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ﻣﺸﺨﺼﺎت ﻓﯿﺰﯾﮑﯽ و ﻣﮑﺎﻧﯿﮑﯽ ﺑﻠﻮک ﺳﺎﺧﺘﻪ ﺷﺪه از ﻣﯿﺴﻠﯿﻮمPhysical and Mechanical Properties of Mycelium Bricks View project
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ChemElectroChem 2017, 4, 1 – 8 1 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
ChemElectroChem 2017, 4, 1 – 8 www.chemelectrochem.org 2 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
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25 0.1 m PBS. It was in good agreement with recent reported
26 results by Mashkour et al.[41] Untreated wet BC exhibited a low
27 power density (0.57 mW/m2) in 0.1 m PBS (usual concentration
28 of PBS in anolyte) compared to graphite under similar
29 conditions. With higher PBS concentration (0.5 M), the MFC
30 generated 2.2 mW/m2 using BC as anode. Unlike BC, for
31 graphite the obtained power was only 1 mW/m2 (in 0.5m PBS),
32 somewhat closer to that recorded for graphite anode at 0.1m
33 PBS concentration. Similar results were recorded for the
34 generated current density as demonstrated in Figure 3D. The
35 measured conductivity for 0.1m and 0.5m PBS were 13 and
36 54 mS, respectively. Regards to the above results, increasing
37 PBS conductivity[42] improved electron transfer in BC and also,
38 the effect of anolyte (PBS) conductivity on the performance of
39 untreated wet BC was more than graphite. In order to explain
40 the difference of the effect of anolyte conductivity on wet BC
41 and graphite, the nature of MFC should be reminded.
42 Figure 2. ATR-FTIR (A) and XRD (B) spectra of BC. BC-PPYR with concen- Exoelectrogens, the electron generators in MFC, create colonies
43 tration of a) 0.01, b) 0.02, c) 0.03, and d) 0.04m pyrrole. on the anode surface. The porosity and morphology of BC give
44 rise to an improved adhesion of microbial cells. Because of the
45 high liquid content of BC and consequently more extended
46 planes. The degree of crystallinity for BC as calculated using contact surface of bacteria with the anolyte, the liquid
47 Segal’s equation was 94 %.[39] PPYR synthesized on BC’s fibers conductivity is expected to be more effective on power and
48 rendered nanocomposites with a decreased degree of crystal- current produced by BC as compared to graphite. For more
49 linity (ranging from 92.8 to 88 %) for concentrations between concentrated PBS (over 0.5 M), the lag phase of bacteria in the
50 0.01, to 0.04 m of pyrrole which indicated a good preservation anode chamber was too high and it was inexcusable to increase
51 of BC crystallinity upon deposition despite the amorphous even more the concentration of PBS.
52 nature of PPYR.[34] These findings can be attributed to the low In previous paragraph, it was shown that conductivity of
53 temperature (5 8C) and particularly mild acidic condition untreated BC in wet state depends on the conductivity of liquid
54 employed during polymerization process. Based on previous by which BC is wetted. Another approach to make BC
55 research, cellulose degrades at high temperatures and under conductive involves deposition of a conductive layer on BC’s
56 strong acidic conditions.[40] fibers. For this purpose, in this study BC was coated with PPYR
57 as a conductive polymer through a trouble-free in situ
ChemElectroChem 2017, 4, 1 – 8 www.chemelectrochem.org 3 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
ChemElectroChem 2017, 4, 1 – 8 www.chemelectrochem.org 4 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
ChemElectroChem 2017, 4, 1 – 8 www.chemelectrochem.org 5 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
ChemElectroChem 2017, 4, 1 – 8 www.chemelectrochem.org 6 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
ChemElectroChem 2017, 4, 1 – 8 www.chemelectrochem.org 7 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim