User's Manual TitriLyzer® Total Hardness (CaCO3) Series of On-Line Hardness (CaCO3) Analyzers

User’s Manual
TitriLyzer® Total Hardness (CaCO3)

Series of on-line Hardness (CaCO3)Analyzers
Serial number: 012.1189.1708.148

User’s Manual
TitriLyzer® Total Hardness (CaCO3)
Series of on-line Hardness (CaCO3) Analyzers
© 2017 – AppliTek NV – Printed in Belgium
All rights reserved. No part of this manual may be reproduced, stored in a retrieval system or
transmitted in any form or by any means - electronic, mechanical, photocopying, recording or
otherwise - without the prior written permission of AppliTek NV.
The content of this document is entirely a non-binding external opinion. Neither AppliTek NV
nor any of its employees can be held liable for damages to people, third parties, goods and
assets that may result from implementing the content.
CONTENTS
Preface – Documents and safety..........................................................................................10
Installation of the analyzer – Overview .............................................................................11
1. Installation of the analyzer ........................................................................................12
1.1 Dimensions of the analyzer ...............................................................................12
1.2 Location and ambient conditions .......................................................................13
1.3 Mounting instructions ........................................................................................13
2. Power and signals ....................................................................................................14
2.1 Power................................................................................................................14
2.2 Signals ..............................................................................................................14
3. Utilities ......................................................................................................................15
3.1 Overview ...........................................................................................................15
3.2 Sample feed ......................................................................................................15
3.3 Drain .................................................................................................................16
3.4 Overflow............................................................................................................16
3.5 Reagents & Calibration/validation solutions feed ...............................................16
3.6 Instrument air ....................................................................................................16
4. Power up & components test ....................................................................................17
4.1 Analyzer design ................................................................................................17
4.2 Wet chemical components ................................................................................18
4.3 Analog output ....................................................................................................21
4.4 Analog input ......................................................................................................21
5. Analyser method .......................................................................................................22
5.1 Specifications ....................................................................................................22
5.2 Analysis ............................................................................................................22
5.3 Calibration .........................................................................................................22
5.4 Validation ..........................................................................................................23
5.5 Cleaning ............................................................................................................23
5.6 Prime ................................................................................................................23
6. Reagent preparation .................................................................................................24
6.1 Reagent consumption .......................................................................................24
6.2 Storage and quality of chemicals and solutions .................................................24
6.3 Acid solution (0.5 M) .........................................................................................25
6.4 Buffer Ca Mg solution ........................................................................................25
6.5 Buffer Ca solution (NaOH 1M)...........................................................................26
6.6 Color solution ....................................................................................................26
6.5 EDTA solution (0.01 M) .....................................................................................27
6.6 Calibration standard solution .............................................................................28
6.7 Validation standard solution ..............................................................................28
6.8 Cleaning solution...............................................................................................29
7. Start-up of the analyser.............................................................................................30
7.1 Access ..............................................................................................................30
7.2 Reagents ..........................................................................................................30
7.3 Analysis procedure............................................................................................31
7.4 Calibration .........................................................................................................35
7.5 Cleaning ............................................................................................................36
7.6 Time List ...........................................................................................................36
7.7 Data and results ................................................................................................37
7.8 Analyzer settings ...............................................................................................38
7.9 Start-up the analyser for on-line measurement..................................................40
8. Maintenance .............................................................................................................41
8.1 Check for leaks and abnormal conditions ..........................................................41
8.2 Check for alarms ...............................................................................................41
8.3 Prepare reagents and fill the reagent containers ...............................................41
8.4 Run the calibration program ..............................................................................42
8.5 Run the cleaning program .................................................................................42
8.6 Replacement of the micropump’s duckbills .......................................................42
8.7 Replacement of the peristaltic pump tubing .......................................................42
8.8 Shutdown of the analyzer for a longer period ....................................................43
9. Troubleshooting ........................................................................................................43
10. Spare Parts ...........................................................................................................43
Addendum ........................................................................................................................44
Addendum 1: Analysis Procedure.....................................................................................44
1.1 Main Method – Analysis ....................................................................................44
1.2 Main Method – Cleaning (optional) ....................................................................44
1.3 Main Method – Priming (optional)......................................................................45
1.4 Ca Hardness Method – Analysis .......................................................................45
1.5 Total Hardness Method – Analysis ....................................................................46
Addendum 2: Analyzer Configuration ...............................................................................48
2.1 Digital Outputs ..................................................................................................48
2.2 Digital Inputs .....................................................................................................48
2.3 Analog Inputs ....................................................................................................48
2.4 Analog Outputs .................................................................................................49
2.5 Communication ports ........................................................................................49
2.6 Results ..............................................................................................................49
2.7 Results Calibration ............................................................................................49
2.8 Results Calculation ...........................................................................................49
2.9 Results Analog output .......................................................................................51
2.10 Result Alarms....................................................................................................51
2.11 Results Graph ...................................................................................................51
2.12 Algorithms .........................................................................................................51
2.13 Alarm and message table..................................................................................53
2.14 Group DO .........................................................................................................53
Addendum 3: Alarms and signals .....................................................................................54
Preface – Documents and safety
Thank you for purchasing this high quality analytical instrument. The analyzer is designed for
installation in industrial environments and intended for professional use. On delivery the
analyzer does not offer readily available end-user functionality. The analyzer needs to be
installed and configured by competent staff prior to use by the end user. Information about
the exact specifications, necessary connections, utilities and maintenance schedules is given
in the accompanying GENERAL SAFETY BOOK (8 languages).
General safety instructions

AppliTek and/or its affiliates use their best efforts to deliver a high quality analytical
instrument and reliable software packages. AppliTek nor its affiliates cannot be held
responsible for any damage that may result from the incorrect use of the software and
hardware, use outside the scope of the analyzer’s specification, misinterpretation of the
safety instructions, errors or deliberate modifications made to the analyzer; in addition, any
warranty issued by AppliTek becomes void.
• Knowledge of the basic safety regulations is essential for the safe handling and
disruption-free operation of the unit. Therefore, please read the entire manual before
setting up the analyzer. Pay attention to danger and caution statements;
• These operating instructions contain the most important guidelines necessary in order
to safely oversee the unit’s operation;
• All persons working on the unit should take note of these operation instructions, and
especially those relevant to safety;
• Protect the analyzer from impacts causing corrosion or preventing components from
working properly;
• Have faulty parts of the analyzer replaced immediately;
• Spare parts must comply with the technical requirements determined by AppliTek;
• When malfunctioning, take the analyzer out of operation. Repair the malfunctions
immediately. Failure to do so could result in serious injury to persons or damage to
the equipment;
• On top of this, all rules and regulations pertinent to accident prevention, which are
applicable at the measuring site, are to be followed.
• It is the operator’s responsibility to allow only those persons to work on the unit who
are familiar with the regulations concerning safe handling and have been informed
how to work with the instrument;
Safety devices
Before any initialization of the unit, all safety devices must be properly mounted and
functional. Safety devices can only be removed:
• During maintenance and repair work by trained personnel or when the unit has been
disconnected from the electrical mains.
• After the unit has been safeguarded against renewed operation.
Electrical dangers
Work on the unit’s power supply and electronics can only be carried out by a qualified
electrician. The mains switch must be switched off during work on electrical components.
10
Installation of the analyzer – Overview
11
1. Installation of the analyzer
1.1 Dimensions of the analyzer
12
1.2 Location and ambient conditions
The analyzer is designed for installation at indoor environmental conditions. Install the
analyzer where the temperature is maintained as stable as possible between 10 and 30 °C
(range 4°C) and is not subject to sudden temperature changes.
The analyzer should be installed as close as possible near the sampling point. If this is not
the case, a fast loop sampling system has to be installed because a long distance between
the analyzer and the sampling point will increase the response time of the analyzer.
Do not mount the analyzer in direct sunlight! This can affect the visibility of the screen
and the analyzer, its components and reagents.
Other points of attention are: - humidity: 5 – 95 % non-condensing

