TUGAS MATA KULIAH OPERASI TEKNIK KIMIA III

Nama : ANNISA DWI CAESAR

No. Pokok : 2017710450159
Kelas : Teknik Kimia A

Question 11.7-6 Distillation of Multicomponent Alcohol Mixture

A feed of 30 mol % methanol (A), 20% Ethanol (B), 15% n-propanol (C), and 35% n-butanol (D) is
distilled at 101,32 kPa absolute pressure to give a distillate composition containing 95 mole %
methanol & a residue composition containing 5% methanol and the other components as calculated.
The feed is below the boiling point, so that q = 1,1. The operating reflux ratio is 3,0. Assume that
Raoult's law applies & use vapor-pressure data from problem 11.7-3. Calculate the following:
a. Composition & amounts of distillate & bottoms for a feed of 100 mol/h
b. Top & bottom temperatures & numbers of stages at total reflux. (Also calculate the distribution of
the other components)

Solution

Diketahui data konstanta Antoine sebagai berikut :

Komponen A B C
CH4O 8.0724 1574.99 238.87
C2H6O 8.2133 1652.05 231.48
C3H8O 7.6192 1375.14 193.01
C4H10O 7.4768 1362.39 178.73

a. Composition & amounts of distillate & bottoms for a feed of 100 mol/h
Komponen XF Feed Distilate XD Bottom XB
CH4O 0.3 30 28.5 0.97 1.5 0.02
C2H6O 0.2 20 1 0.03 19 0.27
C3H8O 0.15 15 0 0.00 15 0.21
C4H10O 0.35 35 0 0.00 35 0.50
Total 1 100 29.5 1.00 70.5 1.00

b. Top & bottom temperatures & numbers of stages at total reflux. (Also calculate the distribution
of the other components)
Mencari Dew Point Distillate
〖 log⁡Pi 〗 ^sat=A⁡- B/(T+C)⁡⁡ maka
P : 101.32 kPa 760 mmHg Pi^sat= 〖 10 〗 ^^⁡(A⁡−⁡⁡B/(T+C))
T: 65.17 C ki =
〖 "Pi"⁡ 〗
^"sat"⁡/"P
"⁡
Komponen Distilate XD (Yi) A B C Pi Sat ki Xi
CH4O 28.5 0.97 8.0724 1574.99 238.87 780.20 1.03 0.94
C2H6O 1 0.03 8.2133 1652.05 231.48 440.85 0.58 0.06
C3H8O 0 0 7.6192 1375.14 193.01 196.31 0.26 0.00
C4H10O 0 0 7.4768 1362.39 178.73 77.80 0.10 0.00
 Total 29.5 1 1.00

Mencari Bubble Point Bottom Product

〖 log⁡Pi 〗 ^sat=A⁡- B/(T+C)⁡⁡ maka
P : 101.32 kPa 760 mmHg
T: 95.83 C Pi^sat= 〖 10 〗 ^^⁡(A⁡−⁡⁡B/(T+C))
ki =
〖 "Pi"⁡ 〗
^"sat"⁡/"P
"⁡
Komponen Bottom XB (Xi) A B C Pi Sat ki Yi
CH4O 1.5 0.02 8.0724 1574.99 238.87 2326.35 3.06 0.07
C2H6O 19 0.27 8.2133 1652.05 231.48 1465.18 1.93 0.52
C3H8O 15 0.21 7.6192 1375.14 193.01 721.50 0.95 0.20
C4H10O 35 0.50 7.4768 1362.39 178.73 327.08 0.43 0.21
Total 70.5 1 1.00

Menentukan jumlah stage menggunakan Fenske Equation

"Nm=⁡"⁡⁡"log"⁡(("X" _"LD" " . D" )/

("X" _"HD" " . D" ))(("X" _"HB" " .⁡
B"⁡)/("X" _"LB" " . ⁡B"⁡))/"log"⁡ 2.557507
⁡"⍺av"⁡⁡ 0.224348
Nm = 11.39972 = 12

Maka jumlah stage yang dibutuhkan sebanyak 12 stage

III

T+C)⁡⁡ maka
−⁡⁡B/(T+C))
ki = "Xi=⁡"⁡⁡
〖 "Pi"⁡ 〗 "Yi"⁡/"ki
^"sat"⁡/"P "⁡
"⁡
⍺i (⍺LD) ⍺av
1.769754 1.676286
1 1
0.445285 0.468266
0.176469 0.198479
T+C)⁡⁡ maka
−⁡⁡B/(T+C))
ki = "Yi=⁡Xi⁡.⁡
〖 "Pi"⁡ 〗 Ki"
^"sat"⁡/"P
"⁡
⍺i (⍺LB)
1.587755
1
0.492432
0.223235