JEE Main 2019 Answer Key Solutions January 12 by Aakash PDF

JEE MAIN 2019
ANSWER KEY & SOLUTIONS

JANUARY 12
BY AAKASH
FOR FORENOON SHIFT
12/01/2019
MORNING
Regd. Office : Aakash Tower, 8, Pusa Road, New Delhi-110005

Ph.: 011-47623456 Fax : 011-47623472
Time : 3 hrs.
Answers & Solutions M.M. : 360
for
JEE (MAIN)-2019
(Online CBT Mode)
(Physics, Chemistry and Mathematics)
Important Instructions :
1. The test is of 3 hours duration.
2. The Test consists of 90 questions. The maximum marks are 360.
3. There are three parts consisting of Physics, Chemistry and Mathematics having 30 questions in each part
of equal weightage. Each question is allotted 4 (four) marks for each correct response.
4. Candidates will be awarded marks as stated above in Instructions No. 3 for correct response of each
question. ¼ (one-fourth) marks will be deducted for indicating incorrect response of each question. No
deduction from the total score will be made if no response is indicated for a question in the answer sheet.
5. There is only one correct response for each question.

JEE (MAIN)-2019 (Online)
PHYSICS
1. A person standing on an open ground hears the 3. The galvanometer deflection, when key K1 is closed
sound of a jet aeroplane, coming from north at an but K2 is open, equal 0 (see figure). On closing K2
angle 60° with ground level. But he finds the also and adjusting R2 to 5 , the deflection in
aeroplane right vertically above his position. If v is 0
the speed of sound, speed of the plane is galvanometer becomes . The resistance of the
5
galvanometer is, then given by [Neglect the internal
2v 3
(1) (2) v resistance of battery]
3 2
K2 R2
v
(3) (4) v R 1 = 220  ( )
2
Answer (3)
G
l cosec 60 l cot 60

Sol. 
v vp
K1
( )
vp
60° (1) 22  (2) 25 

l (3) 5  (4) 12 
Answer (1)
Sol.  i, let RG = R

v
 vp =
2
V
i1 = = k × 0
2. In the figure shown, a circuit contains two identical 220  R
resistors with resistance R = 5  and an inductance
with L = 2 mH. An ideal battery of 15 V is connected V 5 
i2 =  k 0
in the circuit. What will be the current through the 5R R5 5
220 
battery long after the switch is closed? 5R
S
1 5 1
  
L 220   5  R   5R 1  220  R   5
15 V R
1 1
R  
45R  220 5   220  R 
 R = 22 
(1) 7.5 A (2) 3 A
4. The least count of the main scale of a screw gauge
(3) 6 A (4) 5.5 A is 1 mm. The minimum number of divisions on its
Answer (3) circular scale required to measure 5 m diameter of
a wire is
Sol. After long time, the inductor will behave like a wire.
(1) 200 (2) 50
15 30 (3) 100 (4) 500
I=  6 A
R 5
2 Answer (1)
2
Pitch ⎡ ⎡ 1 1⎤ ⎤
Sol. ∵ L.C. = F = Gm ⎢  A ⎢  ⎥  BL ⎥
No. of division on circular scale ⎣ ⎣L  a a ⎦ ⎦
10 3
 5 × 10–6 = ⎡ ⎡1 1 ⎤ ⎤
N = Gm ⎢ A ⎢  ⎥  BL ⎥
⎣ ⎣a a  L ⎦ ⎦
 N = 200 7. There is a uniform spherically symmetric surface
5. A travelling harmonic wave is represented by the charge density at a distance R0 from the origin. The
equation y(x, t) = 10–3 sin (50t + 2x), where x and y charge distribution is initially at rest and starts
are in meter and t is in seconds. Which of the expanding because of mutual repulsion. The figure
following is a correct statement about the wave? that represents best the speed V(R(t)) of the
distribution as a function of its instantaneous radius
(1) The wave is propagating along the negative x-axis R(t) is
with speed 25 ms–1.
V(R(t))
(2) The wave is propagating along the positive x-axis (1)
(3) The wave is propagating along the negative x-axis

Ro R(t)
(4) The wave is propagating along the positive x-axis
with speed 25 ms–1. V(R(t))
(2)
Answer (1)
Sol. y(x, t) = 10–3 sin(50t + 2x)
 50
 v=  = 25 ms–1 Ro R(t)
k 2
And wave is travelling in –ve x-direction. V(R(t))
(3)
6. A straight rod of length L extends from x = a to x =
L + a. The gravitational force it exerts on a point
mass ‘m’ at x = 0, if the mass per unit length of the
rod is A + Bx2, is given by
Ro R(t)
⎡ ⎛ 1 1⎞ ⎤ V(R(t))
(1) Gm ⎢ A ⎜  ⎟  BL ⎥ (4)
⎣ ⎝a L a⎠ ⎦ Vo
⎡ ⎛ 1 1⎞ ⎤
(2) Gm ⎢ A ⎜  ⎟  BL ⎥
⎣ ⎝a L a⎠ ⎦
Ro R(t)
⎡ ⎛1 1 ⎞ ⎤
(3) Gm ⎢ A ⎜  ⎟  BL ⎥
⎣ ⎝ a a  L ⎠ ⎦ Answer (4)
⎡ ⎛1 1 ⎞ ⎤ Q2 Q2 1
(4) Gm ⎢ A ⎜  ⎟  BL ⎥  mv2
⎣ ⎝ a a  L ⎠ ⎦ Sol. ∵ =
4 0 R0 4 0 R 2
Answer (3)
x= a x =L+a Q2 2⎡ 1 1⎤
x=0 dx  v=  ⎢  ⎥
Sol. 4 0 m ⎣ R0 R ⎦
a L
So v increases and attains a finite value after large
L a
 A  B x  dx
2
time.
dF = Gm ∫
a
x2
3
8. A proton and an -particle (with their masses in the 10. In a meter bridge, the wire of length 1 m has a non-
ratio of 1 : 4 and charges in the ratio of 1 : 2) are
dR
accelerated from rest through a potential difference uniform cross-section such that, the variation of
V. If a uniform magnetic field (B) is set up
dl
perpendicular to their velocities, the ratio of the radii dR 1
rp : r of the circular paths described by them will be its resistance R with length l is  . Two
dl l
(1) 1 : 3 equal resistances are connected as shown in the
figure. The galvanometer has zero deflection when
(2) 1 : 2
the jockey is at point P. What is the length AP ?
(3) 1 : 3
R R
(4) 1 : 2
Answer (4)
G
mv 2m  (qV )
Sol. r =  P
qB qB
A B
m l 1 l
 r 
q (1) 0.2 m (2) 0.35 m
mp (3) 0.25 m (4) 0.3 m

rp q
 = 
r m qp Answer (3)
dR K
rp 1 2 1 Sol. d l 
 =   l
r 4 1 2
R l
dl
9. For the given cyclic process CAB as shown for a ∫ dR  K
0
∫
0 l
gas, the work done is
 R  2K l
A
6.0 C
R 2K l
5  
R  2K 1  l 
p (Pa) 4
 2 l 1
3
2 1
 l  0.25 M
1 4
B
11. The output of the given logic circuit is
1 2 3 4 5
V (m3) A
(1) 30 J (2) 10 J
Y
(3) 5 J (4) 1 J
Answer (2)
B
Sol. W = Area under PV graph
(1) AB  AB (2) AB
1
= ×4×5 (3) AB  AB (4) AB
2
= 10 J Answer (2)
4
A A
Sol. B  B1  B2
a
A·B Y
Sol. b
A·B
B B
1 d
a  A. A . B
d 2
 A A.B
 A A.B
i
b  A.B  B B1  B2  0
4d
 AB B 1
0 i
B= = 10–4
Y a.b a b 2d
2  10 7  i
a  A  AB   10 4
4  10 2
= A·  A  B 
2
 i  20 A
10 1
= A A  AB
13. An ideal battery of 4 V and resistance R are
a  AB
connected in series in the primary circuit of a
Y  a b potentiometer of length 1 m and resistance 5 . The
value of R, to give an potential difference of 5 mV
 a1 across 10 cm of potentiometer wire, is
 AB  0  AB (1) 480  (2) 490 
(3) 495  (4) 395 

12. As shown in the figure, two infinitely long, identical
wires are bent by 90° and placed in such a way that Answer (4)
the segments LP and QM are along the x-axis, while
Sol. VAB = 5 × 10–3
segments PS and QN are parallel to the y-axis. If
OP = OQ = 4 cm, and the magnitude of the RAB = 0.5 
magnetic field at O is 10–4 T, and the two wires carry
equal currents (see figure), the magnitude of the V
currents in each wire and the direction of the  i  AB  10 –2 A
RAB
magnetic field at O will be (0 = 4 × 10–7 NA–2)
S y 4V
R
OQ
L P M x 5

m
N A B
10 cm
(1) 40 A, perpendicular into the page
(2) 20 A, perpendicular into the page 4
 i  10 –2
(3) 40 A, perpendicular out of the page R5
 R + 5 = 400
(4) 20 A, perpendicular out of the page
Answer (2)  R = 395 
5
14. A cylinder of radius R is surrounded by a cylindrical 16. Two electric bulbs, rated at (25 W, 220 V) and (100
shell of inner radius R and outer radius 2R. The W, 220 V), are connected in series across a 220 V
thermal conductivity of the material of the inner voltage source. If the 25 W and 100 W bulbs draw
cylinder is K1 and that of the outer cylinder is K2. powers P1 and P2 respectively, then
Assuming no loss of heat, the effective thermal
conductivity of the system for heat flowing along the (1) P1 = 9 W, P2 = 16 W
length of the cylinder is
K1  K 2 K1  3K 2 (2) P1 = 4 W, P2 = 16 W
(1) (2)
2 4
2K1  3K 2 (3) P1 = 16 W, P2 = 9 W
(3) K1 + K2 (4)
5
Answer (2) (4) P1 = 16 W, P2 = 4 W
Sol.
Answer (4)
K A  K 2 A2
∵ K eq  1 1 1 1 1
A1  A2 Sol.  
K P 25 100
K R 2  K 2 3R 2 K1
 K eq  1 R
2R
4R 2 25 W 100 W
K1  3K 2
=
4
15. A passenger train of length 60 m travels at a speed

of 80 km/hr. Another freight train of length 120 m
travels at a speed of 30 km/hr. The ratio of times
taken by the passenger train to completely cross the  P = 20 W
freight train when : (i) they are moving in the same
∵ Power  R
direction, and (ii) in the opposite directions is
25 PR1
(1) P1   16 W
11 R1  R2
5 P2 = 4 W
(2)
2
17. A 100 V carrier wave is made to vary between 160
11 V and 40 V by a modulating signal. What is the
(3)
5 modulation index?
3 (1) 0.5 (2) 0.4
(4)
2
(3) 0.6 (4) 0.3
Answer (3)
Answer (3)
l1  l2
Sol. t1  (when moving in same direction) and, Sol. VC + Vm = 160
v1 – v 2
and, VC – Vm = 40
l l
t2  1 2 (when moving in opposite direction)  VC = 100 V
v1  v 2
 Vm = 60 V
t1 v1  v 2 80  30 11
    Vm 3
t2 v1 – v 2 80 – 30 5 Modulation index    0.6
Vc 5
6
18. Two light identical springs of spring constant k are

⎛   1 ⎞ m ⎛ 0  1 ⎞
attached horizontally at the two ends of a uniform (1) m ⎜ 0
2 ⎜⎝ 0  1 ⎟⎠
⎟ (2)
horizontal rod AB of length l and mass m. The rod ⎝ 0  1 ⎠
is pivoted at its centre ‘O’ and can rotate freely in
horizontal plane. The other ends of the two springs m ⎛ 0  1 ⎞ ⎛   1 ⎞
(3) (4) m ⎜ 0 ⎟
2 ⎜⎝ 0  1 ⎟⎠
are fixed to rigid supports as shown in figure. The
rod is gently pushed through a small angle and ⎝ 0  1 ⎠
released. The frequency of resulting oscillation is
Answer (1)
A Sol. u = 0
y v = 1
O
u θ0
 =
x v θ1
B
M–m
Now, v = ×u
1 k M+m
(1)
2 m
M + m u θ0
 = =
1 2k M–m v θ1
(2)
2 m
M θ + θ1
 = 0
1 3k m θ0 – θ1
(3)
2 m
⎛ θ + θ1 ⎞
 M =m 0
1 6k ⎜⎝ θ – θ ⎟⎠
(2) 0 1
2 m
20. Let the moment of inertia of a hollow cylinder of
Answer (4) length 30 cm (inner radius 10 cm and outer radius
Sol.  = I  20 cm), about its axis be I. The radius of a thin
cylinder of the same mass such that its moment of
inertia about its axis is also I, is
Ml2 ⎛ l⎞⎛ l⎞
  2k ⎜ ⎟ ⎜ ⎟  
12 ⎝ 2⎠ ⎝ 2⎠ (1) 14 cm (2) 12 cm
(3) 16 cm (4) 18 cm
2 2 O
Ml k l
  Answer (3)
12 2
M 2
Sol.
2
(R1 + R22 ) = MR 2
6k
 
m
R12 + R22
R =
1 6K 2
 
2 m
19. A simple pendulum, made of a string of length l and 100 + 400

=
a bob of mass m, is released from a small angle 0. 2
It strikes a block of mass M, kept on a horizontal
surface at its lowest point of oscillations, elastically. = 250
It bounces back and goes up to an angle 1. Then
M is given by  16 cm
7
21. A particle A of mass ‘m’ and charge ‘q’ is then, m1 = 2L, and r1cm  (L, L)
accelerated by a potential difference of 50 V. Another
particle B of mass ‘4 m’ and charge ‘q’ is ⎛ L⎞
m2 = L, and r2 cm  ⎜ 2L, ⎟
accelerated by a potential difference of 2500 V. The ⎝ 2⎠
A ⎛ 5L ⎞
ratio of de-Broglie wavelengths  is close to m3 = L, and r3 cm  ⎜ , 0 ⎟
B ⎝ 2 ⎠
(1) 0.07 m1x1  m2 x2  m3 x3

 Xcm =
(2) 14.14 m1  m2  m3
(3) 4.47
13
 Xcm = L
(4) 10.00 8
Answer (2)
m1y1  m2 y 2  m3 y 3 5
and, Ycm =  L
h h m1  m2  m3 8
Sol.  = p =
2mqv
23. An ideal gas occupies a volume of 2 m 3 at a
pressure of 3 × 106 Pa. The energy of the gas is
⎛ h ⎞ (1) 108 J
λA ⎜⎝ 2mq × 50 ⎟⎠
= = 200 = 14.41 (2) 9 × 106 J
λB ⎛ h ⎞
⎜ ⎟
⎝ 2 × 4m × q × 2500 ⎠ (3) 6 × 104 J
(4) 3 × 102 J