- avoid corrosive atmospheres
Variation of these conditions can seriously affect the analyzer results and damage the
analyzer and its components!
1.3 Mounting instructions
The analyzer is designed for wall mounting and intended for permanent installation. Make
sure the location is easy accessible. The dimensions of the analyzer are given on the
previous page. The indicated footprint is a strict minimum and doesn’t take into account the
space needed for tubing and cables.
The analyzer has four mounting holes for screws M8x10mm at the back of the cabinet.
These bolts are fastened into/onto the supporting structure from the inside of the electrical
cabinet at the back.
This analyzer has to be installed by qualified technical personnel to ensure adherence

to all applicable electrical plumbing requirements.
13
2. Power and signals
2.1 Power
First open the electrical cabinet door by pulling the two levers and unhook them. Make
provisions for removing power to the analyzer during servicing. The AC power cable enters
on the left side of the cabinet at the back through the upper left cable gland. The terminals for
the power and ground are located at the upper left hand corner of the cabinet at the back, as
you face the unit. Connect your wiring to the upper side of the terminals. Connect the AC
feed as follows:
- The protective ground at the yellow/green terminal block.

- The hot/line (L) and neutral (N) wire are to be connected at the circuit breaker.
Terminal North American wire color European wire color

Protective Ground (PE) Green Green/yellow
Hot/line (L) Black Brown
Neutral (N) White Blue
2.2 Signals
External 24Vdc power supply
Note: If additional AO, DI or DO connections are required, extra terminals will be present.
Connections:
AO1-AO2: Analog Outputs

4-20mA, active current,
max. load 500R
FCT1-FCT5: Free ConTacts

(digital output)
Relay output, contact loading
max. 24VDC/0,5A
PCT1-PCT4: Power ConTacts

(digital outputs)
24VDC/0,5A output
INP1-INP4: INPut
(digital input)
24VDC, to trigger with external
potential free contact
14
CONTACT INPUT/OUTPUT NAME
AO1 AO1 Result Tot Hard STR1
AO2 AO2 Result Ca Hard STR1
AO3 AO3 Result Tot Hard STR2
AO4 AO4 Result Ca Hard STR2
FCT1 DO25 Malfunction
FCT2 DO26
FCT3 DO27
FCT4 DO28
FCT5 DO29
PCT1 DO21 EXT SV STR1
PCT2 DO22 EXT SV STR2
PCT3 DO23
PCT4 DO24
INP1 DI1
INP2 DI2
INP3 DI3
INP4 DI4
3. Utilities
3.1 Overview
Consumption/ Consumption/28 days

Comment Connection
analysis (1 analysis/10 min)
Atmospheric
Sample ~ 80 ml ~ 350 L 1/8”
pressure
Atmospheric
Rinse (for cleaning) N.A. 1/8”
pressure
Vent / / Free 1/4”
Atmospheric
Reagents See Chapter 6 See Chapter 6 1/8”
pressure
3.2 Sample feed
The sample feed to the analyzer must be at atmospheric pressure if the analyzer uses a
peristaltic pump for sampling. The sample feed to the analyzer must be higher than the
sample flow in the analyzer. It is recommended to use a small overflow vessel (next to the
analyzer) from which the analyzer will take fresh sample. Thus the sample in the overflow
vessel should be continuously refreshed. If the size of the solids present in the sample is too
high, it is recommended to filter the sample.
Connection: 1/8” OD tubing (PFA)

Location: Left side of the analyzer
The analyzer is not designed for use with samples that are explosive or flammable. If a
solution other than water is used, this solution should be tested to test the
compatibility with the instrument!
15
3.3 Drain
The analyzer needs a drain to discharge both sample and reagents after analysis. A floor or
sink drain is satisfactory, but it must be unrestricted and located at a lower level than the
analyzer so that gravity will carry away the liquid. The drain must have a vent to the
atmosphere and the drain tube from the analyzer must not be submerged. Pay attention that
the drain line is never blocked. A water connection is also recommended so that the drain
sink and piping is regularly flushed with clean water in order to avoid clogging due to
crystallization. Steepness of the draining pipe must be sufficient.
Drain piping: recommended diameter of 32 mm

Location: Bottom side of the analyzer
Although the chemical reagents are diluted, the user has to check that the external
drain/overflow system is appropriate for reagents and corrosive wastes! Used
reagents shall be treated for disposal according to national or local regulations!
3.4 Overflow
The analyzer needs an overflow tube in order to drain the analysis compartment in case of
leakage of sample fluids, reagent fluids (and combination of both) in the compartment. A floor
or sink drain is satisfactory, but it must be unrestricted and located at a lower level than the
analyzer so that gravity will carry away the liquid. The overflow tube from the analyzer must
not be submerged. Pay attention that the overflow line is never blocked. Steepness of the
overflow pipe must be sufficient.

Location: Bottom side of the analyzer
3.5 Reagents & Calibration/validation solutions feed
Connections have to be made between the reagent containers and the dispensers, the micro
pumps and the cleaning valve. The calibration/validation solutions can be connected to the
REF1 or REF2 selection valve.
Connection: 1/8” OD tubing

Location: Bottom or left side of the analyzer
Although the chemical reagents are diluted, the user has to check that the external
drain/overflow system is appropriate for reagents and corrosive wastes! Used
reagents shall be treated for disposal according to national or local regulations!
3.6 Instrument air
The instrument air must be dry and dust free (according to ISA-S7.0.01-1996). The minimal
pressure of the instrument air necessary for the analyzer is 1 bar (100 kPa or 15.5 psi).
Instrument air is used for purging the analyzer in order to prevent corrosion by corrosive
gases such as chlorine gas from outside the analyzer.
16
4. Power up & components test
The analyzer and its components must be tested before the unit can be put into online
service. Make sure that all necessary connections were made before testing the following
components. Switch on the analyzer by means of the circuit breakers lever in the electrical
compartment and (if present) the external power switch.
When connecting the power of the analyzer, the software is started up. First, the initial
startup screen appears. While this screen is visible, the parameters are loaded (loading of
methods, configuration …) and the dispensers are initialized. Next, the MAIN screen (F1)
becomes visible automatically.
Initial startup screen MAIN screen
4.1 Analyzer design
17
4.2 Wet chemical components
Menu path:
→ F2
In the Visualization (F2) submenu, the wet chemical components (reagent pumps, stirrer,
dispenser…) can be controlled manually. Press the icons on the screen to control the
components. A control panel appears on the right side of the screen. By use of this panel,
the chemical components can be controlled. Check if these components are working
properly.
1. Stirrer
Press the stirrer icon. Switch the stirrer

ON/OFF by pressing the ‘ON/OFF’ button. It
is also possible to turn the stirrer ON for a
specified time. Insert the time (in seconds)
and press the ‘Start’ button.
2. Micropump
Press the micropump icon. Insert the number

of pulses. Press ‘Pulse’ to start the
micropump. Press the ‘Stop’ button to stop
the micropump.
18
3. Drain pump and Drain/Level valve
The drain/level valve is used in combination

with the drain pump for draining or leveling
the analysis vessel.
When the drain pump is started and the

drain/level valve is not activated, the analysis
vessel is drained.
Press the pump icon. Switch the pump

is also possible to turn the pump ON for a
specified time. Fill in the time (in seconds)
The ‘Group’ function is implemented for

safety reasons. If for example a valve must
be opened before a pump is started, the
group action can be used, if programmed.
Press the valve icon. Activate/deactivate the

valve by pressing the ‘ON/OFF’ button. It is
also possible to activate the valve for a
When the pinch valve and the drain pump

are activated, the level action takes place:
the excess of sample is removed from the
analysis vessel. The level action is used to
make sure that the amount of sample in the
analysis vessel is equal for each analysis.
4. Sample pump
The sample pump is used in combination with

the SV1, REF1, REF2 or Cleaning valve for
sampling.
Press the pump icon. Switch the pump

is also possible to turn the pump ON for a
The ‘Group’ function is implemented for

safety reasons. If for example a valve must be
opened before a pump is started, the group
action can be used, if programmed.
19
When the sample enters because one or
more valves are switched, it is necessary to
switch these valves on before the sample
pump is started. Press the icon of the
corresponding valve. Switch the valve
is also possible to turn a valve ON for a
Next, press the sample pump and start the

sample pump.
Components that are not visible on the visualization screen can be controlled in the DO
submenu.
Menu path:
Select the digital output by use of the Edit

(E) button.
The value of the digital output can be toggled

manually with the ‘ON/OFF’ button. After
entering an activation time (seconds), the
‘START’ button can be pressed to activate
the digital output. The digital output will then
be active during the inserted number of
seconds. After entering a number of pulses,
the digital output will give the set number of
pulses.
Press ‘Stop’ to stop any action of the DO.

Press the arrow keys at the top of the screen
to select another DO. Press ‘Back’ to quit
the screen.
20
4.3 Analog output
Menu path:
Press the EDIT (E) button to control the

selected analog output.
Use a multimeter to check if the analog

output signal is working.
Insert a value by use of numeric keyboard

and confirm. Press Accept to update this
value.
Check if this value corresponds to the value

the multimeter is giving.
Check the ‘Installation Manual’ to make the

right connections.
4.4 Analog input
Menu path:
Check if all analog inputs are responding

correctly.
Press the EDIT (E) button to control the

selected analog input.
4.4.1 Photometer
The calibration of the photometer is

performed in distilled water (media 1)
Press enter to start calibration

Put sensor in media 1 and enter
Stabilizing, press enter to continue
Update calibration data
21
5. Analyser method
5.1 Specifications
Specifications are subject to change without notice.
Method: Colorimetric titration
Wavelength: 610 nm
Parameter: Total Hardness (as mg/L CaCO3) and Ca Hardness
Range: 50 – 1000 mg/L CaCO3
Precision: < 2 % of full scale range (with standard solutions)
Analysis time: < 10 minutes
Sample requirements: Atmospheric pressure, flow rate between 10 and 30 ml/minute,

sample temperature between 5 and 60 °C
Sample dilution: pump head and sample valves for sampling

dispenser for internal dilution
Stream selection: Channel1: stream 1 (Sample valve and EXT SV1)

Channel2: stream 2 (Sample valve and EXT SV2)
Channel8: validation (REF2 valve)
Channel10: REF2 (REF2 valve)
5.2 Analysis
The analysis vessel is cleaned and filled with fresh sample. After sampling, the acid, buffer
(buffer Ca Mg) and color solution are added to the sample. Next, the photometric titration
(610 nm) with EDTA is performed and the calcium and magnesium concentrations in the
sample are determined (Total Hardness as mg/L CaCO3).
When measuring the Ca hardness the buffer (buffer Ca) changes the pH to 12. The Mg
settles and when the EDTA is added, the calcium concentration in the sample is only
determined.
The acid solution is added to dissolve all carbonates (CaCO3 dissolves into Ca2+ and (CO3)2-
which is removed as CO2 in acidic environment). The buffer solution is added to reach an
alkaline pH in which the color solution forms a purplish-blue color. The color changes to red
when contacting free calcium or magnesium. The color changes to blue when EDTA is
added to the sample. The change from the red to blue color is measured.
5.3 Calibration
The calibration procedure measures a REF2 or 1000 mg/l CaCO3 solution (channel 10 –
REF2 valve) to correct for any deviation in the results by external influences (sample volume,
micropump volume, reagent concentration).
22
5.4 Validation
The validation method is used to verify the functioning of the analyzer with a standard
solution. The validation procedure measures a standard solution with a known CaCO3
concentration (channel 8 – REF2 valve) to validate the analyzer.
5.5 Cleaning
The cleaning procedure should prevent any build-up of chemicals in the analyzer. To obtain
an effective cleaning procedure one has to test the cleaning solution and the cleaning
interval for each application. Perform the cleaning procedure with the selected cleaning
solution and interval for a trial period, check then the effectiveness of the procedure and
change if necessary.
5.6 Prime
The prime procedure can be used when starting up the analyzer or after a shutdown of the
analyzer: the reagent tubings are flushed with fresh reagent solution and the sample tubing
and the analysis vessel are flushed with fresh sample.
23
6. Reagent preparation
Warning:
Some of the chemicals used are corrosive or harmful! All operating
! personnel should wear protective gloves, goggles and acid-proof
clothing! Check the MSDS before starting to handle the chemicals.
The information in this document is based on the present state of our knowledge and is
applicable to the products with regard to appropriate safety precautions. It does not guarantee
any of the properties of the products. AppliTek shall not behold liable for any damage resulting
from handling or from contact with any product described in this manual.
6.1 Reagent consumption
In the tables below, the products that are needed to prepare the reagents are listed. The
product name, the formula, the molecular weight, the CAS No. and the amount needed to
prepare 1 liter of the reagents is given. Check the consumption of the reagents (28 days) to
adapt the volumes needed.
Consumption/analys Consumption/28 days Recommandable

Product
is (1 analysis/10 min) conatiner (L)
Acid solution ~ 0.5 ml < 2.5 L Plastic – 2.5L
Buffer Ca solution ~ 1 ml <5L Plastic – 5L
Buffer Ca Mg
~ 0.5 -0.75 ml <5L Plastic – 5L
solution
Color solution ~ 0.75 ml <5L Plastic – 5L
Concentration
EDTA solution dependent
Concentration dependent Plastic – 10L
Calibration
~ 80 ml N.A. N.A.
solution REF2
6.2 Storage and quality of chemicals and solutions
Quality of chemicals:
All chemicals should be of ACS grade or better. We recommend the use of pro analysis
chemicals.
Quality of water:
Reagent grade, de-ionized water (calcium- and magnesium-free) must be used to prepare
the chemical solutions and for rinse purposes.
Laboratory equipment:
Reagent and solutions should be prepared and kept in plastic vessels. Avoid the use of
glassware.
24
6.3 Acid solution (0.5 M)
Product Formula MW (g/mol) CAS No. Product number

