TECHNOLOGICAL INSTITUTE OF THE PHILIPPINES
-79, 500J /
MANILA
ANALYTICAL CHEMISTRY
NAME:__________________________DATE: 02/26/18
ENGR. LORRAINE CARRILLO
INSTRUCTIONS: Encircle the correct answer and provide
the solutions for problem solving questions. No working
equation written, no credit. Answer in Chrono order, box
your correct answer in problem solving solutions.
1. The ________ is all of the components in the sample
containing an analyte.
a. species b. interference c. matrix d. replicates
2. Calculate the equilibrium concentration of sulfuric acid in a
solution of H2SO4 with 1.0 M analytical concentration
c. 0.00M
3. (a) What mass of Silver Nitrate is needed to convert 2.33 g of
sodium carbonate to silver carbonate ?
b. 7.47 g
4. A zwitterion is an ion that bears both a positive and a negative
charge. Write the zwitterion form of glycine (NH2CH2COOH)
A.NH3+CH2COO¯
5. What mass of barium iodate can be dissolved in 500.0 mL of
water at 25°C given its Ksp = 1.57 x 10 – 9 ?
0.178 g
6. Common name for hydrated sodium sulfate.
a. gypsum b. glauber’s salt c. Epsom salt d. Mohr’s salt
7. Calculate the solubility of barium iodate in a solution
prepared by mixing 200 mL of 0.0100 M barium nitrate with
100 mL of 0.100 M sodium iodate?
b. 3.93 x 10-6
8. An iodide sample which weighs 3.000g is analyzed by the
Volhard process; 49.50 mL 0.2000 M AgNO3 is added, and 6.50
mL 0.1000 M KSCN is needed to titrate the excess silver.
Calculate the percentage of iodide in the sample.
A. 25.36% B. 32.18% C. 39.13% D. NOTG
9. The pH interval over which a given indicator exhibits a color
change is influenced by the following except,
a. temperature b. ionic strength of the medium
c. concentration of the indicator
d. presence of organic solvents and colloidal particles
10. Calculate the hydronium ion concentration in a solution that
is 2.0 × 10-4 M in anilinium hydrochloride, C6H5NH3Cl.
C.5.94 x 10 – 5
11. Calculate the hydroxide ion concentration of a 0.0750 M
NH3 solution (Kb = 1.75 x 10 – 5).
B. 1.15 x 10 – 3 M
12. Calculate the concentration of Ni²⁺ in a solution that was
prepared by mixing 50.0 mL of 0.0300 M Ni²⁺ with 50.0 mL of
0.0500 M EDTA. The mixture was buffered to a pH of 3.0.
A. 1.4 x 10 – 8
13. There are four types of coprecipitation, which of these is not
a type of coprecipitation. , occlusion, and the last is _________.
A. surface adsorption B. mixed-crystal formation
C. mechanical entrapment D. nucleation
14. The following results were obtained in the replicate
determination of the lead content of a blood sample: 0.752,
0.756, 0.752, 0.751, and 0.760 ppm Pb. Calculate the mean and
the standard deviation of this set of data.
A. 0.754 ppm, 0.00377 ppm
15. Elemental analyses using neutralization titration include the
following elements except
a. Chlorine b. Fluorine c. iodine d. Phosphorus
16 – 17. Calculate the (16) thermodynamic potential (in volts) of
the following cell and (17) the free energy change associated
with the cell reaction (in joules).
16. +0.412V 17.
18. – 19. An iron ore was analyzed by dissolving a 1.1324-g
sample in concentrated HCl. The resulting solution was diluted
with water, and the iron (III) was precipitated as the hydrous
oxide Fe2O3‧xH2O by the addition of NH3. After filtration and
washing, the residue was ignited at a high temperature to give
0.5394 g of pure Fe2O3 (159.69 g/mol). Calculate (17) the % Fe
(55.847 g/mol) and (18) the % Fe3O4 (231.54 g/mol) in the
sample.
(18) 33.32% (19) 46.04%
20. The salting coefficient for H2CO3 in seawater is about 0.075.
If a seawater sample has an ionic strength of 0,70 M, what is the
activity coefficient for H2CO3?
a. 0.82 b. 1.13 c. 1.85 d. 2.04
21 - 23. A 50.00-mL aliquot of 0.0500 M NaCN is titrated with
0.1000 M HCl. Calculate the pH after the addition of (20) 0.00,
(21) 10.00, (22) 25.00 mL of acid.(KCN = 6.2 x 10 – 10 )
21. 10.95 22. 9.38 23. 5.34
24 – 25. A 0.8040-g sample of an iron ore is dissolved in acid.
The iron is then reduced to Fe²⁺ and titrated with 47.22 mL of
0.02242 M KMnO₄ solution. Calculate the results of this analysis
in terms of (a) % Fe (55.847 g/mol) and (b) % Fe₃O₄ (231.54
g/mol).
24. 36.77% 25. 50.81%
26. A 0.7121-g sample of a wheat flour was analyzed by the
Kjeldahl method. The ammonia formed by addition of
concentrated base after digestion with H₂SO₄ was distilled into
25.00 mL of 0.04977 M HCl. The excess HCl was then back
titrated with 3.97 mL of 0.04012 M NaOH. Calculate the percent
protein in the flour.
B. 12.16%
27 – 28 . A solution contains NaHCO₃, Na₂CO₃ , and NaOH,
either alone or in permissible combination. Titration of a 50.0-mL
portion to a phenolphthalein end point requires 22.1 mL of 0.100
M HCl. A second 50.0-mL aliquot requires 48.4 mL of the HCl
when titrated to a bromocresol green end point. Calculate the
molar solute concentrations of the (26) Na2CO3 (27) NaHCO3
27. 0.0442M 28. 0.0084M
29. – 30. It is desired to separate Ni and Zn by precipitation as the
sulfides NiS and ZnS. The solubility products are (Ksp) NiS =
4.0×10¯²⁰ and (Ksp)ZnS = 3.0×10¯²⁵. If excess KCN is added to a
solution initially containing 0.01 M each of Ni²⁺ and Zn²⁺ and the
volume remains approximately constant, both ions form the
complex almost exclusively, which precipitates first and (28)
what is the concentration of the precipitating ion and (29) non-ppt
ing ion?
(29) 1.2 x 10 – 22 Zn (30) 3.1 x 10 – 33 Ni