Corriente Descripcion Temperatura °C Presion (atm)

1 Cloro gaseoso (Cl2) 25 1

2 Cloro gaseoso (Cl2) 190 4.8
3 Cloro gaseoso (Cl2) 90 4.8
4 Etileno gaseoso (C2H4)
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
Caudal (TM/año) Caudal (kmol/h)
36220.8 72.88
36220.8 72.88
36220.8 72.88
Componente Peso Molecular Kg/Kmol Presión (atm) T. Ebullicion (°C)
DCE 98.96 1 83.7
Etileno 28.5 1
Cloral 147.39 1
HCL 36.5 1 -84.8
Tricloroetano 133.4 1
CVM 62.5 1 -13.8
Cl2 71
Cloracion directa
Corriente Componente Flujo (kmol/h) T1 °C T2 °C Cp(KJ/kmol K)
3 Cloro 72.88 185 140
6 Etileno 71.60 135 140
7 Mezcla
8 Mezcla
Oxicloracion (entradas)
Corriente Componente Flujo (kmol/h) T1 °C T2 °C Cp(KJ/kmol K)
2' Etileno 81.824 25 120 48.75
3 Oxigeno 37.857 25 120 29.65
15 HCl 151.86 -41.9 120 29.09

Oxicloracion (Salida)
Corriente Componente Flujo (kmol/h) T1 °C T2 °C Cp(KJ/kmol K)
DCE 72.18 220 40 148.04
Cloral 2.005 220 40 109.16
9' Agua 78.15 220 40 34.23
Etileno 7.571 220 40 54.58
HCl 0.7961 220 40 29.15

Reactor Pirolisis (Salida)

Corriente Componente Flujo (kmol/h) T1 °C T2 °C Cp(KJ/kmol K)
HCl 151.86 500 90 29.54
15' CVM 151.43 500 90 79.29
DCE 101.27 500 90 110.86

Diseñar el HEN
Corriente F (kmol/h) T entrada T salida FCp (KJ/kmol C)
1 72.88 185.00 140.00 0 Caliente
2 71.60 135.00 140.00 0 Fria
2' 81.82 25.00 120.00 48.75 Fria
3 37.86 25.00 120.00 29.65 Fria
15 151.86 -41.90 120.00 29.09 Fria
9' 160.70 220.00 40.00 Caliente
15' 404.56 500 90 Caliente
 Cp total
0
0

Cp total
48.75
29.65
29.09

Cp total

Cp total Fraccion molar

11.0884526399 0.3753707732
29.6788726023 0.3743078901
27.7506233933 0.2503213368

68.5179486356

Para cambios de fase

Componente F (kmol/h)
D H Cambio fase
Agua 78.15
DCE 7.571
Cloral 0.7961
Corriente ComponenteFlujo (kmol/h) Cp Liq(KJ/kmol K) x Cp liquido Fraccion molar
DCE 141.63 0 0
15' Cloral 2.005 166.31 4.1600842118 0.0250140353
agua 78.15 76.66 74.7424240534 0.9749859647
Etileno 0 0 0 0
HCl 0 0 0 0
80.16 78.9025082652 1

160.71

Corriente ComponenteFlujo (kmol/h) Cp Liq(KJ/kmol K)

DCE 72.18 141.63
15' Cloral 2.005 166.31
agua 78.15 76.66
Etileno 7.571 -
HCl 0.7961 -
160.7021
Flujo (kmol/h) Cp gas(KJ/kmol K) x Cp gas Fraccion molar
72.18 87.77 78.6526 0.8961216481
113.65 0 0
34.83 0 0
7.571 52.83 4.9657 0.0939946938
0.7961 29.22 0.2888 0.0098836581
80.55 318.3 83.91 1 Cp total = 3.634

