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PETROLEUM REFINERIES
By-
Asheesh Padiyar (1RV12CH006)
Department of Chemical Engineering
R.V College of Engineering
A petrochemical Refinery
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JUSTIFICATION
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OVERALL REFINERY WATER
BALANCE
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CONTIMINANTS IN RAW WATER
AND METHOD FOR REMOVAL
• Turbidity- Coagulation, settling filtration
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PROCESS WATER
Water that has been in intimate contact with the
hydrocarbons in the refinery.
• Desalter effluent
• Sour water
• Tank bottom draws
• Spent caustic
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DESALTER
• Prevent fouling
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Typical desalter unit configuration
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SOUR WATER
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Sour water stripper configuration
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TANK BOTTOM DRAWS
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Crude tank water draw
DESALTER EFFLUENT TREATMENT
• Desalter oil/water separation- Inorganic salts are present
in the crude oil as emulsified solution of salt. The
amount of water received at the refinery with crude is
about 0.1 -2.0 % by volume.
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• Desalter effluent stripper
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SEQUENCE FOR TREATING PRE’s
[3]
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• Primary treatment
API separator
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Dissolved air floatation system
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• Secondary treatment
A. Activated sludge
B. Aerated lagoons
A. Trickling filters
B. Rotating biological contactors
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Activated sludge system
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Trickling filter
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• Tertiary treatment
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Anthracite
Coal
Sand
Sand filtration
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NEED FOR POSSIBLE NEW
TECHNOLOGIES
Several advancement have been made to improve performance
ranging from bio-augmentation to fluidized bioreactors.
However, the problems of high sludge generation, low
tolerance to toxic load and organic shock coupled with a slow
degradation rate persist. Other methods are either require
extreme temperature and pressure operating conditions or
cannot handle large volumes of refinery waste waters
effectively.
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• Reverse electro dialysis (RED)
• Photocatalytic degradation
A process that potentially mineralizes all of the organic
and inorganic components typically found in the refinery
effluent to environmentally benign by-products
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References
1. “Petroleum refining water/wastewater use and
management”- IPIECA
2. Basheer Hasan Diya’uddeen “Treatment technologies
for petroleum refinery effluents: A review” Process
Safety and Environmental Protection 8 9 (2011) 95–
105
3. Javad ,” Organic Pollutants Removal from Petroleum
Refinery Wastewater with Nano-titania Photo-catalyst
and UV Light Emission” International Journal of
Photo-energy ,Volume 2012
4. Felipe Pombo, “Technology Roadmap for Wastewater
Reuse in Petroleum Refineries in Brazil”, Journal of
Environmental Management in Practice, DOI:
10.5772/20297
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THANK YOU
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