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THERMAL PROPERTIES OF
PROPERTIES OF MATTER
MATTER
3. Measurement of Temperature:
SYNOPSIS
a) When a substance is heated, its various physical
THERMOMETRY
properties change. By measuring the changes
1. Heat : of the properties, the temperature of a body is
a) The energy transferred between two or more estimated relative to a fixed point.
systems by virtue of temperature difference is b) The change in volume of a liquid, the change in
called heat (or) The energy transferred by a pressure of a gas, the change in resistance of a
non mechanical method is heat metal wire, the change in vapour pressure, the
b) This energy may be transferred between the measurement of thermo emf and the
system and the surroundings. measurement of thermal radiations are some
physical properties used in the measurement of
c) The net flow of energy (Heat flow) is from a
temperature.
body at higher temperature to a body at lower
temperature. 4. Different scales of temperature:
d) The unit of heat is Joule. a) For liquid thermometers, If lo is the length of
e) Calorie is the unit of heat in CGS system. mercurous at 0°C, l100 is the length at 100°C
f) 4.186 Joule=1 Calorie, for all calculations it can and lt is the length at t° C then temperature ‘t’
be taken as 4.2 joule = 1 calorie.
2. Temperature:
(lt lo )
given by t x100C
(l100 lo )
a) Temperature is the quantity which determines
the direction of flow of heat energy. b) For constant pressure gas thermometers, If
b) The concept of temperature is given by Zeroth V0 , Vt and V100 be the respective volumes of a
law of thermodynamics, considering thermal gas in the thermometer at constant pressure
equilibrium. corresponding to temperatures 0°C, t°C and
100°C respectively, then
c) When two systems are in thermal equilibrium,
the temperature of the two systems is same. V V0
t t 100C
d) The degree of hotness of a body is its V100 V0
temperature and indicates the relative hotness
or coldness. c) For constant volume gas thermometers, If P0,
e) Temperature is a relative measure. Pt, and P100 be the pressures of a gas at
f) Hence a reference point is required for the constant volume corresponding to
representation of temperature. temperatures 0°C, t o C and 100°C
g) The melting point of ice at normal pressure respectively, then
and the boiling point of water at normal pressure P P0
are taken as the reference points called, ice point t t 100C
and steam point. P100 P0
h) Ice point is called lower fixed point and steam d) For resistance thermometers, If R0, Rt and R100
point is called upper fixed point. be the resistances of the platinum wire at
i) Now a days the triple point of water is taken as temperatures 0°C, t°C and 100°C respectively,
fixed point. then
j) The tripple point is the temperature at which
the three states of matter (ice, water, steam) R R0
t t 100C
coexist. R100 R 0
b) Silver Iodide, Silica glass, some Nickel Steel 17. Co-efficient of cubical or volume expansion of a
alloys, India rubber, castiron, type metal solid:
contract on heating v2 v1
10. Isotropic solids expand equally in all directions. a) v (t t ) b) S.I. unit : K–1
1 2 1
Eg : Metals, glass
18. Relation among ,, and (for isotopic solids)
11. Anisotropic solids do not expand equally in all
directions. a) : : = 1 : 2 : 3
Eg : Ice land spar [CaCO3], crystals 2
b) = 2 =
12. Solids have linear, areal and cubical expansions. 3
Hence solids have three coefficients of expansion 3
namely coefficient of lienar expansion , coefficient c) = 3 =
2
of areal expansion and coefficient of volume d) = 3 = + 2 = + .
expansion .
13. Co-efficient of linear expansion of a solid() 19. The numerical values of a, b & g are 5/9 times if
l2 l1 l Fahrenheit scale is used instead of Celsius scale
a) l (t t ) l (t)
1 2 1 1
33. In the above case, while mixing, if the external work maximum for H2 gas
done is zero and the energy of the system remain Thermal capcity :
constant then n1T1 +n2T 2 ..= (n1+n2+ . .)T where * The heat required to raise the temperature of a
n1, n2 . . . are the number of moles in those gases given substance by 10C is called its thermal capacity.
respectively. * Thermal capacity of a substance depends on its
mass and nature.
XIth Class (C.B.S.E) SRI CHAITANYA 7
Physics THERMAL PROPERTIES OF MATTER
Water - equivalent : * In case of substances like ice and rubber which
* Water - equivalent of a substance is the mass of contracts on melting VF < VI and hence VF – VI
water which when given same amount of heat as negative i.e melting point is lowered with increase
given to the substance, changes the temperature of in pressure.
water through same range as that of the substance. * Addition of imputities changes melting point, and
boiling point
* Water equivalent of a substance is expressed in
gm of water Triple point of water
* Triple point is a point in the phase diagram where a
Latent heat : The amount of heat required to change
solid, liquid and vapour can co -exit (or will be in
the state of unit mass of a substance at a constant
equilibrium)
temperature is called the latent heat.
