Vidyamandir Classes

Mock IIT Advanced Test - 1/2017

20/07/2015 M.M. : 270
TEST CODE : ACEG
10:00 AM - 01:00 PM TIME : 3.00 Hrs

Read the following Instructions very carefully before you proceed.

1. The question paper consists of 3 parts (Part I : Chemistry, Part II : Physics, Part III : Mathematics).
Each Part has 2 sections (Section I, Section II & Section III).
2. Section I contains 2 types of questions [Type 1 &Type 2]
 Type 1 contains 10 Single Correct Answer Type Questions. Each question has 4 choices (A), (B),
(C) and (D), out of which ONLY ONE Choice is Correct.
Marking scheme [3 Marks for Correct answer & –1 NEGATIVE MARKING for wrong]
 Type 2 contains 8 Multiple Correct Answer Type Questions. Each question has 4 choices (A), (B),
(C) and (D), out of which ONE OR MORE CHOICES may be correct.
Marking scheme [4 Marks for Correct answer & NO NEGATIVE MARKING for wrong]
5. Section II contains 3 Single Integer Value Type Questions. The answer to each of the questions is a
single-digit integer, ranging from 0 to 9 (both inclusive)
Marking scheme [4 Marks for Correct answer & –1 NEGATIVE MARKING for wrong]
3. Section III contains 2 Match the columns type questions. Each question contains statements given in
2 columns. Statements in the first column have to be matched with statements in the second column.
Multiple matching can be possible. The answers to these questions have to be appropriately bubbled in
the answer sheet.
4. For each question in Section III, you will be given 8 Marks if you darken ALL the bubbles corresponding
ONLY to the correct answer or given 2 Marks each for correct bubbling of answer in any row.
No Negative mark will be given for an incorrectly bubbled answer.
6. For answering a question, an ANSWER SHEET (OMR SHEET) is provided separately. Please fill your
Test Code, Roll No. and Group Properly in the space given in the ANSWER SHEET.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers, pager, mobile
phone, any electronic device, etc., except the Admit Card inside the examination hall/room.
8. On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator on duty in
the Room/Hall. However, the candidates are allowed to take away this Test Booklet with them.
9. No one is permitted to leave the test room before the end of the test, i.e. 5.00 PM

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PART - I (CHEMISTRY) 90 MARKS

SECTION - I [Type 1]
SINGLE CORRECT ANSWER TYPE
This section contains 10 Single Choice Questions. Each Question has 4 choices A, B, C & D, out of which ONLY
ONE Choice is Correct.
Single choice
1. 0.50 gm mixture of K 2 CO 3 and Li 2CO 3 required 30 ml of 0.25 N HCl for complete neutralization. The
% of Li 2 CO3 in given mixture is
(A) 96% (B) 4% (C) 14% (D) 86%

2. 20dm3 of SO 2 diffuses through a porous partition in 60 second. What volume be O 2 will diffuse under
similar condition in 30 seconds.
(A) 22.4dm3 (B) 28.28dm 3 (C) 14.14dm3 (D) 141.4dm3

3. The kinetic energy an electron in the second Bohr orbit of Hydrogen atom is (a0 is Bohr radius).
h2 h2 h2 h2
(A) (B) (C) (D)
42 ma 02 162 ma 02 322 ma 02 642 ma 02

4. If r0 is the radius of real gas molecule A than calculate value of Vander waal’s gas constant b if
Avogadro number is taken as N0
N0  2 4 3 16 3 8 3
(A) (B) r0  N0 (C) r0 N 0 (D) r0 N 0
r0 3 3 3

5.

Which of the following is true for compound (A)?

