Scrubber Final

Reactor System Pollutant Name HBS
HCl 0.02
HBS
Water 0.01
ETA
Diketone
IPA
HCl
Toluene
QTP-IV
NN Dimethyl Aniline
R-1638 POCl3
Toluene
QTP-VI Water
HCl
Pregablin
CO2
TBA
Bupropion BUP-1
Chloroform
ETA
Diketone
IPA
HCl
Toluene
QTP-IV
NN Dimethyl Aniline
R-1645 POCl3
TBA
Bupropion BUP-1
Chloroform
HCl
Pregablin
CO2
HCL
IPA
Celecoxib Water
Water 0.02
HBS HCl 0.03
IPA
Diketone Water
IPA
R-1677 Water
Hcl
QTP-VI Toluene
Toluene
QTP-IV Water
Toluene
Bupropion Water
HCl
Pregablin
Toluene
IPA
QTP--IV
HCl
Water
IPA
Water
QTP-VI
Hcl
Toluene
R-1671
HCl 0.1
HBS CO2 31
SO2 69
HCL
IPA
Celecoxib Water
Toluene
Bupropion
HCl
Toluene
QTP-IV Water
HCl 0.1
HBS CO2 31
R-1694 SO2 69
Methanol
Pregablin CO2
Toluene
Bupropion
HCl
QTP-IV Toluene
N Methyl Pyrollidone
QTP-VI Toluene
R-1666
CO2
Toluene
Bupropion TBA
QTP-IV Toluene
QTP-VI Toluene
R-1641 Bupropion Toluene
Toluene
Pregablin
Methanol
HBS Methanol 0.1

Diketone Water
Centrifuge Celecoxib IPA
CF-1690 QTP-IV Toluene
QTP-VI Toluene
Acetone
Bupropion
Centrifuge
CF-1690
Bupropion Toluene
HBS Methanol 0.1

Centrifuge Diketone IPA
CF-1691 QTP-IV Toluene
Acetone
Bupropion Toluene
QTP-IV Toluene
RCVD HBS Methanol 0.02
Diketone IPA
Diketone Celecoxib QTP-IV QTP-VI
1.1
0.6
1.1
0.6
0.01
1.4
0.01
0.39
0.1
0.01
1.4
0.01
0.01
0.78
0.97
0.25
Bupropion Pregablin Total emission Pollutant Flow rate(Kg/hr)
Air flow rate(m3/hr) Air flow rate based on vent lines
0 0.00
Sl. No. Equipment Tag No MOC
1 Reactor R-1638 MSGL
A) Charging of Toluene at temperature 25-30°C to Reactor
10 m3/hr
Connected Pump Charging rate
Tank Capacity 20 KL
Volume qty
S.No Component Name Mol. Weight
charged
Mw Vi
m3
1 Toluene 92.14 1.8
Total
The empty vessel was previously made inert with nitrogen, and the vessel is ve
System Pressure PT =
Partial Pressure of Nitrogen pN2 =
Moles of Nitrogen Emission En, N2 =
Weight of Nitrogen Emission Ewt, N2 =
Nitrogen Emission rate ER, N2 =
Summary
Toluene Emission Rate ER, ni =
B) Charge POCl3 into the reactor containing Toluene and QTP-II at temperature 25-30°C fro
Above Surface Addition
2 m3/hr
Connected Pump Charging rate
From Drum
Assumed that QTP-II is non Volatile Component

Initial Vessel Contents Analysis
Volume qty
charged
Mw Vi
Kg/Kgmol m3
1 Toluene 92.14 1.8
2 QTP-II 227.29 0.45
Total
Calculation of the average batch and vapor-phase compositions
S.No Component Name Mol. Weight Xi
Mw
Kg/Kgmol
1 Toluene 92.14 0.895
2 POCl3 153.33 1.000
3 Nitrogen 28
Total
Summary
POCl3 Emission Rate ER, ni =
C) Heat the reaction mass to reflux temperature 105°C.
Volume qty
Mol. Weight
charged
S.No Component Name
Mw
Vi
Kg/Kgmol m3
1 Toluene 92.14 1.8
2 POCl3 153.33 0.2226
3 N,N Dimethyl aniline 121.19 0.149
Total
4 Nitrogen (Residual) 28
Volume of Head Space Available in Reactor =

Initial Temperature (T1) =
Final Temperature (T2) =
time for Heating (t) =
Calculate the average gas space molar volume
= 0.285381692
= 0.014841973
= 0.208568178
= 0.284005282
Component Name Mol. Weight Avg pi

S.No
Mw
Kg/Kgmol (mm Hg)
1 Toluene 92.14 281.89

2 POCl3 153.33 46.45
Total 329.75
Summary
N,N Dimethyl aniline ER, ni =
D) Reaction involving multicomponent gas evolution
HCl and unreacted POCl3 is liberated during reaction

Assumed that QTP-III, PO2Cl, is non Volatile Component
Distillate
Mol. Weight
S.No Component Name Volume
Mw Vi
Kg/Kgmol m3
1 Toluene 92.14 1.8
2 unreacted POCl3 153.33 0.2226
4 PO2 Cl 98.4256
5 Hcl 36.45
6 QTP-III 245.73
Total
time for reaction (t) =

Calculate the toluene emission rate by the ratio of vapor pressures
=
En-i, *Mw
=
En-i, *Mw/t
Summary
HCl ER, ni =
E) Distill out the POCL3 and Toluene below 115°C (Atm dist)
Assumed that QTP-III, PO2Cl, is non Volatile Component
Distillate
Mol. Weight
S.No Component Name Volume
Mw
Vi
Kg/Kgmol m3
1 Toluene 92.14 1.8
2 POCl3 153.33 0.06
Total

= 0.285381692
= 0.013237594
= 0.187176955
= 0.195097427

S.No
Mw
Kg/Kgmol (mm Hg)
1 Toluene 92.14 282.03

2 POCl3 153.33 12.52
Total 295.96
Summary
F Collection of POCl3 and Toluene
Volume qty
charged
Mw Vi
m3
1 Toluene 92.14 0.615
2 POCl3 153 0.06
Total
Summary
POCl3 Emission rate ER, N3 =
G Charging of Toluene at temperature 70°C to Reactor
Volume qty
charged
Mw Vi
m3
1 Toluene 92.14 3.3
Total
Summary
H Charging of Toluene at temperature 25-30°C to Reactor-1666
Volume qty
charged
Mw Vi
m3
1 Toluene 92.14 5
Total
Summary
I Heat the reaction mass to reflux temperature 80°C.
Volume qty
Mol. Weight
S.No Component Name charged
Mw Vi
Kg/Kgmol m3
1 Toluene 92 5
Total

= 0.194331154
= 0.050421674
= 0.068500796
= 0.065614744

S.No
Mw
Kg/Kgmol (mm Hg)
1 Toluene 92 163.50
Total 396.50
Summary
Filteration
J Charging of reaction mass into filter
Volume qty
charged
Mw Vi
m3
1 Toluene 92.14 4.7
Total
Summary
K Charging toluene into filter
Volume qty
charged
Mw Vi
m3
1 Toluene 92.14 0.45
Total
Summary
L Charging of reaction mass into Reactor R-1694
Volume qty
charged
Mw Vi
m3
1 Toluene 92.14 5.083
Total
Summary
L Charging of IPA+HCL+water on top of reaction mass
Assumed that QTP-IV is non Volatile Component
Volume qty
charged
Mw Vi
Kg/Kgmol m3
1 Toluene 92.14 1.8
Total
Mw
Kg/Kgmol
1 Toluene 92.14 0.895
2 IPA 60 0.297
3 HCl 36.5 0.110
4 Water 18 0.594
Total
Nitrogen 28
Summary
IPA Emission rate ER, ni =
HCl Emission rate ER, N2 =
Water emission rate ER, N3 =
Second filteration
M Charging reaction mass into centrifuge
Volume qty
charged
Mw Vi
m3
1 Toluene 92.14 5.914
Total
Summary
N Charging toluene for washing
Volume qty
charged
Mw Vi
m3
1 Toluene 92.14 0.45
Total
Summary
O Drying
kg
Volume qty
charged
Mw Vi
m3
1 Toluene 92 0.108
Total
Summary
Toluene ER, ni =
Capacity
8 KL
Weight qty Weight Mole

Density Moles
Charged Fraction Fraction
ρ Wi Xi
Kg/m3 Kg
866 1559 1.00 16.918 1.000
1559 16.918
rogen, and the vessel is vented to atmosphere

760 mm Hg
PT - Pi = 723.35 mm Hg
pnV/RT = 0.07 Kg moles
En, N2*Mw = 1.93 Kg
Ewt, N2 /t = 3.86 Kg/hr
0.64 Kg/hr
3.86 Kg/hr
temperature 25-30°C from drums.

Density Moles
ρ Wi Xi
Kg/m3 Kg Kg moles
866 1559 0.78 16.918 0.895
1000 450 0.22 1.980 0.105
2009 18.898
Ẋi Vapor Partial System

ϕA, ϕB
Pressure Pressure Temp.
Pi pi
(mm Hg) (mm Hg) °C
T
1.00 0.9 36.7 32.80 30
1.00 1.0 45.32 45.32 30
681.88 30
760
0.04 Kg/hr
0.08 Kg/hr
0.22 Kg/hr
System Pressure PT = 760

Density Moles
ρ Wi Xi
Kg/m3 Kg Kg moles
866 1559 0.75 16.918 0.826
1640 365 0.18 2.381 0.116
960 143 0.07 1.180 0.058
2067 20.479
7.877 m3
30
105
2.5 hrs
Average
Average
Fraction to Total Average Emission Emission
Emission
rate
(Kg moles) (Kg) (Kg/hr)
En-i, *Mw En-i, *Mw/t

0.855 0.24 22.4 8.9
0.141 0.04 6.1 2.5
0.004 0.00 0.1 0.1
1.000 0.28
8.9 Kg/hr
2.5 Kg/hr
0.1 Kg/hr
0.48 Kg/hr
Liberation of Weight Mole

Density Moles
Vapor/gas Fraction Fraction
ρ Wi Xi
Kg/m3 Kg Kg moles
866 1559 0.75 16.918 0.826
1640 61 0.03 0.397 0.019
960 143 0.07 1.180 0.058
195 0.09 1.980 0.097
1180 72 0.03 1.983 0.097
487 0.24 1.980 0.097
2516 24.438
6 hrs
Toluene unreacted POCl3
10.1279922444 0.138864574
933.1932053986 Kg 21.2921052
155.5322008998 Kg/hr 3.5486842

155.5 Kg/hr
3.5 Kg/hr
0.5 Kg/hr
12.0 Kg/hr

Density Moles
ρ Wi Xi
Kg/m3 Kg Kg moles
866 1559 0.75 16.918 0.826
1640 98 0.05 0.642 0.031
960 143 0.07 1.180 0.058
1800 18.740
7.877 m3
30
105
2.5 hrs
Average
Average
Emission
rate

0.953 0.27 24.9 10.0
0.042 0.01 1.8 0.7
0.005 0.00 0.2 0.1
1.000 0.28
10.0 Kg/hr
0.7 Kg/hr
0.1 Kg/hr
0.37 Kg/hr

Density Moles
ρ Wi Xi
Kg/m3 Kg
866 533 0.84 5.780 0.900
1640 98 0.16 0.643 0.100
631 6.423

760 mm Hg
PT - Pi = 463.793516 mm Hg
En, N2*Mw = 0.36 Kg
Ewt, N2 /t = 0.07 Kg/hr
0.13 Kg/hr
0.07 Kg/hr
0.00 Kg/hr