* For water the values of pressure and temperature
* If 'Q' heat changes the state of mass 'm' of a corresponding to triple point are 4.58 mm of Hg
(0.006 atm) and 273.16K respectively.
substance at constant temperature, then latent heat
Note: The negative slope of Ice line shows that melting
Q point of Ice decreases with the increase of
L Q mL pressure.
m
* Latent heat depends on nature and state of Principle of method of mixtures :
substance * When two substances at different temperatures are
mixed, heat will be transferred from substance at
* The latent heat during melting or freezing is called
higher temperature to a substance at lower
the latent heat of fusion while during boiling or temperature till both acquire same temperature.
condensation is called latent heat of vaporisation Heat lost = Heat gained
Note(1): If a solid such as camphor directly * Principle of calorimetry represents the law of
converts into gaseous phase at all temperatures the conservation of heat energy.
process is called sublimation. * The temperature of mixture can never be lesser
Note(2): If vapours by releasing heat directly than lower temperature and can never be greater
changes into solid state without passing through than higher temperature TL Tmix TH
liquid phase, the process is called "Hoar forst"
* If 'm' g of steam at 1000C is mixed with 'm' g of ice
* In melting or boiling heat supplied is used to increase at 00C then
the internal potential energy of the substance while
a) Resultant temperature of mixture is 1000C
internal kinetic energy remains constant. m
* Clausius and clapeyron has shown the effect of b) Mass of steam condensed = g
3 2m
pressure on boiling point of liquids and melting points g
c) Mass of steam left uncondensed =
of solids is related to latent heat heat L(cal/g) thorugh 4m 3
dP JL d) The finial mixture contains g of water and
= T V V where VF and VI are final and 2m 3
dT K F g of steam both at 1000C
initial specific volumes (cc/g). 3
HEAT TRANSFER
* In case of boiling as volume of vapours VF is always
* Heat is Transmitted by three methods namely,
dP Conduction, Convection and Radiation.
greater than volume of liquid VI. hence is
dT CONDUCTION
positive. i.e boiling point of every liquid rises with
increase in pressure * It is the phenomenon of Heat transfer without the
actual displacement of the particles of the medium.
* In case of melting for substances like wax and
The particles of the medium execute vibratory
sulphur which expands on melting,
motion.
VF > VI and hence melting point rises with increase
in pressure. Ex. : Heat Transfer in a metal rod (solid)
1 2 n K1
Q
H1 H2 H3 ..... Hn
t
Kn
K1A 1 2 K 2 A 2 3 KnA n1 n
1 2 n * Equivalent thermal resistance
* Equivalent thermal resistance is 1 1 1 1 1
........
R=R1+R2+...Rn R p R1 R 2 R 3 Rn
* Equivalent thermal conductivity is calculated R1R2
as follows RS = R1 +R2 + R3 +.... * for two slabs Rp
R1 R2
1 2 ... n 1 2 * Temperature grandient is same across each slab.
... n * Heat current in each slab will be different
KS K1 K 2 Kn
1 2 .... n * Net heat current H H1 H2 H3 ............Hn
Ks
1 2 K A 1 A 2 ...... A n K1A1 K2A2 KA
... n
.............. n n
K1 K 2 Kn
* If n slabs of equal length are in series then K1A1 K2 A 2 .... KnAn
K
n 1 1 1 A1 A 2 .... A n
... K1 k 2 ....K n
KS K1 K2 Kn For n slabs of equal area K
2K1K 2 n
* For two slabs of equal length, Ks =
K1 K2 . K1 K 2
For two slabs of equal area K
Junction Temperature : If two metal slabs of equal 2
areas of crosssection, having lengths l 1 , l 2 , Growth of thickness of Ice layer on Ponds :
coefficients of thermal conductivities k1,k2 and free * When atmospheric temperature falls below 0°C,
end Temperatures 1, 2 are kept in contact with water in a lake starts freezing.