(A) C  1, C  2, C  3 lie on same axis
(B) All three carbon lie in same plane
(C) C  1 and C  2 lie in mutually perpendicular planes
(D) All C  1, C  2, C  3 carbon an sp 2 hybridize

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6. Let the most probable velocity of hydrogen molecules at a temperature tº C is v0 . Suppose all the
molecules dissociates in to atoms when the temperature is raised to (2t  273º C) then the new rms
velocity is
2  273 
(A) v0 (B) 3 2   v0 (C) 2 3 v0 (D) 6 v0
3  t 
o
7. Find the % covalent character of HX having bond length = 1.62 A and observed dipole moment is 0.39 D.
(A) 5% (B) 80% (C) 95% (D) 20%

8. 50 ml of a mixture of NH 3 & H 2 was completely decomposed by sparking in to N 2 & H 2 . 40 ml of O 2

was then added and mixture was sparked again. After cooling to room temperature, the mixture was then
shaken with alkaline pyrogallol and contraction of 6 ml was observed. The % of H 2 in the original
mixture (Assuming N 2 does not react with O 2 ) is
(A) 72% (B) 68% (C) 28% (D) 32%

9. Correct order of magnetic moment of give ions.

Fe3 , Ni 2 , Cr 3 , Sc 3 [Atomic mass Fe = 26, Ni = 28, Cr = 23, Sc = 21]
(A) Fe3  Ni 2  Cr 3  Sc 3 (B) Fe3  Cr 3  Ni 2  Sc 3
(C) Sc 3  Ni 2  Cr 3  Fe3 (D) Cr 3  Fe3  Ni 2  Sc 3

10. Total number of spectral lines of H atom found in visible range when e  return back from 7th shell to 2nd
excited state of H atom.
(A) 15 (B) 21 (C) 5 (D) 0

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SECTION - I [Type 2]
MULTIPLE CORRECT ANSWERS TYPE
This section contains 8 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which ONE
or MORE Choices may be Correct:
PV
11. The given graph represents the variation of compressibility factor z  verses p, for three real gas
nRT
A, B and C.
Identify the correct statement.
(A) For the gas A, a = 0 and its dependence on p is linear at all pressure.
(B) For the gas B, b = 0 and its dependences on p is linear at all pressure.
(C) For the gas C, this is a typical real gas.
(D) At high pressure, the slope is positive for all real gases.

12. Which of the following is correct order?

(A) N 2  N 2  N 2 Bond strength (B) BF3  BCl3  BBr3 Lewis acid character

(C) PCl 4  PCl5  PCl6 % of s character (D) BeCl2  BCl3  CCl4 bond angle

13. Which types of  bond is present in ethyl acetate [CH 3COOC 2 H5 ]

(A) sp3s (B) sp3sp 2 (C) sp 2 p 2 (D) sp 2 sp 2

14. 10 ml C 2 H 5 OH (d = 0.8 g/ml) are mixed to get a solution. If density of resultant mixture is 0.96 g/ml then
(A) Volume of solution is 29.17 ml (B) Molarity of solution is 60 M
(C) Molarity of solution nearly 6 M (D) % change in volume is 2.78%

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15. Which of the following graphs are correctly matching?

(A) (B)

(C) (D)

16. Pick out the orbitals with the maximum number of nodal planes
(A) dxy (B) 5s (C) 3px (D) 3dx 2  y 2

17. Which of the following statement is/are correct?

(A) Alkali metals are highly electro positive elements
(B) F has maximum electron affinity
(C) He has highest ionization energy
(D) F is more reactive element

18. Which of the following species has/have non zero dipole moment?
(A) XeO3 F2 (B) SCl4 (C) XeF4 (D) XeO3

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SECTION - II
SINGLE INTEGER VALUE CORRECT TYPE
This section contains 3 single Integer Value Correct type Questions. Each question has an integer answer
between 0 and 9. Fill the answer bubbles in the OMR Sheet APPROPRIATELY and CAREFULLY.
1. Find kinetic energy (in eV) of ejected electron from platinum surface when radiation of 200 nm falls on it
work function of platinum is 5.2 eV.

2. Calculate the ratio of rate of diffusion of gas A to B if their pressures are in the ratio 2 : 1 and their
molecules travel with rms speed ratio 1 : 2 and ratio of kinetic energy is 1 : 16.

3. Find No. of nodal planes in 3d subshell.

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SECTION - III
MATRIX MATCH TYPE
This section contains 2 questions. Each question contains statements given in two columns, which have to be
matched. Statements in Column 1 are labelled as (A), (B), (C) & (D) whereas statements in Column 2 are
labeled as p, q, r, s & t. The answers to these questions have to be appropriately bubbled. More than one
choice from Column 2 can be matched with Column 1.
1. Match the following
Column-I Column-II
(A) XeO3 (P) 3
sp d hybridization
(B) I3 (Q) sp3 hybridization
(C) H3O  (R) Linear shape
(D) XeF2 (S) Pyramidal shape
(T) More than one lone pairs of electron on
central atom

2. Match the following

Column-I Column-II
(A) Density of gas (P)  pressure
(B) Kinetic energy of gas (Q) 1

Molar mass
(C) Rate of diffusion of gas (R)  Temperature
(D) Liquefaction of gas (S) 1

density

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PART - II (PHYSICS) 90 MARKS

SECTION - I [Type 1]
SINGLE CORRECT ANSWER TYPE
This section contains 10 Single Choice Questions. Each Question has 4 choices A, B, C & D, out of which ONLY
ONE Choice is Correct.
 m 
1. Velocity and acceleration of a particle at some instant of time are v  (2iˆ  ˆj  2kˆ) and a  (iˆ  6 ˆj  kˆ) .
s
Then, the speed of the particle is ..................... at a rate of ..................... m/s2.
(A) increasing, 2 (B) decreasing, 2 (C) increasing, 4 (D) decreasing, 4

2. At t = 0 a particle leaves the origin with a velocity of 6 m/s in the positive y direction. Its acceleration is

given by a = 2iˆ  3 ˆj m/s2. The x and y coordinates of the particle at the instant the particle reaches
maximum y coordinate are
(A) 2m, 3m (B) 4m, 6m (C) 1m, 3m (D) 2m, 6m

  
3. A particle is moving westward with a velocity v1 where | v1 | = 5 m/s. Its velocity changed to v2 where
    
| v2 | = 5 m/s and is towards north. The change in velocity vector  V  v2  v1  is:
 
(A) 5 m/s towards north west (B) zero
(C) 5 2 m/s towards north west (D) 5 2 m/s towards north east


4. A frame of reference F2 moves with velocity v with respect to another frame F1. When an object is
  
observed from both frames, its velocity is found to be v1 in F1 and v2 in F2. Then v2 is equal to :

        v
(A) v1  v (B) v1  v (C) v  v1 (D) | v  v1 | 1
| v1 |

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5. A student is standing on a train travelling along a straight horizontal track at a speed of 10 m/s. The
student throws a ball into the air along a path that he sees to make an initial angle of 60° with the
horizontal along the track. The professor standing on the ground observes the ball to raise vertically, the
maximum height reached by the ball is
(A) 15/4 m (B) 15 3 (C) 5 3 (D) 15 m

6. In a Rectilinear motion of a particle, velocity defined by the equation V3 = x2. The acceleration of the
particle when x = 8m is (here x is the position of the particle)
2 –2 3 4
(A) ms (B) ms–2 (C) ms–2 (D) Data are insufficient
3 4 3

7. Some persons hire a boat for 4 hours. The river flows at a speed of 5 km/hr and the boat moves with
speed of 15 km/hr relative to the water. How far along the flow direction, they can go if they have to
return in 4 hrs.
80
(A) 5 km (B) 7.5 km (C) km (D) 15 km0
3
8. How many significant figures are there in the numbers 108.023 and 0.19000?
(A) 6&5 (B) 6&2 (C) 6&4 (D) 5&3

9. A police man in a jeep is chasing a terrorist on a straight road with a constant speed V. The terrorist is
riding a motor cycle and when the jeep is at a distance 50 m away, the terrorist starts with a constant
acceleration 1 ms–2. The terrorist will be caught if
(A) V  10 ms–1 (B) V  10 ms–1 (C) V  1 ms–1 (D) V  3 ms–1

10. Which of the following functions of A and B is possibly correct if A and B possess different dimensions?
A B A B
(A) ( A/ B )
(B) (C) (D) A B
e log( A / B ) B e

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SECTION - I [Type 2]
MULTIPLE CORRECT ANSWERS TYPE
This section contains 8 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which ONE
or MORE Choices may be Correct:
11. Two particles A and B move on a straight line. A moves with constant positive velocity. B moves with
constant positive acceleration. At t = 0, A and B are moving equally fast. Which of the following is
possible?
(A) The distance between them keeps increasing.
(B) The distance between them first decreases and then increases.
(C) The distance between them first increases, then decreases and finally keeps increasing.
(D) The distance between them first decreases, then increases, then decreases and finally keeps
increasing.