Density Moles
ρ Wi Xi
Kg/m3 Kg
866 2858 1.00 31.016 1.000
2858 31.016

760 mm Hg
PT - Pi = 557 mm Hg
En, N2*Mw = 2.41 Kg
Ewt, N2 /t = 1.20 Kg/hr
1.44 Kg/hr
1.20 Kg/hr
Density Moles
ρ Wi Xi
Kg/m3 Kg
866 4330 1.00 46.994 1.000
4330 46.994

760 mm Hg
PT - Pi = 723 mm Hg
En, N2*Mw = 5.74 Kg
Ewt, N2 /t = 2.87 Kg/hr
0.48 Kg/hr
2.87 Kg/hr

Density Moles
ρ Wi Xi
Kg/m3 Kg Kg moles
866 4330 1.00 47.065 1.000
4330 47.065
5.2 m3
30
80
4 hrs
Average
Average
Emission
rate

1.000 0.07 6.0 1.5
1.000 0.15
1.5 Kg/hr
0.08 Kg/hr
Density Moles
ρ Wi Xi
Kg/m3 Kg
866 4070 1.00 44.174 1.000
4070 44.174

760 mm Hg
PT - Pi = 723 mm Hg
En, N2*Mw = 5.39 Kg
Ewt, N2 /t = 2.70 Kg/hr
0.45 Kg/hr
2.70 Kg/hr

Density Moles
ρ Wi Xi
Kg/m3 Kg
866 390 1.00 4.229 1.000
390 4.229

760 mm Hg
PT - Pi = 723 mm Hg
En, N2*Mw = 0.52 Kg
Ewt, N2 /t = 0.26 Kg/hr
0.04 Kg/hr
0.26 Kg/hr

Density Moles
ρ Wi Xi
Kg/m3 Kg
866 4402 1.00 47.774 1.000
4402 47.774

760 mm Hg
PT - Pi = 723 mm Hg
En, N2*Mw = 5.83 Kg
Ewt, N2 /t = 2.92 Kg/hr
0.49 Kg/hr
2.92 Kg/hr

Density Moles
ρ Wi Xi
Kg/m3 Kg Kg moles
866 1559 0.78 16.918 0.895
1559 16.918

ϕA, ϕB
Pi pi
(mm Hg) (mm Hg) °C
T
1.00 0.9 37.0 33.10 30
1.00 0.3 58 17.21 30
1.00 0.1 21 2.30 30
1.00 0.6 31 18.40
760
688.99 30
0.07 Kg/hr
0.02 Kg/hr
0.00 Kg/hr
0.01 Kg/hr
0.46 Kg/hr

Density Moles
ρ Wi Xi
Kg/m3 Kg
866 5122 1.00 55.584 1.000
5122 55.584
760 mm Hg
PT - Pi = 723 mm Hg
En, N2*Mw = 6.78 Kg
Ewt, N2 /t = 3.39 Kg/hr
0.57 Kg/hr
3.39 Kg/hr

Density Moles
ρ Wi Xi
Kg/m3 Kg
866 390 1.00 4.229 1.000
390 4.229

760 mm Hg
PT - Pi = 723 mm Hg
En, N2*Mw = 0.52 Kg
Ewt, N2 /t = 0.26 Kg/hr
0.04 Kg/hr
0.26 Kg/hr
Density Moles
ρ Wi Xi
Kg/m3 Kg
886 91 1.00 0.992 1.000
91 0.992

760 mm Hg
PT - Pi = 469 mm Hg
En, N2*Mw = 0.06 Kg
Ewt, N2 /t = 0.03 Kg/hr
0.07 Kg/hr
0.03 Kg/hr
R = 62.363577 m3. mm Hg/ (K. Kmol)
Antonie co efficients
System Partial Average
Time Vapor Pressure
Temp. Pressure Emission
t mm Hg °C mm Hg (Kg moles)
hr Pi T pi piV/RT
0.5 36.7 30 36.65 0.0035
Inlet Stream Analysis:
Dilution factor for the Component

S.No
initial vessel contents Name
1.00 1 POCl3
1.00
Total
Average
Average Emission Average Emission Emission Air velocity Flow
rate
(m3/hr)
piV/RT ER, ni
0.0004 0.04 0.04
0.0005 0.08 0.08
0.0080 0.22 0.22
mm Hg
Vapor Partial
Vapor Pressure Partial Pressure
Pressure Pressure
Pi @ 30°C pi @ 30°C Pi @ 105°C pi @ 105°C
(mm Hg) (mm Hg) (mm Hg) (mm Hg)
36.7 30.28 646.1 533.78

45.32 5.27 753.82 87.64
1.02 0.06 47.91 2.76
35.60 624.18
724.40 135.82
mm Hg
Pi @ 105°C pi @ 105°C
(mm Hg) (mm Hg)
646.1 533.78
753.82 14.63
47.91 2.76
551.17
N,N Dimethyl aniline
0.0262143443
3.1769163817
0.5294860636
mm Hg
Vapor Partial
Pressure Pressure
Pi @ 30°C pi @ 30°C Pi @ 105°C Pi @ 105°C

36.7 30.28 646.1 533.78

45.32 1.42 753.82 23.62
1.02 0.06 47.91 2.76
31.76 560.16
728.24 199.84
Time Vapor Pressure
hr Pi T pi piV/RT
5 291.0 80 261.863714 0.0073
5 343.0 80 34.3427701 0.0001
Time Vapor Pressure
hr Pi T pi piV/RT
2 203.0 70 203 0.0313
Time Vapor Pressure
hr Pi T pi piV/RT
2 37.0 10 37 0.0105
mm Hg
Vapor Partial
Pressure Pressure
Pi @ 30°C pi @ 30°C Pi @ 80°C pi @ 80°C
37.0 37.00 290.0 290.00
37.00 290.00
723.00 470.00
760
Time Vapor Pressure
hr Pi T pi piV/RT
2 37.0 10 37 0.0099
Time Vapor Pressure
hr Pi T pi piV/RT
2 37.0 10 37 0.0009
Time Vapor Pressure
hr Pi T pi piV/RT
2 37.0 10 37 0.0107

S.No
1.00 1 IPA
2 HCl
3 Water
Total
Average
Average Emission Average Emission Emission Air velocity Flow
rate
(m3/hr)
piV/RT ER, ni
0.0008 0.07 0.07
0.0004 0.02 0.02
0.0001 0.00 0.00
0.0005 0.01 0.01
0.0164 0.46 0.46
Time Vapor Pressure
hr Pi T pi piV/RT
2 37.0 10 37 0.0124
Time Vapor Pressure
hr Pi T pi piV/RT
2 37.0 10 37 0.0009
Time Vapor Pressure
hr Pi T pi piV/RT
2 291.0 80 291 0.0014
mm Hg/ (K. Kmol)
Average Average Air

Flow Flow
Emission Emission rate velocity
(Kg) (Kg/hr) (m3/hr) (CFM)
ER, ni
0.32 0.64
Volume qty Weight qty Weight
Mol. Weight Density Time Moles
charged Charged Fraction
Mw Vi ρ Wi t Xi
Kg/Kgmol m3 Kg/m3 Kg hr Kg moles

153.33 0.2226 1640 365 1.00 1.00 0.007
365 0.007
Flow
(CFM)
Average Average Air
Flow Flow
ER, ni
0.67 0.13
0.01 0.00
Average Average Air
Flow Flow
ER, ni
2.89 1.44
Average Average Air
Flow Flow
ER, ni
0.97 0.48
Average Average Air
Flow Flow
ER, ni
0.91 0.45
Average Average Air

Flow Flow
ER, ni
0.09 0.04
Average Average Air
Flow Flow
ER, ni
0.98 0.49

Mw Vi ρ Wi t Xi
60 - - 163 0.50 1.00 0.008
65 - - 65 0.20 1.00 0.003
18 - - 98 0.30 1.00 0.017
0.45 325 0.028
Flow
(CFM)
Average Average Air

Flow Flow
ER, ni
1.14 0.57
Average Average Air
Flow Flow
ER, ni
0.09 0.04
Average Average Air
Flow Flow
ER, ni
0.13 0.07
the inlet stream is in direct contact with the vessel headspace as it enters the
vessel.Therefore, the equilibrium vapor composition for the inlet stream will be
based on the exact composition ,of the inlet stream. A dilution factor ϕ for the
inlet stream will be assumed to be 1.0
Mole Dilution factor for the
Fraction inlet stream
1.000 1.00
the inlet stream is in direct contact with the vessel headspace as it enters the
vessel.Therefore, the equilibrium vapor composition for the inlet stream will be
based on the exact composition ,of the inlet stream. A dilution factor ϕ for the
inlet stream will be assumed to be 1.0

0.297
0.110
0.594 1.00
325 65 0.4
162.5
97.5
A) Charging of Water at temperature 30°C to Reactor
S.No Component Name Mol. Weight Volume qty charged
Mw Vi
m3
1 Water 18 3
Total
The empty vessel was previously made inert with nitrogen, and the vessel is vented to atm
Summary
Water Emission Rate ER, ni =
B) Charge Toluene into the reactor containing Water and NaoH at temperature 40°C from drum
Assumed that NaOH is non Volatile Component

Mw Vi
Kg/Kgmol m3
1 Water 18 3
2 NaoH 40 0.077
Total
Mw
Kg/Kgmol
1 Water 18 0.976
2 Toluene 92 1.000
3 Nitrogen 28
Total
Summary
C) Heat the reaction mass to 50 °C.
Assumed that QTP-IV and NaOH are non Volatile Component
Mol. Weight Volume qty charged

S.No Component Name
Mw Vi
Kg/Kgmol m3
1 Toluene 92.14 3
2 Water 18 3
Total

= 0.0755185626
= 0.0044927324
= 0.0088129443
= 0.0009403177

S.No
Mw
Kg/Kgmol (mm Hg)
1 Toluene 92.14 9.38

2 Water 18 58.85
Total 68.23
Summary
D Charging of Reaction mass at temperature 30°C to Reactor second reactor
Mw Vi
m3
1 Toluene 92 2.8
Total
Summary
Assuming QTP is not volatile
E Heat the reaction mass to reflux temperature 105°C.

Assumed that QTP-iv is non Volatile Component

S.No Component Name
Mw
Vi
Kg/Kgmol m3
1 Toluene 92.14 2.8
2 N-Methyl pyrolidone 99 0.45
Total

= 0.2203493019
= 0.0107438611
= 0.1423580633
= 0.1437701229
S.No
Mw
Kg/Kgmol (mm Hg)
1 Toluene 92.14 289.83

2 N- Methyd Pyrollidone 153.33 2.74
Total 292.58
Summary
N-methyl Pyrolidone ER, ni =
F Charging of Toluene at temperature 30°C to Reactor third reactor with reaction mass and w
Mw Vi
m3
1 Toluene 92 2.8
Total
Summary
Assuming QTP is not volatile
G Charging of Toluene at temperature 30°C to Reactor third reactor on top of reaction mass c
Mw Vi
m3
1 Toluene 92 2
Total
Summary
H Heat the reaction mass to reflux temperature 105°C.
Assumed that QTP-iv is non Volatile Component

S.No Component Name
Mw
Vi
Kg/Kgmol m3
1 Toluene 92.14 2.8
Total

= 0.1591210348
= 0.0072319031
= 0.1022012192
= 0.1777195626

S.No
Mw
Kg/Kgmol (mm Hg)
1 Toluene 92.14 289.83
Total 289.83
Summary
I Charging of Toluene at temperature 70 into collection vessel after distillation
Mw Vi
m3
1 Toluene 92 1
Total
Summary
Repeat the above two steps twice
Filteration
J Charging of Toluene at temperature 10°C to Reactor second reactor
Mw Vi
m3
1 Toluene 92 4.7
Total
Summary
K Charging of Toluene at temperature 10°C to Reactor second reactor
Mw Vi
m3
1 Toluene 92 1
Total
Summary
L Charging of IPA+HCL+water on top of reaction mass