22. The position vector of the centre of mass r cm of
Answer (2)
an asymmetric uniform bar of negligible area of
cross-section as shown in figure is 3
Sol. U = nRT for monoatomic gas
2
y
3
=  (PV )
2
3
L =  3  106  2
2
L 2L 3L x
= 9 × 106 J
5 13 24. A satellite of mass M is in a circular orbit of radius

(1) r cm = L xˆ  L ŷ R about the centre of the earth. A meteorite of the
8 8
same mass, falling towards the earth, collides with
the satellite completely inelastically. The speeds of
3 11
(2) r cm = L xˆ  L ŷ the satellite and the meteorite are the same, just
8 8 before the collision. The subsequent motion of the
combined body will be
13 5
(3) r cm = L xˆ  L ŷ
8 8 (1) Such that it escapes to infinity
(2) In a circular orbit of a different radius

11 3
(4) r cm = L xˆ  L ŷ
8 8 (3) In an elliptical orbit
Answer (3) (4) In the same circular orbit of radius R
Sol. Let assume linear mass dinsity is  Answer (3)
8
Sol.
<
d
 d/2
M 
v0 M < d/2
d d
v0 <
Sol. 

d
L <
GM
v0  2L
R
After collision

mv 0   ˆj   mv 0  iˆ   2mv d

y
d / 2 2L
v v  y=d
v   0 iˆ  0 jˆ
2 2 Hence, the distance over which the image can be
seen is d + d + d = 3d.
v
v  0  0.7 v 0 26. A particle of mass m moves in a circular orbit in a
2
1 2
central potential field U(r) = kr . If Bohr’s
∵ v < v0 2
 The path will be elliptical. quantization conditions are applied, radii of possible
orbitals and energy levels vary with quantum number
25. A point source of light, S is placed at a distance L n as
in front of the centre of plane mirror of width d which
is hanging vertically on a wall. A man walks in front (1) rn  n, En  n
of the mirror along a line parallel to the mirror, at a
distance 2L as shown below. The distance over (2) rn  n , En  n
which the man can see the image of the light source
in the mirror is 1
(3) rn  n , En 
n
1
(4) rn  n 2 , En 
n2
S
d
Answer (2)
L
 dU mv 2
Sol. F =  kr 
2L dr r
k 2
d  v2 = r
(1) (2) 3d m
2
(3) 2d (4) d k
 v= r ... (i)
m
Answer (2)
9
nh 0.96
And, mvr = ... (ii)   E12  E22
2 
Solving (i) and (ii)

0.96
 E2   E0
k nh 1.5
m r .r 
m 2
= 0.8 × (30)
 r n = 24 V/m
And, E = PE + KE 28. What is the position and nature of image formed by
lens combination shown in figure? (f1, f2 are focal
1 2 1 mk 2 lengths)
= kr  r
2 2 m
 E  r2 2 cm
 En A B
27. A light wave is incident normally on a glass slab of O
refractive index 1.5. If 4% of light gets reflected and
20 cm f1 = +5 cm f2 = –5 cm
the amplitude of the electric field of the incident light
is 30 V/m, then the amplitude of the electric field for
the wave propogating in the glass medium will be
20
(1) cm from point B at right; real
(1) 6 V/m 3
(2) 10 V/m (2) 70 cm from point B at right; real

(3) 24 V/m (3) 40 cm from point B at right; real
(4) 30 V/m (4) 70 cm from point B at left; virtual
Answer (3) Answer (2)
1 Sol. For lens A

1
Sol. v  , c
 0 0 0 1 1 1
 
v ( 20) 5
v 0
  20
c 0  v  cm
3
For lens B
1
I 2  E 22  v 20
2 u 2
3
1 14
I1   0 E12  c u  cm
2 3
I2  E2 v 1 1 1
   22    
I1 0 E1 c v 14 5
3
c 2 E22 v  v = 70 cm
 0.96   
v 2 E12 c
Image is real and right of B.
10
29. In the figure shown, after the switch ‘S’ is turned 30. Determine the electric dipole moment of the system
from position ‘A’ to position ‘B’, the energy dissipated of three charges, placed on the vertices of an
in the circuit in terms of capacitance ‘C’ and total equilateral triangle, as shown in the figure
charge ‘Q’ is
–2q
A B y l l
S +q
 +q
l x
C 3C
(1) 2ql ˆj
jˆ  iˆ
(2) 3 ql
3 Q2 2
(1)
8 C
(3)  3 ql ˆj
1 Q2
(2)
8 C iˆ  ˆj
(4) ql 
2
5 Q2
(3) Answer (3)
8 C
Sol.
3 Q2
(4) y
4 C
Answer (1)
–2q
Sol. H = U
l l
1 C  3C
=  (V 2 )
2 C  3C
+q l +q x
1 3 3
=  CV 2  CV 2
2 4 8 P  2  ql cos30 ˆj
3 Q2
H = P   3 ql ˆj
8 C

11
CHEMISTRY
1. Water samples with BOD values of 4 ppm and 4. A metal on combustion in excess air forms X. X
18 ppm, respectively, are upon hydrolysis with water yields H2O2 and O2 along
with another product. The metal is
(1) Clean and Highly polluted
(1) Rb (2) Li
(2) Clean and Clean
(3) Mg (4) Na
(3) Highly polluted and Clean
Answer (1)
(4) Highly polluted and Highly polluted
Sol. Rb + O2  RbO2
Answer (1)
excess
Sol. Clean water have BOD value of less than 5 ppm
whereas highly polluted water could have BOD value 2RbO2 + 2H2O  2RbOH + H2O2 + O2
of 17 ppm or more. 5. The correct order for acid strength of compounds
2. Given CH  CH, CH3 — C  CH and CH2 == CH2
Gas H2 CH4 CO2 SO2 is as follows :
Critical 33 190 304 630 (1) CH3 — C  CH > CH  CH > CH2 == CH2
Temperature/K (2) CH3 — C  CH > CH2 == CH2 > HC  CH
On the basis of data given above, predict which of (3) CH  CH > CH2 == CH2 > CH3 — C  CH
the following gases shows least adsorption on a (4) HC  CH > CH3 — C  CH > CH2 == CH2
definite amount of charcoal?
Answer (4)
(1) SO2 (2) CO2
Sol. Order of acidic strength is
(3) CH4 (4) H2
CH  CH > CH3 — C  CH > CH2 == CH2
Answer (4)
sp hybridised sp hybridised sp2 hybridised
Sol. More easily liquefiable a gas is (i.e. having higher
carbon carbon and + I carbon
critical temperature), the more readily it will be
adsorbed. (more effect of —CH3 (less
 Least adsorption is shown by H2 (least critical electronegative) electronegative)
temperature)
6. The hardness of a water sample (in terms of
3. The metal d-orbitals that are directly facing the equivalents of CaCO3) containing 10–3 M CaSO4 is
ligands in K3[Co(CN)6] are (molar mass of CaSO4 = 136 g mol–1)
(1) dxy, dxz and dyz (1) 10 ppm (2) 100 ppm
(2) dxz, dyz and dz2 (3) 90 ppm (4) 50 ppm
(3) dx2 – y2 and dz2 Answer (2)
(4) dxy and dx2 – y2 Sol. 10–3 M CaSO4  10–3 M CaCO3
Answer (3)  10–3 M CaCO3 means 10–3 moles of CaCO3 are
present in 1L
Sol. K3[Co(CN)6]
ie 100 mg of CaCO 3 is present in 1L solution.
During splitting in octahederal co-ordination entities,
Hardness of water = Number of milligram of CaCO3
dx2 – y2 and dz2 orbitals point towards the direction
per litre of water.
of ligands (i.e. they experience more repulsion and
their energy is raised)  Hardness of water = 100 ppm
12
7. In the following reaction 9. The molecule that has minimum/no role in the
formation of photochemical smog, is
HCI
Aldehyde + Alcohol Acetal (1) NO (2) CH2 == 0
Aldehyde Alcohol (3) O3 (4) N2
HCHO tBuOH Answer (2)
CH3CHO MeOH Sol. NO, O3 and HCHO are involved in the formation
photochemical smog.
The best combination is
N2 has no role in photochemical smog
(1) HCHO and MeOH (2) HCHO and tBuOH
10. The increasing order of reactivity of the following
(3) CH3CHO and tBuOH (4) CH3CHO and MeOH compounds towards reaction with alkyl halides
directly is
Answer (1)
O O
Sol.
NH2 NH
HCl
Aldehyde + Alcohol Acetal
O
(A) (B)
more less steric
reactive alcohol CN NH2
aldehyde NH2
 Best combination is HCHO and MeOH

(C) (D)
8. Poly--hydroxybutyrate-co--hydroxyvalerate (PHBV)
is a copolymer of ___. (1) (A) < (B) < (C) < (D)
(1) 3-hydroxybutanoic acid and 4-hydroxypentanoic (2) (B) < (A) < (C) < (D)
acid (3) (B) < (A) < (D) < (C)
(2) 3-hydroxybutanoic acid and 2-hydroxypentanoic (4) (A) < (C) < (D) < (B)
acid Answer (2)
(3) 2-hydroxybutanoic acid and 3-hydroxypentanoic Sol. Reactivity of compounds (nucleophiles) with alkyl
acid halides will depend upon the availability of lone pair
of electrons on nitrogen (amines or acid amides)
(4) 3-hydroxybutanoic acid and 3-hydroxypentanoic
acid
Answer (4)
Sol.
OH OH
—
CH 3 — CH — CH 2 — COOH + CH 3 — CH 2 — CH — CH 2 — COOH OH
3-Hydroxybutanoic acid 3-Hydroxypentanoic acid 11. CH3 CH2 C CH3 cannot be prepared by
Ph
—O — CH — CH 2 — C — O — CH — CH 2 —C— (1) PhCOCH2CH3 + CH3MgX

—
—
—
—
—
—
CH 3 O CH 2— CH 3 O n (2) CH3CH2COCH3+ PhMgX
PHBV (3) HCHO+PhCH(CH3)CH2MgX

(4) PhCOCH3+ CH3CH2MgX
 Monomers of PHBV are 3-Hydroxybutanoic acid
and 3-Hydroxypentanoic acid. Answer (3)
13
O OH 13. The standard electrode potential E

–
and its
1. CH3MgX
Sol. 1. Ph C CH 2CH 3 Ph C CH 2 CH 3 –
⎛ dE ⎞
2. H3O+ temperature coefficient ⎜⎝ ⎟ for a cell are 2 V and
dT ⎠
CH 3
OH – 5 × 10–4 VK –1 at 300 K respectively. The cell
O
reaction is
1. PhMgX
2. CH3 CH2 C CH3 CH3CH2 C CH3
2. H3 O+ Zn(s) + Cu2+(aq)  Zn2+ (aq) + Cu(s)
Ph –
The standard reaction enthalpy (rH ) at 300 K in
O kJ mol–1 is,
3. H C H + PhCH(CH3)CH 2MgX [Use R = 8 JK–1 mol–1 and F = 96,000 C mol–1]

(1) 206.4
H3O+
HOCH2 CH 2 CH Ph
(2) –384.0
CH3 (3) –412.8
(4) 192.0
O OH Answer (3)
1. CH3CH2 MgX
4. Ph C CH3 Ph C CH3
2. H3O+ dE
Sol. r H  nFE  nF T
CH2 CH3 dT
Reaction (3) gives primary alcohol which is different Cell reaction : Zn(s)  Cu2  aq  Zn2  aq  Cu(s)
from tertiary alcohol given by the remaining
reactions.  rH° = –2 × 96000 (2 + 300 × 5 × 10–4)
12. Two solids dissociate as follows = – 2 × 96000 (2 + 0.15)

= – 412.8 × 103 J/mol
B ( g) + C ( g) ;K P1 = x atm
A ( s )

2
rH° = – 412.8 kJ/mol

C ( g) + E ( g) ;K P2 = y atm
D ( s )

2
14. Decomposition of X exhibits a rate constant of

The total pressure when both the solids dissociate 0.05 g/year. How many years are required for the
simultaneously is decomposition of 5 g of X into 2.5 g?
(1) x2 + y2 atm (2) (x + y) atm (1) 40
(3) x + y atm (4) 2 ( x+y ) atm

(2) 20
(3) 50
Answer (4)
(4) 25
Sol. A(S) 
 B(g)  C(g) KP = P1(P1 + P2) = x Answer (3)
P1 P1  P2 1
Sol. Rate constant of decomposition of X = 0.05 g/year