12. Which of the following expressions has magnitude unity?

  
a b 
(A)   (B) | aˆ  bˆ | when angle between a and b is 120°
|a b |
aˆ  bˆ  
(C) (D) | aˆ  bˆ | when angle between a and b is 60°
| aˆ  bˆ |

13. A cubical box dimension L = 5/4 metre starts moving with an


acceleration a = 0.5 m/s2 iˆ from the state of rest. At the same time, a

stone is thrown from the origin with velocity V = v1 iˆ + v2 ĵ – v3 k̂

with respect to earth. Acceleration due to gravity g = 10m/s2 (– ĵ ).
The stone just touches the roof of box and finally falls at the
diagonally opposite point then:
3 5 5
(A) v1 = (B) v2 = 5 (C) v3 = (D) v3 =
2 4 2
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14. An ant is scampering on a paper with velocity 10 m/s. Now you y

begin to pull the paper with velocity 10 m/s along x-axis as shown
in figure. Coordinate system has origin fixed to ground as shown in
figure. The initial position of ant is (0, 0). Select the correct Motion of paper
37°
alternative(s) : x

(A) Velocity of ant in ground frame is (18iˆ  6 ˆj ) m/s. vant/paper
(B) Position vector of ant with respect to ground after 3 sec. is (54iˆ  18 ˆj ) m.
(C) In ground frame, velocity vector of ant is at an angle < 37°.
(D) In ground frame velocity vector of ant is at an angle > 37°.

a
15. The displacement x of a particle moving along a straight line, at time t is given by x = (1–e–bt) where a
b
and b are real positive constants. Therefore
(A) the graph of velocity vs displacement is a straight line with negative slope
(B) the velocity and acceleration of the particle at t = 0 are a and (–ab) respectively
(C) the particle cannot reach a point at a distance x' from its starting point if x' > a/b
(D) the particle will return to its starting point at t .

16. A particle has a rectilinear motion and the figure gives its displacement as a function of time. Which of
the following statements are true with respect to the motion?
(A) in the motion between O and A the velocity is positive and
acceleration is negative
(B) between A and B the velocity and acceleration are positive
(C) between B and C the velocity is negative and acceleration is positive
(D) between C and D the acceleration is positive

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17. A particle having a velocity v = v0 at t = 0 is decelerated at the rate |a| =  v , where  is a positive
constant.
2 v0
(A) The particle comes to rest at t =

(B) The particle will come to rest at infinity.
2v03/ 2
(C) The distance travelled by the particle is .

2 v03/2
(D) The distance travelled by the particle is
3 

18. Ram and Shyam see a trolley moving on a straight line. They are both stationary and located as shown.
(A) The angular displacement measured by both in same time interval is same.
(B) The displacement measured by both in the same time interval is the same
(C) The angular velocity of the line joining both the observers to the trolley any
instant is the same. Ram

(D) The velocity of the trolley as observed by both the observers at any instant is
the same. Shyam

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SECTION - II
SINGLE INTEGER VALUE CORRECT TYPE
This section contains 3 single Integer Value Correct type Questions. Each question has an integer answer
between 0 and 9. Fill the answer bubbles in the OMR Sheet APPROPRIATELY and CAREFULLY.
1. James bond is standing on a bridge above the road and his pursuers are getting too close for comfort. He
spots a flat bed truck loaded with mattresses approaching at 30 m/s which he measures by knowing that
the telephones poles the truck is passing are 20 m apart in this country. The bed of truck is 20m below the
bridge and bond quickly calculates how many poles away the truck should be when he jumps down the
bridge onto the truck making his get away. How many poles is it?

2. A ball is projected horizontally from an incline so as to strike a cart v0 = 10 m/s

sliding on the incline. Neglect height of cart and point of projection of
sliding
6m
ball above incline. At the instance the ball is thrown, the speed of cart is frictionlessly
on incline
'v' (in m/s). Find 'v' so that the ball strikes the cart. =37°

3. Two cars A & B are at same point at rest. Car A accelerates at 2 m/s2. After 2 sec.
of start of car A car B starts moving with some constant acceleration in same
direction. Car B catches car A 8 sec after the start of car A. If the acceleration of car
B is 32/x m/s2, find x.

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SECTION - III
MATRIX MATCH TYPE
This section contains 2 questions. Each question contains statements given in two columns, which have to be
matched. Statements in Column 1 are labelled as (A), (B), (C) & (D) whereas statements in Column 2 are
labeled as p, q, r, s & t. The answers to these questions have to be appropriately bubbled. More than one
choice from Column 2 can be matched with Column 1.
v
1. A particle is moving along a straight line. Its v - t graph is as
shown in figure. Point 1, 2 and 3 marked on graph are three 2
3
different instants. Column-I has fill in the blanks, which are
1
to be filled by the entries in column-II.
t

Column-I Column-II
(A) a1 is .......... a2 (P) Parallel to
(B) v1 is .......... v2 (Q) Anti parallel to
(C) v3 is .......... v1 (R) Greater than (in magnitude)
(D) a1 is .......... v1 (S) Less than (in magnitude)

2. The velocity of an aircraft as seen by the driver of a car is 5 m/s upwards. A passenger in a train
simultaneously sees the car to move southwards with 5 m/s. The conductor of a bus feels that the train is
moving north with a velocity of 10 m/s. A dacoit running towards the bus feels it moving 6 m/s
eastwards. A police jeep chasing the dacoit feels him to be moving westwards with 3 m/s. A person
standing on the ground sees the police jeep moving north-west with 15 2 m/s.
Column-I Column-II
(A) Velocity of the aircraft as seen by the conductor (P) 3 iˆ  5 ˆj  5 kˆ
(B) Velocity of the conductor as seen by the police (Q) 5 ˆj  5 kˆ
(C) Velocity of the aircraft (R) 3iˆ
(D) Velocity of police as seen by the pilot of aircraft (S) 12 iˆ  20 ˆj  5 kˆ

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PART - III (MATHS) 90 MARKS

SECTION - I [Type 1]
SINGLE CORRECT ANSWER TYPE
This section contains 10 Single Choice Questions. Each Question has 4 choices A, B, C & D, out of which ONLY
ONE Choice is Correct.
1. The harmonic mean of the roots of the equation (5  2) x 2  (4  5) x  8  2 5  0
(A) 2 (B) 4 (C) 6 (D) 8

2. Consider the sequence in the form of groups (1), (2, 2), (3, 3, 3), (4, 4, 4, 4), (5, 5, 5, 5, 5),……., then the
sum of first 2000 terms is
(A) 84336 (B) 96324 (C) 78466 (D) None of these

3. The number of five-digit numbers that contain 7 exactly once is

(A) (41)(93) (B) (37)(93) (C) (7)(94) (D) (41)(94)

   
4. If tan   tan      tan      k tan 3 , then k is equal to
 3  3
1
(A) 1 (B) 3 (C) (D) None of these
3

5. If 4n   then cot .cot 2.cot 3.......cot(2 n  1) is equal to

(A) 1 (B) –1 (C)  (D) None of these

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sin 3 x
6. If f ( x )  , where x  n , then the range of values of f ( x) for real values of x is
sin x
(A) [–1, 3] (B) [,  1] (C) (3,  ) (D) [–1, 3)

7. The number of integral values of x satisfying  x 2  10 x  16  x  2 is

(A) 0 (B) 1 (C) 2 (D) 3

8. ABCD is a square of length a, a  N , a  1 . Let L1 , L2 , L3 ,……be points on BC such that

BL1  L1 L2  L2 L3  .....  1 and M1 , M 2 , M 3 ,.... be points on CD such that
a 1
CM 1  M1M 2  M 2 M 3  .....  1 . Then  ( AL2n  Ln M n2 ) is equal to
n 1

1 1
(A) a(a  1) 2 (B) (a  1)(2 a  1)(4 a  1)
2 2
1
(C) a (a  1)(4a  1) (D) None of these
2

9. The sum of 20 terms of a series of which every even term is 2 times the term before it, and every odd term
is 3 times the term before it, the first term being unity, is

(A)
 2  10
  6 1
7
  (B)
 3  10
  6 1
7
  (C) 
 3  10
  6 1
5
 (D) none of these

10. The coefficient of x5 in the expansion of (1  x) 21  (1  x) 22  ...  (1  x)30 is

(A) 51
C5 (B) 9
C5 (C) 31
C6  21C6 (D) 30
C5  20C5

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SECTION - I [Type 2]
MULTIPLE CORRECT ANSWERS TYPE
This section contains 8 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which ONE
or MORE Choices may be Correct:
(ac  ab  bc )(ab  bc  ac )
11. If a, b , and c are in H.P. then the value of is
(abc) 2

(a  c)(3a  c) 2 1 2 1 (a  c)(3a  c)
(A) (B)  (C)  (D)
4a 2 c 2 bc b 2 bc a 2 4a 2 c 2
12. Let S1 , S 2 ,..... be squares such that for each n  1 , the length of a side of Sn equals the length of a
diagonal of S n 1 . If the length of a side of S1 is 10 cm, then for which of the following values of n is the
area of Sn less than 1 sq. cm?

(A) 7 (B) 8 (C) 9 (D) 10

13. If cos is the geometric mean between sin  and cos , where 0  ,    /2 , then cos 2 is equal to

       
(A) 2sin 2     (B) 2cos 2     (C) 2sin 2     (D) 2cos 2    
4  4  4  4 

14. If 4sin 4 x  cos 4 x  1 , then x is equal to (n  Z )

2 2n 
(A) n (B) n  sin 1 (C) (D) 2 n 
5 3 4

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sin 4 x cos 4 x 1
15. If   , then
2 3 5

2 sin 8 x cos8 x 1
(A) tan 2 x  (B)  
3 8 27 125

1 sin 8 x cos8 x 2
(C) tan 2 x  (D)  
3 8 27 125

2 x k 2
16. If the equation x log a x  ,(a  0, a  1) , has exactly one solution for x, then the value of k is/are
ak

(A) 64 2 (B) 26 3 (C) 64 2 (D) 26 3

17. The values of r satisfying the equation 69

C3r 1  69C  69 C  69 C3r is
r2 r 2 1

(A) 1 (B) 2 (C) 3 (D) 7

18. If 5  12i  5  12i  z , then principal value of arg z can be

  3 3
(A)  (B) (C) (D) 
4 4 4 4

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SECTION - II
SINGLE INTEGER VALUE CORRECT TYPE
This section contains 3 single Integer Value Correct type Questions. Each question has an integer answer
between 0 and 9. Fill the answer bubbles in the OMR Sheet APPROPRIATELY and CAREFULLY.
sec4  sec4 
1. Find the minimum value of  , Where ,   K  /2, K  I
tan 2  tan 2 

2. a, b, c, d are in increasing G.P. If the AM between a and b is 6 and the AM between c and d is 54, then
the AM of a and d is 6k . The numerical value of k is…..

3. If log a x  p, logb x 2  q, log c x3  r & pqr  6. (a, b, c, x > 1) Then the least value of logx abc is ……

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SECTION - III
MATRIX MATCH TYPE
This section contains 2 questions. Each question contains statements given in two columns, which have to be
matched. Statements in Column 1 are labelled as (A), (B), (C) & (D) whereas statements in Column 2 are
labeled as p, q, r, s & t. The answers to these questions have to be appropriately bubbled. More than one
choice from Column 2 can be matched with Column 1.
1. Consider all possible permutations of the letters of the word “ RACHITIHCAR”
Column I Column II
The number of words containing the word
(A) (P) 56700
ACHIT is
The number of words beginning with ‘RA’
(B) (Q) 630
and ending with ‘AR’ is
The number of words in which vowels occur
(C) (R) 22680
at the odd places is
The number of words in which the word IIT
(D) (S) 2520
appears is
(T) 45360

2. Match the following

Column-I Column-II
(A) If  n  210 , then  n 2
is divisible by the greatest (P) 16

prime number which is greater than

(B) Between 4 and 2916 is inserted odd number (Q) 10
 2n  1 G.M ' s . Then the  n  1 th G.M. is divisible
by greatest odd integer which is less than
(C) In a certain progression, the consecutive terms are 40, (R) 34
30, 24, 20. Then the integral part of the next term of
the progression is more than
(D) 4 7 10 a (S) 30
1  2  3  .......to   , where H.C.F  a, b   1 ,
5 5 5 b
then a  b is less than
(T) 36

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   End of Mock IIT Advanced - 1/JEE-2017   

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