Professional Documents
Culture Documents
Heat Treatment
• Why do we heat treat?
– To relieve stresses (i.e. from cold working)
– To increase softness, ductility and toughness
– and/or to produce a specific microstructure
• Why is it important to understand thermal
processing in metal alloys?
– Because it can produce mechanical properties required
for specific applications.
– Because the mechanical properties of an alloy that has
been heat treated can be altered significantly if it is re-
heated (i.e. welding).
2
1
Annealing Processes
• Annealing refers to a heat treatment with the
following stages:
1. Heat to the desired temperature.
2. Hold or “soak” at that temperature.
• to allow for any necessary transformation reactions to occur.
3. Cool, usually to room temperature.
2
Heat Treatment of Steel – Quench
and Temper
1. Austenitize
– Heat to a temperature
region where 100% 727°C
Austenite is formed
– Hold to allow complete
transformation
Tempering of Martensite
3
Tempering of Martensite
Microstructure Changes
Property Changes 7
Martensite
24.6 µm 2 µm
• Quench • Tempered
– 564°C
– small particles cementite
8
– matrix is α ferrite
4
Effect of Carbon Content on Hardness
(Martensite)
Precipitation Hardening
5
Precipitation Hardening
• Precipitation hardening
will only occur in alloys
that: 1.
1. show appreciable solid
solubility of one
2.
alloying component
(several %) in the
other.
2. show a solubility limit
that rapidly decreases
in concentration of one
major component with
temperature reduction 11
12
6
Microstructural Changes During Ageing
• Aged at T2
• Formation of very small β
precipitates
– 1 – 10 nm
• The character of β
precipitates and strength
and hardness depend on
– T2
– Time at T2
• Some alloys age at room
temperature over a period
of time (Natural Ageing)
• Some need elevated
temperature (Artificial
Ageing) 13
• Yield Strength
increases as zones or
precipitates form
• Strength reaches a
peak value
• And then decreases
(overageing)
14
7
Precipitation Hardening in Al-Cu
• Precipitation
hardening most
widely studied in
Al-Cu alloys
• α phase is a
substitutional solid
solution of Cu in
Al
• θ phase is an
intermetallic
compound CuAl2
15
16
8
Mechanism of Hardening during
Artificial Ageing
(Stages for Al-Cu system)
Strengthening Curve
18
9
Ageing Curves
(2014 Al Alloy, 4 different temperatures)
• Strengthening Process
is accelerated if
temperature is
increased
• Ideally the temperature
and time for
precipitation heat
treatment should be
designed to produce a
hardness or strength in
the vicinity of the
maximum.
19
Mechanism of Strengthening
20
10
Precipitation hardening versus
Quenching and Tempering
Al-Cu Alloy Steel
• Solution treat to obtain a single • Ausenitise to form single phase γ
phase α (θ phase dissolves) – Fe3C dissolves
– FCC (No change) – BCC ⇒ FCC
• Quench to prevent formation of • Quench to prevent Fe3C
precipitates (Supersaturated at formation and transform γ to
R.T.) martensite
– FCC – FCC ⇒ BCT
– Low strength – high strength, very brittle
• Age to form zones or • Temper to precipitate very fine
precipitates Fe3C
– Strength increases – strength decreases
– Peaks and then decreases – ductility increases
21
11
Strengthening Mechanism Review
−1
1. Grain Size reduction σ y = σ o + kyd 2
2. Cold Working
– Increase in yield stress as dislocation density
increases
12