t A 150
c) Silver Iodide d) Type metal
1) a & b 2) b & c 3) c & d 4) d & a
tB 100 37. When the temperature of a body increases
1) density and moment of inertia increases
0 Temperature( B) 100
2) density and moment of inertia decreses
t A 180 t
B
t A 30 t
B 3) density decreases and moment of inertia
1) 2)
100 150 150 100 increases
t A 180 t A t B 40 t 4) density increases and moment of inertia
3) 4) A
150 100 100 180 decreases
___________________________________________________________
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ANSWER ANY 10 QUESTIONS 8. The higher and lower fixed points on a
thermometer are separated by 150mm. When
1. Express OK on Fahrenheit scale. the length of the mercury thread above the
lower temperature is 30 mm, the temperature
1) -459.67°F 2) 240.6°F 3) -320°F 4) 373°F
reading would be
1) 200C 2) 300C 3) 100C 4) 00C
2. A faulty thermometer has its fixed points
marked as 3° and 102°. The temperature of a
9. A centrigrade and a Fahrenheit thermometer
body as measured by the faulty thermometer
are dipped in boiling water. The water
is 80°. Find the correct temperature of the
temperature is lowered until the Fahrenheit
body on Celsius scale.
thermometer registers 1760F. What is the fall
1) 36.5°C 2) 77.8°C 3) 25.8°C 4) 66.8°C in temperature as registered by the
Centigrade thermometer
3. At what temperature on the Fahrenheit scale 1) 200C 2) 400C 3) 600C 4) 800C
will the reading be double of the reading on
the Celsius scale?
1) 340°F 2) 240.6°F 3) 330°F 4) 320°F 10. Two liquids at temperatures 60o C and 20o C
respectively have masses in the ratio 3 : 4
and their specific heats in the ratio 4 : 5. If
4. A acurate Celsius thermometer and a the two liquids are mixed, the resultant
Fahrenheit thermometer register 60° and temperature is
141° respectively when placed in the same
constant temperature enclosure. What is the 1) 70oC 2) 50oC 3) 40oC 4) 35oC
error in the Fahrenheit thermometer?
1)1°F 2) 3°F 3) -5°F 4) 2°F 11. Two liquids are at 40ºC and 30°C. When they
are mixed in equal masses, the temperature
5. The reading of centigrade thermometer of the mixture is 36°C. Ratio of their specific
coincides with that of Fahrenheit thermometer heats is
in a liquid. The temperature of the liquid is 1) 3 : 2 2) 2 : 3 3) 4 : 3 4) 3 : 4
1) -400C 2) 00C 3) 1000C 4) 3000C
6. Two thermometers one Celcius and other 12. The quantity of heat which can rise the
Fahrenheit are put in a hot bath. The reading temperature of x gm of a substance through
on Fahrenheit scale is just three times the t1°C can rise the temperature of y gm of water
reading on Celcius thermometer. The through t2°C is same. The ratio of specific
temperature of the bath is heats of the substances is
1) 1000C 2) (80/3) 0C 3) 800C 4) 700C 1) yt1/xt2 2) xt2/yt1 3) yt2/xt1 4) xt1/yt2
13. A fixed mass of an ideal gas is maintained at 20. The ratio of the lengths of two rods is 4:3.
constant volume the pressure of the gas at The ratio of their coefficients of cubical
triple point of water is p tr then the expansion is 2:3. Then the ratio of their linear
thermodynamic temperature of the gas when expansions when they are heated through
the pressure is P same temperature difference is
1) 2:1 2) 1:2 3) 8:9 4) 9:8
P PP
tr 21. The ratio of lengths of two rods is 1 : 2 and
1) 273.16 P K 2) 273.16 P K
tr tr the ratio of coefficient of expansions is
2 : 3. The first rod is heated through 60 0C.
Ptr P Ptr Find the temperature through which the
3) 273.16 K 4) 273.16 K
P P second rod is to be heated so that its expansion
14. The steam point and the ice point of a mercuary is twice that of first is
thermometer are wrongly marked as 920C and 1) 600C 2) 400C 3) 300C 4) 100C
20 C respectively. The correct temperature 22. A wire of length 60 cm is bent into a circle
read by this thermometer is with a gap of 1 cm at its ends. On heating it by
1) 20C 2) 50C 3) 100C 4) 200C 100°C, the length of the gap increases to 1.02
cm. of material of wire is
15. A Fahrenheat thermometer reads 1130F while
a faulty celsius thermometer reads 440C. The 1) 2 x 10–4/°C 2) 4 x 10–4/°C
correction to be applied to the celsius 3) 6 x 10–4/°C 4) 1 x 10–4/°C
thermometer is 23. A metal metre scale gives correct
1) –10C 2) +10C 3) +20C 4) –20F measurement at 00C. It is generally used at a
16. On a hypothetical scale X, the ice point is 400 temperature of 40 0 C. The correction to be
and the steam point is 1200. For another scale made for every metre is ( 106 /10 C )