Hydrochloric acid (0.5 M) HCl 36.46 7647-01-0 318957 (Sigma-Aldrich)
Hydrochloric acid 0.5 M
Hazard statement(s):
H290: May be corrosive to metals.
Precautionary statement(s):
None
This solution is stable for several months.
6.4 Buffer Ca Mg solution
Product Formula MW (g/mol) CAS No. 1 liter solution

Ammonium chloride NH4Cl 53.49 12125-02-9 54 g
Ammonia solution 25% NH4OH 35.05 1336-21-6 350 ml
Mg-EDTA* C10H12MgN2Na2O8·4H2O 430.56 29932-54-5 5g
*ethylenediaminetetraacetic acid magnesium disodium salt tetrahydrate
Ammonium chloride
H302: Harmful if swallowed.
H319: Causes serious eye irritation.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
Ammonia solution 25%
H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
H335: May cause respiratory irritation.
H400: Very toxic to aquatic life.
25
P261: Avoid breathing vapours.
P273: Avoid release to the environment.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.
P310: Immediately call a POISON CENTER or doctor/ physician.
Mg-EDTA (ethylenediaminetetraacetic acid magnesium disodium salt tetrahydrate)
Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008. This substance is
not classified as dangerous according to Directive 67/548/EEC.
Preparation:
Dissolve 54 g of ammonium chloride (NH4Cl) in de-ionized water using a volumetric flask of
1000 ml. Add 350 ml of 25% ammonium hydroxide solution (NH4OH). Add 5 g Mg-EDTA,
dissolve completely and fill up to 1 liter with de-ionized water.
This solution is stable for 1 month.
6.5 Buffer Ca solution (NaOH 1M)

Sodium hydroxide NaOH 40.00 1310-73-2 40 g
Sodium hydroxide (pellets)
Hazard statement(s)
H314: Causes severe skin burns and eye damage
Precautionary statement(s)
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P310: IF exposed or if you feel unwell: immediately call a POISON CENTER or
doctor/physician.
Preparation:
Dissolve 40 g of sodium hydroxide (NaOH p.a., > 99 %) in 500 ml of demineralized water and
dilute to 1 liter with demineralized water.
6.6 Color solution

Calmagite HOC10H5[N=NC6H3(OH)CH3]SO3H) 358.37 3147-14-6 0.2 g
26
Calmagite
H315: Causes skin irritation.
H335: May cause respiratory irritation.
P261: Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
Preparation:
Dissolve approximately 0.2 g Calmagite (HOC10H5[N=NC6H3(OH)CH3]SO3H) in 400 mL
degassed de-ionized water using a volumetric flask of 1L. Fill up to the grade mark with de-
ionized water.
6.5 EDTA solution (0.01 M)

EDTA* C10H14N2Na2O8.2H2O 372.2 6381-92-6 3.722 g
OR
EDTA-Na2**
C10H14N2Na2O8 336.21 139-33-3 100 ml
0.1M
*ethylenediaminetetraacetic acid disodium salt dihydrate
**ethylenediaminetetraacetic acid disodium salt solution
EDTA (ethylenediaminetetraacetic acid disodium salt dihydrate)
Hazard statement(s)
Precautionary statement(s)
EDTA (ethylenediaminetetraacetic acid disodium salt solution)

Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008. Not a hazardous
substance or mixture according to EC-directives 67/548/EEC or 1999/45/EC.
Preparation:
Dissolve accurately 3.722 g ethylenediaminetetraacetic acid disodium salt dihydrate
(C10H14N2Na2O8.2H2O) in 500 ml degassed de-ionized water and fill up to 1000 ml.
27
OR
Dilute a 0.1 M EDTA stock solution by taking exactly 100 ml of the 0.1 M EDTA solution using
a volumetric flask of 1000 ml and adding de-ionized water up to the mark grade.
6.6 Calibration standard solution

Calcium chloride dihydrate CaCl2.2H2O 147.02 10035-04-8 3.668 g
Calcium chloride dihydrate
H319: Causes serious eye irritation
Preparation:
1000 mg/L Ca stock solution
Prepare a stock solution of 1000 mg/L CaCO3: dissolve accurately 3.668 g calcium chloride
dihydrate (CaCl2.2H2O) in 200 ml degassed de-ionized water (DI water), using a volumetric
flask of 1000 ml. Add de-ionized water up to the mark grade.
1000 mg/L CaCO3 calibration standard solution

Prepare a standard solution of 1000 mg/L CaCO3: take accurately 400 ml of the 1000 ppm Ca
stock solution and transfer a volumetric flask of 1000 ml. Add de-ionized water up to the mark
grade.
6.7 Validation standard solution

Calcium chloride dihydrate CaCl2.2H2O 147.02 10035-04-8 3.668 g
Magnesium chloride
MgCl2.6H2O 203.30 7791-18-6 8.365 g
hexahydrate
Calcium chloride dihydrate
28
H319: Causes serious eye irritation
Magnesium chloride hexahydrate

Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008. This substance is
not classified as dangerous according to Directive 67/548/EEC.
Preparation:
1000 mg/L Ca stock solution
Dissolve accurately 3.668 g calcium chloride dihydrate (CaCl2.2H2O) in 200 ml de-ionized
water, using a volumetric flask of 1000 ml. Add de-ionized water up to the mark grade.
1000 mg/L Mg stock solution

Dissolve accurately 8.365 g magnesium chloride hexahydrate (MgCl2.6H2O) in 200 ml de-
ionized water, using a volumetric flask of 1000 ml. Add de-ionized water up to the mark grade.
Preparation validation standard solution 250 mg/l CaCO3 :

Take accurately 50 ml of the 1000 ppm Ca stock solution and 30 ml of the 1000 ppm Mg
stock solution and transfer into 200 ml de-ionized water, using a volumetric flask of 1000 ml.
Add de-ionized water up to the mark grade.
This solution contains the equivalent of 100 mg/l Ca or 250 mg/l CaCO3.
6.8 Cleaning solution
The cleaning procedure should prevent any build-up of chemicals in the analyser. To obtain
an effective cleaning procedure one has to test the cleaning solution and the cleaning
interval for each application. Perform the selected cleaning solution and interval for a trial
period, check then the effectiveness of the procedure and change if necessary.
29
7. Start-up of the analyser
7.1 Access
Menu path:
→ F1 → User → Enter Access password
Press the black box next to ‘User:’ to change the userlevel by use of the corresponding
password.
Depending on the userlevel some menus are accessible and some are not. Normally, when
the analyzer is started up, the ‘Automatic’ userlevel appears. This level is also used in
online situations. The analyzer is locked, which means that the METHOD (F4) and CONFIG
(F5) menu are not accessible. If modifications of the software are needed, higher userlevels
can be used. The access to certain crucial parameters is only given if the ‘Administrator’
password is used. Enter the password by pressing the ‘Enter Access password’ button.
Default passwords:
User Password
Automatic -
User1 a
User2 b
7.2 Reagents
Menu path:
→ F1 → 1.Method → Priming
Select the method with the navigation buttons at the bottom of the MAIN (F1) screen. The
method screen appears.
If all wet chemical components are working properly, the reagents can be connected to the
analyser. Press the ‘Priming’ button to fill up all tubings to the analysis vessel with reagent
30
Make sure there is no air present in the tubings. Also, make sure there is no air present in
the dispenser, the tubing to the dispenser and the tubing from the dispenser to the analysis
vessel.
7.3 Analysis procedure
Follow the procedure below to start the method. It is recommended to run the method
several times and to make sure the measurements are stable before a calibration of the
analyzer is performed. Make sure all flushing times are set correctly before the analyzer is
started for on-line measurement.
Menu path:
→ F1 → 1.Method
Select the method with the navigation buttons at the bottom of the MAIN (F1) screen. The
method screen appears.
Menu path:
→ F1 → Method → Playlist → Automatic sequence
Press the Playlist button. Press the Automatic sequence button and insert the desired
module, channel and number of analysis. Press Accept to confirm. Press Back to quit the
window without saving the changes.
Start parameters:
Module: Analysis, Preconditioning, Cleaning, Priming, Init, and Exit.

CH: Automatic sequence or channel 1 to 10
# Runs: Insert the number of runs of the module (0 = Continuous analysis)
Comment: Add a comment concerning the analysis (Optional). This comment will also be
displayed in the data table.
31
7.3.1 Single stream analysis
- Module: select Analysis

- CH: insert the number of the stream
(Sample = stream 1 – 8; REF1 = stream 9; REF2 = stream 10)
- #Runs: insert the desired number of runs (=1 for single stream analysis)
- Continuous analysis: insert 0 as #Runs in the method main screen

- Fixed number of analysis: insert the desired #Runs in the method main screen
For example:
- The third sample stream needs to be analyzed
- Insert ‘3’ as channel (CH) and 1 as #Runs
7.3.2 Single stream analysis with cleaning

- Module: select the desired module (Analysis or Cleaning)
(For cleaning, always use channel 1)
Repeat for each stream that needs to be analyzed.

For example:
- There one streams that need to be analyzed. After 10 analysis, a cleaning is needed.
- Insert ‘Analysis’ as Module, ‘1’ as channel and ‘10’ as #runs
- Insert ‘Cleaning’ as Module, ‘1’ as channel and ‘1’ as #runs
7.3.3 Multiple stream analysis

- Module: select Analysis
32
For example:
- There are five streams that need to be analyzed.
- Insert ‘1’ as channel and 1 as # runs
7.3.4 Multiple stream analysis with cleaning

- Module: select the desired module (Analysis or Cleaning)

For example:
- There are two streams that need to be analyzed. Next, a cleaning is needed.
- Insert ‘Cleaning’ as Module, ‘1’ as channel and ‘1’ as #runs
33
7.3.5 Start the method
Menu path:
→ F1 → 1.Method1 → Playlist → Start
7.3.6 Stop the method
Menu path:
→ F1 → 1.Method1 → Stop
Press the ‘Stop’ button. The method will be finished and the analyzer will stop (status will
change from ‘Run’, to ‘Stopped’ and then ‘Ready’).
Menu path:
→ F1 → 1.Method1 → Abort
Press the ‘Abort’ button to stop the method immediately after confirmation.
Menu path:
→ E-Stop
In case of emergency, all methods can be stopped directly by pressing the E-STOP button
(SOFTWARE emergency stop) at the bottom of the screen.
34
7.3.7 Remote control
Menu path:
→ F1 → 1.Method1 → Is Master
Press the ‘Is Master’ button. The following instruction screen appears. Press ‘Toggle’ to put
the analyzer in ‘Is Slave’ position. If the method is in this position, it is impossible to start the
method manually. The method can only be started remotely i.e. by a digital input, by Modbus
communication, by a sequence…
Press Abort to stop the method. Press the ‘Is Slave’ button to put the analyzer in ‘Is Master’
position again.
7.4 Calibration
When the analysis results are stable, the analyzer can be calibrated.
Menu path:
→ F1 → Method → Calibrate
Press the ‘Calibrate’ button. The calibration procedure will start automatically after
confirmation. The calibration procedure consists of following steps:
- Number of runs (REF1): 3x stream 9

- Number of runs (REF2): 3x stream 10
The concentration of the REF1 and REF2 solution and the number of runs is programmable
in the Configuration (F5) menu (See Configuration Manual for more information).
Press the ‘Calibration history’ button to get an overview of the previous calibration data.
35
7.5 Cleaning
Menu path:
→ F1 → Method → Cleaning
To clean the analyzer (the analysis vessel) press the ‘Cleaning’ button. The cleaning
subroutine will be executed and the analyzer is stopped.
When the analyzer is on-line, the cleaning procedure starts after the Analysis subroutine is
finished. The analyzer is started again for on-line measurements after the Cleaning
subroutine is finished.
7.6 Time List
Menu path:
→ F1 → Method → Time list
Press the Time list button to configure the time list. An overview of the configured time tables
is displayed. Scroll through the list by use of the arrow keys.
Press the Edit (E) button to configure the selected time table. Every time table can be turned
ON or OFF by pressing the toggle (T) button.
Make sure the ‘Direct’ button is selected to guarantee the proper functioning of the Time list.
Press Back to quit the screen.
36
7.6.1 Configuration of the time list
Only a configured time list can be used. Make sure the time list is turned ‘ON’ and the
‘Direct’ button is selected.
Refer to the Configuration manual for additional information about the configuration of the
time list. Press Accept to confirm. Press Back to quit the screen.
Example:
An automatic calibration on stream 1 of
method 1 is needed, every day at 12 o’clock.
- HH: 12
- Channel: 1
- Start function: Calibration
- Index: Method1
7.7 Data and results
Menu path:
→ F3 → Database
The analysis results of every method are displayed in the ‘Database’ submenu. A method
can be selected by use of the arrow keys at the right side of the screen. Press the Edit (E)
button to view the result for the selected method. The arrow keys on the right side of the
screen can be used to scroll through the list.
The file can be exported to a memory stick by pressing the ‘Export’ button. The data are
exported to a CSV-file that can be opened for example in EXCEL.
37
Menu path:
→ F6
The course of a titration can be followed in the F6 submenu. Select the titration algorithm by
use of the dropdown menu. The graph can be appointed by use of the alphanumeric
keyboard. The screen can be copied to an USB stick by pressing the Export button. Press
the orange arrow key to view the titration data table. The titration algorithm can be selected
by use of the dropdown menu.
7.8 Analyzer settings
Adjustments to the analyzer configuration are made in the Configuration (F5) menu. We
recommend you to read the instructions very carefully before making adjustments to the
analyzers configuration: the functioning of the analyzer may be disturbed!
For more information about the analyzer settings, refer to the Configuration Manual.
7.8.1 Adaptation of flushing intervals

Menu path:
→ F5 → Software → CH Interval
The time set in a channel interval is channel dependent. Change this time in order to
extend/reduce for example the flush time of the sample through the analysis vessel.
Repeat for every channel (sample stream) if necessary.
38
7.8.2 Adaptation of constant values
Menu path:
→ F5 → Software → Constants
Constant values are used in the calculation of the results. Change these values if necessary.
7.8.3 Adaptation of group DO times