Flujo (kmol/h) Cp gas(KJ/kmol K) Cp total Fraccion molar

72.18 87.77 63.6136889 0.4491540559
2.005 113.65 2.07496697 0.0124765016
78.15 34.83 37.2800293 0.4863035393
7.571 52.83 2.48892784 0.0471120166
0.7961 29.22 0.14475257 0.0049538867
160.7021 105.60 4.7140338672
Segmen Cp mezcla
Flujo
to de la Tentrad Tsalida FCp
(kmol/h (KJ/kmo (KW/°C)
corrient a (°C) (°C)
)
160.7 220 160.03 l°C)
2.697
e6-A6
6-B 2.005 160.03 159.03 -
6-C 160.7 160.03 152.41 2.726
6-D 78.15 152.41 151.41 -
6-E 160.7 152.41 145.76 3.634
6-F 72.18 145.76 144.76 -
6-G 160.7 145.76 40 4.714
Corriente 1 2 5 7 3

FCp 0.71 1.03 2.7 7.57 1.28

✘ Input Input Input Input Input Input

Corriente T ent T sal Delta T FCp CalienteQ caliente FCp Frias Q frias

0 0.71 0 0
0 1.03 0 0
0 0 1.28 0
0 0.33 0 0
30 -41.8 280
0 0 1.23 0
0 2.7 0 0
1 0 7.81 2186.8

0 7.57 0 0

0 2186.8
 Segmen
Flujo
4 6
to de la Tentrad Tsalida
(kmol/h
corrient a (°C) (°C)
)
e6
1.23 7.81 6-A 160.7 220 160.03

Input Input ✘ Input 6-B 2.005 160.03 159.03

64.86

6-C 160.7 160.03 152.41

-66.72 -1.86
0.18 -1.68 6-D 78.15 152.41 151.41
2.76 1.08 6-E 160.7 152.41 145.76
-1.08 0 6-F 72.18 145.76 144.76
19.78 19.78 6-G 160.7 145.76 40
19.41 39.19
2.76 41.95
22 63.95
Q intervalo 811.31 875.26
-2186.80 32.06 907.32
23.93 931.25
592.01 1523.26
79.52 1602.78
486.1 2088.88
208.92 2297.8
-88.31 2209.49
2209.49
 FCp
(KW/°C)
2.7

18.72

2.726
Delta H
801.91 0 2209.49
3.633 71.8 88.31
580.25 60 73.8
4.712 38 46.74
6.76 8.31
1 1.23
2.24 2.76

3.41 8.56

1 2.51
2.59 6.5
4.03 41.59
10 103.2
20.97 216.41
30 309.6
280 2186.8
Temperatura Delta H H acumulado
40 40 0 0
100 60 282.72 282.72
138 38 532.84 815.56
144.76 6.76 87.83 903.39
Diagrama d
145.76 1 593.24 1496.63 600
148 2.24 26.69 1523.32
151.41 3.41 40.62 1563.94
500
152.41 1 813.82 2377.76
155 2.59 28.51 2406.27
159.03 4.03 44.35 2450.62 400
160.03 1 29.73 2480.35
190 29.97 329.07 2809.42

Temperatura (°C)
220 30 308.1 3117.52 300
500 280 2119.6 5237.12

200
Temperatura Delta H H acumulado
-41.8 0 2209.49 2209.49
30 71.8 88.31 2297.8 100
90 60 73.8 2371.6
128 38 46.74 2418.34
134.76 6.76 8.31 2426.65 0
0 1000 2000
135.76 1 1.23 2427.88
138 2.24 2.76 2430.64
-100
141.41 3.41 8.56 2439.2
142.41 1 2.51 2441.71
145 2.59 6.5 2448.21
149.03 4.03 41.59 2489.8
159.03 10 103.2 2593
180 20.97 216.41 2809.41
210 30 309.6 3119.01
490 280 2186.8 5305.81
 Diagrama de Curva Compuesta

