TUGAS 2 KINETIKA REAKSI

Program Studi Magister Teknik Kimia

Dosen Pengampu:
MUHAMMAD MUFTI AZIS, S.T., M.Sc., Ph.D.

Dikerjakan oleh:
HASAN RAHMAN MUHARRAM (17/422468/PTK/12047)
MUHAMMAD ABDUL GHONY (17/422471/PTK/12050)
MUKMIN SAPTO PAMUNGKAS (17/422472/PTK/12051)

DEPARTEMEN TEKNIK KIMIA

FAKULTAS TEKNIK

UNIVERSITAS GADJAH MADA

YOGYAKARTA

2018
SOAL:
CAi = PAin / HA
101,325 Pa
= 3 = 28.95 mol / m3
3,500 Pa.m / mol
CB >> CA, so we can assume CB ≅ constant

√DA x k x CB √DA x k x CB
MH = =
kAl kAla
a
2 3
√1.4 x 10−9 m x 0.433 m x 300 mol
3
s mol.s m
= 0.025 s−1
= 2.0469
m2
120 3
m

DB x CBout x HA
Ei = 1 +
b x DA x PAi
mol
300 3 x 3,500 Pa .m3 / mol
m
= 1+ = 11.3627
1 x 101,325 Pa
Ei > 5 MH, so E = MH = 2.0469
 1
−ra′′′ = PA
1 HA HA
+ +
kAga kAla x E k x CB x fl
Using fig. 23.4:

Reaction zone approaches interface, then we assume PA = PAi,

1
so the resistance in gas film is negligible: kAga = 0
 101,325 Pa
−ra′′′ =
3,500 Pa . m3 / mol 3,500 Pa . m3 / mol
0 + +
0.025 s−1 x 2.0469 m3 mol
0.433 x 300 3 x 0.08
mol. s m
-ra’’’ = 1.4764 mol/m3.s

Using equation from Plug Flow G/ Mixed Flow L – Mass

Transfer + Reaction in Bubble.
YAin
dYA
Vr = Fg ∫
(−rA′′)a
YAout
YAin
dYA
Vr = vo x Cgo ∫
(−rA′′)a
YAout
1
3
3
m mol dYA
0.6041 m = 0.0363 x 28.95 3 ∫
s m mol
YAout 1.4764 x1
m3 . s
YAout = 0.1513

Fraction of entering CO2 absorbed = dYA

dYA = YA in - YA out = 0.8487
1

2
Step 1. Express the material balance and find CB2 in the exit
stream
PA1 = 0.0236 % x 1 atm = 2.36 x 10-4 atm
PA2 = 2.36 % x 1 atm = 0.0236 atm
CB1 = 10 % x 2,736 mol/m3
= 273.6 mol/m3

Using equation from Plug Flow G/ Plug Flow L – Mass

Transfer + Reaction in a Countercurrent Tower, dilute
systems (solution containing a relatively small quantity
of solute as compared with the amount of solvent).
Fl
(Acs) π
(PA3 − PA1) = (CB1 − CB3)
Fg
(Acs) b x CT
mol
250 2 x 1 atm
−4
(PA3 − 2.36 x 10 atm) = s. m (273.6 mol/m3 − CB3)
mol mol
100 x 2 x 2736 3
s. m2 m
PA3 = 0.125236 – 4.5687 x 10-4 CB3

At the bottom of the tower, PA3 = PA2, so

1
CB2 = 4.5687 x 10−4 (0.125236 – 0.00236) = 268.9517 mol/m3
Step 2. Find which of the many forms of rate equation should be
used.

At top,
mol −4
mol
kAga x PA = 133 x 2.36 x 10 atm = 0.0314
hr. m3 . atm hr. m3
−1
mol mol
kla x CB = 45 hr x 273.6 3 = 12,312
m hr. m3

At bottom,
mol mol
kAga x PA = 133 x 0.0236 atm = 3.1388
hr. m3 . atm hr. m3
−1
mol mol
kla x CB = 45 hr x 268.9517 3 = 12,102.8265
m hr. m3

At both ends of the tower kAgPA < klaCB; therefore, gas-phase

resistance controls and we have a pseudo first-order reaction as
given by Eq. 16 of Chapter 23
-ra’’’ = kAga x PA = 133 PA
Step 3. Determine the tower height.

Fg PA2 dPA
Vr = ∫
π PA1 (−rA′′)a
Fg PA2 dPA
h x Acs = ∫
π PA1 133 PA x 1
Fg 1 PA2
h = x ln
Acs x π 133 PA1
100 1 0.0236
h = x ln
1 133 2.36 x 10−4
h = 3.46 m