Menu path:
→ F5 → Software → Group DO → E (Edit)
Group actions are implemented to run several actions simultaneously. Be careful when
changing the ‘group DO’ settings, the functioning of the analyzer may be disturbed.
Select the ‘group DO’ by use of the arrow keys and press the Edit button to change the
settings.
The times are entered in millisecond (ms). To avoid problems with analyzer functioning, only
change the time with the greatest value. Press Accept to save the settings. Test the changes
before starting the analyzer for on-line measurements.
39
7.8.4 Adaptation of algorithms
Menu path:
→ F5 → Software → Algorithms
Settings for algorithms are configured in the AppliTek lab with standard solutions.
Depending on the problems that occur in the field, other settings need to be adapted.
For more information about the algorithm settings, refer to the Configuration Manual.
7.9 Start-up the analyser for on-line measurement
The analyser is now set-up and ready to go online. Make sure all analyser components are
working properly and all settings are correct before the analyser is started.
40
8. Maintenance
Task Daily Weekly Monthly Quarterly Annually
Check for leaks and abnormal
X X X X X
conditions
Check for alarms X X X X X
Prepare reagents and fill the
X X X
reagent containers
Run the calibration program (X) (X) X
Replace the duckbills X
Replace all peristaltic pump
X X
tubing
Replace all pinch valve tubing X
Replace all tubing X
Perform a regular inspection of the analyzer to ensure proper performance.
8.1 Check for leaks and abnormal conditions
It is recommended that the instrument and preconditioning system is inspected visually on a

regular basis in order to guarantee the correct functioning of the system and to check the
integrity of the output.
• Check for alarms on the instrument display

• Check all the components in the analysis compartment, the outside connectors and tubings
for leaks.
• Confirm sample flow by checking the constant delivery of the sample
• Check the liquid levels in the reagent and standard solution containers
• Check if all the components in the analyzer cabinet are functioning (pumps, valves,
dispensers, photometer/electrode and stirrer). The photometer/electrode can be checked
by checking if the measurement values are normal. If not, double-check by performing a
calibration.
• Check the air pressure.
8.2 Check for alarms
Check the alarm page on the touch screen PC for alarms.
8.3 Prepare reagents and fill the reagent containers
Use reagents supplied by AppliTek or a qualified company or prepare them yourself by

following the instructions in chapter 6. Refill the reagent containers with the fresh made
reagents or use supplied reagents. Make sure that the tubings reach the bottom of the
reagent containers.
Never pour the fresh reagents in containers with old reagents!

Dispose the old reagents before pouring new reagent into its specific container.
41
8.4 Run the calibration program
Refer to chapter 7.4 if analysis results are not as expected.
8.5 Run the cleaning program
Refer to chapter 7.5 to perform a manual cleaning.

Refer to chapter 7.6 to program the automatic cleaning procedure.
8.6 Replacement of the micropump’s duckbills
• Open the electrical cabinet of the analyzer.

• Disconnect the micropump and remove the old duckbill valves. Keep in mind their original
position.
• Place the new duckbill valves in the same position as the previous duckbills. Be careful the
duckbills are tightened well when reconnecting the micropump.
8.7 Replacement of the peristaltic pump tubing
• Unfasten the wingnuts that fix the peristaltic pumps onto the electric motor coupler.
• Remove the pump head.
• Separate the front pump half from the back half. Hold the pump axle and the back pump
half together (1a).
• Remove the tubing. Keep in mind the length of both endings coming out of the pump head.
• Cut new tubing of the same size at the same length of the old one.
• Assemble the tube in the exact same way the old one was placed and push it down the
back pump half in front of the pump axle rollers. Then twist the pump axle a bit while you
keep pushing the tubing down so it is pressed between the pump housing and the pump
axle rollers (1b +1c).
• Join the two pump halves and make sure the tubing is not squeezed between the two
halves (1d).
• Place back the pump head and align the pump axle with the motor axle by pushing it
against the motor axle while turning the pump axle with a screwdriver.
• Fasten the wingnuts.
• Activate the pump and check if it is running properly.
42
8.8 Shutdown of the analyzer for a longer period
If the analyzer is stopped for a longer period (more than 3 days), it is recommended to rinse
the sample tubing, the reagent tubing, the dispensers and the analysis vessel with de-
mineralized water or a cleaning solution. In order to increase the lifetime of the electrodes, it
is recommended to take out the electrodes and store them with the original electrode cap. To
prevent evaporation of the electrolyte in the electrode, the electrode cap has to be filled with
electrolyte. Storage of the electrodes in de-mineralized water will significantly decrease the
lifetime of the electrodes.
9. Troubleshooting
If analysis results are unstable the following items should be checked:
a) Micropumps: make sure the reagents are dosed correctly and that no air is present in the
tubings
b) Peristaltic pumps: check if the drain and sample pump are working correctly
c) Valves: make sure the sample/REF1/REF2/Clean valves are working correctly
d) Stirrer: check if there is a magnetic stirrer bar in the analysis vessel and if the solution is
stirred during analysis
e) Check the positioning of the tubings inside the analysis vessel

• The drain tubing must be positioned at the back side of the analysis vessel and in
the ringlets.
• Other tubing should be positioned above the liquid level.
f) Check the reagents. Prepare a new set of reagents when the reagent containers are
empty. Flush/Prime all tubing before performing a measurement.
10. Spare Parts

See Material Date Sheet with corresponding analyzer serial number.
43
Addendum
Addendum 1: Analysis Procedure

Remark:
Adjustments to the methods are made in the METHOD (F4) menu. We recommend you to
read the ‘Configuration Manual’ carefully before making adjustments to the method: the
functioning of the analyzer may be disturbed.
1.1 Main Method – Analysis
Streamselection Channel DO
Channel 1 (sample) Sample (STR1)
Channel 2 (sample) Sample (STR2)
Channel 8 (validation) REF2
Channel 10 (calibration) REF2
Nr Step Name Interval Volume Pulses

1 PROGMOD1: Analysis
2 Run: Ca Hardness 1s
3 Wait for Method 1800 s
4 Run: Total Hardness 1s
5 Wait for Method 1800 s
6 Write to database 1s
7 Waiting Variable: Waiting
1.2 Main Method – Cleaning (optional)

9 PROGMOD3: Cleaning
10 Clean ON 50 ms
11 DP CCW Interval 30 s
12 Sample Group 8000 ms
13 Drain Group 16000 ms
15 Stirrer ON 50 ms
16 Waiting 60 s
18 Clean OFF 50 ms
20 Waiting 1s
44
1.3 Main Method – Priming (optional)

21 PROGMOD4: Priming
22 DP CCW ON 50 ms
23 Acid pulses 1s 150p
24 Buffer Ca pulses 1s 150p
25 Buffer CaMg pulses 1s 150p
26 Color pulses 1s 150p
27 EDTA pulses 150 s 150p
28 SP CW ON 50 ms
29 Clean Interval 15 s
30 REF2 Interval 15 s
31 Spare Interval 15 s
32 Sample Interval 15 s
33 SP CW OFF 50 ms
34 Waiting 30 s
35 DP CCW OFF 50 ms
36 Rinse Group 10000 ms
40 Waiting 1s
1.4 Ca Hardness Method – Analysis