D(S) 
 C(g)  E(g) KP = P1(P1 + P2) = y
From unit of rate constant, it is clear that the
P2 P1 P2 2 decomposition follows zero order kinetics.
 P1(P1 + P2) + P2(P1 + P2) = x + y For zero order kinetics,
 (P1 + P2)2 = x + y [X] = [X]0 – kt
 P1 + P2 = xy 5  2.5
 t
0.05
 Total pressure = 2(P1 + P2) = 2  x  y  atm at
2.5
equilibrium   50 years
0.05
14
15. In the Hall-Heroult process, aluminium is formed at Sol. In general, polarity increases the intermolecular force
the cathode. The cathode is made out of of attraction and as a result increases the melting
point.
(1) Carbon
18. In the following reactions, products A and B are
(2) Copper
(3) Platinum O O
dil NaOH
(4) Pure aluminium H3C H [A]
H 3C CH3
Answer (1)
+
H3O
Sol. In Hall-Heroult process, steel vessel with carbon [A] [B]

lining acts as cathode.
O O
16. What is the work function of the metal if the light of
CH3 CH3
wavelength 4000 Å generates photoelectrons of
(1) A = CH3 ;B= CH3
velocity 6 × 105 ms–1 from it?
HO
(Mass of electron = 9 × 10–31 kg
Velocity of light = 3 × 108 ms–1 O O
CH3 CH3
Planck’s constant = 6.626 × 10–34 Js
(2) A = CH3 ;B= CH3
Charge of electron = 1.6 × 10–19 JeV–1) HO
(1) 4.0 eV (2) 2.1 eV
O
(3) 3.1 eV (4) 0.9 eV O
OH
C CH3
Answer (2) H3C H H
(3) A = ;B=
12400 H3C H 3C
Sol. Ephoton   3.1 eV CH3 CH3
4000
1 1 O O
KEe  mv 2   9  10 31  36  1010 J OH H 2C
2 2 H H
H3C
(4) A = ;B=
 1.62 × 10–19 J H3C H 3C
CH3 CH3
1 eV
Answer (2)
 Work function  3.1 – 1
Sol.
 2.1 eV
17. Among the following four aromatic compounds, which
one will have the lowest melting point? O O O O
OH
H H
O
OH
(1) (2) OH
O
O
CH3 HO
OH +/
H 3O
O
(3) O
(4)
O
CH3
Answer (1)
15
19. The pair of metal ions that can give a spin only
magnetic moment of 3.9 BM for the complex CHO CHO
[M(H2O)6]Cl2, is (1) (2)
O OH
(1) V2+ and Co2+ (2) Co2+ and Fe2+
O CHO
(3) V2+ and Fe2+ (4) Cr2+ and Mn2+
Answer (1)
CH = NH CHO
Sol. μ = 3.9 BM (3) (4)
OH O
So, the central metal ion has 3 unpaired electrons.
OH
 Configuration is either d3 or d7 as H2O is a weak field
ligand. Answer (2)
V2+ has d3 configuration. Sol. DIBAL-H followed by hydrolysis converts nitrile to
aldehyde and ester to aldehyde and alcohol.
Co2+ has d7 configuration.
CHO
K CN
20. In a chemical reaction, A  2B 2C  D , the
DIBAL-H OH
initial concentration of B was 1.5 times of the O +
concentration of A, but the equilibrium concentrations H3O H
O
of A and B were found to be equal. The equilibrium O
constant (K) for the aforesaid chemical reaction is 22. For a diatomic ideal gas in a closed system, which
(1) 1 (2) 16 of the following plots does not correctly describe the
relation between various thermodynamic quantities?
1
(3) 4 (4)
4
Answer (3) CV
U
Sol. (1) (2)
A  2B 2C  D T V
t0 2 3
t eq 2  x 3 – 2x 2x x
Given, 3 – 2x = 2 – x CV Cp
(3) (4)
⇒ x=1
 [C] = 2, [D] = 1 T P
[A] = 1, [B] = 1 Answer (4)

Sol. C p and C v for ideal gases are dependant on
22  1
 Kc  4 temperature only. So, C p will not change with
12  1 pressure.
21. The major product of the following reaction 23. The volume of gas A is twice than that of gas B. The
compressibility factor of gas A is thrice than that of
CN gas B at same temperature. The pressure of the
gases for equal number of moles are
O (ii) H3O+ (1) PA = 2PB (2) PA = 3PB
O (3) 3PA = 2PB (4) 2PA = 3PB

Answer (4)
16
Sol.
PVm
Sol. Z 
RT
Cl
MeO MeO Cl
Z A P A VA 
  Cl2 /CCl 4
ZB PB VB
AlCl3
PA
3 2
PB MeO
2PA = 3PB Cl
24. Among the following compounds most basic amino

acid is 27. Iodine reacts with concentrated HNO3 to yield Y
along with other products. The oxidation state of
(1) Serine iodine in Y, is
(2) Lysine (1) 7 (2) 1
(3) Histidine (3) 5 (4) 3
(4) Asparagine Answer (3)
Answer (2) Sol. Conc. HNO3 oxidises I2 to iodic acid (HIO3).
Sol. Lysine is the most basic among the given amino 28. The element with Z = 120 (not yet discovered) will be
acids. an/a
25. Mn2(CO)10 is an organometallic compound due to
(1) Inner-transition metal (2) Transition metal
the presence of
(3) Alkaline earth metal (4) Alkali metal
(1) Mn – C bond
Answer (3)
(2) Mn – Mn bond
Sol. Element with Z = 120 will belong to alkaline earth
(3) Mn – O bond
metals.
(4) C – O bond
29. Freezing point of a 4% aqueous solution of X is
Answer (1) equal to freezing point of 12% aqueous solution of Y.
If molecular weight of X is A, then molecular weight
Sol. It is organometallic compound due to presence of
of Y is
Mn – C bond.
(1) 2A
26. The major product of the following reaction is
(2) 3A
CH3O
(1) Cl2/CCl4 (3) A
(2) AlCl 3(anhyd.)
(4) 4A
Cl Cl Answer (2)
(1) CH3O (2) CH3O 4 12

Sol. 
Mx My
 My = 3Mx
(3) CH3O (4) CH3O
 My = 3A
Cl
Cl (Since density of solutions are not given therefore
assuming molality to be equal to molarity and given
Answer (4)
% as % W/V)
17
30. 50 mL of 0.5 M oxalic acid is needed to neutralize  M=2

25 mL of sodium hydroxide solution. The amount of
NaOH in 50 mL of the given sodium hydroxide 2  50
 Moles of NaOH in 50 mL =
solution is 1000
(1) 10 g (2) 40 g
2 1
(3) 20 g (4) 80 g = 
20 10
Answer (*)
 Weight = 4 grams
Sol. 2 × 50 × 0.5 = 25 × M
No option is correct

18
MATHEMATICS

The maximum value of 3cos   5 sin ⎛⎜   ⎞⎟ for any
Now T5 : T7
1.
⎝ 6⎠
real value of  is ⎛ 1
4
⎛ 1
6
   
1 6
⎞ 1 4 ⎞
10
C4 3 ⎜ 1 ⎟ : 10C6 3 ⎜ 1 ⎟
(1) 34 (2) 19 2 ⎜ ⎟ 2 ⎜ ⎟
⎝ 2.3 3 ⎠ ⎝ 2.3 3 ⎠
79
(3) (4) 31 2
⎛ 1
 
2  2
⎞
:⎜ 1 ⎟
2 3 ⎜ ⎟
Answer (2) ⎝ 2.3 3 ⎠
 
Sol. f ()  3 cos   5 sin   cos  5 sin cos  2 2
6 6 2 3  22  3 3
2 1
 = 4.6 3 : 1  4  (36)3 : 1
1
⎛ 5⎞ 3
 ⎜ 3  ⎟ cos   5  sin 
⎝ 2⎠ 2 3. Let f and g be continuous functions on [0, a] such
that f(x) = f(a – x) and g(x) + g(a – x) = 4, then
a
1 5 3
 cos   sin  ∫ f ( x )g ( x ) dx is equal to
2 2
0
a a
1 25 76
max f ()  
4 4
3 
4
 19 (1) ∫ f ( x )dx (2) 4 ∫ f ( x )dx
0 0
2. A ratio of the 5th term from the beginning to the 5th

term from the end in the binomial expansion of a a
(3) 3 ∫ f ( x )dx (4) 2∫ f ( x )dx

10 0 0
⎛ 1 1 ⎞
⎜ 23  ⎟ is
1
⎜⎜ ⎟⎟ Answer (4)
⎝ 2(3) 3
⎠
Sol. f(x) = f(a – x)
1
g(x) + g(a – x) = 4
1
(1) 1: 4(16)3 (2) 1: 2(6)3 a
I  ∫ f ( x )g ( x )dx
0
1 1
(3) 2(36)3 : 1 (4) 4(36)3 : 1 a
 ∫ f (a  x )  g (a  x )dx
0
Answer (4)
a
10 I  ∫ f ( x )[4  g ( x )]dx
⎛ 1 1 ⎞ 0
Sol. ⎜ 2 3  1
⎟
⎜⎜ ⎟
2(3) ⎟⎠
3 a a
⎝ I  ∫ 4f ( x )dx  ∫ f ( x )  g ( x )dx
0 0
2 
a
1 6 1 I  ∫ 4f ( x )dx  I
5th term from beginning T5  10C4
2.3 
3 0
1 4
3
a
2I  ∫ 4f ( x )dx
0
6
⎛ 1
 
1 4
⎞ a
10
5th term from end T115 1  C6 3 ⎜ 1 ⎟ I  2∫ f ( x )dx
2 ⎜ ⎟ 0
⎝ 2.3 3 ⎠
19
4. An ordered pair (, ) for which the system of linear Now, equation of plane
equations  7(x – 1) – 14(y – 4) + 7 (z + 4) = 0
(1 + ) x + y + z = 2 x – 1 – 2y + 8 + z + 4 = 0
x + (1 + )y + z = 3 x – 2y + z + 11 = 0
x + y + 2z = 2 Now, distance from (0, 0, 0) to the plane
has a unique solution, is 11 11
 
(1) (1, –3) (2) (2, 4) 1 4  1 6
(3) (–3, 1) (4) (–4, 2) 6. Consider three boxes, each containing 10 balls
Answer (2) labelled 1, 2, ...,10. Suppose one ball is randomly
drawn from each of the boxes. Denote by ni, the
Sol. For unique solution, label of the ball drawn from the ith box, (i = 1, 2, 3).
Then, the number of ways in which the balls can be
1   1 chosen such that n1 < n2 < n3 is
  1  1  0 (1) 240
  2
(2) 120
1     1  1 (3) 164
  1 1  0
(4) 82
2  2
Answer (2)
1  1 Sol. Collecting different labels of balls drawn = 10 × 9 × 8
     2 1   1 1  0 Now, arrangement is not required so
1  2
10  9  8
 120
1  1 3!
     2 0 1 0 0 7. In a random experiment, a fair die is rolled until two
0 0 1 fours are obtained in succession. The probability that
the experiment will end in the fifth throw of the die
( +  + 2) 1(1)  0 is equal to
2  0 150 225

(1) 5 (2)
6 65
5. The perpendicular distance from the origin to the
plane containing the two lines, 175 200
(3) 5 (4)
6 65
x 2 y 2 z5 x 1 y  4 z  4
  and   , is
3 5 7 1 4 7 Answer (3)
Sol. To end the experiment in the fifth throw, possibility
(1) 11 6 (2) 6 11
is 4 × × 4 4, × 4 × 4 4, × × × 4 4 (where × is any
number except 4)
11
(3) 11 (4)
6 ⎛ 1⎞ ⎛5⎞ ⎛5⎞ ⎛ 1⎞ ⎛ 1⎞ ⎛5⎞ ⎛ 1⎞ ⎛5⎞
Probability = ⎜ ⎟ ⎜ ⎟ ⎜ ⎟ ⎜ ⎟ ⎜ ⎟ + ⎜ ⎟ ⎜ ⎟ ⎜ ⎟
⎝6⎠⎝6⎠⎝6⎠⎝6⎠⎝6⎠ ⎝6⎠⎝6⎠⎝6⎠
Answer (4)
3 2
Sol. Equation of plane containing both lines. ⎛ 1⎞ ⎛ 1⎞ ⎛5⎞ ⎛ 1⎞
⎜ ⎟⎜ ⎟+ ⎜ ⎟ ⎜ ⎟
⎝6⎠⎝6⎠ ⎝6⎠ ⎝6⎠
iˆ ˆj kˆ
D.R. of plane = 3 5 7  7iˆ – 14 ˆj  7kˆ 25  25  125 175
=  5
1 4 7 65 6
20
8. If a variable line, 3x + 4y –  = 0 is such that the two

circles x2 + y2 – 2x – 2y + 1 = 0and x2 + y2 – 18x ⎡ 2 0 0⎤
– 2y + 78 = 0 are on its opposite sides, then the set Q  I3  P 5  ⎢⎢ 15 2 0 ⎥⎥
of all values of  is the interval ⎢⎣ 135 15 2⎥⎦
(1) (2, 17) (2) (12, 21)
q21  q31 15  135
(3) (13, 23) (4) (23, 31)   10
q32 15
Answer (2)
Sol. Condition 1: (1, 1) and (9, 1) should lie on opposite 10. The product of three consecutive terms of a G.P. is
side of the line 3x + 4y –  = 0 512. If 4 is added to each of the first and the second
of these terms, the three terms now form an A.P.
(7 – ) (27 + 4 – ) < 0 Then the sum of the original three terms of the given
 ( – 7) ( – 31) < 0 G.P. is
 (7, 31) …(i) (1) 36
Conditon 2 : Perpendicular distance from centre on (2) 32

line  radius of circle. (3) 24
(4) 28
|34|
 1
5 Answer (4)
 | – 7|  5 a
Sol. Let three terms be , a, ar
12 or 2 …(ii) r
a3 = 512
| 27  4   |
Also 2 a=8
5
41 or 21 …(iii) 8
 4, 12, 8r form an A.P
Intersection of (i), (ii) and (iii) gives  [12, 21] r
⎡1 0 0⎤ 8
24   8r  4
9. Let P  ⎢⎢3 1 0 ⎥⎥ and Q = [q ij ] be two 3 × 3 r
⎢⎣9 3 1⎥⎦  2r2 – 5r + 2 = 0
q  q31
matrices such that Q – P5 = l3. Then 21 is
q32  (2r –1) (r – 2) = 0
equal to
1
(1) 10 (2) 135 r  or 2
2
(3) 9 (4) 15
Answer (1) 8
Sum of three terms =  8  16
2
⎡ 1 0 0⎤ ⎡ 1 0 0⎤ ⎡ 1 0 0⎤ = 28
Sol. P 2  ⎢3 1 0⎥ ⎢3 1 0⎥  ⎢ 6 1 0⎥
⎢ ⎥ ⎢ ⎥ ⎢ ⎥ 11. A tetrahedron has vertices P(1, 2, 1), Q(2, 1, 3),
⎢⎣9 3 1⎥⎦ ⎢⎣9 3 1⎥⎦ ⎢⎣27 6 1⎥⎦
R(–1, 1, 2) and O(0, 0, 0). The angle between the
faces OPQ and PQR is
⎡ 1 0 0⎤ ⎡ 1 0 0⎤ ⎡ 1 0 0 ⎤
P  ⎢⎢ 6 1 0⎥⎥ ⎢⎢ 6 1 0⎥⎥  ⎢⎢ 12 1 0 ⎥⎥
4 ⎛ 19 ⎞
(1) cos –1 ⎜ ⎟
⎛ 9 ⎞
(2) cos –1 ⎜ ⎟
⎝ 35 ⎠ ⎝ 35 ⎠
⎣⎢27 6 1⎦⎥ ⎢⎣ 27 6 1⎦⎥ ⎣⎢ 90 12 1 ⎦⎥
⎛ 17 ⎞ ⎛ 7 ⎞
⎡ 1 0 0 ⎤ ⎡ 1 0 0⎤ ⎡ 1 0 0⎤ (3) cos –1 ⎜ ⎟ (4) cos –1 ⎜ ⎟
⎝ 31 ⎠ ⎝ 31 ⎠
P  ⎢⎢12 1 0 ⎥⎥ ⎢⎢ 3 1 0⎥⎥  ⎢⎢ 15 1 0⎥⎥
5
⎢⎣90 12 1 ⎥⎦ ⎢⎣ 9 3 1⎥⎦ ⎢⎣ 135 15 1⎥⎦ Answer (1)
21
Answer (4)
Sol. Let x1 and x2 be the vectors perpendicular to the
plane OPQ and PQR respectively. dy y
Sol.  = logex
dx x
iˆ ˆj kˆ
1
∫ x dx
x1  OP  OQ  1 2 1 IF = e =x
2 1 3
Solution is yx = ∫ x ln x dx
 5iˆ – jˆ – 3kˆ
x2 1 x2
 xy = ln x · ∫  dx
2 x 2
iˆ jˆ kˆ

