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CHEMISTRY
Q.1 Which of the following is used in the preparation of Nylon 6, 6
(1) HOOC–(CH2)4–COOH, NH2–(CH2)4–NH2 (2) HOOC–(CH2)6–COOH, NH2–(CH2)6–NH2
(3) HOOC–(CH2)2–COOH, NH2–(CH2)6–NH2 (4) HOOC–(CH2)4–COOH, NH2–(CH2)6–NH2
Ans. [4]
Q.6 If the value of spin only magnetic moment for Mn+2 ion complex is 5.9 B.M. then which of the following can
form compound most suitably -
(1) CN– (2) en (3) CO (4) SCN–
Ans. [4]
2 th
Q.7 An open vessel is heated at 27ºC at constant atmospheric pressure to escape amount of gas. How much
5
temperature is required for it ?
(1) 750 K (2) 750 ºC (3) 500 K (4) 500 ºC
Ans. [3]
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Q.9 8 gm NaOH is dissolved in 18 gm H2O calculate mole fraction of NaOH and it molality =
(1) 0.16, 11.11 (2) 0.18, 11.2 (3) 0.2, 9.2 (4) 0.3, 8.8
Ans. [1]
Q.11 Mn(II) form homoleptic octahedral complex for that which is suitable ligand
(1) CN (2) CO (3) CNS (4) CH2 – NH2
|
CH2 – NH2
Ans. [2]
Q.12 In upper stratosphere O3 layer prevent us from sunlight. What is wavelength of sunlight absorb by O3
(1) 200 nm – 330 nm (2) 0.8 nm – 1.5 nm
(3) 600 nm – 700 nm (4) 450 nm – 550 nm
Ans. [1]
Q.13 Which of the following component is not present in photo chemical smog
(1) O3 (2) PAN
(3) CF2Cl2 (4) CH2 = CH – C – H
||
O
Ans. [3]
Q.15 Radius of nth orbit of a hydrogen atom is 1.5 a0. What is the n/z ratio when a0 is first Bohr radius
(1) 2.17 (2) 2.5 (3) 3.2 (4) 1.98
Ans. [1]
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Q.16 If we have 1 equivalent of grignard reagent, which compound do not give grignard product
CHO CHO CHO CHO
Q.19 Ksp of Ag2CO3 in water is 8 × 10–12 find out the solubility of Ag2CO3 in 0.1 M AgNO3
(1) 8 × 10–12 (2) 8 × 10–13 (3) 8 × 10–10 (4) 8 × 10–14
Ans. [3]
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Q.20 Which of the following curves are not related to isothermal process :
P PV U P
V P V V
(a) (b) (c) (d)
Q.21 The value of rate constant at 400K is 10–5 sec–1 if temperature raises for 400 K to 500 K. Calculate rate
constant at 500 K.
1
T
(1) 10–4 sec–1 (2) 2 × 10–4 sec–1 (3) 4 × 10–4 sec–1 (4) 3 × 10–4 sec–1
Ans. [1]
CH2–CH3
NaOEt
Q.22 Cl C OC2H5
CH3
OC2 H5 O–C2H5
CH2–CH3 CH2–CH3
CH3 CH3
Ans. [1]
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O
|| (A) HNO2
Q.23 CH3 – C – O NH2
(B) CrO3
(C) H+/
(1) CH2 – C – O
||
O
O
(2) CH2 – C – O
||
O
O
O O
(3) CH2 – C
||
O
OH
O
|| O
(4) CH3 – C O
Ans. [1]
Cl NaOH
Q.24
CH3
OH
(1) CH3 (2)
OH
OH
(3) OH (4)
Ans. [3]
NaBH4
Q.25 Product Product is
O O O O–H
OH
(1) (2) (3) (4)
OH
Ans. [4]
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Q.27 If ln HCl = 424.9 –1 cm2 mol–1
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