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MEEEGS, AKOLA.
12th SSPCB Chemistry Test on Solid State +Halogen family & Nable gases 28.10.18
46. Chlorine is used in water for 58. The correct order of solubility in water for He, Ne,
(1) Killing germs (2) Prevention of pollution Ar, Kr, Xe, is
(3) Cleansing (4) Removing dirt (1) He > Ne> Ar>Kr>Xe (2) Ne>Ar>Kr>He>Xe
47. Bromine is liberated when an aqueous solution of (3) Xe>Kr>Ar>Ne>He (4) Ar>Ne>He>Kr>Xe
potassium bromide is treated with 59. In XeF2, XeF4, XeF6 the number of lone pairs on Xe
(1) Cl2 (2) I2 is respectively
(3) Dilute H2SO4 (4) SO2 (1) 2, 3, 1 (2) 1, 2, 3 (3) 4, 1, 2 (4) 3, 2, 1
48.When chlorine is passed over dry slaked lime at 60. Among the following molecule
room temperature, the main reaction product is (i) XeO3 (ii) XeOF4 (iii) XeF6
(1) Ca(ClO2)2 (2) CaCl2 Those having same number of lone pairs on Xe are
(3) CaOCl2 (4) Ca(OCl2)2 (1) (i) and (ii) only (2) (i) and (iii) only
49. Which of the following statements is not true (3) (ii) and (iii) only (4) (i), (ii) and (iii)
(1) HF is a stronger acid than HCl 61. When electric discharge is passed through neon at
(2) Among halide ions, iodide is the most powerful low pressure, the colour of the glow is
reducing agent (1) Red (2) Green (3) Yellow (4) Orange
(3) Fluorine is the only halogen that does not show a 62. The mole gas which forms maximum number of
variable oxidation state compounds is
(4) HOCl is a stronger acid than HOBr (1) Ar (2) He (3) Xe (4) Ne
50. Which one of the following oxides is expected 63. Which of the following gases exist more
exhibit paramagnetic behavior abundantly in nature than the others
(1) CO2 (2) SO2 (3) ClO2 (4) SiO2 (1) Helium (2) Neon (3) Argon (4) Krypton
51. Which one of the following orders is not in 64. Which of the following represent noble gas
accordance with the properly stated against it configuration
(1) F2>Cl2>Br2>I2: Electronegativity (1) 1s2, 2s22p6, 3s23p63d10,4s2, 4s24p64d10, 5s25p6
(2) F2 > Cl2>Br2 > I2: Bond dissociation energy (2) 1s2, 2s22p6, 3s23p63d10, 4s24p64d104f14,
(3) F2 > Cl2 >Br2>I2: Oxidizing power 5s25p65d16s2
(4) HI > HBr > HCl >HF: Acidic property in water (3) 1s2,2s2sp6,3s23p63d10, 4s24p64d10, 5s25p65d1, 6s2
52. The correct order of increasing bond angles in the (4) 1s2, 2s22p6, 3s23p63d10, 4s24p64d10
following species is 65. Which of the following in not obtained by direct

(1) ClO 2 <Cl2O<ClO2

(2) Cl2O < ClO2 < ClO 2 reaction of constituent elements
 
(1) XeF2 (2) XeF4 (3) XeO3 (4) XeF6
(3) ClO2 <Cl2O < ClO 2 (4) Cl2O < ClO 2 <ClO2 66. Which of the following lattices exists only as
53. In which of the following options the order of primitive Bravais lattice?
arrangement does not agree with the variation of (1) Monoclinic (2) Trigonal
property indicated against it (3) Cubic (4) Tetragonal
(1) B <C<N<O (increasing first ionization enthalpy) 67. In the closest packing of atoms,
(2) l<Br <Cl<F(increasing electron gain enthalpy) (1) The size of tetrahedral void is greater than that
(3) Li<Na<K<Rb(increasing metallic radius) of octahedral void
(4) both (1) & (2) (2) The size of tetrahedral void is smaller than that
54. Which one of the following orders is correct for
of octahedral void
the bond dissociation enthalpy of halogen molecules
(3) The size of tetrahedral void is equal to that of
(1) l2 >Br2>Cl2>F2 (2) Cl2 >Br2>F2>I2
octahedral void
(3) Br2 >I2>F2>Cl2 (4) F2 >Cl2>Br2>I2
55. Which of the following fluoro-compounds is most
(4) The size of tetrahedral void may be greater or
likely to behave as a Lewis base smaller or equal to that of octahedral void
(1) SiF4 (2) BF3 (3) PF3 (4) CF4 depending upon the size of atoms
56. The correct geometry and hybridization for XeF4 68. If the same type of atoms are packed in cubical
are closest packing (CCP) and hexagonal closets
(1) Square planar. sp3d2 (2) Octahedral, sp3d2 packing (HCP), then
(2) Trigonal bipyramidal, sp d
3 (1) Density of HCP is smaller than that in CCP
(4) Planar triangle, sp3d3 (2) Density of HCP is greater than that in CCP
57. Which one of the following noble gases is the least (3) Densities of HCP is the same as in CCP
polarizable (4) Density of HCP may be smaller than or greater
(1) Xe (2) Ar (3)Ne (4) He than or equal to the density of CCP depending upon
the size of atom.