2 Streamselection ON 50 ms
3 Stirrer ON 50 ms
5 ABS Meas. 5s
6 ABS drain Calc. 1s
7 SP CW ON 50 ms
8 DP CCW ON 50 ms
9 Flushing Variable: Flushing
10 SP CW OFF 50 ms
11 Waiting 5s
12 DP CCW OFF 50 ms
18 Level Group 11000 ms
19 Streamselection OFF 50 ms
45
20 ABS Meas. 5s
21 ABS sample Calc. 1s
22 Sample Detection Calc. 1s
23 Waiting 15 s
24 Sub procedure 0 0s
25 Drain / Level OFF 50 ms
26 Stirrer ON 50 ms
28 Waiting 60 s
29 Buffer Ca pulses 18 s 18p
30 Color pulses 12 s 12p
31 Waiting 5s
32 Hardness Algorithm 1200 s
33 Waiting 1s
34 Algorithm check Calc. 1s
35 ml. infl Ca Calc. 1s
36 Ca Hardness Calc. 1s
48 Ca Hardness Calc. 1s
51 Waiting 1s
1.5 Total Hardness Method – Analysis

3 Stirrer ON 50 ms
5 ABS Meas. 5s
6 ABS drain Calc. 1s
7 SP CW ON 50 ms
8 DP CCW ON 50 ms
9 Flushing Variable: Flushing
46
10 SP CW OFF 50 ms
11 Waiting 5s
12 DP CCW OFF 50 ms
18 Level Group 11000 ms
20 ABS Meas. 5s
21 ABS sample Calc. 1s
22 Sample Detection Calc. 1s
23 Waiting 15 s
26 Stirrer ON 50 ms
28 Waiting 60 s
29 Buffer CaMg pulses 15 s 15p
30 Color pulses 12 s 12p
31 Waiting 5s
32 Hardness Algorithm 1200 s
33 Waiting 1s
34 Algorithm check Calc. 1s
35 ml. infl TH Calc. 1s
36 Total Hardness Calc. 1s
48 Total Hardness Calc. 1s
51 Waiting 1s
47
Addendum 2: Analyzer Configuration
See also ‘Material Date Sheet’ with corresponding analyzer serial number.
Software: PP65 UPA V3.06.70
2.1 Digital Outputs
Nr Name
1 SP CW
2 SP CCW
3 DP CW
4 DP CCW
5 Drain / Level
6 Stirrer
7 Acid
8 Buffer Ca
9 Buffer CaMg
10 Color
11 EDTA
12 Spare
13 REF2
14 Clean
15 Rinse
16 Sample
21 EXT SV STR1
22 EXT SV STR2
25 Malfunction
2.2 Digital Inputs
Nr Name
1 INP1
2 INP2
3 INP3
4 INP4
2.3 Analog Inputs
Nr Name
1 ABS
48
2.4 Analog Outputs
Nr Name
1 Result Tot Hard STR1
2 Result Ca Hard STR1
3 Result Tot Hard STR2
4 Result Ca Hard STR2
2.5 Communication ports
Nr Name Function Baudrate Databit Parity Stopbit

1 COM1 0 9600 8 0 1
2.6 Results
Nr Name Unit
1 Sample Detection N.A.
2 ABS drain Ca mAU
3 ABS sample Ca mAU
4 ml. infl Ca ml
5 Algorithm check N.A.
6 Ca Hardness ppm
7 Total Hardness ppm
8 ABS mAU
9 ml. infl TH ml
10 ABS drain TH mAU
11 ABS sample TH mAU
2.7 Results Calibration
Name A1 Min A1 Max A1

Total Hardness 7,15776 0 20
Ca Hardness 7,21652 0 20
Name Conc. Ref2 Runs Ref2

Total Hardness 1000 3
Ca Hardness 1000 3
2.8 Results Calculation
Sample Detection
1 M1 - M2
2 IF R1 < 100 THEN Set alarm byte: 1 Value: 1
3 IF R1 >= 100 THEN Set alarm byte: 1 Value: 0
4 IF R1 < 100 THEN goto subprocedure 1000
5 IF R1 >= 100 THEN goto subprocedure 0
6 R1 End of calculation
49
ABS drain Ca
1 M1 End of calculation
ABS sample Ca
ml Infl. Ca
Algorithm check
1 IF M-Alarm3 = 1 THEN GOTO R3
2 0 End of calculation
3 IF 0 = 0 THEN goto subprocedure 1000
4 1 End of calculation
Ca Hardness
1 M3 write to calibration
2 M3 / Factor a1
3 R2 * Conc. ref2
Total Hardness
1 M6 write to calibration
2 M6 / Factor a1
3 R2 * Conc. ref2
ABS
1 ABS End of calculation
ml Infl. TH
ABS drain TH
ABS sample TH
50
2.9 Results Analog output
Result Channel Analog output Value 4mA Value 20mA

Ca Hardness 1 Result Ca Hard STR1 0 1000
Ca Hardness 2 Result Ca Hard STR2 0 1000
Total Hardness 1 Result Tot Hard STR1 0 1000
Total Hardness 2 Result Tot Hard STR2 0 1000
2.10 Result Alarms
Result Channel Low alarm DO High alarm DO Low value High value
Ca
0 0 1500
Hardness
Total
0 0 1500
Hardness
2.11 Results Graph
Result Channel Low value High value

Ca Hardness 0 0 1000
Total Hardness 0 0 1000
2.12 Algorithms
Name: Ca Hardness
Sensor: ABS
Pauze
Pauze drift: 0
Pauze Max time: 0
Pauze Min time: 0
Initial dosing
Init steps: 3
Init time: 5
Init Volume: 0,1
Init Speed: 30
Dynamic dosing
Dyn. slope: 5
Dyn. speed: 30
Dyn. refill speed: 60
Dyn. min step: 0.1
Dyn. max step: 0.2
Dyn. min time: 5
Dyn. max time: 6
Dyn. drift: 0
Dyn. nr of points: 5
EP minimum: 0,05
EP peak: 2
51
EP filter: 6
EP threshold: 50
EP1
M-position: 3
Window-low: 0
Window-high: 2000
Threshold: 250
Stop
Stop volume (ml) 10
Stop at measured value: 2900
Drift: 0
Number of EP: 1
Dosed volume after EP: 0.1
Stop time: 1200
Graph
Graph Low: 0
Graph High: 2500
Name: Total Hardness

Sensor: ABS
Pauze
Pauze drift: 0
Pauze Max time: 0
Pauze Min time: 0
Initial dosing
Init steps: 3
Init time: 5
Init Volume: 0,1
Init Speed: 30
Dynamic dosing
Dyn. slope: 5
Dyn. speed: 30
Dyn. refill speed: 60
Dyn. min step: 0.1
Dyn. max step: 0.4
Dyn. min time: 5
Dyn. max time: 10
Dyn. drift: 0
Dyn. nr of points: 5
EP minimum: 0
EP peak: 2
EP filter: 6
EP threshold: 0
EP1
M-position: 6
52
Window-low: 0
Window-high: 2000
Threshold: 250
Stop
Stop volume (ml) 10
Stop at measured value: 2900
Drift: 0
Number of EP: 1
Dosed volume after EP: 0.1
Stop time: 1200
Graph
Graph Low: 0
Graph High: 2500
2.13 Alarm and message table
Nr Type Apply Function Message Reset