Y the ice point and steam points are 300 1) 4 X 10–5 m 2) 4 X 10–5 m to be added
1) –50 2) –80 3) –100 4) –120 3) 4 X 10–5 m must be deducted
17. A gas thermometer measures the tempera- 4) None of the above.
ture from the variation of pressure of a sample 24. The temperature of a thin uniform rod
of gas. If the pressure measured at the melt- increases by t . If moment of inertia I about
ing point of lead is 2.20 times the pressure an axis perpenducular to its length, then its
measured at the triple point of water find the moment of increases by
melting point of lead. 1) 0 2) I t 3) 2 I t 4) 2 I t
1) 601 K 2) 420 K 3) 790 K 4) 510 K 25. A metal rod has a length of 1m at 30°C.
EXPANSION OF SOLIDS ' ' of metal is 2.5 x 10–5/°C. The temperature
at which it will be shortened by 1mm is
18. Coefficient of cubical expansion of a solid is
(0.000027/°C). If the temperature is measured 1) –30°C 2) –40°C 3) –10° C 4) 10°C
on Fahreheit scale, numerical value of 26. Upon heating, the length of the side of a cube
coefficient of linear expansion of solid is changes by 2%. The volume of the cube
1) 0.000009/°F 2) 0.000005/°F changes by
1) 1% 2) 6 % 3) 0.5 % 4) 4 %
3) 0.000015/°F 4) 0.000018/°F
27. Radius of a sphere is 100cm at 0°C and
19. If coefficient of cubical expansion is x times
100.1cm at 100°C. Coefficient of cubical
coefficient of superficial expansion, then the
expansion of the sphere is
value of x is
1) 30 x 10–6/C 2) 10 x 10–6/°C
1) 1.5 2) 2 3) 2.5 4) 3
3) 60 x 10–6/°C 4) 20 x 10–6/°C
XIth Class (C.B.S.E) SRI CHAITANYA 28
Physics THERMAL PROPERTIES OF MATTER
28. A brass disc at 0°C has a diameter of 50Cm 36. The density of lead at 0°C is 11.34 g/cm3. The
and a hole of diameter 10cm. For Brass density of land at 100°C, if the coefficient of
a = 18 x 10–6/°C. When the disc is heated to linear expansion of lead = 28 x 10-6/°C is
100°C, the diameter of the hole becomes. 1) 13.25 gm/cm3 2) 17.25 gm/cm3
1) 10.018 cm 2) 10.180 cm 3) 18.25 gm/cm3 4)11.25 gm/cm3
3) 10.8 cm 4) 10.81 cm 37. A steel scale is correct at 0°C. The length of
29. Density of a substance at 0°C is 10.6 gm/c.c a brass tube measured by it at 40°C is 4.5m.
and at 100°C is 10 gm/c.c. coefficient of linear The correct length of the tube at 0°C is
expansion of solid is (Coefficients of linear expansion of steel and
brass are 11 × 10 -6 /°C and 19 × 10 -6 /°C
1) 0.0006/°C 2) 0.0004/°C
respectively).
3) 0.0003/°C 4) 0.0002/°C 1) 4.001 m 2) 5.001 m 3) 4.999m 4) 4.501m
30. A steel rod of dimesions 4 x 4cm2 is tightly 38. A brass meter bar is correct at 20°C. The
fixed between two supports and is not allowed length of a rod as measured by it at 35°C is
to expand. It is heated through 2°C. Thermal 50cm. The true length of the rod at 35°C is
stress developed is ....10 6 N/m2 (coefficient of linear expansion of brass is
(Y= 20×1010N/m2 = 18 x 10–6/‚C) 19 × 10-6/°C)
1) 7.2 2) 2.7 3) 3.6 4) 0.72 1) 40.01m 2) 25.02 m 3) 50.01m 4) 45.01 m
31. A length of 2m is measured using a metal tape
39. Two thin metal strips, one of brass and the
at 100C. It is calibrated at a temperature 300C.
other of iron are fastened together parallel to
The actual length is ( 1 10 4 / 1C0 )
each other, a distance 2 mm apart to form a
1) 2.004 m 2) 1.996 m 3) 1.004 m 4) 0.004 cm bimetallic strip. If the strips are of equal length
32. A metal tape gives correct measurement at at 0°C. The radius of the arc formed by the
150C. It is used to measure a distance of 100m bimetallic strip when heated to 80°C is
at 45 0C. The error in the measurement, if (Coefficient of linear expansion of brass =
12 10 6 / 10 C is 19 × 10-6/°C and of iron = 12 × 10-6/°C).
1) 36 cm 2) 36 m 3) 42 mm 4) 36 mm 1) 1.50 m 2) 3.57 m 3) 5.57 m 4) 0.57 m
33. The ratio of the lengths of an iron rod and an 40. An iron ring 1.20 m in diameter is to be put on
aluminium rod for which the difference in the a wooden cart wheel. The diameter of this wheel
lengths is independent of temperature is is 1.0 cm greater than that of the ring. The
(Coefficient of linear expansion of iron and temperature of the ring that must be raised
aluminium are 12 x 10-6/°C and 24x10-6/°C before it slips on the wooden wheel is
respectively) (Coefficient of linear expansion of iron =
1) 2:1 2) 3:1 3) 1:2 4) 4:1 12 × 10-6/°C).
34. A piece of copper wire has a length of 2m at 1) 600.4°C 2) 694.4°C
10°C. Its length at 100°C is (Coefficient of 3) 294.4°C 4) 300.4°C
linear expansion of copper = 17 x 10-6/°C)
41. A steel bar 0.5 cm square (cross–sectional
1) 20.00306 m 2) 2.00306 m area) and 25 cm long at 30°C fits into the space
3) 4.000306m 4)15.000306m between two fixed supports. If the bar is now
35. A piece of steel has a length of 30cm at 15°C. heated to 230°C, the force it exerts against
At 90°C its length increases by 0.027 cm. Its the supports is (Coefficient of linear expansion
coefficient of linear expansion is forsteel = 11 × 10-6/°C and Young's modulus
1) 15 x 10-6/°C 2)12 x 10-6/°C for steel 2 × 1011N/m2).
3)15 x 15-6/°C 4) 20 x 10-6/°C 1) 11000N 2) 22000N
3) 33000N 4) 44000N
3) m1 < m2 4) m1 = 2 m2 V
NOTE: thermal capacity or heat capacity are same equal to the product of mass and specific heat
_________________________________________________________
1. The densities of two substances are in the ratio 9. Two liquids at temperatures 60o C and 20o C
5 : 6 and the specific heats are in the ratio 3 : respectively have masses in the ratio 3 : 4
5 respectively. The ratio of their thermal and their specific heats in the ratio 4 : 5. If
capacities per unit volume is
the two liquids are mixed, the resultant
1) 2 : 1 2) 1 : 2 3) 4 : 1 4) 1 : 4 temperature is
1) 70oC 2) 50oC 3) 40oC 4) 35oC
2. The thermal capacity of 10g of a substance is
8 calories. The specific heat is in J/kg-K 10. Two liquids are at 40ºC and 30°C. When they
1) 3360 2) 3630 3) 6330 4) 3306 are mixed in equal masses, the temperature
of the mixture is 36°C. Ratio of their specific
3. A piece of metal of mass 112g is heated to
heats is
100°C and dropped into a copper calorimeter
of mass 40g containing 200g of water at 16°C. 1) 3 : 2 2) 2 : 3 3) 4 : 3 4) 3 : 4
Neglecting heat loss, the specific heat of the
mettal is nearly, if the equilibrium temperature 11. 10 grams of steam at 100°C is mixed with
reached is 24.1°C , 50 gm of ice at 0°C then final temperture is
1) 0.294 cal/gm°C 2) 0.394cal/gm°C 1) 20°C 2) 50°C 3) 40°C 4) 100°C
3) 0.194 cal/gm°C 4) 0.494cal/gm°C
12. Hailstones fall from a certain height. If only
4. A copper block of mass 500 gm and specific 1% of the hailstones melt on reaching the
heat 0.1 cal/gm°C is heated from 30°C to ground, find the height from which they fall.
290°C, the thermal capacity of the block is (g = 10 ms -2 . L = 80 calorie/g and
1) 50cal/ºC 2) 50gm J = 4.2J/calorie)
3) 5cal/ºC 4) 5gm 1) 336 m 2) 236 m 3) 436 m 4) 536 m
5. Two spheres with radii in the ratio 1 : 2 have 13. A steel ball of mass 0.1 kg falls freely from a
specific heats in the ratio x : y and densities height of 10m an bounces to a height of 5.4m
in the ratio z : x. The ratio of their thermal from the ground. If the dissipated energy in
capacities is this process is absorbed by the ball, the rise
1) Z : 2y 2) Z : 8y 3) Zy : 8 4) xy : 2Z in its temperature is (specific heat of
steel =460 JKg–1K–1) (g=10ms-2). (2000 M)
0 0
1) 0.01 C 2) 0.1 C 3) 1 C 0 4) 1.10C
6. The specific heat of a substance is
0.09 cal/gm°C. If the temperature is measured 14. Two spheres A and B with masses in the ratio
on Fahrenheit scale the value of its specific 2 : 3 and specific heat 2 : 3 fall freely from
heat in cal/gm/°F is rest. If the rise in their temperatures on
1) 0.09 2) 0.9 3) 0.05 4) 0.5 reaching the ground are in the ratio 1 : 2 the
ratio of their heights of fall is
7. The quantity of heat which can rise the 1) 3 : 1 2) 1 : 3 3) 4 : 3 4) 3 : 4
temperature of x gm of a substance through
t1°C can rise the temperature of y gm of water
through t2°C is same. The ratio of specific
heats of the substances is
1) yt1/xt2 2) xt2/yt1 3) yt2/xt1 4) xt1/yt2
82. The equation of state crresponding to 8 gm 89. Calculate the value of the gas constant for one
gram of hydrogen, given that the density of
of O2 is
RT hydrogen at N.T.P is 0.00009 g/cm3
1) PV = RT 2) PV =
4 1) 4.12J/K-g 2) 2.12J/K-g
RT RT 3) 5.12J/K-g 4) 3.12J/K-g
3) 4) PV =
3 2 90. The mass of a litre of dry air at N.T.P is 1.293
83. A vessel is filled with an ideal gas at a pres- g. Find the mass of 3 litres of air at 1170C and
sure of 20 atm and is at a temperature of 27°C. a pressure of 4 atmospheres ?
One half of the mass of the gas is removed from
the vessel and the temperature of the remain- 1) 10.86 g 2) 5.6 g 3) 6.4 g 4) 7.2 g
ing gas is increased to 87°C. At this temperature Calorimetry
the pressure of the gas will be 91. The densities of two substances are in the ratio
1) 80 atm 2) 8.3atm 3) 12atm 4) 0.12 atm 5 : 6 and the specific heats are in the ratio 3 :
5 respectively. The ratio of their thermal
84. The volume of a mass of gas at 370C and a
pressure of 75 cm of mercury is 620 c.c. Find capacities per unit volume is
the volume at N.T.P. 1) 2 : 1 2) 1 : 2 3) 4 : 1 4) 1 : 4
1) 500CC 2) 480CC 92. The thermal capacity of 10g of a substance is
8 calories. The specific heat is in J/kg-K
3) 326CC 4) 538.8CC
1) 3360 2) 3630 3) 6330 4) 3306
85. A Steel tank is filled with a gas at 150
atmosphere and at 200C. If the pressure raise 93. A piece of metal of mass 112g is heated to
to 250 atmospheres, the tank explodes. Find 100°C and dropped into a copper calorimeter
the temperature at which the tank explodes. of mass 40g containing 200g of water at 16°C.
Neglecting heat loss, the specific heat of the
1) 215.30C 2) 273.30C
mettal is nearly, if the equilibrium temperature
3) 100.30C 4) 373.30C reached is 24.1°C ,
86. A glass vessel contains air at 600C. To what 1) 0.294 cal/gm°C 2) 0.394cal/gm°C
temperature must it be heated to expel one
third of the air, the pressure remaining con- 3) 0.194 cal/gm°C 4) 0.494cal/gm°C
stant. (Neglect the expansion of the vessel) 94. A copper block of mass 500 gm and specific
heat 0.1 cal/gm°C is heated from 30°C to
1) 1270C 2)226.50C 3) 3270C 4)4270C
290°C, the thermal capacity of the block is
87. A balloon of volume V contains a gas of mass
1) 50cal/ºC 2) 50gm
m at a pressure P and temperature 150C. Gas
is pumped into the balloon so that its volume 3) 5cal/ºC 4) 5gm