x2  PQ  PR  1 –1 2 x2 x2
 xy =  ln x  c
–2 –1 1 2 4
At x = 2,
 iˆ – 5 jˆ – 3kˆ
2y = 2ln 2 – 1 + c
ln4 – 1 = ln4 – 1 + c
n ·n 5  5  9 19
cos   1 2  
n1 · n2 25  1  9 35 i.e. c =0
x2 x2
⎛ 19 ⎞  xy = ln x 
  cos ⎜ –1
⎟ 2 4
⎝ 35 ⎠
x x
12. If the sum of the deviations of 50 observations from  y= ln x 
2 4
30 is 50, then the mean of these observations is
e e e
(1) 31 (2) 30  y(e) =  
2 4 4
(3) 50 (4) 51
Answer (1) cot3 x – tan x
14. lim is

x  cos ⎛⎜ x  ⎞⎟

Sol. Given, ∑ x i – 30   50
4 ⎝ 4⎠
∑x i – 50  30   50
(1) 8 2 (2) 4
 ∑x i  1550
(3) 4 2 (4) 8
Mean, x 
∑x i Answer (4)
N
cot 3 x  tan x
Sol. lim
1550 x
 ⎛ ⎞
 4 cos ⎜ x  ⎟
50 ⎝ 4 ⎠
= 31 (1  tan2 x )(1  tan x )(1  tan x )

 lim
13. Let y = y(x) be the solution of the differential  ⎛ cos x  sin x ⎞
x
4 tan3 x ⎜ ⎟
dy ⎝ 2 ⎠
equation, x  y  x loge x,( x  1) . If 2y(2) =
dx
(1  tan2 x )(1  tan x )(cos x  sin x )
loge4 – 1, then y(e) is equal to  lim
x
 sin3 x ⎛ cos x  sin x ⎞
e2 e 4 ⎜ ⎟
(1) (2) – cos2 x ⎝ 2 ⎠
4 2
(2)(2)
e2 e  8
(3) – (4) 1
2 4 ( 2)( 2)
22
15. The area (in sq. units) of the region bounded by the
t2 2t 1
parabola, y = x 2 + 2 and the lines, y = x + 1, 1
x = 0 and x = 3, is Area of PXQ = 4 4 1
2
9 6 1
15 21
(1) (2)
2 2 = –5t2 + 5t + 30
15 17 = –5(t2 – t – 6)
(3) (4)
4 4
⎡⎛ 2
Answer (1) 1⎞ 25 ⎤
= 5 ⎢ ⎜ t  ⎟  ⎥
⎢⎣ ⎝ 2⎠ 4 ⎥⎦
Sol.
⎛ 25 ⎞ 125
Maximum area = 5 ⎜ ⎟ 4
⎝ 4 ⎠
(0, 2) y=x+1
17. Let C1 and C2 be the centres of the circles x2 + y2
– 2x – 2y – 2 = 0 and x2 + y2 – 6x – 6y + 14 = 0
respectively. If P and Q are the points of intersection
(0, 0) x=3 of these circles, then the area (in sq. units) of the
quadrilateral PC1QC2 is
(1) 4 (2) 9
y2 = 4x (3) 6 (4) 8
3
2 Answer (1)
Area = ∫ ⎡⎣( x  2)  ( x  1)⎤⎦ dx
0
P
Sol.
3
⎡ x3 x2 ⎤
= ⎢   x⎥
⎢⎣ 3 2 ⎥⎦ C1 C2
9 15
=9– 3 
2 2
Q
16. Let P(4, –4) and Q(9, 6) be two points on the
parabola, y2 = 4x and let X be any point on the arc 2g1g2 + 2f1f2 = 2(–1)(–3) + 2(–1)(–3) = 12
POQ of this parabola, where O is the vertex of this
parabola, such that the area of PXQ is maximum. C1 + C2 = 14 – 2 = 12
Then this maximum area (in sq. units) is
As 2g1g2 + 2f1f2 = C1 + C2
75 125 Hence circles intersect orthogonally
(1) (2)
2 4
⎛1 ⎞
 Area = 2 ⎜ (C1P )(C2P ) ⎟
625 125 ⎝ 2 ⎠
(3) (4)
4 2
1
Answer (2)  2 r1r2  (2)(2) = 4 sq. units
2
2 Q(9, 6)
Sol. X(t , 2t ) 18. The sum of the distinct real values of , for which
the vectors, iˆ  jˆ  kˆ , iˆ  jˆ  kˆ , iˆ  jˆ  kˆ
are co-planar, is
(1) 2 (2) 1
P(4, –4) (3) –1 (4) 0
Answer (3)
y2 = 4x
23
Sol. For coplanar vectors, 20. Considering only the principal values of inverse
functions, the set
 1 1
1  1 0
1 1 

A  x  0: tan–1(2 x )  tan–1(3 x ) 

4 
(1) Is a singleton
 (2 – 1) + 1 –  + 1 –  = 0
(2) Contains two elements
 (1 – )[2 – ( + 1)] = 0
(3) Contains more than two elements
 (1 – ) [2 +  – 2] = 0
(4) Is an empty set
  = 1, –2
Answer (1)
Sum of all real values = 1 – 2 = –1

19. If  be the ratio of the roots of the quadratic equation Sol. tan–1(2x) + tan–1(3x) =
4
in x, 3m2x2 + m(m – 4)x + 2 = 0, then the least
1 ⎛ 5x ⎞ 
value of m for which    1, is  tan–1 ⎜ ⎟
 ⎝ 1 6x 2 ⎠ 4
5x
(1) 4 – 2 3  1
1 6x 2
(2) 4 – 3 2 i.e. 6x2 + 5x – 1 = 0
(6x–1)(x + 1) = 0
(3) 2 – 3
1
(4) –2  2  x= (as x  0)
6
Answer (2) Hence A is a singleton set
Sol. Let roots are , . 21. If the straight line, 2x – 3y + 17 = 0 is perpendicular

to the line passing through the points (7, 17) and
 (15, ), then  equals
Given,  =

35
(1) – (2) –5
  3
 1
 
35
(3) 5 (4)
(  )  2
2 3
1
 Answer (3)
m(4  m ) 4  m 2 2 2
As,  +  =  ,  = Sol. Slope of straight line = 
3m 2
3m 3m 2 3 3
2
  17
⎛4m⎞ Slope of line passing through two points =
⎜ ⎟ 15  7
⎝ 3m ⎠
2 =3
  17
3m 2 =
8
 (m – 4)2 = 18 m1m2 = – 1
m = 4  18 ⎛ 2 ⎞ ⎛   17 ⎞
⎜ ⎟⎜ ⎟ =–1
⎝ 2 ⎠⎝ 2 ⎠
Least value is 4 – 18  4  3 2  =5
24
Area = (2t) (12 – t2)

z–
22. If (  R ) is a purely imaginary number and
z A = 24t – 2t3
|z| = 2, then a value of  is dA
= 24 – 6t2
dt
(1) 2
– + –
(2) 2 –2 +2
1 At t = 2, area is maximum = 24(2) – 2(2)3

(3)
2 = 48 – 16 = 32 sq. units
(4) 1 24. If the vertices of a hyperbola be at (–2, 0) and (2, 0)
Answer (2) and one of its foci be at (–3, 0), then which one of
the following points does not lie on this hyperbola?
z
Sol. Let t =
z (1)  4, 15 
t t 0
(2)  6, 5 2 
z z 
  0
z z 
(3) 2 6, 5 
  z    z      z    z     0
 z z  2  z z  2  0
(4)  –6, 2 10 
Answer (2)
 z z  2  0
Sol. A(2, 0), A(–2, 0), S(–3, 0)
 |z|2 – 2 = 0
 Centre of hyperbola is O(0, 0)
 2 = 4
A A = 2a  4 = 2a  a = 2
=±2
3
23. The maximum area (in sq. units) of a rectangle  OS = ae  3 = 2e  e =
2
having its base on the x-axis and its other two
vertices on the parabola, y = 12 – x2 such that the  b2 = a2 (e2 – 1) = a2e2 – a2 = 9 – 4 = 5
rectangle lies inside the parabola, is
x2 y 2
(1) 32  Equation of hyperbola is  1 …(i)
4 5
(2) 36
(3) 20 2  6, 5 2  does not lie on (i)
(4) 18 3 dy
25. For x > 1, if (2x)2y = 4e2x – 2y, then 1  loge 2 x 
2
Answer (1) dx
is equal to
Sol. x2 = 12 – y
y
(0, 12) (1) loge2x

×
(2) x loge2x
(–t, 12 – t2 ) 2
(t , 12 – t )
x loge 2 x  loge 2
(3)
x x
x loge 2 x – loge 2
(4)
x
Answer (4)
25
Sol. (2x)2y = 4e2x–2y Sol. f(x) = min {sinx, cosx}

Taking log on both sides
2y ln(2x) = ln4 + (2x – 2y) …(i)
y = sinx
Differentiate w.r.t x y
1 dy dy y=1
2y 2  2 ln(2 x )  022
2x dx dx
3 

4 2
dy 2y 2 x  2y   x
2 (1  ln(2 x ))  2   …(ii) –  
dx x x 2 4
From (i) and (ii),

y = –1
dy 1 ⎛ ln 2  x ⎞
(1  ln 2 x )  1  ⎜ ⎟
dx x ⎝ 1  ln 2 x ⎠ y = cosx
dy ⎛ x  ln 2 ⎞ x ln(2 x )  ln 2
(1  ln 2 x )2  1  ln(2 x )  ⎜ ⎟ 3 
dx ⎝ x ⎠ x  f(x) is not differentiable at x   ,
4 4
 
26. Let S = {1, 2, 3, ... , 100}. The number of non-empty
subsets A of S such that the product of elements in  S   3 , 
4 4
A is even is
(1) 2100 –1 28. The integral ∫ cos  loge x  dx is equal to (where C is
(2) 250 +1 a constant of integration)
(3) 250(250 –1)
(4) 250 – 1 (1) x ⎡⎣cos  loge x  – sin  loge x  ⎤⎦  C
Answer (3)
x
(2) ⎡cos  loge x   sin  loge x  ⎤⎦  C
Sol. Number of required = Total number of subsets 2⎣
subsets – Total number of subsets
having only odd numbers x
(3) ⎡ sin  loge x  – cos  loge x  ⎤⎦  C
= 2100 – 250 2⎣
= 250(250 – 1)
(4) x ⎣⎡cos  loge x   sin  loge x  ⎦⎤  C
27. Let S be the set of all points in (–, ) at which the
function, f(x) = min {sinx, cosx} is not differentiable. Answer (2)
Then S is a subset of which of the following?
Sol. I = ∫ cos  ln x  dx
(1) –
3  3 
4
,– , ,
4 4 4  I = cos (ln x ) .x – ∫
– sin (ln x )
. x dx
x
(2) –
3   3
4
,– , ,
2 2 4  = x cos(ln x) + ∫ sin (ln x ) dx
(3)     
– ,– , ,
2 4 4 2  = x cos (ln x) + sin(ln x).x – ∫
cos  ln x 
x
. x dx
 
  2I = x(cos(ln x) + sin(ln x)) + C
(4) – ,0
4 4
x
I= [ cos (ln x ) + sin (ln x )] + C
Answer (1) 2
26
1  2  3  ...  k 1
29. Let Sk  . If = [ 505 ]
k 4
5 505 12
S12  S22  ...  S10
2
 A, then A is equal to 
12 A= = 303
4 5
(1) 303 30. The Boolean expression ((p  q)  (p   q)) 
(2) 156 ( p  q) is equivalent to
(3) 301 (1) p q (2) ( p) ( q)
(4) 283 (3) p ( q) (4) p ( q)
k ( k + 1) k + 1 Sol.  ( p  q )  ( pv ∼ q )  ( ∼ p ∼ q )
Sol. Sk = =
2k 2
 ( p ∼ q )  ( ∼ p  ∼ q )
5 1
 A = [ 22 + 33 + ... + 112 ]
12 4   ( p ∼ q ) ∼ p    ( p ∼ q ) ∼ q 
1 ⎡ 11  12  23 ⎤    p ∼ p   ( ∼ q  ∼ p)  ∼ q
 – 1⎥
4 ⎢⎣ 6 ⎦
 ( ∼ p  ∼ q ) ∼ q  ( ∼ p  ∼ q )

27
FOR AFTERNOON SHIFT
12/01/2019
EVENING
Regd. Office : Aakash Tower, 8, Pusa Road, New Delhi-110005

Ph.: 011-47623456 Fax : 011-47623472
Time : 3 hrs.
Answers & Solutions M.M. : 360
for
JEE (MAIN)-2019
(Online CBT Mode)
(Physics, Chemistry and Mathematics)
Important Instructions :
1. The test is of 3 hours duration.
2. The Test consists of 90 questions. The maximum marks are 360.
3. There are three parts consisting of Physics, Chemistry and Mathematics having 30 questions in each part
of equal weightage. Each question is allotted 4 (four) marks for each correct response.
4. Candidates will be awarded marks as stated above in Instructions No. 3 for correct response of each
question. ¼ (one-fourth) marks will be deducted for indicating incorrect response of each question. No
deduction from the total score will be made if no response is indicated for a question in the answer sheet.
5. There is only one correct response for each question.

