
1. Dissolved oxygen
2. Dissolved CO2
3. Dissolved salts
Dissolved oxygen
Removal
a)Chemical method
2Na2SO3 + O2 2Na2SO4
b) Mechanical method
Water is allowed to fall slowly on the perforated plates fitted inside the tower.
The high temp. & low pressure produced inside the tower reduces the dissolved oxygen content
of the water.
Dissolved CO2
Dissolved CO2 in water produces carbonic acid which is acidic & corrosive in nature.
Removal
Dissolved MgCl2
Salts like MgCl2, CaCl2 undergo hydrolysis at higher temperature to give HCl which corrodes the
boiler.
Fe + 2HCl FeCl2 + H2
Corrosion by acids can be avoided by the addition of alkali to the boiler water.
SOFTENING METHODS
The process of hardness producing salts from water is known as softening or conditioning of
water.
1. External conditioning
2. Internal conditioning
EXTERNAL CONDITIONING
It involves the removal of hardness producing salts from water before feeding into boiler. The
external treatment can be done by Ion exchange process.
This process removes almost all ions present in the hard water. The process is carried out by
using ion exchange resins, which are long chain, cross linked, insoluble organic polymers with a
micro porous structure. The functional groups attached to the chains are responsible for the ion
exchanging properties.
Cation exchanger
Resins containing acidic functional groups (-COOH, -SO3H) are capable of exchanging their H+
ions with other cations of hard water. It is represented as RH2
Anion exchanger
Resins containing basic functional groups (-NH2, -OH) are capable of exchanging their anions
with other anions of hard water. It is represented as R (OH) 2
The hard water first passed through a cation exchanger column which absorbs all the cations like
Ca2+, Mg2+, Na+ & K+ present in the hard water.
The cation free water is then passed through a anion exchange column which absorbs all the
anions like Cl-, SO42- present in the water.
The water coming out of the anion exchange is completely free from cations & anions.
Regeneration
When the cation exchange resin is exhausted it can be regenerated by passing dil. HCl.
Advantages
Disadvantages
It involves the removal of scale forming substance, which were not removed in the external
treatment, by adding chemicals directly into the boiler.
1. Carbonate conditioning
Scale formation can be avoided by adding Na2CO3 to the boiler water. CaSO4 is converted into
CaCO3 which can be removed easily.
2. Phosphate conditioning
Scale formation can be avoided by adding sodium phosphate. The phosphate reacts with Ca2+ &
Mg2+ salts to give soft sludges of Ca & Mg phosphates.
3. Calgon conditioning
Calgon is sodium hexa Meta phosphate Na2 (Na4 (PO3)6). This salt interacts with Ca ions forming
a highly soluble complex & prevents the precipitation of scale forming salt.
DESALINATION
The process of removing common salt from water is known as desalination. Depending upon the
quantity of dissolved solids, water is graded as
(ii)Brackish water _ contains > 1000 but < 35000 ppm of dissolved solids
REVERSE OSMOSIS
When two solutions of different concentrations are separated by a semi permeable membrane,
solvent flows from a region of lower concentration to higher concentration. This process is called
osmosis & the driving force is called osmotic pressure.
If hydrostatic pressure in excess of osmotic pressure is applied on the higher concentration side,
the solvent flows from higher concentration to lower concentration. Thus in the process of
reverse osmosis pure water is separated from salt water. The membranes used are cellulose
acetate, cellulose butyrate etc.
Advantages
(i)The life time of the membrane is high, & it can be replaced within few minutes.
(iii)Due to low capital cost, simplicity, low operating, this process is used for converting sea
water into drinking water.