is doubled and the pressure is trebled. If the 95. Two spheres with radii in the ratio 1 : 2 have
temperature increases 60C in the process, find specific heats in the ratio x : y and densities
the ratio of the increase in mass to the origi- in the ratio z : x. The ratio of their thermal
nal mass. capacities is
1) 34 : 5 2) 239:49 3) 199 : 21 4) 3 : 4 1) Z : 2y 2) Z : 8y 3) Zy : 8 4) xy : 2Z
88. The density of a gas at N.T.P. is 1.3 kg / m3 96. The specific heat of a substance is
the density of the gas at – 15 0 C and at a 0.09 cal/gm°C. If the temperature is measured
pressure of 84 cm of Hg ........... on Fahrenheit scale the value of its specific
1) 1.52 kg/m3 2) 0.52 kg/m3 heat in cal/gm/°F is
1) 0.09 2) 0.9 3) 0.05 4) 0.5
3) 0.052 kg/m3 4) 15.2 kg/m3
97. 5 gm of steam at 100°C is passed into 104. 6 gm of steam at 100°C is mixed with 6 gm of ice
calorimeter containing liquid. Temperature of at 0°C.The mass of steam left uncondensed is
liquid rises from 32°C to 40°C. Then water 1) 2 gm 2) 4 gm 3) 3 gm 4) 1 gm
equivalent of calorimeter and contents is
105. 10 grams of steam at 100°C is mixed with
1) 40 gram 2) 375 gram 50 gm of ice at 0°C then final temperture is
3) 300 gram 4) 160 gram 1) 20°C 2) 50°C 3) 40°C 4) 100°C
98. The quantity of heat which can rise the CONDUCTION
temperature of x gm of a substance through
106. In steady state condition, the temperatures
t1°C can rise the temperature of y gm of water
at the two ends of a metal rod of length 25 cm
through t2°C is same. The ratio of specific are 100°C and 0°C. Then temperature at a
heats of the substances is point 8cm from the hot end is
1) yt1/xt2 2) xt2/yt1 3) yt2/xt1 4) xt1/yt2 1) 68°C 2) 40°C 3) 32°C 4) 60°C
99. Density of a liquid 'A' is 0.5 g/c.c and that of 107. A copper bar 2m long has a circular cross section
liquid 'B' is 0.6 g/c.c. Heat capacity of 8 litres of radius 1 cm. One end is kept at 1000C and
of ‘A’ is equal to that of 10 litres of 'B'. Then the other at 00C. It is assumed that negligible
their specific heats ratio is heat is lost through the surface. (a) The thermal
1) 4 : 5 2) 3 : 2 3) 2 : 3 4) 1 : 1 resistance of the bar is (b) The temperature
100. Quantity of heat lost in condensation of 10 gm gradient is (c) The temperature at 25 cm from
of steam at 100°C is the hot end will be (K = 400 SI units)
136. If the maximum intensity of radiation for a 142.A body at 50 0C cools in a surroundings
black body is found at 2.65m , the maintained at 300C. The temperature at which
temperature of the radiating body is (Wien’s the rate of cooling is half that of the begining is
constant = 2.9 × 10–3 mK) 1) 16.30C 2) 26.30C
1) 927 K* 2) 1094 K 3) 2027 K 4) 2173K 3) 400C 4) 46.30C
137. The wavelength of maximum emitted energy EXERCISE - II(A)
of a body at 700 K is 4.08 m . If the tempera-
ANSWERS
ture of the body is raised to 1400 K, the wave-
length of maximum emitted energy will be 1) 1 2) 3 3) 2 4) 4 5) 1
1) 1.02m 2) 16.32m
6) 1 7) 2 8) 1 9) 1 10) 1
3) 8.16 m 4) 2.04 m 11) 2 12) 1 13) 1 14) 4 15) 2
138. A)Two bodies A and B a have thermal emis- 16) 3 17) 1 18) 2 19) 1 20) 3
sivities of 0.01 and 0.81 respectively. The
21) 2 22) 1 23) 2 24) 3 25) 3
outer surface areas of the two bodies are the
same. The two bodies emit total radiant power 26) 2 27) 1 28) 1 29) 4 30) 1
of the same rate. The wavelength B corre- 31) 2 32) 4 33) 1 34) 2 35) 2
sponding to maximum spectral radiancy in the
36) 4 37) 4 38) 3 39) 2 40) 2
radiation from B shifted from the wavelength
corresponding to maximum spectral radiancy 41) 1 42) 2 43) 1 44) 1 45) 2
in the radiation from A, by 1.00 µm. If the 46) 2 47) 3 48) 3 49) 3 50) 2
temperature of A is 5802 K
51) 2 52) 3 53) 2 54) 4 55) 4