0 None Global Emergency stop E-stop/Reinitialize the dispensers! Automatic
1 Alarm Global Direct alarm No sample detected Automatic
2 Alarm Global Calibration failure Calibration error Automatic
3 Alarm Global SensorABS Sensor ABS error Automatic
4 Alarm Global M-Alarmml infl. Inflection point not found Automatic
5 Alarm Global Titration algorithm Titration Ca error Automatic
6 Alarm Global Titration algorithm Titration TH error Automatic
2.14 Group DO
Action DO1 Status DO2 Status Time (ms)

Sample 1 SP CW On Stirrer Off 3000
2 SP CW On Stirrer On 4000
Drain 1 DP CCW On Stirrer On 5000
2 DP CCW On Stirrer Off 10000
Level 1 Drain/Level Continue Stirrer Off 1000
2 DP CCW On 9000
Rinse 1 Rinse On Stirrer Off 3000
2 Rinse On Stirrer On 6000
53
Addendum 3: Alarms and signals
3.1 Alarms
Introduction
All alarms are implemented as follows:
• Closed contact: the alarm is off and the Analyzer is On-line

• Open contact: the alarm is active
Alarm list
• Malfunctioning alarm:
Every alarm activates the malfunctioning alarm output (contact is opened).
o Emergency stop
When the emergency stop is activated, the analyzer shall stop immediately.
o Leak detection
There is a sensor installed inside the analyzer cabinet to detect leaks. When a leak
is detected, the malfunctioning alarm is triggered and the analyzer is stopped
(optional). A message box appears on the main screen.
o Sensor
When there is a problem with one of the sensors, the malfunctioning alarm is
activated. A massage appears in the message or history submenu.
o Titration alarm
When there is a problem during the titration (titration out of time, no inflection
points detected…) the malfunctioning alarm is activated. A massage appears in
the message or history submenu.
• Maintenance alarm:
When the maintenance mode is active after pressing the MAINTENANCE ON/OFF
button, a digital output is activated (maintenance contact is opened) to indicate
remotely that the analyzer is not running on-line. When the maintenance mode is
active, the analyzer is always in the local control mode: the analyzer can only be
started manually.
3.2 Signals
The standard signal is an active 4-20 mA signal.
RS232/MODBUS are optional, but can be programmed and used if the proper remote IO is
installed.
54
Warranty
1. Warranties
AppliTek NV/SA warrants that its products are free from defects in materials and workmanship (under
normal conditions of use and service) for a period one (1) year from date of shipment to original
purchaser.
2. Limited warranty and liability

On principle, the “General terms of and conditions of sale and delivery” of the company AppliTek
apply. All warranty and liability claims made for damage to persons or property are invalid when they
prove to have as a cause one or more of the following:
• Operating the unit for reasons other than its designed purpose
• Improper assembly, initializing, operating or maintenance of the unit
• Operating the unit when any safety or protection devices are defect or non-functioning
• Non-adherence of any instruction in the operating manual
• Unauthorized constructional alterations to the measuring unit
• Unauthorized constructional alterations to the utilities (for example instrument air supply).
• Incorrect maintenance of unit components
• Maintenance and repair work improperly carried out
• Catastrophes caused by outside interference, natural disaster, labor unrest, acts of war,
terrorism, civil strife or acts of any governmental jurisdiction.
Warranty also does not cover:

Freight charges on expedited or express shipment of warranted parts or product
Travel fees associated with on-site warranty repair
3. Inspection and claims

Claims for damage in shipment must be filed immediately with delivering carrier. Claims for shortages,
shipping errors or any claim that the goods do not conform with the terms of the contract must be
submitted to the AppliTek NV/SA in writing within five (5) days of receipt. If buyer fails to comply with
the term ‘within 5 days of receipt’, the goods shall be deemed to conform with contract terms, and
buyer shall accept and pay for the goods in accordance with the contract. Buyer waives any right to
revoke acceptance after such five days period. All claims must be accompanied by a copy of the
shipment note.
4. Indemnity for products manufactured according to customer’s requirements

In the event AppliTek NV/SA provides products in accordance with drawings, models or samples
provided by the customer, customer shall indemnify AppliTek NV/SA from any liability, cost or expense
suffered by AppliTek NV/SA as a result of the violation of any law or regulation or the infringement of
any industrial property right or other right of third parties.
5. Notification of product hazards and recall of products

Customer will inform AppliTek NV/SA immediately in writing about any events which indicate any
hazards connected with the product. Upon written notice of the AppliTek NV/SA about hazards in
connection with the products or unfitness for use of the products and recall of products, the customer
will immediately cease using the products for any reason, the customer, as its sole remedy shall be
entitled compensation equivalent to the current value of the used product, but in no event more than
the purchase price. AppliTek NV/SA shall not be liable for buyer’s loss of profit or incidental
consequential or special damages of any kind.
55

User's Manual TitriLyzer® Total Hardness (CaCO3) Series of On-Line Hardness (CaCO3) Analyzers

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User’s Manual

TitriLyzer® Total Hardness (CaCO3)

Serial number: 012.1189.1708.148

© 2017 – AppliTek NV – Printed in Belgium

General safety instructions

1.1 Dimensions of the analyzer

Other points of attention are: - humidity: 5 – 95 % non-condensing

1.3 Mounting instructions

This analyzer has to be installed by qualified technical personnel to ensure adherence

- The protective ground at the yellow/green terminal block.

Terminal North American wire color European wire color

External 24Vdc power supply

AO1-AO2: Analog Outputs

FCT1-FCT5: Free ConTacts

PCT1-PCT4: Power ConTacts

Consumption/ Consumption/28 days

3.2 Sample feed

Connection: 1/8” OD tubing (PFA)

Drain piping: recommended diameter of 32 mm

Connection: 3/8” OD tubing (PFA)

3.5 Reagents & Calibration/validation solutions feed

Connection: 1/8” OD tubing

3.6 Instrument air

Connection: 1/4” OD tubing (PFA)

Initial startup screen MAIN screen

4.1 Analyzer design

Press the stirrer icon. Switch the stirrer

Press the micropump icon. Insert the number

The drain/level valve is used in combination

When the drain pump is started and the

Press the pump icon. Switch the pump

The ‘Group’ function is implemented for

Press the valve icon. Activate/deactivate the

When the pinch valve and the drain pump

The sample pump is used in combination with

Press the pump icon. Switch the pump

The ‘Group’ function is implemented for

Next, press the sample pump and start the

Select the digital output by use of the Edit

The value of the digital output can be toggled

Press ‘Stop’ to stop any action of the DO.

Press the EDIT (E) button to control the

Use a multimeter to check if the analog

Insert a value by use of numeric keyboard

Check if this value corresponds to the value

Check the ‘Installation Manual’ to make the

4.4 Analog input

Check if all analog inputs are responding

Press the EDIT (E) button to control the

The calibration of the photometer is

Press enter to start calibration

Method: Colorimetric titration

Parameter: Total Hardness (as mg/L CaCO3) and Ca Hardness

Range: 50 – 1000 mg/L CaCO3

Precision: < 2 % of full scale range (with standard solutions)

Analysis time: < 10 minutes

Sample requirements: Atmospheric pressure, flow rate between 10 and 30 ml/minute,

Sample dilution: pump head and sample valves for sampling

Stream selection: Channel1: stream 1 (Sample valve and EXT SV1)

6.1 Reagent consumption

Consumption/analys Consumption/28 days Recommandable

6.2 Storage and quality of chemicals and solutions

Product Formula MW (g/mol) CAS No. Product number