PHYSICS
IC Sol. (P2 – P1)A = mg

l1
RB C RC ⎡ nRT nRT ⎤
⎢  ⎥
B ⎣ Al 2 Al1 ⎦ A = mg
E ~ v0 l2
1. IE
v1 ~ VBB VCC nRT ⎡ l1  l 2 ⎤
⎢ ⎥
g ⎣ l1l 2 ⎦ = m
3. A galvanometer, whose resistance is 50 ohm, has 25

In the figure, given that VBB supply can vary from 0
divisions in it. When a current of 4 × 10–4 A passes
to 5.0 V, V CC = 5V,  dc = 200, R B = 100 K,
through it, its needle(pointer) deflects by one
RC = 1 K and VBE = 1.0V. The minimum base
division. To use this galvanometer as a voltmeter of
current and the input voltage at which the transistor
range 2.5 V, it should be connected to a resistance
will go to saturation, will be respectively:
of:
(1) 25 A and 3.5 V (2) 20 A and 2.8 V
(1) 6250 ohm (2) 250 ohm
(3) 25 A and 2.8 V (4) 20 A and 3.5 V
(3) 200 ohm (4) 6200 ohm
Sol. VCC – ICRC = 0 Sol. Ig = 25 × 4 × 10–4
VBB – IbRb = VBE = 10–2 A
IC = 200 Ib V = Ig(R + 50)
IC = 5 mA, Ib = 25 A R = 200 
VBB – 25 × 10–6 × 100 × 103 = 1 4. In the circuit shown, find C if the effective
capacitance of the whole circuit is to be 0.5 F. All
VBB = 3.5 V
values in the circuit are in F.
2. A vertical closed cylinder is separated into two parts
C 2
by a frictionless piston of mass m and of negligible
A
thickness. The piston is free to move along the
2 2 1
length of the cylinder. The length of the cylinder
above the piston is I1, and that below the piston is
2
I 2 , such that I 1 > I 2 . Each part of the cylinder
contains n moles of an ideal gas at equal 2 2
temperature T. If the piston is stationary, its mass,
m will be given by : B
(R is universal gas constant and g is the 7

(1) F
acceleration due to gravity) 11
(2) 4F
nRT ⎡ I1 – I2 ⎤ nRT ⎡ 1 1⎤
(1) ⎢ ⎥ (2) ⎢  ⎥
g ⎣ I1 I2 ⎦ g ⎣ I2 I1 ⎦ 6
(3) F
5
RT ⎡ 2I1  I2 ⎤ RT ⎡ I1 – 3I 2 ⎤
(3) ⎢ ⎥ (4) ⎢ ⎥ 7
g ⎣ I1 I2 ⎦ ng ⎣ I1 I 2 ⎦ (4) F
10
2
7. The moment of inertia of a solid sphere, about an

C 2 2 axis parallel to its diameter and at a distance of x
Sol.
A from it, is ‘I(x)’. Which one of the graphs represents
2 the variation of I(x) with x correctly?
4
B
C 7/3 I(x)
A B
(1)
7 O x
C
3 1

7 2
C
3
I(x)
 14C = 3C + 7
(2)
7
 C= F
11 O x
5. The mean intensity of radiation on the surface of the
Sun is about 10 8 W/m 2 . The rms value of the
corresponding magnetic field is closet to: I(x)
(1) 102 T (2) 10–4 T
(3) 1 T (4) 10–2 T (3)
Answer (2) O x
B02 108
Sol. 
20 c I(x)
2  108  4  10 7
B0  (4)
3  108
B0 O x
Brms =
2
out of given option, option (2) is correct. Answer (3)
6. In a radioactive decay chain, the initial nucleus is Sol. I(x) = I0 + mx2

232
90 Th . At the end there are 6 -particles and Hence option (3) is correct.
particles which are emitted. If the end nucleus is 8. A simple harmonic motion is represented by :
A
ZX , A and Z are given by:
y  5(sin3t  3 cos3t )cm
(1) A = 200; Z = 81 (2) A = 202; Z = 80
The amplitude and time period of the motion are:
(3) A = 208; Z = 80 (4) A = 208; Z = 82
Answer (4) 2 2
(1) 10 cm, s (2) 5 cm, s
3 3
Sol. 232 – 6 × 4 = A
A = 208 3 3
(3) 10 cm, s (4) 5 cm, s
Z = 90 – 6 × 2 + 4 × 1 2 2
= 82 Answer (1)
3
 
10. When a certain photosensistive surface is illuminated
Sol. y  5 sin 3t  3 cos 3t with monochromatic light of frequency , the
V0
stopping potential for the photo current is – .
⎛ ⎞ 2
y  10 sin ⎜ 3t  ⎟ When the surface is illuminated by monochromatic
⎝ 3 ⎠

light of frequency , the stopping potential is –V0.
A = 10 cm 2
The threshold frequency for photoeletric emission is:
2
 3 3 4
T (1) (2) 
2 3
2
T  s 5
3 (3) (4) 2 
3
9. In the given circuit diagram, the currents, I1= – 0.3
A, I4 = 0.8 A and I5 = 0.4 A, are flowing as shown. Answer (1)
The currents I2, I3 and I6, respectively, are: Sol. 2h = 2 + eV0
h
P I6 Q    eV0
2
I3
3h 

2
I5 I2 I1
3
S I4 R 0 
2
11. A load of mass M kg is suspended from a steel wire
(1) 1.1 A, 0.4 A, 0.4 A
of length 2 m and radius 1.0 mm in Searle’s
(2) 1.1 A, – 0.4 A, 0.4 A apparatus experiment. The increase in length
produced in the wire is 4.0 mm. Now th load is fully
(3) 0.4 A, 1.1 A, 0.4 A
immersed in a liquid of relative density 2. The relative
(4) –0.4 A, 0.4 A, 1.1 A density of the material of load is 8.
Answer (1) The new value of increase in length of the steel wire
is:
Sol. At Node S
(1) 4.0 mm (2) zero
I4 = I3 + I5
(3) 5.0 mm (4) 3.0 mm
I4 = I3 + 0.4
Answer (4)
0.8 – 0.4 = I3, I3 = 0.4 A
Sol. Area of wire A = r 2
At Node R
Mg 
I1+ I2 = I4
2
 Y
r 0
– 0.3 + I2 = 0.8
Mg 4  10 3
I2 = 1.1 A  2
 ·Y ...(i)
r 2
at Node Q
8v00 = M
I3 + I6 = I1 + I2
Now when load is immersed in liquid then
0.4 + I6 = –0.3 + 1.1
8v 0 0 g  2v 0 0 g 
 Y ...(ii)
I6 = 0.4 A r 2 0
4
6v 0 0 g  If the whole set up is immersed in water without

 2
 Y
r 0 disturbing the object and the screen positions, what
will one observe on the screen?
 6v 0 0 g
3
 (1) Erect real image (2) No change
4  10 8v 0 0 g
(3) Image disappears (4) Magnified image
6
    4  10 3 m
8 Answer (3)
  = 3 × 10–3 m = 3 mm 1 ⎛3 ⎞2 ⎡ 3⎤
Sol.: Initially,  – 1⎟ ⎢ for glass  2 ⎥
12. A particle of mass 20 g is released with an initial f ⎜⎝ 2 ⎠R ⎣ ⎦
velocity 5 m/s along the curve from the point A, as
 f=R
shown in the figure. The point A is a height h from
point B. The particle slides along the frictionless Now for water w = 4/3
surface. When the particle reaches point B, its
angular momentum about O will be: 4 2 64R
  ⇒ f 
3f  6R 32
(Take g = 10 m/s2)
 f  = 4R = 4f
O
Now object in placed is between focus and lense, so
there will not be any real image on screen.
a = 10 m
14. A 10 m long horizontal wire extends from North East
to South West. It is falling with a speed of 5.0
A ms–1, at right angles to the horizontal component of
h = 10 m the earth’s magnetic field, of 0.3×10–4 Wb/m2. The
value of the induced emf in wire is:
B
(1) 1.1 × 10–3 V (2) 0.3 × 10–3 V
(1) 2 kg-m2/s (2) 3 kg-m2/s
(3) 2.5 × 10–3 V (4) 1.5 × 10–3 V
(3) 8 kg-m2/s (4) 6 kg-m2/s
Answer (1)
Answer (4)
Sol.
Sol.: L  mv0r –5 2
BH = 3 × 10 wb/m
1 1 45°
mv 02  mv i2  mgh
2 2
 v02 = 25 + 2 × 10 × 10 = 225
1
v0 = 15 m/s   vBl  5  3  105  10   1.06  103 volt
2
Now, L  20  10  15  20  6 kg-m s
–3 2 –1
  1.1 103 volt

13. Formation of real image using a biconvex lens is
shown below: 15. An alpha-particle of mass m suffers 1-dimensional
elastic collision with a nucleus at rest of unknown
mass. It is scattered directly backwards losing, 64%
of its initial kinetic energy. The mass of the nucleus
screen is:
2f
2f f f (1) 1.5 m (2) 3.5 m
(3) 4 m (4) 2 m
Answer (3)
5
6v0 1 3
v0 10 v1 Sol. 2  mg  mg ...(i)
M 2 2
Sol.
m
mg 3
 mg  10 ...(ii)
6mv 0 2 2
mv 0  Mv1 
10
 2 + mg = 10  mg = 8
16 mv 0
⇒  Mv1
10 3
From eq (i), 6    8 
2
Also vApp = vsep.
6 v0 4v 26
 v0   v1 ⇒ v1  0  
10 10 8 3
16 mv 0 4v 0
So  M ⇒ M 4m
10 10 3
 
16. To double the covering range of a TV transmission 2
tower, its height should be multiplied by:
18. A soap bubble, blown by a mechanical pump at the
(1) 2 (2) 2 mouth of a tube, increases in volume, with time, at
a constant rate. The graph that correctly depicts the
1 time dependence of pressure inside the bubble is
(3) (4) 4
2 given by:
Answer (4)
Sol. d  2hR P
 For d  to be 2d (1)
log(t)
2d 2h R
 ⇒ 4h  h
d 2h R
17. A block kept on a rough inclined plane, as shown in P

the figure, remains at rest upto a maximum force 2
(2)
N down the inclined plane. The maximum external
force up the inclined plane that does not move the 1
block is 10 N. The coefficient of static friction t
between the block and the plane is:
[Take g = 10 m/s2]
P
N
10 (3)
1
3
t
2 N 30°
1 3
(1) (2) P
2 2
(4)
3 2
(3) (4) t
4 3
Answer (2) Answer (No option is correct) [Bonus]
6
4S 5102
Sol. P  P0  2 x 2
R  y
2g 0
4S
 P  P0
R 162  25  104
 y  1.9 cm  2.0 cm
2  10
1/3
⎡ 4 ⎤
 P  4S ⎢ ⎥  P0 20. A plano-convex lens (focal length f2, refractive index
⎣ 3v ⎦
2 , radius of curvature R) fits exactly into a plano-
concave lens(focal length f1, refractive index 1,
1/3
⎡ 4 ⎤ radius of curvature R). Their plane surfaces are
P  4S ⎢ ⎥  P0
⎣ 3kt ⎦ parallel to each other. Then, the focal length of the
combination will be:
4 R
Also v  R 3
3 (1) f1 – f2 (2)  – 
2 1
1/3
⎡ 3v ⎤ 2 f1 f2
 ⎢ 4 ⎥ R (3) f  f (4) f1 + f2
⎣ ⎦ 1 2
Given v = kt Answer (2)
Sol. For plano convex lens

⎛ 1 ⎞
Correct form: P  m ⎜ 1/3 ⎟  c 1 2  1
⎝t ⎠ 
f2 R ...(i)
19. A long cylindrical vessel is half filled with a liquid.
When the vessel is rotated about its own vertical For plano – concave lens
axis, the liquid rises up near the wall. If the radius
1 ⎡   1⎤
of vessel is 5 cm and its rotational speed is 2  ⎢ 1 ⎥ ...(ii)
f1 ⎣ R ⎦
rotations per second, then the difference in the
heights between the centre and the sides, in cm, will
be:
(1) 1.2 (2) 0.1
(3) 0.4 (4) 2.0
Answer (4)
Now for combination
Sol.
2 1 2  1
 
v1  
1 2 2  1
 
v '1 v1 R
 2
1 1 1  1
 = 4 rad/sec x  
f v '1 
dy 2 x
1 (2  1) 1 1
  
tan    g f R f1 f2
dx g
h x
2 x R
⇒ ∫ dy  ∫ g
 dx
 f   
0 0 2 1
7
21. In a Frank-Hertz experiment, an electron of energy

V
5.6 eV passes through mercury vapour and emerges Sol. t 
with an energy 0.7 eV. The minimum wavelength of T
photons emitted by mercury atoms is close to
T
(1) 1700 nm (2) 2020 nm V
P
(3) 250 nm (4) 220 nm
Answer (3) T
t
P
Sol. Energy lost by electron = 5.6 – 0.7 = 4.9 eV
hc t1 5 1
 4.9    6  108
min t2 3 2
1240 = 3.87 × 10–8 s

⇒  min   250 nm
4.9
24. I2
22. Two satellites, A and B, have masses m and 2 m
C R2
respectively. A is in a circular orbit of radius R, and
B is in a circular orbit of radius 2 R around the earth. L R1 I1
TA
The ratio of their kinetic energies, is
TB ~
1
(1) 1 (2)
2 3
In the above circuit, C  F, R 2 = 20 ,
2
1
(3) 2 (4)
2 3
L H and R1 = 10 . Current in L-R1 path is
Answer (1) 10
I1 and in C–R2 path it is I2. The voltage of A.C
2 source is given by
V GM
Sol.  2
r r
V  200 2 sin(100 t ) volts. The phase difference
2 GM between I1 and I2 is
 V 
r
1
mVA2 2 (1) 0° (2) 60°
TA 2 1 ⎛ VA ⎞ 1 RB
  ⎜ ⎟  1
TB 1 2 V
⎝ B⎠ 2 RA (3) 30° (4) 90°
2mVB2
2
Answer (No option is correct) [Bonus]
23. An ideal gas is enclosed in a cylinder at pressure of
2 atm and temperature, 300 K. The mean time 1 1 2 20
Sol. XC    106  kΩ
between two successive collisions is 6 × 10–8 s. If C 100  3 3
the pressure is doubled and temperature is
increased to 500 K, the mean time between two
X C  L  10 3 
successive collisions will be close to
(1) 2 × 10–7 s (2) 3 × 10–6 s As XC >> R2, I2 leads V by 90°.
(3) 0.5 × 10–8 s (4) 4 × 10–8 s I1 lags V by 60°
Answer (4)  Phase difference between I1 and I2 150°.
8
25. A paramagnetic material has 1028 atoms/m3. Its dq

magnetic susceptibility at temperature 350 K is 2.8 Sol. I  = slope of q – t graph.
dt
× 10–4. Its susceptibility at 300 K is
28. A parallel plate capacitor with plates of area 1 m2
(1) 3.726 × 10–4 (2) 3.672 × 10–4 each, are at a separation of 0.1 m. If the electric
field between the plates is 100 N/C, the magnitude
(3) 2.672 × 10–4 (4) 3.267 × 10–4
of charge on each plate is:
Answer (4)
⎛ –12 C2 ⎞
1 ⎜⎜ TakeE0  8 .85  10 ⎟
Sol.   ⎝ N – m2 ⎟⎠
T
1T1 = 2T2 (1) 8.85 × 10–10 C
(2) 9.85 × 10–10 C

