OCT CORRE a.

90 and 234
DAY 1 b. 90 nd 242
1. . c. 94 and 234
2. . d. 94 and 242
3. . 13. (picture) is what type of nuclear rxn?
4. . a. Bombardment (alpha bomb)
5. Related in what manner? (picture in paper) b. Decay
a. Isotopes c. Fission
b. Constitutional isomer d. Fusion
c. Same structure 14. A simple NaNO3 weighing 8.5g is placed in a
d. Composed of diff elements 500 mL vol. flask and distilled water was added
6. In the following rxn, how many H’s do you add to the mark on the neck of the flask. Molarity of
or lose? (picture in paper) the resulting soln?
a. Add a. 0.5 Molar NaNO3
b. Add 2 b. 0.35
c. Lose 1 c. 0.25
d. No change d. 0.2
7. Smallest number of carbon atoms possible in a 15. An analysis for disulfiram, C10H20N2S4, in
molecule of a ketone? Antabuse is carried out by oxidizing the sulfur to
a. 4 H2SO4 and titrating the H2SO4 with NaOH. If a
b. 3 0.4613-g sample of Antabuse is taken through
c. 2 this procedure, requiring 34.85 mL of 0.02500
d. 1 M NaOH to titrate the H2SO4, what is the %w/w
8. IUPAC name? (picture) disulfiram in the sample? 7%
a. 3-isopropyl-5-ethylheptane
b. 3.5-diethyl-2-methylheptane
c. 2-methyl-3-ethylheptane
d. 2-methyl-3,5-diethylheptane
9. Which is not a balanced NUCLEAR eqn (picture)
Be  Li + B
10. A sample of neptunium-234, with a half life of
4.40 days, is allowed to decay for 7.1 days.
What percent of the original sample remains?
a. 19.9%
b. 20.6
c. 32.7
d. 61.9
11. The measured mass of neutral Li-6 is 6.01512
amu. What is the mass defect of this isotope?
(picture)
a. 0.04947 16. A sample of an ore was analyzed for Cu2+ as
b. 0.03435 follows. A 1.25 gram sample of the ore was
c. 0.03038 dissolved in acid and diluted to volume in a 250-
d. 0.01512 mL volumetric flask. A 20 mL portion of the
12. In the nuclear eqn (picture) the letters Z and A resulting solution was transferred by pipet to a
are, respectively 50-mL volumetric flask and diluted to volume.
 An analysis of this solution gave the b. Are consumed in chm rxn
concentration of Cu2+ as 4.62 μg/L. What is the c. Are always stored in active form
weight percent of Cu in the original ore? 0.231% d. All of the above
24. Hydrolysis could be correctly described as the
________
a. Heating of a compound in order to drive
off its excess water and concentrate its
volume
b. Breaking of a long-chain compound into
its subunits by adding water molecules
to its structure between the subunits
c. Linking of two or more molecules by the
removal of one or more water
molecules
d. constant removal of hydrogen atoms
from the surface of a carbohydrate
17. Which of the following must be true about a e. Process of condensation in reverse (not
binary liquid mixture that obeys Raoult’s Law? included in paper)
I. The partial pressure of each component 25. -26. Given the ff balanced eqn, in a batch rxn
at eq. is proportional to its mole (picture) Given the reactor capacity of 100,000L,
fraction calculate the required glucose needed, if the
II. The volume of the mixture is equal to target yield concentration is (di ko mabasa..)
the sum of the volumes of each a. 13 020 kg
component before… b. 12 030
III. Intermolecular interactions in the c. 13 200
mixture are identical to intermolecular d. 12 300
interactions…. 26. Determine Y (mass yield of biomass per
a. I only substrate)
b. III only a. 0.384
c. I and III b. 0.843
d. I II III c. 0.348
18. . d. 0.4
19. . 27. Phospholipids can be found mainly on
20. . a. Cell wall
21. The phase diagram above shows the b. Cell membrane
composition of mixtures of component A and B c. Nervous sys
at diff. temp. d. Hormones
a. A B is initially added, 28. Which is wrong
22. Which of the following isomer of C6H12 a. Ozone is not responsible for
has the highest heat of combustion greenhouse effect
a. Cyclohexane b. Ozone can oxidize sulfur dioxide
b. Methylcyclopentane present in the atm to sulfur ….
c. Trans-2,20dimethylethylbutane? c. Ozone hole is thinning of ozone layer
d. …..propane present in stratosphere
23. Enzymes: d. Ozone is produced in upper
a. Increase the rate of chm rxn stratosphere by the action of …. Oxygen
 REAGENTS: HBr and ether?? (III. ben-OH & ben-
29. 11 000 CH3Br?)