Mw Vi
Kg/Kgmol m3
1 Toluene 92.14 4.5
Total
Mw
Kg/Kgmol
1 Toluene 92.14 1.000
2 IPA 60 0.297
3 HCl 36.5 0.110
4 Water 18 0.594
Total
Nitrogen 28
Summary
IPA Emission rate ER, ni =
HCl Emission rate ER, N2 =
Water emission rate ER, N3 =
Weight qty Mole
Density Weight Fraction Moles
Charged Fraction
ρ Wi Xi
Kg/m3 Kg
1000 3000 1.00 166.667 1.000
3000 166.667
he vessel is vented to atmosphere

760 mm Hg
PT - Pi = 728.2598327288 mm Hg
En, N2*Mw = 3.24 Kg
Ewt, N2 /t = 3.24 Kg/hr
0.09 Kg/hr
3.24 Kg/hr
perature 40°C from drums.
Weight qty Mole

Charged Fraction
ρ Wi Xi
Kg/m3 Kg Kg moles
1000 3000 0.95 166.667 0.976
2120 163 0.05 4.081 0.024
3163 170.748
Ẋi Partial System
ϕA, ϕB Vapor Pressure
Pressure Temp.
Pi pi
(mm Hg) (mm Hg) °C
T
0.93 0.9 31.7 28.81 40
1.00 1.0 59.6330512895 59.63 40
671.56 40
760
0.15 Kg/hr
1.57 Kg/hr
5.39 Kg/hr
Weight qty Mole

Charged Fraction
ρ Wi Xi
Kg/m3 Kg Kg moles
866 2598 0.46 28.196 0.145
1000 3000 0.54 166.667 0.855
5598 194.863
1.923 m3
30
50
2 hrs
Fraction to Average Average

Average Emission
Total Emission Emission rate

0.137 0.000129244 0.011908519 0.0059542595
0.863 0.000811074 0.0145993316 0.0072996658
1.000 0.00
0.0059542595 Kg/hr
0.0072996658 Kg/hr
0.0052605296 Kg/hr
Weight qty Mole

Charged Fraction
ρ Wi Xi
Kg/m3 Kg
866 2425 1.00 26.357 1.000
2425 26.357

760 mm Hg
PT - Pi = 722.7839443451 mm Hg
En, N2*Mw = 3.00 Kg
Ewt, N2 /t = 3.00 Kg/hr
0.51 Kg/hr
3.00 Kg/hr
Weight qty Mole

Charged Fraction
ρ Wi Xi
Kg/m3 Kg Kg moles
866 2425 0.84 26.316 0.849
1030 464 0.16 4.682 0.151
2888 30.998
6.082 m3
30
105
5 hrs
Average Emission

0.991 0.14 13.1 2.6
0.009 0.0013477942 0.2 0.0
1.000 0.14
2.6 Kg/hr
0.0413314584 Kg/hr
0.28 Kg/hr
th reaction mass and water

Weight qty Mole
Charged Fraction
ρ Wi Xi
Kg/m3 Kg
866 2425 1.00 26.357 1.000
2425 26.357

760 mm Hg
PT - Pi = 723 mm Hg
En, N2*Mw = 3.00 Kg
Ewt, N2 /t = 3.00 Kg/hr
0.50 Kg/hr
3.00 Kg/hr
n top of reaction mass contatining toluene
Weight qty Mole
Charged Fraction
ρ Wi Xi
Kg/m3 Kg
866 1732 1.00 18.826 1.000
1732 18.826

760 mm Hg
PT - Pi = 723 mm Hg
En, N2*Mw = 2.14 Kg
Ewt, N2 /t = 2.14 Kg/hr
0.36 Kg/hr
2.14 Kg/hr
Weight qty Mole

Charged Fraction
ρ Wi Xi
Kg/m3 Kg Kg moles
866 2425 0.84 26.316 0.849
2425 26.316
4.392 m3
30
105
5 hrs

Average Emission

1.000 0.14 13.2 2.6
1.000 0.14
2.6 Kg/hr
0.20 Kg/hr
stillation
Weight qty Mole
Charged Fraction
ρ Wi Xi
Kg/m3 Kg
866 866 1.00 9.413 1.000
866 9.413

760 mm Hg
PT - Pi = 557 mm Hg
En, N2*Mw = 0.73 Kg
Ewt, N2 /t = 0.73 Kg/hr
0.87 Kg/hr
0.73 Kg/hr
Weight qty Mole

Charged Fraction
ρ Wi Xi
Kg/m3 Kg
866 4070 1.00 44.241 1.000
4070 44.241

760 mm Hg
PT - Pi = 738 mm Hg
En, N2*Mw = 5.50 Kg
Ewt, N2 /t = 1.83 Kg/hr
0.18 Kg/hr
1.83 Kg/hr
Weight qty Mole

Charged Fraction
ρ Wi Xi
Kg/m3 Kg
866 866 1.00 9.413 1.000
866 9.413

760 mm Hg
PT - Pi = 738 mm Hg
En, N2*Mw = 1.17 Kg
Ewt, N2 /t = 0.39 Kg/hr
0.04 Kg/hr
0.39 Kg/hr
Weight qty Mole
Charged Fraction
ρ Wi Xi
Kg/m3 Kg Kg moles
866 3897 1.00 42.294 1.000
3897 42.294
Ẋi Partial System
ϕA, ϕB Vapor Pressure
Pressure Temp.
Pi pi
(mm Hg) (mm Hg) °C
T
1.00 1.0 37.0 36.99 30
1.00 0.3 58 17.21 30
1.00 0.1 21 2.30 30
1.00 0.6 31 18.40
760
685.09 30
0.08 Kg/hr
0.02 Kg/hr
0.00 Kg/hr
0.01 Kg/hr
0.45 Kg/hr
R = 62.363577 m3. mm Hg/ (K. Kmol)
Vapor System Partial

Time Average Emission
Pressure Temp. Pressure
hr Pi T pi piV/RT
1 31.7 30 31.740167271 0.0050
Dilution factor for the initial

S.No Component Name
vessel contents
0.9299437075 1 Toluene
1
Total
Average
Average
Average Emission Emission Air velocity Flow
Emission
rate
(m3/hr)
piV/RT ER, ni
0.0041 0.07 0.15
0.0086 0.79 1.57
0.0963 2.70 5.39
mm Hg
Partial Vapor Partial

Vapor Pressure
Pressure Pressure Pressure
Pi @ 30°C pi @ 30°C Pi @ 50°C pi @ 105°C
37.2 5.39 92.4087415 13.37 50

45.32 38.76 92.2998881 78.94 50
44.15 92.32
715.85 667.68
hr Pi T pi piV/RT
1 37.2 30 37.216055655 0.0055
mm Hg

Vapor Pressure
Pi @ 30°C pi @ 30°C Pi @ 105°C pi @ 105°C

36.7 31.11 646.1 548.55

15 2.27 21.32 3.22
33.38 551.77
726.62 208.23
hr Pi T pi piV/RT
1 37.0 30 37 0.0055
hr Pi T pi piV/RT
1 37.0 30 37 0.0039
mm Hg

Vapor Pressure
Pi @ 30°C pi @ 30°C Pi @ 105°C pi @ 105°C

36.7 31.11 646.1 548.55
31.11 548.55
728.89 211.45
hr Pi T pi piV/RT
1 203.0 70 203 0.0095

hr Pi T pi piV/RT
3 22.0 10 22 0.0059
hr Pi T pi piV/RT
3 22.0 10 22 0.0012

S.No Component Name
vessel contents
1.00 1 IPA
2 HCl
3 Water
Total
Average
Average
Average Emission Emission Air velocity Flow
Emission
rate
(m3/hr)
piV/RT ER, ni
0.0009 0.08 0.08
0.0004 0.02 0.02
0.0001 0.00 0.00
0.0005 0.01 0.01
0.0160 0.45 0.45

Average Average Air
Flow Flow

ER, ni
0.09 0.09
Volume qty Weight qty Weight Mole

charged Charged Fraction Fraction
Mw Vi ρ Wi t Xi

92 2.8 866 2425 1.00 0.50 26.357 1.000
2425 26.357
Flow
6.577
(CFM)
Average Average Air
Flow Flow

ER, ni
0.51 0.51
Average Average Air
Flow Flow

ER, ni
0.50 0.50
Average Average Air
Flow Flow

ER, ni
0.36 0.36
Average Average Air
Flow Flow

ER, ni
0.87 0.87
Average Average Air

Flow Flow

ER, ni
0.54 0.18
Average Average Air
Flow Flow

ER, ni
0.11 0.04
Mw Vi ρ Wi t Xi
60 - - 181 0.50 1.00 0.008 0.297
65 - - 72 0.20 1.00 0.003 0.110
18 - - 108 0.30 1.00 0.017 0.594
0.44 361 0.028
Flow
(CFM)
the inlet stream is in direct contact with the vessel
headspace as it enters the vessel.Therefore, the equilibrium
vapor composition for the inlet stream will be based on the
exact composition ,of the inlet stream. A dilution factor ϕ for
the inlet stream will be assumed to be 1.0
Dilution
factor for
the inlet
stream
1.00
the inlet stream is in direct contact with the vessel
headspace as it enters the vessel.Therefore, the equilibrium
vapor composition for the inlet stream will be based on the
exact composition ,of the inlet stream. A dilution factor ϕ for
the inlet stream will be assumed to be 1.0
325 65
Dilution
factor for
the inlet
stream 162.5
97.5
1.00
INPUT
Component Mass in qty

Kg
QTP-II 450
Toluene 1558.8
POCl3 364.5
N,N Dimethyl aniline 143.55
Total 2517
OUTPUT
Mol. wt Component
Kg/Kmol
227.29 QTP-III
92.14 Toluene
153.33 Po2 Cl
121.19 Hcl
unreacted POCl3
N,N Dimethyl aniline
594 Total
Mass in qty Mol. wt
Kg Kg/Kmol
486.5 245.730
1558.8 92.140
194.9 98.426
72.3 36.5
60.9 153.33
143.6 121.19
2516.9 747
A Charge HCl into reactor containing water and solid 4-ABS

4-ABS considered as non volatile component
Mw Vi
Kg/Kgmol m3
1 water 18 1
2 4-ABS 178 0.463
Total
Mw
Kg/Kgmol
1 Water 18 0.952
2 HCl 36.5 1.000
3 Nitrogen 28
Total
Summary
Water emission rate ER, ni =
HCl Emission rate ER, ni =
B Evolution of CO2 and SO2
S.No Component Name Gas generated Mol. Weight
1 NaHCO3 CO2 84
2 NaHSO3 SO2 104
C Charge HCl into reactor containing water and reaction mass
Mw Vi
Kg/Kgmol m3
1 water 18 1
Total
Mw
Kg/Kgmol
1 Water 18 0.952
2 HCl 36.5 1.000
3 Nitrogen 28
Total
Summary
Sl. No. Equipment Tag No MOC

1 Reactor R-1638 MSGL
D Methanol Wash
Mw Vi
m3
1 Methanol 32 0.5
Total
Partial Pressure of Nitroge pN2 =
Weight of Nitrogen Emissio Ewt, N2 =
Summary
Methanol Emission Rate ER, ni =
E Charge HCl into reactor containing water and reaction mass

Mw Vi
Kg/Kgmol m3
1 water 18 1.8
Total
Mw
Kg/Kgmol
1 Water 18 1.000
2 HCl 36.5 1.000
3 Nitrogen 28
Total
Summary
F Methanol Wash
Mw Vi
m3
1 Methanol 32 0.5
Total
Summary
G Drying
Methanol d 91.3 kg
Mw Vi
m3
1 Methanol 32 0.1155696203
Total
Summary
I Heat the reaction mass to 92

S.No Component Name
Mw
Vi
Kg/Kgmol m3
1 Water 18 5
2 HCl 36.5 2.5
Total
Volume of Head Space Available in Reactor=

= 0.0736077503
= 0.0388853873
= 0.0492520881
= 0.0851898831

S.No
Mw
Kg/Kgmol (mm Hg)
1 Water 18 231.17
2 HCl 36.5 122.96
Total 396.50
Summary
Water ER, ni =
HCl ER, ni =

BS
sidered as non volatile component

Density Moles
ρ Wi Xi
Kg/m3 Kg Kg moles
1000 1000 0.67 55.556 0.952
1080 500 0.33 2.809 0.048
1500 58.365

ϕA, ϕB
Pi pi
(mm Hg) (mm Hg) °C
T
0.84 0.8 31.7 25.24 30
1.00 1.0 21 21.00 30
713.76 30
760
0.01 Kg/hr
0.02 Kg/hr
0.40 Kg/hr
Number of
Molecular
Weight Charged moles of gas Emission Time
weight of gas
generated
488.000 5.81 44.0 255.6190476 8
906.000 8.71 64.0 557.5384615 8
mass

Density Moles
ρ Wi Xi
Kg/m3 Kg Kg moles
1000 1000 0.67 55.556 0.952
1000 55.556

ϕA, ϕB
Pi pi
(mm Hg) (mm Hg) °C
T
0.61 0.6 31.7 18.54 30
1.00 1.0 21 21.00 30
720.46 30
760
0.0055928413 Kg/hr
0.0128435096 Kg/hr
0.34 Kg/hr
Capacity
8 KL

Density Moles
ρ Wi Xi
Kg/m3 Kg
790 395 1.00 12.344 1.000
395 12.344
nitrogen, and the vessel is vented to atmosphere

760 mm Hg
PT - Pi = 705 mm Hg
En, N2*Mw = 0.56 Kg
Ewt, N2 /t = 1.12 Kg/hr
0.10 Kg/hr
1.12 Kg/hr
mass
Density Moles
ρ Wi Xi
Kg/m3 Kg Kg moles
1000 1800 1.00 100.000 1.000
1800 100.000

ϕA, ϕB
Pi pi
(mm Hg) (mm Hg) °C
T
0.82 0.8 31.7 25.90 30
1.00 1.0 21 21.00 30
713.10 30
760
0.0156211497 Kg/hr
0.0256870193 Kg/hr
0.67 Kg/hr
Density Moles
ρ Wi Xi
Kg/m3 Kg
790 395 1.00 12.344 1.000
395 12.344

760 mm Hg
PT - Pi = 705 mm Hg
En, N2*Mw = 0.56 Kg
Ewt, N2 /t = 1.12 Kg/hr
0.10 Kg/hr
1.12 Kg/hr

Density Moles
ρ Wi Xi
Kg/m3 Kg
790 91 1.00 2.853 1.000
91 2.853

760 mm Hg
PT - Pi = 705 mm Hg
En, N2*Mw = 0.13 Kg
Ewt, N2 /t = 0.26 Kg/hr
0.02 Kg/hr
0.26 Kg/hr
System Pressur PT = 760

Density Moles
ρ Wi Xi
Kg/m3 Kg Kg moles
1000 5000 0.63 277.778 0.773
1190 2975 0.37 81.507 0.227
7975 359.285
2 m3
30
92
6 hrs
Average
Average Average
Fraction to Total Emission
Emission Emission
rate

0.583 0.05 0.9 0.1
0.310 0.03 1.0 0.2
1.000 0.15
0.1 Kg/hr
0.2 Kg/hr
0.45 Kg/hr
R = 62.3636 m3. mm Hg/ (K. Kmol)
Compon Volume
Dilution factor for the
S.No ent Mol. Weight qty
initial vessel contents
Name charged
Mw Vi
Kg/Kgmol m3
0.84 1 HCl 36.5 0.75
0.84
Total
Average
Average Air
Average Emission Emissio Flow Flow
Emission velocity
n rate
(m3/hr) (CFM)
piV/RT ER, ni
0.0010 0.02 0.01
0.0008 0.03 0.02
0.0283 0.79 0.40
Emission per hour
31.9523809524
69.6923076923
Compon Volume
Name charged
Mw Vi
Kg/Kgmol m3
0.61 1 HCl 36.5 2.533
Total
Average
Average Air
Emission velocity
n rate
(m3/hr) (CFM)
piV/RT ER, ni
0.0025 0.04 0.01
0.0028 0.10 0.01
0.0966 2.70 0.34
R = 62.3636 m3. mm Hg/ (K. Kmol)
Partial Average Average Average

System
Time Vapor Pressure Pressur Emissio Emissio Emissio
Temp.
e n n n rate
t mm Hg °C mm Hg(Kg moles) (Kg) (Kg/hr)

hr Pi T pi piV/RT ER, ni
0.5 55.0 10 55 0.0016 0.05 0.10
Compon Volume
Name charged
Mw Vi
Kg/Kgmol m3
0.82 1 HCl 36.5 1.483
Total
Average
Average Air
Emission velocity
n rate
(m3/hr) (CFM)
piV/RT ER, ni
0.0035 0.06 0.02
0.0028 0.10 0.03
0.0956 2.68 0.67
R = 62.3636 m3. mm Hg/ (K. Kmol)


System
Temp.
e n n n rate

0.5 55.0 10 55 0.0016 0.05 0.10

System
Temp.
e n n n rate

0.5 55.0 10 55 0.0004 0.01 0.02
mm Hg
Vapor Partial
Vapor Pressure Partial Pressure Pressur Pressur
e e
Pi @ pi @
Pi @ 30°C pi @ 30°C
80°C 80°C
(mm Hg) (mm Hg)
(mm Hg) (mm Hg)
32.0 24.74 566.0 437.60

21 4.76 542 122.96
29.50 560.56
730.50 199.44
760
the inlet stream is in direct contact with the vessel hea
it enters the vessel.Therefore, the equilibrium vapor co
for the inlet stream will be based on the exact compos
inlet stream. A dilution factor ϕ for the inlet stream will
assumed to be 1.0
Weight Dilution factor

Weight Mole
Density qty Time Moles for the inlet
Fraction Fraction
Charged stream
ρ Wi t Xi
Kg/m3 Kg hr Kg moles
1180 885 1.00 2.00 24.247 1.000 1.00
885 24.247
Weight Mole
Fraction Fraction
Charged stream
ρ Wi t Xi
1180 2989 1.00 8.00 81.889 1.000 1.00
2989 81.889
Air
Flow Flow
velocity
(m3/hr) (CFM)
Weight Mole
Fraction Fraction
Charged stream
ρ Wi t Xi
1180 1750 1.00 4.00 47.944 1.000 1.00
1750 47.944
Air
Flow Flow
velocity
(m3/hr) (CFM)
Air
Flow Flow
velocity
(m3/hr) (CFM)
contact with the vessel headspace as
ore, the equilibrium vapor composition
based on the exact composition ,of the
or ϕ for the inlet stream will be
A) Charging of IPA
Volume qty
charged
Mw Vi
m3
1 IPA 60 0.76
Total
Summary
IPA ER, ni =
B) Charging ETA into reactor containing IPA
Volume qty
charged
Mw Vi
Kg/Kgmol m3
1 IPA 60 0.76
2 MAP 134 0.597
Total
Mw
Kg/Kgmol
1 IPA 60 0.690
2 ETA 142 1.000
3 Nitrogen 28
Total
Summary
IPA Emission ER, ni =
ETA Emissiom ER, ni =
C) Heating to 45 °C
Volume qty
Mol. Weight
charged
S.No Component Name
Mw
Vi
Kg/Kgmol m3
1 IPA 60 0.76
2 ETA 142 0.637
Total

= 0.2555154397
= 0.0093887963
= 0.1159042075
= 0.0547058556

S.No
Mw
Kg/Kgmol (mm Hg)
1 IPA 60 116.44
2 ETA 142 81.41
Total 197.86
Summary
ETA Emission ER, ni =
D Charging of reaction mass into reactor
Volume qty
charged
Mw Vi
m3
1 IPA 60 0.76
Total
Summary
IPA ER, ni =
E Charging IPA into reactor

Volume qty
charged
Mw Vi
m3
1 IPA 60 0.6
Total
Summary
IPA ER, ni =
F Charging IPA over water and ipa
Volume qty
charged
Mw Vi
Kg/Kgmol m3
1 IPA 60 0.6
2 Water 18 3.6
Total
Mw
Kg/Kgmol
1 IPA 60 0.545
2 Water 18 0.962
3 IPA 60 1.000
3 Nitrogen 28
Total
Summary
Water emission ER, ni =
G Charging of reaction mass into Centrifuge
Volume qty
charged
Mw Vi
m3
1 IPA 60 1.5
Total
Summary
IPA ER, ni =
G Charging of wash IPa into Centrifuge
Volume qty
charged
Mw Vi
m3
1 IPA 60 0.9
Total
Summary
IPA ER, ni =
H Drying
Volume qty
charged
Mw Vi
m3
1 IPA 60 0.391
Total
Summary
IPA ER, ni =
Weight qty
Density Weight Fraction Moles Mole Fraction Time
Charged
ρ Wi Xi t
Kg/m3 Kg hr
786 597 1.00 9.956 1.000 0.3
597 9.956
n, and the vessel is vented to atmosphere

760 mm Hg
PT - Pi = 698.9890939094 mm Hg
En, N2*Mw = 0.79 Kg
Ewt, N2 /t = 2.62 Kg/hr
0.49 Kg/hr
2.62 Kg/hr
Dilution factor
Weight qty for the initial
Density Weight Fraction Moles Mole Fraction
Charged vessel
contents
ρ Wi Xi
Kg/m3 Kg Kg moles
786 597 0.50 9.956 0.690 0.85
1005 600 0.50 4.478 0.310 0.85
1197 14.434
Ẋi Partial Average
ϕA, ϕB Vapor Pressure System Temp.
Pressure Emission
Pi pi
(mm Hg) (mm Hg) °C (Kg moles)
T piV/RT
0.85 0.6 61.0 35.79 30 0.0012
1.00 1.0 212 212.00 30 0.0071
512.21 30 0.0173
760
0.07 Kg/hr
1.01 Kg/hr
0.48 Kg/hr
System Pressure PT = 760 mm Hg
Weight qty Vapor

Charged Pressure
Pi @ 30°C
(mm Hg)
ρ Wi Xi
Kg/m3 Kg Kg moles
786 597 0.44 9.956 0.651 8.0
1192 759 0.56 5.347 0.349 60.000600006
1357 15.303
6.22 m3
5
45
3 hrs
Average
Emission
Total Emission Emission
rate

0.589 0.03 1.9 0.6
0.411 0.02 3.2 1.1
1.000 0.05
0.6 Kg/hr
1.1 Kg/hr
1.50 Kg/hr
Weight qty
Charged
ρ Wi Xi t
Kg/m3 Kg hr
786 597 1.00 9.956 1.000 0.3
597 9.956

760 mm Hg
PT - Pi = 698.9890939094 mm Hg
En, N2*Mw = 0.79 Kg
Ewt, N2 /t = 2.62 Kg/hr
0.49 Kg/hr
2.62 Kg/hr
Weight qty
Charged
ρ Wi Xi t
Kg/m3 Kg hr
786 472 1.00 7.860 1.000 0.3
472 7.860

760 mm Hg
PT - Pi = 698.9890939094 mm Hg
En, N2*Mw = 0.62 Kg
Ewt, N2 /t = 2.07 Kg/hr
0.39 Kg/hr
2.07 Kg/hr
Dilution factor
Weight qty for the initial
Charged vessel
contents
ρ Wi Xi
Kg/m3 Kg Kg moles
786 472 0.39 7.860 0.545 0.97
1000 3600 0.88 200.000 0.962 0.97
4072 207.860
Ẋi Partial Average
ϕA, ϕB Vapor Pressure System Temp.
Pressure Emission
Pi pi
(mm Hg) (mm Hg) °C (Kg moles)
T piV/RT
0.97 0.5 61.0 32.31 30 0.0011
0.97 0.9 32 29.86 30 0.0010
1.00 1.0 61 61.00 30 0.0021
636.83 30 0.0215
760
0.07 Kg/hr
0.02 Kg/hr
0.12 Kg/hr
0.60 Kg/hr
Weight qty
Charged
ρ Wi Xi t
Kg/m3 Kg hr
786 1179 1.00 19.650 1.000 0.3
1179 19.650

760 mm Hg
PT - Pi = 698.9890939094 mm Hg
En, N2*Mw = 1.55 Kg
Ewt, N2 /t = 5.18 Kg/hr
0.97 Kg/hr
5.18 Kg/hr
Weight qty
Charged
ρ Wi Xi t
Kg/m3 Kg hr
786 707 1.00 11.790 1.000 0.3
707 11.790

760 mm Hg
PT - Pi = 698.9890939094 mm Hg
En, N2*Mw = 0.93 Kg
Ewt, N2 /t = 3.11 Kg/hr
0.58 Kg/hr
3.11 Kg/hr
Weight qty
Charged
ρ Wi Xi t
Kg/m3 Kg hr
786 307 1.00 5.122 1.000 0.3
307 5.122

760 mm Hg
PT - Pi = 698.9890939094 mm Hg
En, N2*Mw = 0.40 Kg
Ewt, N2 /t = 1.35 Kg/hr
0.25 Kg/hr
1.35 Kg/hr
62.3636
Vapor
Pressur System Temp.
Pressure Emission Emission Emission rate
e
mm Hg °C mm Hg (Kg moles) (Kg) (Kg/hr)
Pi T pi piV/RT ER, ni
61.0 30 61.0109060906 0.0025 0.15 0.49
Component Volume qty

S.No Mol. Weight
Name charged
Mw Vi
Kg/Kgmol m3
1 ETA 142 0.637
Total
Average
Average
Emissio Air velocity Flow Flow
Emission rate
n
(m3/hr) (CFM)
(Kg) (Kg/hr)
ER, ni
0.07 0.07
1.01 1.01
0.48 0.48
Partial
Partial
Pressur Vapor Pressure
Pressure
e
pi @
Pi @ 105°C pi @ 105°C
30°C
(mm Hg) (mm Hg)
(mm Hg)
5.20 350.0 227.68

20.97 405.9940599406 141.86
26.17 369.54
733.83 390.46
62.3636
Vapor
e
61.0 30 61.0109060906 0.0025 0.15 0.49
62.3636
Vapor
e
61.0 30 61.0109060906 0.0019 0.12 0.39
Component Volume qty

S.No Mol. Weight
Name charged
Mw Vi
Kg/Kgmol m3
1 IPA 60 0.9
Total
Average
Average
Emissio Air velocity Flow Flow
Emission rate
n
(m3/hr) (CFM)
(Kg) (Kg/hr)
ER, ni
0.07 0.07
0.02 0.02
0.12 0.12
0.60 0.60
62.3636
Vapor
e
61.0 30 61.0109060906 0.0048 0.29 0.97
62.3636
Vapor
e
61.0 30 61.0109060906 0.0029 0.17 0.58
62.3636
Vapor
e
61.0 30 61.0109060906 0.0013 0.08 0.25
Air velocity Flow Flow
(m3/hr) (CFM)
headspace as it enters the vessel.There

equilibrium vapor composition for the inl
based on the exact composition ,of the i
dilution factor ϕ for the inlet stream will b
1.0
Dilution
factor
Density Time Moles for the
inlet
stream
ρ Wi t Xi
1192 759 1.00 1.00 5.347 1.000 1.00
759 5.347
(m3/hr) (CFM)
(m3/hr) (CFM)
headspace as it enters the vessel.There

equilibrium vapor composition for the inl
based on the exact composition ,of the i
dilution factor ϕ for the inlet stream will b
1.0
Dilution
factor
Density Time Moles for the
inlet
stream
ρ Wi t Xi
786 707 1.00 1.00 11.790 1.000 1.00
707 11.790
(m3/hr) (CFM)
(m3/hr) (CFM)
(m3/hr) (CFM)
nters the vessel.Therefore, the
composition for the inlet stream will be
t composition ,of the inlet stream. A
r the inlet stream will be assumed to be
nters the vessel.Therefore, the
composition for the inlet stream will be
t composition ,of the inlet stream. A
r the inlet stream will be assumed to be
Sl. No. Equipment Tag No MOC Capacity
1 Reactor R-1638 MSGL 8 KL
A) Charging of IPA at temperature 25-30°C to Reactor
Connected Pump Charging rate 10 m3/hr

Tank Capacity 20 KL
Volume qty
S.No Component Name Mol. Weight Density
charged
Mw Vi ρ
m3 Kg/m3
1 IPA 60 2.8 789
Total
The empty vessel was previously made inert with nitrogen, and the vessel is vented to atmos
Partial Pressure of Nitrogen pN2 = PT - Pi
Moles of Nitrogen Emission En, N2 = pnV/RT
Weight of Nitrogen Emission Ewt, N2 = En, N2*Mw
Nitrogen Emission rate ER, N2 = Ewt, N2 /t
Summary
IPA Emission Rate ER, ni = 0.60
Nitrogen Emission rate ER, N2 = 2.87
B Heat the reaction mass to reflux temperature 45°C.
Volume qty
Mol. Weight Density
charged
S.No Component Name
Mw
Vi ρ
Kg/Kgmol m3 Kg/m3
1 IPA 60 2.8 789
Total
Volume of Head Space Available in Reactor = 6.94

Initial Temperature (T1) = 30
Final Temperature (T2) = 45
time for Heating (t) = 2
= 0.251434422
= 0.0249743813
= 0.0524919362
= 0.004195114
Fraction to
Component Name Mol. Weight Avg pi Total
S.No
Mw
Kg/Kgmol (mm Hg)
1 IPA 60 109.00 1.000
Total 109.00 1.000
Summary
Toluene Emission Rate ER, ni = 0.1
C Charge HCl into reactor containing IPA
Assumed that CXB 1 is non Volatile Component
Volume qty
charged
Mw Vi ρ
Kg/Kgmol m3 Kg/m3
1 IPA 60 2.8 789
2 CXB-1 230 0.76 921
3 Water 18 1.4 1000
Total

S.No Component Name Mol. Weight Xi ϕA, ϕB
Mw
Kg/Kgmol
1 IPA 60 0.313 0.98
2 HCl 36.5 1.000 1.00
3 Water 18 0.661 0.98
3 Nitrogen 28
Total
Summary
HCl Emission Rate ER, ni = 0.01
D Heat the reaction mass to reflux temperature 75
Volume qty
Mol. Weight Density
charged
S.No Component Name
Mw
Vi ρ
Kg/Kgmol m3 Kg/m3
1 IPA 60 2.8 789
Total
Volume of Head Space Available in Reactor = 3.147

Initial Temperature (T1) = 45
Final Temperature (T2) = 75
time for Heating (t) = 3
= 0.1154030236
= 0.0238028996
= 0.0800434058
= 0.0679240162
Fraction to
Component Name Mol. Weight Avg pi Total
S.No
Mw
Kg/Kgmol (mm Hg)
1 Toluene 60 351.00 1.000
Total 351.00 1.000
Summary

E Charging reaction mass into centrifuge
Volume qty
charged
Mw Vi ρ
m3 Kg/m3
1 IPA 60 5.4 789
Total
Summary
Toluene Emission Rate ER, ni = 0.78
F Charging IPA and water into cntrifuge
Volume qty
charged
Mw Vi ρ
m3 Kg/m3
1 IPA 60 0.7 789
2 Water 18 0.7 1000
Total 1.4
Summary
IPA ER, ni = 0.04
Water Emission rate ER, H2O = 0.02
R
Weight Mole Vapor

Weight qty Charged Moles Time
Fraction Fraction Pressure
Wi Xi t mm Hg
Kg hr Pi
2209 1.00 36.820 1.000 1 68.0
2209 36.820
sel is vented to atmosphere

mm Hg
= 692 mm Hg
= 0.10 Kg moles
= 2.87 Kg
= 2.87 Kg/hr
Kg/hr
Kg/hr
Mole Partial
Weight qty Charged Moles Vapor Pressure
Fraction Pressure
pi @
Pi @ 30°C
30°C
(mm Hg)
(mm Hg)
Wi Xi
Kg Kg moles
2209 36.820 1.000 68.0 68.00
2209 36.820 68.00
692.00
m3
hrs
Average Average
Average Emission
Emission Emission rate

0.004195114 0.3 0.1
0.00
Kg/hr
Kg/hr
Dilution factor
Weight Mole
Weight qty Charged Moles for the initial
Fraction Fraction
vessel contents
Wi Xi
Kg Kg moles
2209 0.51 36.820 0.313 0.98
700 0.16 3.043 0.026 0.98
1400 0.32 77.778 0.661 0.98
4309 117.641
Average
Ẋi Vapor Partial System Average
Emissio
Pressure Pressure Temp. Emission
n
Pi pi
(mm Hg) (mm Hg) °C (Kg moles) (Kg)
T piV/RT
0.3 150.0 46.07 45 0.0003 0.02
1.0 53 53.00 45 0.0004 0.01
0.6 31 20.09 45 0.0001 0.00
660.93 45 0.0046 0.13
760
Kg/hr
Kg/hr
Kg/hr
Weight Mole Partial

Weight qty Charged Moles Vapor Pressure
pi @
Pi @ 45°C
45°C
(mm Hg)
(mm Hg)
Wi Xi
Kg Kg moles
2209 1.00 36.820 1.000 150.0 150.00
2209 36.820 150.00
610.00
m3
hrs
Average Average
Average Emission

0.07 4.1 1.4
0.07
Kg/hr
Kg/hr
Weight Mole Vapor

Wi Xi t mm Hg
Kg hr Pi
4261 1.00 71.010 1.000 1.5 68.0
4261 71.010

mm Hg
= 692 mm Hg
= 0.20 Kg moles
= 5.54 Kg
= 3.69 Kg/hr
Kg/hr
Kg/hr
Weight Mole Vapor

Wi Xi t mm Hg
Kg hr Pi
552 0.44 9.205 0.191 1.5 68.0
700 0.56 38.889 0.809 1.5 31.0
1252 48.094
mm Hg
= 721.918331042 mm Hg
= 0.05 Kg moles
= 1.50 Kg
= 1.00 Kg/hr
Kg/hr
Kg/hr
Kg/hr
= 62.363577 m3. mm Hg/ (K. Kmol)
Average Average Average

System Partial Air
Emissio Emissio Emissio Flow Flow
Temp. Pressure velocity
n n n rate
°C mm Hg (Kg moles) (Kg) (Kg/hr) (m3/hr) (CFM)

T pi piV/RT ER, ni
30 68 0.0101 0.60 0.60
Vapor Partial
Pressure Pressure
Pi @ 45°C pi @ 45°C
(mm Hg) (mm Hg)
150.0 150.00
150.00
610.00
Compon Volume Weight

Weight
S.No ent Mol. Weight qty Density qty Time Moles
Fraction
Name charged Charged
Mw Vi ρ Wi t Xi
1 HCl 36.5 0.139 1180 164 1.00 1.00 4.494
Total 164 4.494

Average
Emission Air velocity Flow Flow
rate
(m3/hr) (CFM)
(Kg/hr)
ER, ni
0.02
0.01
0.00
0.13
Vapor Partial
Pressure Pressure
Pi @ 75°C pi @ 75°C
(mm Hg) (mm Hg)
552.0 552.00
552.00
208.00

System Partial Air
n n n rate

T pi piV/RT ER, ni
30 68 0.0194 1.17 0.78

System Partial Air
n n n rate

T pi piV/RT ER, ni
30 13.01495917 0.0010 0.06 0.04
30 25.06670979 0.0019 0.03 0.02
headspace as it enters the vessel.Therefore, the
equilibrium vapor composition for the inlet stream will be
based on the exact composition ,of the inlet stream. A
dilution factor ϕ for the inlet stream will be assumed to be
1.0
Dilution
factor
Mole
for the
Fraction
inlet
stream
Kg moles
1.000 1.00
pH adjustment
B Evolution of CO2
S.No Component Name
1 NaHCO3
R-1677
D Charge HCl into reactor containing water and r
S.No
Calculation of the average batch and vapor-phase
S.No
1
2
3
Summary
CO2 may also be released
B) Charge Methanol
S.No Component Name
1 methanol
Total
The empty vessel was previously made inert with n

System Pressure
Partial Pressure of Nitroge
Moles of Nitrogen Emission
Weight of Nitrogen Emissio
Nitrogen Emission rate
Summary
Toluene Emission Rate
Nitrogen Emission rate
Assumed that reaction mass is non Volatile Component

Mol. Weight
S.No Component Name
Mw
Kg/Kgmol
1 Methanol 32
Total
Volume of Head Space Available in Reactor

Initial Temperature (T1)
Final Temperature (T2)
time for Heating (t)
Component Name Mol. Weight

S.No
Mw
Kg/Kgmol
1 Methanol 32
Total
Summary
Methanol ER, ni
Nitrogen Emission rate ER, N2
B Evolution of CO2
S.No Component Name Gas generated Mol. Weight
1 NaHCO3 CO2 84
R-1641 Methanol distillation

Assumed that reaction mass is non Volatile Component
Mol. Weight
S.No Component Name
Mw
Kg/Kgmol
1 Methanol 32
Total

=

S.No
Mw
Kg/Kgmol
1 Methanol 32
Total
Summary
Toluene Emission Rate ER, ni
Vacuum Distillation of methanol

S.No Component Name
Mw Vi
Kg/Kgmol m3
1 Methanol 32 4.1
B) Charge Methanol
Mw
1 Toluene 92
Total
The empty vessel was previously made inert with nitrogen, and the vessel
System Pressure PT
Partial Pressure of Nitrog pN2
Moles of Nitrogen Emissio En, N2
Weight of Nitrogen Emissi Ewt, N2
Summary
Vacuum Distillation of Toluene

S.No Component Name
Mw Vi
Kg/Kgmol m3
1 Toluene 92 2.4
R-1638 & R-1645
CO2
Number of moles
Gas generated Mol. Weight Weight Charged
of gas generated
CO2 84 61.000 0.73
nto reactor containing water and reaction mass
ontents Analysis
Volume qty
Component Name Mol. Weight Density
charged
Mw Vi ρ
Kg/Kgmol m3 Kg/m3
water 18 5.2 1000
Total
the average batch and vapor-phase compositions
Component Name Mol. Weight Xi ϕA, ϕB
Mw
Kg/Kgmol
Water 18 0.056 0.97
HCl 36.5 1.000 1.00
Nitrogen 28
Total
Water emission rate ER, ni = 0.0008162148

HCl Emission rate ER, ni = 0.0202830578
Nitrogen Emission ratER, N2 = 0.55
Volume qty Weight qty
Mol. Weight Density
charged Charged
Mw Vi ρ Wi
m3 Kg/m3 Kg
32 3.2 792 2534
2534
sel was previously made inert with nitrogen, and the vessel is vented to atmosphere
PT = 760 mm Hg
pN2 = PT - Pi =
En, N2 = pnV/RT =
Ewt, N2 = En, N2*Mw =
ER, N2 = Ewt, N2 /t =
ER, ni = 1.11 Kg/hr

ER, N2 = 2.57 Kg/hr
System Pressure PT
Weight qty
Volume qty charged Density Weight Fraction
Charged
Vi ρ Wi
m3 Kg/m3 Kg
3.2 792 2534 1.00
2534
= 5.6 m3
= 30
= 58
= 4 hrs
0.2157168911
0.0619420505
0.1584407078
0.1496884204
Avg pi Average
Fraction to Total Average Emission
Emission
(Kg moles) (Kg)
(mm Hg)
En-i, *Mw
396.50 1.000 0.15 4.8
396.50 1.000 0.15
= 1.2 Kg/hr
= 0.25 Kg/hr
Number of moles Molecular weight

Weight Charged Emission
of gas generated of gas
533.000 6.35 44.0 279.1904761905
System Pressure PT
Weight qty
Charged
Vi ρ Wi
m3 Kg/m3 Kg
4.1 792 3247 1.28
3247
= 5.6 m3
= 30
= 58
= 4 hrs
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
Avg pi Average
Fraction to Total Average Emission
Emission
(Kg moles) (Kg)
(mm Hg)
En-i, *Mw
508.02 1.281 0.19 6.1
508.02 1.281 0.19
= 1.5 Kg/hr
= #DIV/0! Kg/hr
Vapour Pressure
Operating pressure Time Partial pressure
of methanol at 10
Por P Pi
mm Hg Kg mm hg
100 97 16.00 3.000
Weight qty
Charged
Vi ρ Wi
m3 Kg/m3 Kg
2.1 886 1861 1.00
1861
e inert with nitrogen, and the vessel is vented to atmosphere

= 760 mm Hg
= PT - Pi = 723
= pnV/RT = 0.08
= En, N2*Mw = 2.21
= Ewt, N2 /t = 0.74
= 0.12 Kg/hr
= 0.74 Kg/hr
Vapour Pressure
Operating pressure Time Partial pressure
of Toluene at 20
Por P Pi
mm Hg Kg mm hg
50 22 16.00 28.000
Molecular weight of
Emission Time Emission per hour
gas
44.0 31.9523809524 2 15.9761904762
Weight
Weight qty Charged Moles Mole Fraction
Fraction
Wi Xi
Kg Kg moles
5200 1.00 288.889 0.056
5200 288.889
Ẋi Vapor Partial
System Temp.
Pressure Pressure
Pi pi
(mm Hg) (mm Hg) °C
T
0.1 31.7 1.71 30
1.0 21 21.00 30
737.29 30
760
Kg/hr
Kg/hr
Kg/hr
Mole
Weight Fraction Moles Time
Fraction
Xi t
hr
1.00 79.200 1.000 1
79.200
551 mm Hg
0.09 Kg moles
2.57 Kg
2.57 Kg/hr
= 760 mm Hg
Vapor
Moles Mole Fraction Partial Pressure
Pressure
Pi @ 30°C pi @ 30°C
Xi (mm Hg) (mm Hg)
Kg moles
79.200 1.000 209.0 209.00
79.200 209.00
551.00
Average Emission
rate
(Kg/hr)
En-i, *Mw/t
1.2
Time Emission per hour
2 139.595238095
= 760 mm Hg
Vapor
Moles Mole Fraction Partial Pressure
Pressure
Pi @ 30°C pi @ 30°C
Xi (mm Hg) (mm Hg)
Kg moles
101.475 1.281 209.0 267.78
101.475 267.78
492.22
Average Emission
rate
(Kg/hr)
En-i, *Mw/t
1.5
Displacement Vleakage Leakage Totol
m3
0.001 4.0 0.02 0.8
Moles Mole Fraction Time Vapor Pressure
Xi t mm Hg
hr Pi
20.224 1.000 3 37.0
20.224
mm Hg
Kg moles
Kg
Kg/hr
Displacement Vleakage Leakage Totol
m3
0.004 4.0 0.01 0.0118962083

62.36

S.No
vessel contents
0.97 1
Average Average
Average Emission Air velocity

piV/RT ER, ni
0.0000 0.00 0.00
0.0006 0.02 0.02
0.0195 0.55 0.55
R = 62.363577
Average
Vapor Pressure System Temp. Partial Pressure
Emission
mm Hg °C mm Hg (Kg moles)
Pi T pi piV/RT
209.0 35 209 0.0348
Pi @ 58°C pi @ 58°C
(mm Hg) (mm Hg)
584.0 584.00
584.00
176.00
Pi @ 58°C pi @ 58°C
(mm Hg) (mm Hg)
584.0 748.25
748.25
11.75
Total emission
En
Kg
24.17
Average Average
System Temp. Partial Pressure
Emission Emission
°C mm Hg (Kg moles) (Kg)

T pi piV/RT
35 37 0.0040 0.37
Total emission
En
Kg
0.38
Volume Weight
Component Weight
Mol. Weight qty Density qty Time Moles
Name Fraction
charged Charged
Mw Vi ρ Wi t Xi
HCl 36.5 0.5 1180 590 1.00 1.00 16.164
Total 590 16.164
Flow Flow
(m3/hr) (CFM)
m3. mm Hg/ (K. Kmol)
Average Average Air

Flow Flow
ER, ni
1.11 1.11
Average
Emission rate
(Kg/hr) (m3/hr) (CFM)

ER, ni
0.12
Dilution factor
Mole
for the inlet
Fraction
stream
1.000 1.00
Sl. No. Equipment Tag No
1 Reactor R-1638
A) Charging of Bup-1 at temperature 25-30°C to Reactor
0.555
Vacuum transfer/ Lutz pump transfer
From drum
Mw
1 Bup-1 247
Total
The empty vessel was previously made inert with nitrogen, and the vessel is vented to
System Pressure PT
Partial Pressure of Nitrogen pN2
Moles of Nitrogen Emission En, N2
Weight of Nitrogen Emission Ewt, N2
Summary
Bup-1 Emission Rate ER, ni
B) Distill out the chloroform below 85°C (Vacuum distillaiton)
Mol. Weight
S.No Component Name
Mw
Kg/Kgmol
1 Bup-1 247
2 Chloroform 119.38
Total


S.No
Mw
Kg/Kgmol
1 BUP-1 247
2 Chloroform 73.2
Total
Summary
BUP-1 Emission Rate ER, ni
Chloroform Emission Rate ER, ni
C) Charge TBA into the reactor containing BUP-1 and Chloroform at temperature 15-25°C fr
Connected Pump Charging rate 0.18

From Drum
Vessel capacity 2
Assumed that BUP-1 is
Mw
Kg/Kgmol
1 Bup-1 247
Total
Mw
Kg/Kgmol
1 Bup-1 247
2 TBA 73.2
3 Nitrogen 28
Total
Summary
TBA Emission Rate ER, ni
D) Heat the reaction mass to reflux temperature 32°C.
Mol. Weight
S.No Component Name
Mw
Kg/Kgmol
1 BUP-1 247
2 TBA 73.2
Total

=
S.No
Mw
Kg/Kgmol
1 BUP-1 247
2 TBA 73.2
Total
Summary
BUP-1 Emission Rate ER, ni
E) Charging of reaction mass at temperature 30°C to another Reactor
Gravity transfer 6612
Mw
1 Bup-1 247
2 TBA 73.2
Total
System Pressure PT
Summary
F) Distill out the TBA @ 50 to 55°C (Vacuum distillaiton)
Mol. Weight
S.No Component Name
Mw
Kg/Kgmol
1 TBA 73.2
Total

G) Charge Toluene into the reactor containing reaction mass(TBA) and purified water at 25

From Drum
Vessel capacity 2
Mw
Kg/Kgmol
1 TBA 73.2
2 Purified water 18
Total
Mw
Kg/Kgmol
1 TBA 73.2
2 Purified water 18
3 Toluene 92.1
4 Nitrogen 28
Total
Summary

Purified water Emission rate ER, ni
Toluene Emission rate ER, ni
H) Distill out the TBA+Toluene @ 50 to 55°C (Vacuum distillaiton)
Mol. Weight
S.No Component Name
Mw
Kg/Kgmol
1 TBA +Toluene 82.65
Total
Filled volume

S.No
Mw
Kg/Kgmol
1 TBA+Toluene 82.65
Total
Summary
TBA + Toluene Emission Rate ER, ni
I) Charging of reaction mass(Organic layer) at temperature 25°C to another Reactor(Reacto
Pump transfer 6612

Mw
1 Organic layer(Toluene) 92.1
Total
System Pressure PT
Summary
J) Charge Toluene into the reactor containing Aq.layer(Water) at temperature 50-55°C .

From Drum
Vessel capacity
Mw
Kg/Kgmol
1 Aq. Layer (Water) 18
Total
Mw
Kg/Kgmol
1 Aq. Layer (Water) 18
2 Toluene 92.1
3 Nitrogen 28
Total
Summary
Water Emission Rate ER, ni
K) Heat the reaction mass(Combined organic layer + P.water) to 40 -45°C
Mol. Weight
S.No Component Name
Mw
Kg/Kgmol
2 Purified water 18
Total

=

S.No
Mw
Kg/Kgmol
1 Toluene 92.1
2 Purified water 18
Total
Summary
Purified water Emission Rate ER, ni
L) Charging of reaction mass(Organic layer) at temperature 25°C to another Reactor(Reacto
Gravity transfer 3001

Mw
Total
System Pressure PT
Summary
M) Heat the reaction mass(toluene) to 40 -45°C
Mol. Weight
S.No Component Name
Mw
Kg/Kgmol
Total

=

S.No
Mw
Kg/Kgmol
1 Toluene 92.1
Total
Summary
N) Charge HCl into the reactor containing Organic layer(Toluene) at temperature 40-45°C .
Flow rate 0.854
Vessel capacity 2

Mw
Kg/Kgmol
Total
Mw
Kg/Kgmol
1 Organic Layer (Toluene) 92.1
2 HCl 36.5
3 Nitrogen 28
Total
Summary
HCl Emission Rate ER, ni
O) Charge HCl into the reactor containing Organic layer(Toluene) at temperature 40-45°C .
Flow rate 0.3
Vessel capacity 2
Mw
Kg/Kgmol
Total
Mw
Kg/Kgmol
1 Organic Layer (Toluene) 92.1
2 HCl 36.5
3 Nitrogen 28
Total
Summary
P) Charging of reaction mass(Aq. layer) at temperature 25°C to another Reactor
Pump transfer
Mw
1 Aq. layer(Aq.HCl) 36.5
Total
System Pressure PT
Summary
Q) Charging of reaction mass(Slurry) at temperature 0-5°C to Centrifuge
Pump transfer
Mw
1 Aq. layer(Aq.HCl) 36.5
Total
System Pressure PT
Summary for Feed step per lot

R) Charging of acetone(Wash liquid) at temperature 0-5°C to Centrifuge
Pump transfer
Mw
1 Acetone 58
Total
System Pressure PT
Summary for Wash step per lot

Acetone Emission Rate ER, ni
MOC Capacity
MSGL 8 KL
m3/hr

Density Moles
Vi ρ Wi Xi
m3 Kg/m3 Kg
0.833 1560 1300 1.00 5.263 1.000
1300 5.263
gen, and the vessel is vented to atmosphere

= 760 mm Hg
= PT - Pi = 760 mm Hg
= pnV/RT = 0.03 Kg moles
= En, N2*Mw = 0.94 Kg
= Ewt, N2 /t = 0.63 Kg/hr
= 0.00 Kg/hr
= 0.63 Kg/hr
Distillate Weight qty Weight Mole

Density Moles
Volume Charged Fraction Fraction
Vi ρ Wi
m3 Kg/m3 Kg Kg moles Xi
0.833 1560 1300 0.98 5.263 0.965
0.015 1490 22.5 0.02 0.188 0.035
0.848 1323 5.452
= 7.652 m3
= 30
= 85
= 2.5 hrs
0.284
0.003
0.018
0.032
Average
Average
Avg pi Fraction to Total Average Emission Emission
Emission
rate
(mm Hg)
0.00 0.000 0.000 0.0 0.0
31.11 1.000 0.032 2.3 0.94
31.11 1.000 0.032

= 0.0 Kg/hr
= 0.94 Kg/hr
= 0.018 Kg/hr
rm at temperature 15-25°C from drums.
m3/hr
kL

Density Moles
Vi ρ Wi Xi
Kg moles
m3 Kg/m3 Kg
0.833 1560 1300 1.00 5.263 1.000
1300 5.263

Xi ϕA, ϕB
Pi pi
(mm Hg) (mm Hg) °C
T
1.000 0.35 0.4 0.00 25
1.000 1.00 1.0 369 369.00 25
391.00 25
760
= 4.19 Kg/hr
= 1.70 Kg/hr

Density Moles
Vi ρ Wi
0.833 1560 1300 0.39 5.263 0.161
2.882 696 2006 0.61 27.403 0.839
3.72 3306 32.666
= 4.79 m3
= 25
= 32
= 2.5 hrs
0.193
0.080
0.102
0.024
Average
Average
Emission
rate
(mm Hg)
0.00 0.000 0.000 0.0 0.0
358.20 1.000 0.024 1.8 0.7
b
358.20 1.000 0.024
= 0.0 Kg/hr
= 0.7 Kg/hr
= 0.05 Kg/hr
Kg/hr

Density Moles
Vi ρ Wi Xi
m3 Kg/m3 Kg
0.833 1560 1300 0.39 5.263 0.161
2.882 696 2006 0.61 27.403 0.839
3.715
3306 32.666

= 760 mm Hg
= PT - Pi = 450.45 mm Hg
= En, N2*Mw = 0.57 Kg
= Ewt, N2 /t = 1.13 Kg/hr
= 7.03 Kg/hr
= 1.13 Kg/hr

Density Moles
Vi ρ Wi Xi
m3 Kg/m3 Kg Kg moles
1.25 0.7 3306 1.00 45.164 1.000
1.25 3306 45.164
= 7.377 m3
= 30
= 105
= 8 hrs
TBA) and purified water at 25°C
m3/hr
kL

Density Moles
Vi ρ Wi Xi
1.6 696 1300 0.43 17.76 0.158
1.17 1000 1700 0.57 94.44 0.842
3000 112.204

Xi ϕA, ϕB
Pi pi
(mm Hg) (mm Hg) °C
T
0.158 0.93 0.15 369 54.55 25
0.842 0.93 0.79 23.69 18.62 25
1.000 1.00 1.00 28.49 28.49 25
686.83 25
760
= 0.69 Kg/hr
= 0.03 Kg/hr
= 0.49 Kg/hr
= 3.57 Kg/hr

Density Moles
Vi ρ Wi Xi
0.528 0.8 2500 1.00 30.248 1.000
2500 30.248
= 5.368 m3
= 4.632 m3
= 30
= 55
= 2 hrs
0.179
0.060
0.135
0.132
Average
Average
Emission
rate
(mm Hg)
420.30 1.000 0.132 10.9 5.5
420.30 1.000 0.132
= 5.5 Kg/hr
= 0.21 Kg/hr
°C to another Reactor(Reactor-4)
Kg/hr
Density Moles
Vi ρ Wi Xi
m3 Kg/m3 Kg
3.7 960 3543 1.00 38.469 1.000
3.7
3543 38.469

= 760 mm Hg
= PT - Pi = 731.57 mm Hg
= En, N2*Mw = 4.08 Kg
= Ewt, N2 /t = 4.08 Kg/hr
= 0.52 Kg/hr
= 4.08 Kg/hr
at temperature 50-55°C .
m3/hr
kL

Density Moles
Vi ρ Wi
1.14 1000 1140 1.00 63.333 1.000
1140 63.333
Vapor Partial
Ẋi System
Xi ϕA, ϕB Pressure Pressure @
Temp.
@ 55°C 55°C
Pi pi
(mm Hg) (mm Hg) °C
T
1.000 0.92 0.9 117.78 108.60 55
1.000 1.00 1.0 113.57 113.57 55
537.83 55
760
= 0.224 Kg/hr
= 0.598 Kg/hr
= 0.861 Kg/hr

Density Moles
Vi ρ Wi
4.83 940 4516 0.76 49.034 0.382
1.43 1000 1430 0.24 79.444 0.618
6.26 5946 128.478
= 4.24 m3
= 25
= 45
= 1 hrs
0.168
0.006
0.016
0.037
Average
Average
Emission
rate
(mm Hg)
19.57 0.399 0.015 1.4 1.4
29.49 0.601 0.022 0.4 0.4
49.06 1.000 0.037
= 1.4 Kg/hr
= 0.4 Kg/hr
= 0.01 Kg/hr
°C to another Reactor(Reactor-5)
Kg/hr
Density Moles
Vi ρ Wi Xi
m3 Kg/m3 Kg
4.815 930 4502 1.00 48.882 1.000
4.815
4502 48.882

= 760 mm Hg
= PT - Pi = 731.57 mm Hg
= En, N2*Mw = 5.31 Kg
= Ewt, N2 /t = 3.54 Kg/hr
= 0.45 Kg/hr
= 3.54 Kg/hr

Density Moles
Vi ρ Wi
4.815 930 4502 1.00 48.882 1.000
4.82 4502 48.882
= 5.69 m3
= 25
= 45
= 1 hrs
0.225
0.009
0.021
0.035
Average
Average
Emission
rate
(mm Hg)
51.28 1.000 0.035 3.2 3.2
51.28 1.000 0.035
= 3.2 Kg/hr
= 0.01 Kg/hr
e) at temperature 40-45°C .
m3/hr
kL
Density Moles
Vi ρ Wi
4.815 930 4502 1.00 48.882 1.000
4502 48.882
Vapor Partial
Ẋi System
Temp.
@ 45°C 45°C
Pi pi
(mm Hg) (mm Hg) °C
T
1.000 0.68 0.7 74.12 50.75 45
1.000 1.00 1.0 0.00 45
709.25 45
760
= 0.138 Kg/hr
= 0.000 Kg/hr
= 1.172 Kg/hr
e) at temperature 40-45°C .
m3/hr
kL

Density Moles
Vi ρ Wi
3,686 890 3271 1.00 35.516 1.000
3271 35.516
Vapor Partial
Ẋi System
Temp.
@ 45°C 45°C
Pi pi
(mm Hg) (mm Hg) °C
T
1.000 0.81 0.8 74.12 59.96 45
1.000 1.00 1.0 0.00 45
700.04 45
760
= 0.163 Kg/hr
= 0.000 Kg/hr
= 1.156 Kg/hr
another Reactor
Kg/hr

Density Moles
Vi ρ Wi Xi
m3 Kg/m3 Kg
3.44 1.09 1146 1.00 31.397 1.000
3.44
1146 31.397

= 760 mm Hg
= PT - Pi = 760.00 mm Hg
= En, N2*Mw = 3.94 Kg
= Ewt, N2 /t = 3.94 Kg/hr
= 0.00 Kg/hr
= 3.94 Kg/hr
entrifuge
Kg/hr

Density Moles
Vi ρ Wi Xi
m3 Kg/m3 Kg
3.44 1.09 3751 1.00 102.767 1.000
3.44
3751 102.767

= 760 mm Hg
= PT - Pi = 760.00 mm Hg
= En, N2*Mw = 4.22 Kg
= Ewt, N2 /t = 4.22 Kg/hr
= 0.00 Kg/hr
= 4.22 Kg/hr
Kg/hr

Density Moles
Vi ρ Wi Xi
m3 Kg/m3 Kg
0.557 780 434 1.00 7.483 1.000
0.557
434 7.483

= 760 mm Hg
= PT - Pi = 689.86 mm Hg
= En, N2*Mw = 0.62 Kg
= Ewt, N2 /t = 2.48 Kg/hr
= 0.52 Kg/hr
= 2.48 Kg/hr
R = 62.363577 m3. mm Hg/ (K. Kmol)
Time Vapor Pressure
hr Pi T pi piV/RT
1.5 - 30 0.0 0.000
518
51800
mm Hg
Vapor Partial
Pressure Pressure
Pi @ 30°C pi @ 30°C Pi @ 85°C Pi @ 85°C
242.5 8.38 1557 53.83
8.38 53.83
751.62 706.17

S.No
0.35 1 TBA
Total
Average
Average Emission Average Emission Air velocity Flow
Emission rate
(m3/hr)
piV/RT ER, ni
0.0000 0.00 #DIV/0!
0.0572 4.19 4.19
0.0606 1.70 1.70
mm Hg
Vapor Partial
Pressure Pressure
Pi @ 25°C Pi @ 25°C Pi @ 32°C Pi @ 32°C
0.0 0.00 0.0 0.00

369 309.55 485 406.86
309.55 406.86
450.45 353.14
R = 62.363577 m3. mm Hg/ (K. Kmol)
Time Vapor Pressure
hr Pi T pi piV/RT
0.0 25 0 0.0000
0.5
369 25 309.55 0.048
mm Hg
Vapor Partial
Pressure Pressure
Pi @ 30°C pi @ 30°C Pi @ 55°C Pi @ 55°C
449 449.0 1082 1082
449.00 1082.00
311.00 -322.00

S.No
0.93 1 Toluene
Total
Average
Emission rate
(m3/hr)
piV/RT ER, ni
0.0047 0.34 0.69
0.0008 0.02 0.03
0.0026 0.24 0.49
0.0638 1.79 3.57
mm Hg
Vapor Partial
Pressure Pressure
Pi @ 30°C pi @ 30°C Pi @ 55°C Pi @ 55°C
242.82 242.8 597.78 597.78
517.18 162.22
R = 62.363577 m3. mm Hg/ (K. Kmol)
Time Vapor Pressure
hr Pi T pi piV/RT
1 28.4 25 28.43 0.0057

S.No
0.92 1 Toluene
Total
Average
Emission rate
(m3/hr)
piV/RT ER, ni
0.006 0.11 0.224
0.006 0.60 0.598
0.0308 0.86 0.861
mm Hg
Vapor Partial
Pressure Pressure
Pi @ 25°C Pi @ 25°C Pi @ 45°C Pi @ 45°C
28.43 10.85 74.12 28.29

23.69 14.65 71.70 44.34
25.50 72.62
734.50 687.38
R = 62.363577 m3. mm Hg/ (K. Kmol)
Time Vapor Pressure
hr Pi T pi piV/RT
1.5 28.4 25 28.43 0.0074
mm Hg
Vapor Partial
Pressure Pressure
Pi @ 25°C Pi @ 25°C Pi @ 45°C Pi @ 45°C
28.43 28.43 74.12 74.12
28.43 74.12
731.57 685.88
S.No
0.68 1 HCl
Total
Average
Emission rate
(m3/hr)
piV/RT ER, ni
0.003 0.28 0.138
0.000 0.00 0.000
0.0418 1.17 1.172

S.No
0.81 1 HCl
Total
Average
Emission rate
(m3/hr)
piV/RT ER, ni
0.004 0.33 0.163
0.000 0.00 0.000
0.0413 1.16 1.156
R = 62.363577 m3. mm Hg/ (K. Kmol)
Time Vapor Pressure
hr Pi T pi piV/RT
1 25 0 0.0000
R = 62.363577 m3. mm Hg/ (K. Kmol)
Time Vapor Pressure
hr Pi T pi piV/RT
1 5 0 0.0000
R = 62.363577 m3. mm Hg/ (K. Kmol)
Time Vapor Pressure
hr Pi T pi piV/RT
0.25 70.1 5 70.14 0.0023
m Hg/ (K. Kmol)
Average Average
ER, ni
0.000 0.0000
Mw Vi ρ Wi t Xi
73.2 2.882 696 2006 1.00 1.00 27.404
2006 27.404
Flow
(CFM)
m Hg/ (K. Kmol)
Average Average
ER, ni
0.00 0.00
3.51 7.03
Mw Vi ρ Wi t Xi
92.1 1.727 866 1496 1.00 0.50 16.239
1496 16.239
Flow
(CFM)
m Hg/ (K. Kmol)
Average Average
ER, ni
0.52 0.52

Mw Vi ρ Wi t Xi
92.1 1.17 866 1013 1.00 0.500 10.999
1013 10.999
Flow
(CFM)
m Hg/ (K. Kmol)
Average Average
ER, ni
0.68 0.45
Mw Vi ρ Wi t Xi
36.5 1.709 1.09 1863 1.00 2.000 51.041
1863 51.041
Flow
(CFM)

Mw Vi ρ Wi t Xi
36.5 0.6 1.09 657 1.00 2.000 18.000
657 18.000
Flow
(CFM)
m Hg/ (K. Kmol)
Average Average
ER, ni
0.00 0.00
m Hg/ (K. Kmol)
Average Average
ER, ni
0.00 0.00
m Hg/ (K. Kmol)
Average Average
ER, ni
0.13 0.52
1.000 1.00
1.000 1.00
1.000 1.00
1.000 1.00

1.000 1.00
ANTOINNE EQUATION
A
2-propanol 8.88
acetic acid 8.02
acetic acid 8.27
acetone 7.63
acetone 7.12
chloroform 6.95
ethyl acetate 7.10
ethylene glycol 7.25
methanol 8.08
toluene 6.95
water 8.07
Tertiary butyl amine 7.16
Phosphorus oxychloride (POCl3) 4.28
N,N Dimethyl aniline 7.43
From Elliot and Lira, Introductory Chemical Engineering Thermodynam
CLAUSIUS CLAPEYRON EQN
Diphyl Temp
References
HCL data
https://terpconnect.umd.edu/~nsw/chbe301/chap02.pdf
Yaws handbook
https://books.google.co.in/books?id=MevHBQAAQBAJ&pg=PA61&dq
Calculation of Psat Calculation of Tb
T [ C] =
o
92 Psat [kg/cm2] =
Psat [mmHg] =
B C Tmin[oC] Tmax[oC] Psat[mmHg] Psat [kg/cm2] T [°C]

2010.33 252.64 -26 83 1109.41 1.51 102.86
1936.01 258.45 18 118 313.81 0.43 145.07
2258.22 300.97 118 227 331.74 0.45 146.72
1566.69 273.42 57 205 2207.60 3.00 82.00
1210.60 229.66 -13 55 2257.36 3.07 81.23
1170.97 226.23 -10 60 1883.87 2.56 87.58
1244.95 217.88 16 76 1214.17 1.65 103.10
1448.57 134.12 80 200 7.00 0.01 225.47
1582.27 239.73 -97.68 239.43 2047.18 2.78 86.00
1342.31 219.19 -27 111 433.86 0.59 140.91
1730.63 233.43 1 100 566.59 0.77 123.55
1216.94 240.06 -66.96 210.75 3118.83 4.24 69.16
1445.96 -40.12 2 105.3 508.19 0.69 1406.26
1915.11 228.02 69.77 222.66 27.98 0.04 227.10
Chemical Engineering Thermodynamics
328.5 °C Psat 4.00 kg/cm2 a

chbe301/chap02.pdf
d=MevHBQAAQBAJ&pg=PA61&dq=nn+dimethyl+aniline+vapour+pressure+antoine+constants&hl=en&sa=X&ved=0ahUKEwj1s_bg39DfAhXPSH0K
2.2 absolute
1672
Toluene
TemperatureVP
20 22.372368
25 28.998303
30 37.216056
35 47.318081
40 59.633051
45 74.527741
50 92.408742
55 113.72397
60 138.96396
65 168.66294
log10(P) = A - (B / (T + C)) 70 203.39965
80 290.52712
90 405.88297
100 555.72838
108 705.09798
110.6 759.99386
UKEwj1s_bg39DfAhXPSH0KHSEMCFQQ6AEIKjAA#v=onepage&q=7647-01-0&f=false
TemperatureVP TEMPERATUVP TEMPERATUVP
20 33173.222 20 38.22282 20 22.372368 20
25 37045.333 25 51.414714 25 28.998303 25
30 41212.186 30 68.335704 30 37.216056 30
35 45682.326 35 89.807533 35 47.318081 35
40 50463.766 40 116.77986 40 59.633051 40
45 55563.981 45 150.34076 45 74.527741 45
50 60989.9 50 191.72684 50 92.408742 50
55 242.33291 55 113.72397 55
60 303.72099 60 138.96396 60
65 377.62864 65 168.66294 61
70 465.97642 70 203.39965 5
80 694.62861 80 290.52712
82.349592 759.99996 90 405.88297
100 555.72838
108 705.09798
110.6 759.99386
132.93757 17723.742
168.70745 22492.719
212.42572 28321.404
265.48036 35394.85
329.43195 43921.119
406.02505 54132.803
497.1993 66288.499
605.10001 80674.233
732.08837 97604.803
760.00011 101326.1
61.782423 8237.06743

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Reactor System Pollutant Name HBS

HBS Methanol 0.1

HBS Methanol 0.1

A) Charging of Toluene at temperature 25-30°C to Reactor

Above Surface Addition

Assumed that QTP-II is non Volatile Component

Calculation of the average batch and vapor-phase compositions

S.No Component Name Mol. Weight Xi

C) Heat the reaction mass to reflux temperature 105°C.

Assumed that QTP-II is non Volatile Component

Volume of Head Space Available in Reactor =

Component Name Mol. Weight Avg pi

1 Toluene 92.14 281.89

D) Reaction involving multicomponent gas evolution

HCl and unreacted POCl3 is liberated during reaction

time for reaction (t) =

Assumed that QTP-III, PO2Cl, is non Volatile Component

Volume of Head Space Available in Reactor =

Component Name Mol. Weight Avg pi

1 Toluene 92.14 282.03

F Collection of POCl3 and Toluene

G Charging of Toluene at temperature 70°C to Reactor

Volume of Head Space Available in Reactor =

Component Name Mol. Weight Avg pi

Nitrogen Emission rate ER, N2 =

L Charging of IPA+HCL+water on top of reaction mass

Assumed that QTP-IV is non Volatile Component

Initial Vessel Contents Analysis

Calculation of the average batch and vapor-phase compositions

S.No Component Name Mol. Weight Xi

N Charging toluene for washing

Weight qty Weight Mole

rogen, and the vessel is vented to atmosphere

temperature 25-30°C from drums.

Ẋi Vapor Partial System

System Pressure PT = 760

Weight qty Weight Mole

En-i, *Mw En-i, *Mw/t

System Pressure PT = 760

Liberation of Weight Mole

Toluene unreacted POCl3

155.5322008998 Kg/hr 3.5486842

System Pressure PT = 760

Weight qty Weight Mole

En-i, *Mw En-i, *Mw/t

Weight qty Weight Mole

rogen, and the vessel is vented to atmosphere

Weight qty Weight Mole

rogen, and the vessel is vented to atmosphere

rogen, and the vessel is vented to atmosphere

System Pressure PT = 760

Weight qty Weight Mole

En-i, *Mw En-i, *Mw/t

rogen, and the vessel is vented to atmosphere

Weight qty Weight Mole

rogen, and the vessel is vented to atmosphere

Weight qty Weight Mole

rogen, and the vessel is vented to atmosphere

Weight qty Weight Mole

Ẋi Vapor Partial System

Weight qty Weight Mole

Weight qty Weight Mole

rogen, and the vessel is vented to atmosphere

rogen, and the vessel is vented to atmosphere

En-i, Mw En-i, Mw/t

En-i, Mw En-i, Mw/t

En-i, Mw En-i, Mw/t

En-i, Mw En-i, Mw/t

En-i, Mw En-i, Mw/t