2.8  350
2   104 = 3.267 × 10–4
300 (3) 6.85 × 10–10 C
26. Let I, r, c and  represent inductance, resistance, (4) 7.85 × 10–10 C
capacitance and voltage, respectively. The dimension
Answer (1)
1
of in SI units will be
rcv
 Q
Sol. E    A
(1) [A–1] (2) [LA–2] 0 0
(3) [LT2] (4) [LTA]

Q = EA0 = 100 × 1 × 8.85 × 10–12 C
Answer (1)
= 8.85 × 10–10 C
⎡ l ⎤ ⎡ l ⎤ 29. Two particles A, B are moving on two concentric

Sol. ⎢ ⎥⎢ ⎥
⎣ rcv ⎦ ⎣TV ⎦ circles of radii R1 and R2 with equal angular speed
. At t = 0, their positions and direction of motion
[ML2T–2] = [lA2] are shown in the figure
 [l] = [ML2T–2 A–2] Y
ML2T 2
V   AT
 ML2T 3 A1
A
⎡ l ⎤ ML2T 2 A2
 
⎢ rcv ⎥ T ML2T 3 A1 = [A–1]
⎣ ⎦ R1 X
27. The charge on a capacitor plate in a circuit, as a B

R2
function of time, is shown in the figure
6
5
q(C) 4 
The relative velocity v A – v B at t  is given by
3 2
2
0 (1) (R2 – R1 )i
2 4 6 8
t(s)
(2) (R1 – R2 )i
What is the value of current at t = 4 s?
(3) – (R1  R2 )i
(1) 2 A (2) zero
(3) 3 A (4) 1.5 A (4) (R1  R2 )i

9
(1) 322 ms–1 (2) 341 ms–1

 
Sol.  t   
2 2 (3) 328 ms–1 (4) 335 ms–1
Answer (3)
VA  R1( iˆ)
1
 l 0  11
VB  R2 (– iˆ) Sol.
4

VA  VB   R2  R1  iˆ 2
 l 0  27
4
30. A resonance tube is old and has jagged end. It is
still used in the laboratory to determine velocity of
 2  1
sound in air. A tuning fork of frequency 512 Hz  16 cm
4
produces first resonance when the tube is filled with
water to a mark 11 cm below a reference mark, near
the open end of the tube. The experiment is repeated ⎡ 1 1 ⎤
⇒ V⎢  ⎥  0.64 m
with another fork of frequency 256 Hz which ⎣ 256 512 ⎦
produces first resonance when water reaches a mark
27 cm below the reference mark. The velocity of  V = 512 × 0.64 m/s
sound in air, obtained in the experiment, is close to = 328 m/s

10
CHEMISTRY
1. An open vessel at 27°C is heated until two fifth of Sol. According to Hess’s law, the enthalpy change of a
the air (assumed as an ideal gas) in it has escaped reaction does not depend on the number of steps
from the vessel. Assuming that the volume of the involved in the reaction.
vessel remains constant, the temperature at which
the vessel has been heated is 1
C(graphite) + O (g)  CO (g)H1° = y kJ mol–1
(1) 750 °C 2 2
(2) 750 K
1
(3) 500 °C CO(g) + O (g)  CO2(g)H2° = z kJ mol–1
2 2
(4) 500 K
____________________________________
Answer (4)
C(graphite)+O2(g) °H3 = x kJ mol–1
Sol. Initial number of moles of an ideal gas = n1
∵ H3° = H1°+ H2°
Find number of moles of the ideal gas
x = y + z
2n1 3n1
= n2 = n1 –  ** in reaction ii, Product should be CO (gas) instead
5 5
of CO2 (gas).
At constant volume and pressure, the number of
3. The increasing order of the reactivity of the following
moles of an ideal gas is inversely proportional to
with LiAlH4 is
temperature
O
1
n
T (A) C2H5 NH2
n1T1= n2T2
O
n1 5
T2 = T1 = × 300 = 500 K (B) C2H5 OCH3
n2 3
2. Given O
(i) C (graphite) + O2(g) CO2(g); (C) C2H5 Cl

–1
rH = x kJ mol
–
O O
1
(ii) C (graphite) + 2 O2(g) CO2(g);
(D) C2H5 O C2H5
–1
rH = y kJ mol
–
(1) (A) < (B) < (C) < (D)

1
(iii) CO(g) +
2 O2(g) CO2(g); (2) (B) < (A) < (D) < (C)
–1
rH – = z kJ mol (3) (A) < (B) < (D) < (C)
Based on the above thermochemical equations, find (4) (B) < (A) < (C) < (D)
out which one of the following algebraic relationships
Answer (3)
is correct?
(1) x = y – z Sol. The reactivity order of carboxylic acid derivatives
depends on the leaving tendency of the leaving
(2) x = y + z
group. Higher the leaving tendency of the leaving
(3) y = 2z – x group, higher will be the reactivity of the compound.
(4) z = x + y Therefore, reactivity order towards LiAlH4 is
Answer (2) Acid halide > Acid anhydride > Ester > Amide
11
4. Among the following, the false statement is 6. The magnetic moment of an octahedral homoleptic
(1) Tyndall effect can be used to distinguish Mn(II) complex is 5.9 BM. The suitable ligand for this
between a colloidal solution and a true solution. complex is
(2) Latex is a colloidal solution of rubber particles (1) CO (2) Ethylenediamine

which are positively charged (3) NCS– (4) CN–
(3) Lyophilic sol can be coagulated by adding an Answer (3)
electrolyte.
Sol. Electronic configuration of Mn2+ is
(4) It is possible to cause artificial rain by throwing
electrified sand carrying charge opposite to the Mn+2 : 3d5
one on clouds from an aeroplane. It has 5 unpaired electrons which corresponds to
Answer (2)
magnetic moment of 35 = 5.9 BM. This shows that
Sol. Latex is colloidal solution of rubber particles which the homoleptic complex of Mn2+ has only weak field
are negatively charged. ligands and that is NCS –. The remaining three
5. The major product of the following reaction is ligands are strong field ligands.
CH2CH3 7. The major product of the following reaction is
O
NaOEt
H3C C Cl 


NaBH4

EtOH

COOCH2CH3
CH3CH2C= CH2 O OH
(1)
CO2CH2CH3 (1) (2)
OCH2CH3
OH
(2) H3C H2C C CO2CH2 CH3 OH
(3) (4)
CH3 OEt
CH2CH3
Answer (2)
H3C OCH2CH3 O OH
C
(3) Sol. NaBH

Et O H
4

COOCH2CH3
CO2CH 2CH 3 NaBH4 does not reduces the double bond in -
(4) unsaturated aldehydes/ ketones.
CH 3C = CHCH 3
Only the keto group will be reduced.
Answer (4)
8. If Ksp of Ag2CO3 is 8 × 10–12, the molar solubility of
Sol. High temperature and strong base favours
Ag2CO3 in 0.1 M AgNO3 is
elimination reaction forming more stable alkene
according to Saytzeff rule. (1) 8 × 10–11 M
(2) 8 × 10–12 M
H — CH — CH3 CH — CH3
–
(3) 8 × 10–13 M
C2 H5O + H3C — C — Cl H3 C — C
(4) 8 × 10–10 M
COOC2H5 COOC2 H5
Answer (4)
12
 
Sol. AgNO3  Ag  NO3
0.1 0.1
Sol.


2Ag 
Ag2 CO3 CO32
0.1 2 x x
 0.1
K sp  [Ag ]2 [CO32 ]
= (0.1)2 x = 8 × 10–12 11. The aldehydes which will not form Grignard product
with one equivalent Grignard reagent are
0.01 x = 8 × 10–12
CHO
x = 8 × 10–10 M (A)

9. m  for NaCl, HCl and NaA are 126.4, 425.9 and CHO
100.5 S cm2mol–1, respectively. If the conductivity of
0.001 M HA is 5 × 10 –5 S cm –1 , degree of (B) HO2C
dissociation of HA is
CHO
(1) 0.25
(C) H3CO
(2) 0.125
CHO
(3) 0.50
(4) 0.75 (D) HOH2C
Answer (2) (1) (B), (C) (2) (B), (D)
Sol. °m (NaCl) = 126.4 S cm2 mol–1 (3) (B), (C), (D) (4) (C), (D)
°m (HCl) = 425.9 S cm2 mol–1 Answer (2)
°m (NaA) = 100.5 S cm2 mol–1 Sol. Grignard reagent will not react with aldehydes if it
has a functional group which contains acidic
°m (HA) = 425.9 – 126.4 + 100.5 = 400 S cm2 mol–1 hydrogen. Options (B) and (D) have —COOH and —
K(HA) = 5 × 10–5 S cm–1 CH2OH respectively which contan acidic H-atom.
12. For a reaction, consider the plot of In k versus 1/T
c K  1000 5  10–5  1000
 m=   50 given in the figure. If the rate constant of this
Molarity 0.001 reaction at 400 K is 10–5 s–1, then the rate constant
at 500 K is
cm 50
=   0.125
m 400
CH3CH2CHCH2 (i) KOH alc.

In k Slope = – 4606 K
(ii) NaNH2
Br Br in liq NH3
(1) CH3CH2C  CH 1/T
(2) CH3CH = CHCH2NH2

(1) 4 × 10–4 s–1
(3) CH3CH2CH – CH2 (2) 10–6 s–1
NH2 NH2 (3) 2 × 10–4 s–1
(4) CH3CH = C = CH2 (4) 10–4 s–1

13
Ea
Sol. ln K  ln A 
RT
NH2 NaNO2
CH3 O
Sol. C H
+
E
Slope  a  4606 K
R O OH
OH
⎛ K ⎞ E ⎛ T  T1 ⎞
ln ⎜ 2 ⎟  a ⎜ 2 CrO3/H
+
⎝ K1 ⎠ R ⎝ T1T2 ⎟⎠
OH
OH
4606 100
= H 2SO 4(conc.)/
400  500
= 2.303 HO O
O
⎛ K2 ⎞
 log ⎜ K ⎟  1
⎝ 1⎠
14. The compound that is NOT a common component of
K2 photochemical smog is:
 10
K1
(1) H3C – C – OONO2
 K2 = 10K1 = 10–5 × 10 = 10–4 S–1 O
(2) CH2 = CHCHO
H3C O (3) CF2Cl2

NH2
O (4) O3
Answer (3)
+
(i) NaNO2/H Sol. CF 2 Cl 2 is not a common component of
+
(ii) CrO3/H photochemical smog.
(iii) H2SO4 (conc.),
15. The major product in the following conversion is
HO
(1) CH3O CH = CH – CH3 HBr (excess)
Heat ?
O
CH3 O (1) HO CH2 – CH – CH3

(2)
O Br
O
(2) CH3O CH2 – CH – CH3

O
Br
HO
(3)
(3) HO CH – CH2 – CH3
Br
O
CH3 O
(4)
(4) CH 3O CH – CH 2 – CH 3
O
Br

14
(Given that K f = 5 K kg mol –1 , Molar mass of

HBr benzoic acid = 122 g mol–1)
Sol. CH3O CH == CH — CH3
Excess (1) 1.5 g
(2) 2.4 g
HO CH — CH2 — CH3 (3) 1.8 g
Br (4) 1.0 g
Answer (2)
16. The major product of the following reaction is Sol. 2C6H5COOH  (C6H5COOH)2
H3C t=0 1 0
CH2 HCl t 1 – 2 
H Moles at equilibrium = 1 – 2 +  = 1 – 
2 = 0.8,  = 0.4
CH3
Moles at equilibrium = 0.6
CH2– Cl
(1) i = 0.6
H
⎛ w ⎞
 1000
CH3 Tf = ikfm  2 = 0.6 × 5 × ⎜ 122 ⎟
⎜ ⎟
CH3 ⎝ 30 ⎠
(2) H
w = 2.4 g
Cl
18. Chlorine on reaction with hot and concentrated
CH3 sodium hydroxide gives
CH3 (1) Cl– and ClO–
(3) Cl
H (2) Cl– and ClO2–
(3) ClO3– and ClO2–
CH2– Cl
CH3 (4) Cl– and ClO3–
(4)
H Answer (4)
Sol. 3Cl2 + 6NaOH  5NaCl + NaClO3 + 3H2O
Answer (3)
19. The correct statement(s) among I to III with respect
to potassium ions that are abundant within the cell
CH3 fluids is/are
CH3
CH2
+
I. They activate many enzymes
Sol. C
HCl II. They participate in the oxidation of glucose to
CH3 produce ATP
III. Along with sodium ions, they are responsible for
Cl–
the transmission of nerve signals
CH3
(1) I and III only
C Cl
(2) I, II and III
CH3 (3) III only
(4) I and II only
17. Molecules of benzoic acid (C6H5COOH) dimerise in Answer (2)
benzene. ‘w’ g of the acid dissolved in 30 g of
benzene shows a depression in freezing point equal Sol. K + ions act as carriers for nerve signals, are
to 2 K. If the percentage association of the acid to activators for many enzymes and participate in the
form dimer in the solution is 80, then w is oxidation of glucose to form ATP.
15
20. If the de Broglie wavelength of the electron in nth 24. The two monomers for the synthesis of nylon 6, 6
Bohr orbit in a hydrogenic atom is equal to 1.5 a0 are
(a0 is Bohr radius), then the value of n/z is
(1) HOOC(CH2)6COOH, H2N(CH2)4NH2
(1) 0.40 (2) 1.50
(2) HOOC(CH2)6COOH, H2N(CH2)6NH
(3) 0.75 (4) 1.0
Answer (3)
Sol. n = 2r
Answer (3)
2
n Sol. Monomer of Nylon–6, 6 are adipic acid and
r  a0
z hexamethylene diammine.
2a0n2 25. The pair that does NOT require calcination is

n 
z (1) Fe2O3 and CaCO3 · MgCO3
2a0n2 (2) ZnCO3 and CaO


z (3) ZnO and MgO
n (4) ZnO and Fe2O3 · xH2O
1.5a0  2a0
2 Answer (3)
n 3 Sol. ZnO and MgO
  0.75
z 4
They are oxides while other are carbonates or
21. The volume strength of 1M H2O2 is hydrated oxides which require calcination.
(Molar mass of H2O2 = 34 g mol–1) 26. The upper stratosphere consisting of the ozone layer
(1) 11.35 protects us from the sun’s radiation that falls in the
wavelength region of
(2) 22.4
(1) 200 – 315 nm (2) 600 – 750 nm
(3) 5.6
(3) 400 – 550 nm (4) 0.8 – 1.5 nm
(4) 16.8
Answer (1)
Answer (1)
Sol. Ozone layer protects from ultra violet radiation.
Sol. Volume strength  11.2 × M
 Wavelength range lies in 200 – 315 nm
 11.2
27. The combination of plots which does not represent
22. The correct order of atomic radii is
isothermal expansion of an ideal gas is
(1) Ce > Eu > Ho > N (2) N > Ce > Eu > Ho
(3) Eu > Ce > Ho > N (4) Ho > N > Eu > Ce
Answer (3) P P
Sol. Atomic radii follows the order