36. Which of following statements best describes
the general reactivity of alkynes?
a. An alkyne reacts as a nucleophile, and
is therefore electron poor.
b. An alkyne reacts as an electrophile, and
is therefore electron poor.
c. An alkyne reacts as a nucleophile, and is
therefore electron rich.
d. Alkynes fail to undergo electrophilic
addition reactions, unlike alkenes.
e. An alkyne reacts as an electrophile, and
is therefore electron rich.
37. Distinguish 1-propanol from 2-propanol?
30. If the three-day BOD (BOD3) of a raw sewage is
a. Fehlings (aldehyde, reducing sugar)
55 (k=0.55 /day) what is the ultimate BOD?
b. Tollens (aldehyde, reducing sugar)
a. 68ppm
c. Benedicts (red from non sugar)
31. Assuming that the air is approximately 80%
d. Lucas
nitrogen and 20% oxygen by volume, which of
38. IUPAC name for isobutyl alcohol
the following is closest to the density of air at
a. 2 methyl 1 propanol
0C and 1 atm
b. 2 methyl 1 butanol
a. 0.01 g/L
c. 1 methyl 1 propanol
b. 0.1
d. 1,1 dimethyl 1 ethanol
c. 1
39. A very dilute solution is prepared by dissolving
d. 10
‘x1’ mole in ‘x2’ mole of a solvent. The mole
32. All of the following elements have at least one
fraction of solute is approximately equal to
isotope that is not radioactive EXCEPT
a. X1/x2
a. O
b. 1-(x1/x2)
b. Pb
c. X2/x1
c. Sn
d. a/x2
d. No
40. -41 A 0.2521g sample of an unkown weak acid is
(atomic # > 83 –all radioactive isotope
titrated with 0.1005 M NaOH, requiring
< 83 radioactive & non-radioactive)
42.68mL to reach the phenolphthalein end
33. Molecular geometry of IF5 is
point. Determine compounds equivalent weight
a. Square pyramidal
a. 48.42 g/eq
b. Trigonal planar
b. 58.78
c. Bent
c. 65.36
d. Octahedral
d. 74.43
34. Which of the ff structures contain a nitrile?
41. Which of the ff compounds is most likely to be
(picture) *(with RC≡N)
the unkown weak acid?
a. 1
a. Ascorbic (FW=176) monoprotic
b. 2
b. Malonic (104.1) di
c. 3
c. Succinic (118.1) di
d. 4
d. Citric (192.1) tri
35. Predict the pdt of the following rxn (picture)
42. 71.2 C

43. The normal boiling point of ethylene glycol

C2H6O2 is 197 C, its enthalpy of vap is 801
J/mol. Estimate the temperature at which
ethylene glycol will boil in a vacuum distillation
if the sys were maintained at 50 Torr.
a. 433 K
b. 278
c. 296
d. 387
44. Silver crystallization with a face-centered cubic
unit cell. The radius of a silver atom is 0.144 nm.
Calculate the density of solid silver. Ag (107.87)
a. 24.8 g/mL
b. 21.2
 c. 15.7 49. What was oxidized and what was reduced in the
d. 10.6 following rxn? 2Hg2+ + N2H4  2Hg + N2 +4H+
a. Hg2+ reduced: N2H4 oxidized
50. The first step of gene expression, in which a
particular segment of DNA is coded into mRNA
a. Replication
b. Transcription
c. Translation
d. None of the above
51. An enzyme is produced for manufacturing a sun
protection lotion. Given kinetic data for the
enzyme reaction with Vmax= 2.5mmol/m2 s K=
8.9 mM and…. What would be the time
required for 95% conversion in a batch
bioreactor?