1000 2000 3000 4000 5000 6000

Entalpias H (KW)
Cp liq =A+B*T+C*(T^2)+D*(T^3) T en Kelvin
Componente H2O
Cp(J/mol.K) 75.5565158865
T= 298
Formula Name A B C D
HCl Hydrogen Chloride 73.993 -1.2946E-01 -7.8980E-05 2.6409E-06
C2H3Cl vinyl chloride 48.806 0.28792 -0.0011535 2.1636E-06
C2H4Cl2 1,2-dichloroethane 26.31 0.77555 -0.0022271 2.6109E-06
C2 H 4 ethylene 25.597 0.57078 -0.003362 8.4120E-06
O2 Oxygen 46.432 3.9506E-01 -7.0522E-03 3.9897E-05
Cl2 Chlorine 127.601 -6.0215E-01 1.5776E-03 -5.3099E-07
C2HCl3O trichloroacetaldehyde 49.423 0.77236 -0.0022695 2.7747E-06
H2O Water 92.053 -3.9953E-02 -2.1103E-04 5.3469E-07
 Tmin Tmax
1.6500E+02 308
1.2000E+02 389
2.3800E+02 505
1.0500E+02 254
5.4000E+01 147
1.7200E+02 396
2.1700E+02 509
273 615
Cp gas = A + B*T + C*T^2 + D*T^3 + E*T^4 T en Kelvin
Componente C2HCl3O
Cp(J/mol.K) 97.2035105429
T= 298.15
Formula Name A B C D
HCl Hydrogen Chloride 29.244 -1.2615E-03 1.1210E-06 4.9676E-09
C2H3Cl vinyl chloride 17.193 0.14564 -0.000064281 -3.2380E-09
C2H4Cl2 1,2-dichloroethane 37.275 0.14362 0.000010378 -7.8300E-08
C2 H 4 ethylene 32.083 -0.014831 0.00024774 -2.3770E-07
O2 Oxygen 29.526 -8.8999E-03 3.8083E-05 -3.2629E-08
Cl2 Chlorine 27.213 3.0426E-02 -3.3353E-05 1.5961E-08
C2HCl3O trichloroacetaldehyde 46.176 0.23126 -0.00023659 1.2540E-07
H2O Water 33.933 -8.4186E-03 2.9906E-05 -1.7825E-08
 Tmin Tmax Columna1
-2.4963E-12 50 1500
6.7882E-12 200 1500
2.8872E-11 200 1500
6.8274E-11 60 1500
8.8607E-12 50 1500
-2.7021E-12 50 1500
-2.7197E-11 298 1200
3.6934E-12 100 1500
log10P =A+(B/T)+C*log10(T)+(D*T)+(E*T^2) T en Kelvin P en mmHg
Componente H2O
P(mmHg) = 759.5937909432 P (atm)= 0.9994655144
T= 373.15
Formula Name A B C D
HCl Hydrogen Chloride 43.5455 -1.6279E+03 -1.5214E+01 1.3783E-02
C2H3Cl vinyl chloride 52.965 -2501.6 -17.914 1.0821E-02
C2H4Cl2 1,2-dichloroethane 48.423 -3180.3 -15.37 7.2935E-03
C2 H 4 ethylene 18.796 -999.62 -4.5788 9.9746E-11
O2 Oxygen 20.6695 -5.2697E+02 -6.7062E+00 1.2926E-02
Cl2 Chlorine 28.8659 -1.6745E+03 -8.5216E+00 5.3792E-03
C2HCl3O trichloroacetaldehyde -0.9737 -2255.3 5.7694 -1.6755E-02
H2O Water 29.8605 -3.1522E+03 -7.3037E+00 2.4247E-09
 E Tmin Tmax
-1.4984E-11 159 325
-4.5310E-14 119.36 432
2.6844E-14 237.49 561
6.7880E-06 104.01 282.36
-9.8832E-13 54 155
-7.7867E-13 172 417
9.6236E-06 216 565
1.8090E-06 273 647