NEETPrep Crash Course

Revision Class # 12
Contact Number of NEETPrep: 8527521718

CHEMICAL KINETICS
1. Listed in the table are forward and 3. A graph between log t1/2 and log a
reverse rate constants for the reaction (abscissa), a being the initial
2𝑁𝑂(𝑔) ⇋ 𝑁 (𝑔) + 𝑂 (𝑔) concentration of A in the reaction. For
Temperature Kf(M- Kb(M-1S-1) reaction A→Product, the rate law is :
1 -1
(K) S )
1400 0.29 1.1×10-6
1500 1.3 1.4×10-5

Select the correct statement :

1. Reaction is exothermic and value of
equilibrium constant (Keq) at 1400 K
– [ ]
is 3.79×10-6 1. =𝐾
2. Reaction is endothermic and value – [ ]
2. = 𝐾[𝐴]
of Keq at 1400 K is 2.63×105 – [ ]
3. Reaction is exothermic and value of 3. = 𝐾[𝐴]
– [ ]
Keq at 1400 K is 2.63×105 4. = 𝐾[𝐴]
4. Reaction is endothermic and value 4. If ‘a’ is the initial concentration of the
of Keq at 1500 K is 9.28×104 reactant, the half-period of the reaction
2. Consider a reaction of nth order
.
A(g) ⎯⎯⎯⎯⎯⎯⎯⎯⎯ 2B(g). If initial Is inversely proportional to :
concentration of A is 0.5 M then select 1. an-1
graph. 2. an
1. 3. a1-n
4. an+1
5. In the following reaction A→B + C, rate
constant is 0.001 Ms-1. If we start with 1
M of A then conc. of A and B after 10
2. minutes are respectively :
1. 0.5 M, 0.5 M
2. 0.6 M, 0.4 M
3. 0.4 M, 0.6 M
4. None of these
3. 6. Half life (t1/2) and completion time (T) of
the above reaction (A→2B) are:
1. 500min, 750 min
2. 500 sec. 750 sec
3. 500 sec, 1000 sec
4. 4. None of these
 NEETPrep Crash Course
Revision Class # 12
Contact Number of NEETPrep: 8527521718

CHEMICAL KINETICS
7. For the zero order reaction A→ B + C; 𝐴 𝑒 /
. If A1 = 109, A2 = 1010 and
initial concentration of A is 0.1 M. If A = Ea1 = 1200 cal/mol, then the temperature
0.08 M after 10 minutes, then it’s half at which k1 = k2 is : ( Given; R = 2 cal/K-
life and completion time are mol)
respectively: 1. 300 K
1. 10 min; 20 min 2. 300 × 2.303 K
2. 2×10-3 m; 4×10-3 min; 3. 𝐾
.
3. 25 min, 50 min
4. None of these
4. 250 min, 500 min
11. A catalyst lowers the activation energy
8. The decomposition of azo methane, at
for a certain reaction from 83.314 m to
certain temperature according to the
75 kJ mol-1 at 500 K. What will be the rate
equation (CH3)2N2→ C2H6 + N2 is a first
of reaction as compare to uncatalysed
order reaction.
reaction ? Assume other things being
After 40 minutes from the start, the total
equal
pressure developed is found to be 350
1. Double
mm Hg in place of initial pressure 200
2. 28 times
mm Hg of azo methane. The value of rate
3. 7.38 times
constant k is :
4. 7.38 × 103 times
1. 2.88×10-4 sec-1
12. A radioactive sample had an initial
2. 1.25×10-4 sec-1
activity of 56 dpm. After 69.3 minutes, it
3. 5.77×10-4 sec-1
was found to have an activity of 28 dpm.
4. None of these
Find the number of atoms in a sample
9. For a complex reaction A → products having an activity of 100 dpm
Ea1 = 180 kJ/mol; Ea2 = 80 kJ/mol; Ea3 = 50 1. 693
kJ/mol 2. 100
Overall rate constant k is related to 3. 1000
individual rate constant by the equation 4. 10,000
/
𝑘=
. 13. Ac227 has a half life of 22 years. The
decays follows two parallel paths
Activation energy (kJ/mol) for overall
reaction is:
1. 100
2. 43.44
3. 150
4. 140
What are the decay constants (𝜆) for Th
10. For reaction A→B, the rate constant
and Fr respectively?
𝑘 =𝐴 𝑒 /
and for the reaction 1. 0.03087, 0.00063
X → Y, the rate constant 𝑘 =
 NEETPrep Crash Course
Revision Class # 12
Contact Number of NEETPrep: 8527521718

CHEMICAL KINETICS
2. 0.00063, 0.03087 2. 120 kJ/mol
3. 0.02, 0.98 3. 116 kJ/mol
4. None of these 4. 220 kJ/mol
14. The reaction A(g) + 2B (g) → C (g) is an 17. A reaction takes place in various steps.
elementary reaction. In an experiment The rate constant for first, second, third
involving this reaction, the initial partial and fifth steps are k1, k2, ,k3 and k5
pressures of A and B are PA = 0.40 atm respectively. The overall rate constant is
and PB = 1.0 atm respectively. When PC = given by
0.3 atm, the rate of the reaction relative 𝑘 𝑘 /
to the initial rate is: 𝑘=
𝑘 𝑘
1. If activation energy are 40, 60, 50 and 10
kJ/mol respectively, the overall energy
2.
of activation (kJ/mol) is :
3. 1. 10
4. None of these 2. 20
15. For a first order homogenous gaseous 3. 25
reaction A →2B + C 4. None of these
If the total pressure after time t was Pt
and after long time (𝑡 → ∞) was 𝑃
then k in terms of 𝑃 , 𝑃 and t is
.
1. 𝑘 = 𝑙𝑜𝑔
.
2. 𝑘 = 𝑙𝑜𝑔
.
3. 𝑘 = 𝑙𝑜𝑔 ( )
4. None of these
16. Consider the reaction

The rate constant for two parallel

reactions were found to be 10-2 dm3 mol-
1 -1
s and 4×10-2 dm3 mol-1 s-1 . If the
corresponding energies of activation of
the parallel reaction are 100 and 120
kJ/mol respectively, what is the net
energy of activation (Ea) of A?
1. 100 kJ/mol