a. 1.21 hrs
b. 2.31
c. 3.32
45. In a chemical rxn, equilibrium has been d. 4.23
established when the____ 52. The TDS of a certain sample is recorded as 890
a. Opposing rxn ceases mg/L and its electrical conductivity (EC)
b. Concentrations are equal amounted to 1025 mmohs/cm. Determine the
c. Rxn ceases to generate heat electrical conductivity of another sample which
d. Net velocities of rxn is zero has a TDS of 1450 mg/L. 1667 mmohs/cm
46. A solution containing 0.8 g of a protein in 100
mL of a solution has an osmotic pressure of 2.06
Torr at 25C. What is the molecular mass of the
protein 53. What is the saturation value of dissolved oxygen
a. 65 000 g/mol in a water containing 1000 mg/L of chloride ion
b. 72 000 with a temperature of 22 C at a pressure of 720
c. 83 000 mmHg?
d. 96 000 a. 6.55 mg/L
47. A 38g sample of ice at -11C is placed into 214g b. 7.35
of water at 56 C. Find the system’s final T. c. 8.25
a. 34.7 C d. 9.65
b. 42.5 54. Find the settling velocity of spherical discrete
c. 44.5 particles 0.05 mm in diameter, given that their
d. 51.2 SG is 2.6 settling in water at a temperature of
48. A galvanic cell cocnsists of a Mg electrode in a 20C
1M Mg(NO3)2 soln and a Ag electrode in a 1M a. 3.18 x10-3 m/s
AgNO3 soln. The standard reduction potentials b. 2.17 (2.18)
are (picture) E= 0.8V E= -2.36 V c. 1.37
a. 1.68 V? d. 4.43
b. 2.58 55. What is the electronic configuration of As (+3)
c. 3.17 (0.8+2.36) ion? [Ar} s2 d10 ??? Letter D?
d. 4.52
56. What is the equivalent mass of a metal if its 65. At what pressure does the boiling point of
chloride equivalent mass is 104.2 g/mole water become 300C? If oceanic pressure
a. 68.7 (104.2-35.45???) increases by 1atm for every 10m, to what depth
57. What is the major attraction between water does this pressure correspond? The enthalpy of
molecules in the solid physical state? vap of water is 44.03 kJ/mol
a. Dipole-dipole a. 241 atm, 2410m
b. Electrostatic interactions between b. 214 atm, 2140 m
charged atoms c. 142 atm, 1420m
c. H bonds d. 124 atm, 1240m
d. Physical entanglement of the molecules 66. Which of the ff is an n-type semiconductor?
58. What alkyl groups make up the following ether? a. Silicon
(picture) b. Si carbide
a. Ethyl and phenyl c. Galium-doped silicon (p type=3 GRP +)
b. Propyl and benzyl d. Arsenic doped silicon (n type=5 GRP +)
c. Ethyl and benzyl 67. If 0.9 mol of A and 1.6 mol of B are placed in a
d. Propyl and phenyl 1L vessel and allowed to achieve eq, 0.35 mol C
59. How many isomers does xylene have? is found. Determine the value of the eq
a. 1 constant Bakit walaaaaa hahaha
b. 2 a. 2.3
c. 3 b. 3.4
d. 4 c. 4.5
60. Which of the ff is a substitution reaction? d. 5.6
(picture) B 68. The decomposition of ethane (C2H6) to methyl
61. Structures represent (picture) diastereomers? radicals is a first order reaction with a rate
62. Dehydration of alcohol requires a ____ catalyst constant of 5.36 x10-4 1/s at 700 C (picture)
a. Strong acid a. 21.5 min ( ln2/5.36x10-4 )
b. Nickel b. 34.2
c. Platinum c. 45.3
d. Wilkinsons d. 54.1
63. A solution containing 0.8g of a protein in 100mL
of a solution has an osmotic pressure of 2.06
torr at 25 C, what is the molecular mass of
protein?
a. 65 000 g/mol
b. 72 000
c. 83 000
d. 96 000
64. A mole of electrons is transported across a
potential difference of 1 V from the positive
electrode to the negative electrode. How much
work is required?
a. 12 500 J
b. 65 750
c. 72 250
d. 96 500