1) the temperature of B is 1934 K 56) 2 57) 1 58) 1 59) 2 60) 1
2) B 1.5µm 61) 1 62) 1 63) 1 64) 1 65) 4
3) the temeprature of B is 11604 K 66) 3 67) 3 68) 1 69) 2 70) 1
4) the temperature of B is 2901 K 71) 1 72) 3 73) 2 74) 4 75) 3
NEWTONS LAW OF COOLING 76) 2 77) 4 78) 1 79) 1 80) 2
139. A hot body is placed in cooler surroundings. 81) 1 82) 2 83) 3 84) 4 85) 1
When the body temperature is 75°C, the rate 86) 2 87) 2 88) 1 89) 1 90) 1
of cooling is 4°C/ min. When it is 55°C, the
91) 2 92) 1 93) 3 94) 1 95) 2
rate of cooling is 2°C/ min. The temperature
of the surroundings is 96) 3 97) 2 98) 3 99) 2 100) 2
55. A container of capacity 700 ml is filled with 60. The sum and difference of coefficient of real
two different liquids of volume 200 ml and 500 and apparent expansions of a liquid are in
ml with respective volume coefficients as 1.4 the ratio 2 : 1. The ratio of coefficient of real
x 10–5/0C and 2.1 x 10–5 /0C During the heating expansion and apparent expansions must be
of the vessel, it is obseved that neither any 1) 1 : 1 2) 2 : 3 3) 3 : 1 4) 6 : 5
liquid overflows nor any empty space is 61. A vessel of volume 1 liter is filled with a
created. The volume coefficient of the liquid whose coefficient of volume expansion
container is is 20 times as that of the vessel. At all tem-
1) 1.9105 / 0 C 2) 1.9106 / 0 C peratures if volume of air above the liquid is
constant the volume of that empty space is
3) 1.6105 / 0 C 4) 1.6106 / 0 C 1) 950 c.c 2) 50 c. c
3) 1000 c.c 4) 500 c.c
56. A glass bulb of volume 250cc. is completely
filled with mercury at 200C. The temperature EXPANSION OF GASES
of the system is raised to 100 0 C. If the 62. The pressure of a gas at 00C is 50cm of Hg
coeficient of linear expansiuon of glass is at constant volume it is heated to 800C, then
9 × 10 -6 / 0 C and coefficient of absolute
pressure is 64cm of Hg the pressure
expansion of mercury is 1.8 × 10-4, volume of
coefficient of gas
mercury that overflows is
1) 0.0035/ 0C 2) 0.035/ 0C
1) 1.83 cc 2) 2.56 cc
3) 0.00035/ 0C 4) 0.000035/ 0C
3) 3.06 cc 4) 415 cc
63. A gas at a temperature 300 K and pressure
57. The height of the mercury column in a 30 atm is allowed to expand to atmospheric
barometer provided with a brass scale corrected pressure. If the volume becomes 10 times
at 00C is observed to be 74.9 cm at 150C. Find its initial volume, the final temperature
the true height of the column at 150C. beocmes
brass 20 10 6 / 0 C and Hg 175 10 6 / 0 C
1) 1000C 2) 373K
1) 74.92 cm 2) 79.92 cm
3) 3730C 4) 100K
3) 74.12 cm 4) 72.64 cm
64. A given of gas occupies a volume of 100 c.c
58. A glass vessel just holds 50 gm of toulene at
at one atmospheric and at 1000C. At the same
00C. If the coefficient of absolute expansion
temperature, how much volume the same gas
of toulene is 14.76 x 10 -4 / 0 C the mass of occupies at 4 atmospheric pressure ?
toulene it holds at 600C is [ of glass = 9 x 1) 25c. 2) 15 c.c
10–6/0C] 3) 35 cc 4) 10 cc
1) 28 g 2) 35 g 3) 41 g 4) 46 g
65. The pressure of a gas ta 100 0 C is 2 atm.
59. A piece of metal floats on mercury the
When the gas is heated by keeping volume
coefficient of volume expansion of the metal
constant, at what temperature the pressure
and mercury are 1 and 2 respectively. If raises to 3 atm ?
the temperatures of both mercury and metal 1) 286.50C 2) 168.50C
are increased by an amount T, the fraction 0
3) 186.5 C 4) 366.50C
of volume of the metal submerged in
66. A gas at 27 0 C temperature and 30 atmo-
mercury changes by the factor
spheric pressure is allowed to expand to the
1 1 atmospheric pressure. If the volume
1) r T 2) r r T becomes 10 times its initial volume, then the
2 1 1 2
final temperature becomes
3) r1 r2 T 4) r2 r1 T 1) 1000C 2) 1730C 3) 2730C 4) -1730C