O 1/Vm O Vm
Eu > Ce > Ho > N
(A) (B)
199 pm 183 pm 176 pm 70 pm
PVm
23. The element that does NOT show catenation is
U
(1) Sn
(2) Ge
O P O Vm
(3) Pb (C) (D)
(4) Si (1) (A) and (C) (2) (A) and (D)
Answer (3) (3) (B) and (C) (4) (B) and (D)
Sol. Lead Pb Answer (4)
16
Sol. (B) and (D) are not correct representation for Sol. Carbon has small size so effective, lateral overlapping
isothermal expansion of ideal gas. between 2p and 2p.
28. 8 g of NaOH is dissolved in 18 g of H2O. Mole 30. The correct structure of histidine in a strongly acidic
fraction of NaOH in solution and molality (in mol solution (pH = 2) is
kg–1) of the solution respectively are
(1) 0.2, 22.20 + –
+ H3N – CH – COO
H3N – CH – COOH
(2) 0.167, 22.20
+ NH
(3) 0.167, 11.11 NH2
(1) (2)
(4) 0.2, 11.11 N+
N H
Answer (3)
1 +
n2 5 + – H3N – CH – COOH
Sol. Mole faction    0.167 H3N – CH – COO
n2  n1 1  1
+ NH
5 NH2
(3) (4)
N+
8 18 N H
n2  n1 
40 18
Answer (4)
8 1000 Sol. Histidine (in strongly acidic solution)
Molality =   11.11m
40 18
29. The element that shows greater ability of form COOH

+
p – p multiple bonds, is H3N – CH
(1) Sn
CH2
(2) Si
(3) Ge NH
+
(4) C N
Answer (4) H

17
MATHEMATICS
1. In a class of 60 students, 40 opted for NCC, 30 3. If the angle of elevation of a cloud from a point P
opted for NSS and 20 opted for both NCC and NSS. which is 25 m above a lake be 30° and the angle of
If one of these students is selected at random, then depression of reflection of the cloud in the lake from
the probability that the student selected has opted P be 60°, then the height of the cloud (in meters)
neither of NCC nor for NSS is from the surface of the lake is
5 1 (1) 45 (2) 50
(1) (2)
6 3 (3) 42 (4) 60
Answer (2)
1 2
(3) (4) Sol. Let height of the cloud from the surface of the lane
6 3
is h meters.
Answer (3)
Sol. A = Set of students who opted for NCC
R
B = Set of Students who opted for NSS
n(A) = 40, n(B) = 30, n(AB) = 20 (h – 25) m
n(AB) = n(A) + n(B) – n(AB)
30°
P
= 40 + 30 – 20
25 m 60° Q 25 m
= 50 Lake
h
50 1
 Required probability = 1  
60 6 R

2. Let a, b and c be three unit vectors, out of which
 In PQR :
vectors b and c are non-parallel. If  and  are the

angles which vector a makes with vectors b and c tan 30° = h  25
1 PQ
 2

respectively and a  b × c  b , the | – | is  PQ = (h – 25) 3 ...(1)
equal to
and in PQR: tan 60° = h  25
(1) 90° (2) 45° PQ
(3) 30° (4) 60° h  25
PQ  ...(2)
Answer (3) 3
Sol. ∵ a  b  c 1 From Eq. (1) and (2),
1 h  25
Now a  (b  c )  b (h  25) 3 
2 3
1  h = 50 m
(a  c )b  (a  b )c  b
2 4. The tangent to the curve y = x 2 – 5x + 5, parallel to
1 the line 2y = 4x + 1, also passes through the point
 a c  and a  b  0
2
⎛ 1 7⎞ ⎛1 ⎞
(1) ⎜ , ⎟ (2) ⎜ , – 7 ⎟
1 ⎝ 4 2⎠ ⎝8 ⎠
a c cos   and  = 90°
2
⎛7 1⎞ ⎛ 1 ⎞
(3) ⎜ , ⎟ (4) ⎜ – , 7 ⎟
 = 60° ⎝2 4⎠ ⎝ 8 ⎠
 |  –  | = | 90° – 60° | = 30°
Answer (2)
18
Sol. ∵ Tangent is parallel to line 2y = 4x + 1 6. In a game, a man wins Rs. 100 if he gets 5 or 6 on
Let equation of tangent be y = 2x + c ...(1) a throw of a fair die and loses Rs. 50 for getting any
other number on the die. If he decides to throw the
Now line (1) and curve y = x2 – 5x + 5 has only one die either till he gets a five or a six or to a maximum
point of intersection. of three throws, then his expected gain/loss
 2x + c = x2 – 5x + 5 (in rupees) is
x2 – 7x + (5 – c) = 0 400
(1) gain (2) 0
 D = 49 – 4(5 – c) = 0 3
400 400
29 (3) loss (4) loss
 c=  9 3
4
Answer (2)
29
 Equation of tangent: y = 2x – 2 1
4 Sol. Probability of getting 5 or 6 = P(E) = 
6 3
1 2
⎡ 1 sin  1 ⎤ Probability of not getting 5 or 6 = P(E) = 1– 
⎢ 3 3
5. If A  ⎢ – sin  1 sin ⎥⎥ ; then for all E will consider as success.
⎢⎣ –1 – sin  1 ⎥⎦
Event Success in Success in Success in No success
Ist attempt IInd attempt 3rd attempt in 3 attempt
⎛ 3 5 ⎞ Probability 1 2 1 2 2 1 2 2 2
⎜ , ⎟ , det (A) lies in the interval:     
⎝ 4 4 ⎠ 3 3 3 3 3 3 3 3 3
Gain/loss 100 50 0 –150
⎛ 5⎤ ⎛ 3⎤ His expected gain/loss
(1) ⎜ 1, ⎥ (2) ⎜ 0, ⎥
⎝ 2⎦ ⎝ 2⎦
1 2 8
=  100   50    –150 
⎡5 ⎞ ⎛3 ⎤ 3 9 27
(3) ⎢ , 4 ⎟ (4) ⎜ , 3 ⎥
⎣2 ⎠ ⎝2 ⎦
900  300 – 1200
=
Answer (4) 27
=0
1 sin  1
A   sin  1 sin 
7. If a curve passes through the point (1, –2) and has
Sol.
slope of the tangent at any point (x, y) on it as
1  sin  1
x 2 – 2y
, then the curve also passes through the
x
0 0 2
point
=  sin  1 sin  R1  R1  R3
1  sin  1 (1) (–1, 2) (2)  3, 0 
= 2(sin2 + 1)
(3) (3, 0) (4) – 2, 1 
3 5 ⎞
as   ⎛⎜ , ⎟ Answer (2)
⎝ 4 4 ⎠
Sol.
⎛ 1⎞
2
 sin   ⎜ 0, ⎟ dy x 2 – 2y
⎝ 2⎠ ∵ 
dx x
 det(A)  [2, 3) dy 2
 yx
dx x
3 ⎤
2, 3   ⎛⎜ , 3⎥ 2
∫ x dx
⎝2 ⎦ I.F. = e  e2ln x  x 2
19
Solution of equation
⎧⎪⎛ x ⎞2 x ⎛ e ⎞ x ⎫⎪
e
9. The integral ∫ ⎨⎜ ⎟ – ⎜ ⎟ ⎬ loge x dx is equal to
y  x 2  ∫ x  x 2dx 1⎪ ⎩⎝ e ⎠ ⎝ x ⎠ ⎪⎭
x4
x2y  C 3 1 1 1 1
4 (1) –e– 2 (2) –  –
2 2e 2 e 2e 2
This curve passes through point (1, –2)
9 1 1 3 1 1
 C (3) –e– 2 (4) – –
4 2 e 2 e 2e 2
x2 9
 equation of curve : y  – Answer (1)
4 4x 2
clearly it passes through  3, 0  Sol. I 

e⎧
∫1
⎪⎛
⎨⎜ ⎟
x⎞
2x
⎛e⎞
⎜ ⎟
x⎫
⎪
⎬ loge xdx
⎪⎩⎝ e ⎠ ⎝x⎠ ⎪⎭
8. If sin4   4cos4   2  4 2 sin  cos  ; ,  [0, ],
x
then cos( + ) – cos ( – ) is equal to ⎛x⎞
Let ⎜ ⎟  t
⎝e⎠
(1) 2 (2) – 2
(3) –1 (4) 0 ⎛x⎞

 x ln ⎜ ⎟  ln t
Answer (2) ⎝e⎠
Sol.
 x  ln x  1  ln t
4 4
∵ sin   4cos   2  4 2 On differentiating both sides w.r.t x we get.
sin   cos , ,   0,  dt

ln x  dx 
t
By A.M., G.M. ineqality;
1 1⎛ 2 1 ⎞ dt 1⎛ 1⎞
sin4   4cos4  1  1

 sin4   4cos4  1 1 4 
I ∫1 ⎜⎝ t  ⎟
t⎠ t
 ∫1 ⎜⎝ t  t 2 ⎟⎠ dt
e e
4
1
sin4   4cos4  1  1  4 2 sin   cos  ⎛ 2 ⎞
 ⎜ t  1⎟
⎝ 2 t ⎠1
When cos < 0 then inequality still holds but L.H.S. e
is positive than cos > 0
Here, L.H.S. = R.H.S ⎛1 ⎞ ⎛ 1 ⎞
 ⎜  1⎟  ⎜ 2  e ⎟
⎝ 2 ⎠ ⎝ 2e ⎠
1
 sin4 = 1 and cos4 
4 3 1
 e 2
2 2e
 
  and  
2 4 10. Let S and S be the foci of an ellipse and B be any
one of the extremities of its minor axis. If SBS is
 cos      – cos   –   a right angled triangle with right angle at B and area
(SBS) = 8 sq. units, then the length of a latus
⎛ ⎞ ⎛ ⎞ rectum of the ellipse is
 cos ⎜   ⎟ – cos ⎜ –  ⎟
⎝2 ⎠ ⎝2 ⎠
(1) 4 2 (2) 4
= –sin – sin
(3) 2 2 (4) 2

 –2sin  – 2 Answer (2)
4
20
Sol. (Slope of BS) × (Slope of BS) = –1  2 = e1+c = e·ec

y 2 x
 f(x) = e
B (o, b ) e
2 x
 f ’(x) = e
(–ae, o) e
x h(x) = f (f(x))
x S O S ( ae,o )
h (x) = f (f (x))·f  (x)
2 2 2
y h (1) = f (2)·f  (1) = e · · e = 4e
e e
b b  Option (3) is correct.

  1
ae ae 12. If the function f given by f (x) = x 3 – 3(a – 2)x 2 +
b2 = a2e2 (i) 3ax + 7, for some aR is increasing in (0, 1] and
decreasing in [1, 5), then a root of the equation,
∵ Area g SBS = 8
f ( x ) – 14
1  0 ( x  1) is:
  2ae  b  8 ( x – 1)2
2
b2 = 8 (ii) (1) –7 (2) 5
∵ a2e2 = 8 (3) 6 (4) 7

Answer (4)
b2
∵ e2  1  Sol. f(x) = x3 – 3 (a – 2) x2 + 3ax + 7, f(0) = 7
a2
a2e2 = a2 – b2
y f  (x) = 0 at x = 1
8 = a2 – 8
a2 = 16 (0, 7)
2b 2 2.8
 Length of latus rectum    4units
a 4
x
11. Let f be a differentiable function such that f (1) = 2 O(0, 0) x = 1
and f(x) = f(x) for all xR. If h(x) = f(f(x)), then h(1)
is equal to
(1) 2e (2) 2e 2  f (x) = 3x2 – 6(a – 2) x + 3a
(3) 4e (4) 4e 2 f (1) = 0
Answer (3)  1 – 2a + 4 + a = 0
Sol. f (x) = f(x)  a=5
f x f ( x )  14
1  0
f x ( x  1)2
f   x  dx
  dx x 3  9 x 2  15 x  7  14
f x  0
( x  1)2
 ln|f(x)| = x + c
f(x) = ± ex+c  x  12  x  7 
 0
∵ f(1) = 2  x  12
 f(x) = ex+c = ecex  x=7
21
13. There are m men and two women participating in a 16. The mean and the variance of five observations are
chess tournament. Each participant plays two 4 and 5.20, respectively. If three of the observations
are 3, 4 and 4; then the absolute value of the
games with every other participant. If the number of
difference of the other two observations, is
games played by the men between themselves
exceeds the number of games played between the (1) 5 (2) 7
men and the women by 84, then the value of m is (3) 3 (4) 1
(1) 9 (2) 7 Answer (2)
(3) 11 (4) 12 Sol. Let two observations are x1 and x2
Answer (4) x1  x2  3  4  4
 4
Sol. mC2 × 2 = mC1 · 2C1 × 2 + 84 5
 x1 + x2 = 9 ...(i)
m(m – 1) = 4m + 84
m2 – 5m – 84 = 0
Variance =
∑ xi 2  ( x )2
m2 – 12m – 7m – 84 = 0 N
m(m – 12) +7 (m – 12) = 0 9  16  16  x12  x22
5 · 20 =  16
m = 12, m=–7 5
∵ m>0
(21 · 20)5 = 41 + x12  x22
m = 12
14. Let Z be the set of integers. x12  x22 = 65 ...(ii)
2 From (i) and (ii);
If A = {x Z : 2(x + 2)(x – 5x + 6) = 1
} and
x1 = 8, x2 = 1
B = {xZ : –3 < 2x –1 < 9}, then the number of
subsets of the set A × B, is | x1 – x2 | = 7
(1) 215 (2) 212 17. Let S be the set of all real values of  such that a
plane passing through the points (–  2 , 1, 1),
(3) 218 (4) 210
(1, –2, 1) and (1, 1, – 2) also passes through the
Answer (1) point (–1, –1, 1). Then S is equal to
 3
2
Sol. 2( x  2)( x  5 x  6)
=1 (1) {1, –1} (2)
 (x + 2)(x – 2)(x – 3) = 0
x = –2, 2, 3 (3)  3, – 3  (4) {3, –3}
A = {–2, 2, 3}
Answer (3)
 n(A) = 3
Sol. P(–2, 1, 1), Q(1, –2, 1), R(1, 1, –2), S(–1, –1, 1)
B : –3 < 2x – 1 < 9 lie on same plane
–1 < x < 5 and x  Z
 B = {0, 1, 2, 3, 4} 1  2 2 0
2
n(B) = 5  2 1  0  0
2
n(A × B) = 3 × 5 = 15 2 2   1
 Number of subsets of A × B = 219

 (2 + 1)((1 – 2)2 – 4) = 0
15. The expression ~(~p  q) is logically equivalent to
 (3 – 2)(2 + 1) = 0
(1) p  q (2) p  ~ q
2 = 3
(3) ~ p  ~q (4) ~ p  q
Answer (3) =  3
Sol. ~ (~ p  Q)  ~ (p  q)  ~ p  ~ q S = {  3, 3}
22
z1 lies on a circle with centre C1(0, 0) and radius

x 1 y – 2 z – 3
18. If an angle between the line,   r1 = 9
2 1 –2
z2 lies on a circle with centre C2(3, 4) and radius
⎛2 2⎞ –1 r2 = 4
and the plane, x – 2y – kz = 3 is cos ⎜
⎜ 3 ⎟⎟
,
⎝ ⎠ Minimum value of | z1 – z2 | is zero at point of
then a value of k is contact (i.e. A)
 5
(1) (2)
5 3
5 3 C2
(3) – (4) – A
3 5 C1 (3, 4)
(0, 0)
Answer (2)
Sol. Let angle between line and plane is 
20. The number of integral values of m for which the

quadratic expression, (1 + 2m)x2 – 2(1 + 3m)x +
bn 4(1 + m), xR, is always positive, is:
sin  =
b  n (1) 8
(2) 3
(2iˆ  ˆj  2kˆ )  (iˆ  2 ˆj  Kkˆ ) (3) 6
=
2
9  1 4  K (4) 7
Answer (4)
2  2  2K Sol. Given quadratic expression
=
2
3 5K (1 + 2m)x2 – 2(1 + 3m)x + 4(1 + m), is positive for
all x  R, then
2K 1 + 2m > 0 ...(i)
=
3 5  K2 D<0
 4(1 + 3m)2 – 4(1 + 2m)4(1 + m) < 0
2 2 1
But cos =  sin =  1 + 9m2 + 6m – 4[1 + 2m2 + 3m] < 0
3 3
 m2 – 6m – 3 < 0
2K 1
2
 m  (3 – 2 3 , 3 + 2 3 )
3 5 K 3
4K2 = 5 + K2 1
 m> 
3K2 = 5 2
So m  (3 – 2 3 , 3 + 2 3 )
5
K= 
3 So integral values of m = {0, 1, 2, 3, 4, 5, 6}
19. Let z1 and z2 be two complex numbers satisfying Number of integral values of m = 7
|z1| = 9 and |z2 – 3 – 4i | = 4. Then the minimum 21. If nC4, nC5 and nC6 are in A.P., then n can be:
value of |z1 – z2| is
(1) 12
(1) 0 (2) 2 (2) 9
(3) 1 (4) 2 (3) 14
Answer (1) (4) 11
Sol. | z1 | = 9, | z2 – 3 – 4i | = 4 Answer (3)
23
Sol. 2 nC5  nC4  nC6

⎛ h2  k 2 ⎞
A⎜ , 0⎟
⎜ h ⎟
n
C4 n
C6 ⎝ ⎠
2 n
 n
C5 C5
⎛ h2  k 2 ⎞
B ⎜ 0, ⎟⎟
5 n5 ⎜ k
2  ⎝ ⎠
n4 6
AB = 2R
 12(n – 4) = 30 + n2 – 9n + 20
 AB 2 = 4R2
 n2 – 21n + 98 = 0
(n – 7) (n – 14) = 0 2 2
⎛ h2  k 2 ⎞ ⎛ h2  k 2 ⎞ 2
 ⎜⎜ ⎟⎟  ⎜⎜ ⎟⎟  4R
(n – 7) (n – 14) = 0
⎝ h ⎠ ⎝ k ⎠
n = 7, n = 14
 Locus is (x2 + y2)3 = 4R2 x2 y2
22. If a circle of radius R pases through the origin O and
intersects the coordinate axes at A and B, then the ⎛ n n n 1 ⎞
23. lim ⎜ 2 2  2  2  is equal
locus of the foot of perpendicular from O on AB is: n 
⎝ n 1 n  2
2
n 3 2
5n ⎟⎠
to:
(1) (x 2 + y 2)2 = 4Rx 2y 2
(1) /4 (2) tan–1(3)
(2) (x 2 + y 2)2 = 4R 2x 2y 2
(3) tan–1(2) (4) /2
(3) (x 2 + y 2)3 = 4R 2x 2y 2
Answer (3)
(4) (x 2 + y 2)(x + y) = R 2xy
Answer (3) 2n
n
Sol. As AOB = 90°
Sol. I  nlim ∑ 2
 r2
r 1 n

2
dx r 1
 ∫ 1 x2 n
 x,  dx
r
0
B
2
(h, k)  ⎡⎣ tan1 x ⎤⎦
0
M
G = tan–12
3 x 13  2 x 11
O A
24. The integral 4 ∫ (2x
 3 x 2  1)4
dx is equal to
(where C is a constant of integration)
x4
(1) C
6(2 x  3 x 2  1)3
4
AB  Diameter
x 12
M(h, k) is foot of perpendicular (2) C
(2 x  3 x 2  1)3
4
h
M AB  x 12
k (3) C
6(2 x 4  3 x 2  1)3
h x4
Equation of AB  y  k   ( x  h) (4) C
k (2 x  3 x 2  1)3
4
 hx + ky = h2 + k2 Answer (3)
24
 coty = x – 2 tan
Sol. I  ∫ 3x13  2x11
dx
3 1⎞
4 x  y cot   2 tan 
16 ⎛
x ⎜2  2  4 ⎟
⎝ x x ⎠ 26. If a straight line passing through the point P(–3, 4)
is such that its intercepted portion between the
3 2 coordinate axes is bisected at P, then its equation
3
 5 is:
I∫ x x dx
4
⎛ 3 1 ⎞ (1) 3x – 4y + 25 = 0
⎜2  2  4 ⎟
⎝ x x ⎠
(2) 4x – 3y + 24 = 0
(3) x – y + 7 = 0
3 1 ⎛ 3 2 ⎞
Let 2    t , 2 ⎜ 3  5 ⎟ dx  dt
x2 x 4
⎝ x x ⎠ (4) 4x + 3y = 0
dt Answer (2)
 4 1
I∫ 2 1 t C Sol. P is mid point of AB
t4 2 4  1
B (0, y)
1 1 1
I  C
2  3  ⎛ 3 1 ⎞
3 P (–3, 4)
⎜2  2  4 ⎟ A (x, 0)
⎝ x x ⎠
1 x12
I C

6 2x 4  3 x 2  1 3
 So x = –3 × 2
25. The equation of a tangent to the parabola, x 2 = 8y, x = –6

which makes an angle  with the positive direction and y + 0 = 2 × 4
of x-axis, is:
y=8
(1) x = y cot  – 2tan 
Now equation AB is
(2) y = x tan + 2cot
(3) x = y cot  + 2tan  x y
 1
(4) y = x tan – 2cot 6 8
Answer (3)
 4 x  3 y  24  0
Sol. x2 = 8y
Equation of tangent at P  – 2sin–1 x
27. lim is equal to:
x 1
1– x
2
P (2at, at2) (1)



(2)
2
tx = y + at2 (3) 
y = tx – at2 1
(4)
t = tan 2
y = tanx – 2 tan2 Answer (1)
25
2
  2 sin1 x 27 ⎛ 15  16 ⎞
Sol. lim 225 K  
x 1 1 x 64 ⎜⎝ 2 ⎟⎠
K = 27
 lim f 1  h 
h 0
29. The total number of irrational terms in the binomial
 
1 1 60
expansion of 7 5
–3 10
is:
  2 sin 1  h 
1
 lim
h 0 1  1  h  (1) 48 (2) 49
(3) 54 (4) 55
  2 sin 1 1  h  Answer (3)

 lim
h 0 h 60  r r
⎛ 1⎞ ⎛ 1 ⎞
60
Sol. T 
r 1 Cr ⎜ 7 5 ⎟ ⎜ 310 ⎟
⎜ ⎟ ⎜ ⎟
1 1 ⎝ ⎠ ⎝ ⎠
 2  1 r r
2 2sin 1
1  h  1  1  h 
2
 Cr .  7 
60 12 
5  1r .  3 10
 lim
h 0 1
So for getting rational terms, r should be multiple of
2 h
L.C.M. of (5, 10)
1 1 So r can be 0, 10, 20, 30, 40, 50, 60.
2 sin1 1  h  h 2  h Now total number of terms = 61
 lim
h 0 1 Total irrational terms = 61 – 7 = 54
2 h 30. The set of all values of  for which the system of
linear equations
1 1 2
 2  
 2  x – 2y – 2z = x
x + 2y + z = y
28. if the sum of the first 15 terms of the series
3 3 3 3
–x – y =  z
⎛ 3⎞ ⎛ 1⎞ ⎛ 1⎞ ⎛ 3⎞
⎜⎝ ⎟⎠  ⎜⎝ 1 ⎟⎠  ⎜⎝ 2 ⎟⎠  3  ⎜⎝ 3 ⎟⎠  … is equal to
3
(has a non-trivial solution)
4 2 4 4
(1) Contains exactly two elements
225 k, then k is equal to:
(2) Contains more than two elements
(1) 108 (2) 27
(3) Is a singleton
(3) 9 (4) 54
(4) Is an empty set
Answer (2)
Answer (3)
3 3 3
⎛3⎞ ⎛3⎞ ⎛9⎞ Sol. x(1 –) – 2y – 2z = 0
Sol. S  ⎜ ⎟  ⎜ ⎟  ⎜ ⎟   3   ...
3
⎝4⎠ ⎝2⎠ ⎝4⎠ x + (2 – )y + z = 0

– x – y – z= 0
3 3 3 3
⎛ 3 ⎞ ⎛ 6 ⎞ ⎛ 9 ⎞ ⎛ 12 ⎞
S  ⎜ ⎟  ⎜ ⎟  ⎜ ⎟  ⎜ ⎟  ... for getting a non-trivial solution
⎝4⎠ ⎝4⎠ ⎝4⎠ ⎝ 4 ⎠
=0
3 1   2 2
⎛ 3r ⎞
Tr  ⎜ ⎟ 1 2 1  0
⎝ 4 ⎠
1 1 
15
⎛3⎞
3 15  (1 – )3 = 0
225 K  ∑Tr  ⎜ ⎟ ∑r 3
r 1 ⎝4⎠ r 1 = 1

26

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JEE MAIN 2019

ANSWER KEY & SOLUTIONS

Regd. Office : Aakash Tower, 8, Pusa Road, New Delhi-110005

2. The Test consists of 90 questions. The maximum marks are 360.

5. There is only one correct response for each question.

l cosec 60 l cot 60

60° (1) 22  (2) 25 

Sol.  i, let RG = R

(3) The wave is propagating along the negative x-axis

Sol. y(x, t) = 10–3 sin(50t + 2x)

mp (3) 0.25 m (4) 0.3 m

 AB  0  AB (1) 480  (2) 490 

(3) 495  (4) 395 

15. A passenger train of length 60 m travels at a speed

18. Two light identical springs of spring constant k are

19. A simple pendulum, made of a string of length l and 100 + 400

(1) 0.07 m1x1  m2 x2  m3 x3

5 13 24. A satellite of mass M is in a circular orbit of radius

(2) In a circular orbit of a different radius

Answer (3) (4) In the same circular orbit of radius R

Sol. Let assume linear mass dinsity is  Answer (3)

Solving (i) and (ii)

(2) 10 V/m (2) 70 cm from point B at right; real

1 Sol. For lens A

 Best combination is HCHO and MeOH

—O — CH — CH 2 — C — O — CH — CH 2 —C— (1) PhCOCH2CH3 + CH3MgX

CH 3 O CH 2— CH 3 O n (2) CH3CH2COCH3+ PhMgX

PHBV (3) HCHO+PhCH(CH3)CH2MgX

O OH 13. The standard electrode potential E

3. H C H + PhCH(CH3)CH 2MgX [Use R = 8 JK–1 mol–1 and F = 96,000 C mol–1]

12. Two solids dissociate as follows = – 2 × 96000 (2 + 0.15)

rH° = – 412.8 kJ/mol

14. Decomposition of X exhibits a rate constant of

(3) x + y atm (4) 2 ( x+y ) atm

Sol. Rate constant of decomposition of X = 0.05 g/year

[A] = 1, [B] = 1 Answer (4)

O (3) 3PA = 2PB (4) 2PA = 3PB

24. Among the following compounds most basic amino

(1) CH3O (2) CH3O 4 12

30. 50 mL of 0.5 M oxalic acid is needed to neutralize  M=2

2. A ratio of the 5th term from the beginning to the 5th

(3) 3 ∫ f ( x )dx (4) 2∫ f ( x )dx

2  0 150 225

8. If a variable line, 3x + 4y –  = 0 is such that the two

Conditon 2 : Perpendicular distance from centre on (2) 32

⎢⎣90 12 1 ⎥⎦ ⎢⎣ 9 3 1⎥⎦ ⎢⎣ 135 15 1⎥⎦ Answer (1)

= 31 (1  tan2 x )(1  tan x )(1  tan x )

P(4, –4) (3) –1 (4) 0

Answer (2) Hence A is a singleton set

Sol. Let roots are , . 21. If the straight line, 2x – 3y + 17 = 0 is perpendicular

Area = (2t) (12 – t2)

1 At t = 2, area is maximum = 24(2) – 2(2)3

(3) 20 2  6, 5 2  does not lie on (i)

(0, 12) (1) loge2x

Sol. (2x)2y = 4e2x–2y Sol. f(x) = min {sinx, cosx}

From (i) and (ii),

Regd. Office : Aakash Tower, 8, Pusa Road, New Delhi-110005

2. The Test consists of 90 questions. The maximum marks are 360.

5. There is only one correct response for each question.

IC Sol. (P2 – P1)A = mg

3. A galvanometer, whose resistance is 50 ohm, has 25

(R is universal gas constant and g is the 7

7. The moment of inertia of a solid sphere, about an