Chemistry @ Deshpande Sir, Akola:9421754921, Producing PMT CHEMISTRY Topper Since 16 Years.
 Chemistry @ Deshpande Sir, Akola:9421754921, Producing PMT CHEMISTRY Topper Since 16 Years.

69. The interplanar distance between the closest 78.Which of the following statements are correct?
packed layers in the face-centered cubic unit cell is (1) Amorphous solids have long-range order
(1) Equal to the edge length (2) Crystalline solids have flat faces and sharp
(2) Equal to the half of the edge length edges
(3) Equal to the one third of body diagonal (3) Amorphous solids may be classified as
(4) Equal to the half of face diagonal supercooled liquids with high viscosity.
70. Which of the following statements is correct in (4) Both 1 & 2
the zinc-blende type structure of an ionic 79.The radius of the atom is 100 pm. If it
compound? crystallizes with fee lattice, the length of side of unit
(1) Coordination number of each cation and anion cell is
is two (1) 1.414 pm (2) 141.4 pm
(2) Coordination number of each cation and anion (3) 1,414 pm (4) None of these
is four 80.Silver iodide has the same structure as zinc
(3) Coordination number of each cation and anion sulphide, and its density is 5.67 g cm-3, The edge
is sex length of the unit cell is
(4) Coordination number of each cation and anion (1) 4.50 Å (2) 5.50Å (3) 6.50Å (4) 7.50 Å
is eight 81.The coordination number of metal crystallizing
71. In the spinel structure, oxides ions are cubical- in a hexagonal close packed structure is
closest packed whereas 1/8th of tetrahedral voids (1) 12 (2) 4 (3) 8 (4) 6
are occupied by A2+ cations and 1/2 of octahedral 82. If the edge length of the unit cell of sodiu
voids are occupied by B3+ cations. The general chloride is 600 pm, and the ionic radius of CI- ion is
formula of the compound having spinel structure is 190 pm, then the ionic radius of Na' ion is
(1) A2B2O4 (2) AB2O4 (3) A2B4O2 (4) A4B2O2 (1) 310pm (2) 110 pm (3) 220pm (4) 350 pm
72. In a cubic unit cell, seven of the eight corners 83.The intermetallic compound LiAg crystallizes in
are occupied by atoms A and centres of faces are cubic lattice in which both Li and Ag have
occupied by atoms B. The general formula of the coordination number of eight. The class of crystals is
compound is (1) simple cubic. (2) body centered cubic.
(1) A7B6 (2) A7B12 (3) A7B24 (4) A24B7 (3) face centered cubic. (4) none of these.
73. The cubic unit cell of aluminium (molar mass 84. 4 : 4 coordination is observed in
27.0 g mol-1) has an edge length of 405 pm. Its (1) NaCl. (2) CsCl. (3) ZnS. (4) All of these.
density is 2.7 g cm-3. The unit cell is 85.In antiflouride structure, the negative ions
(1) primitive (2) face-centred (1) occupy tetrahedral voids.
(3) body-centred (4) end-centred (2) occupy octahedral voids.
74. Chromium crystallizes with a body-centred (3) are arranged in ccp (4) are arrange in hcp.
cubic lattice with unit-cell edge length equal to 287 86.Which one of the following schemes of ordering
pm. The atomic radius of chromium atom is about close packed sheets of equal sized sphere do not
(1) 143.5 pm (2) 135.0 pm generate close packed lattice?
(3) 124.3 pm (4) 95.7 pm (1) ABACABAC .... (2) ABCBCABCBC .....
75. Silver has an atomic radius of 144 pm. The (3) ABCABC .... (4) ABBAABBA .....
density of silver is 10.6 g cm-3. The type of cubic 87.The number of atoms contained in a fcc unit cell
crystal of silver is of a monoatomic substance is
(1) primitive (2)body-centred (1) 1 (2) 2 (3) 4 (4) 6
(3) face-centred (4) end-centred 88.When NaCl is doped with MgCI2, the nature of
76. A sample of wustite FexO contains one Fe(III) defect produced is
for every three Fe(II). The value of x is (1) interstitial defect. (2) Schottky defect.
(1) 9/8 (2) 8/9 (3) ¾ (4) 4/3 (3) Frenkel defect. (4) none of these.
77. Which of the following statements is not 89.Select the correct statement(s):
correct? (1) Schottky defect is shown by CsCl.
(1) AgBr shows both Schottky and Frenkel defects (2) Frenkel defect is shown by ZnS.
(2) Ferrous oxide can be prepared in its (3) Hexagonal close packing (hcp) and cubic close
stoichiometric composition packing (ccp) structures have the same
(3) Cationic holes in an ionic crystals impart coordination number 12. (4) All of these.
electrical conductivity to the crystal 90.To get n type doped semiconductor, impurity to
(4) Zinc oxide gives a yellow coloured be added to silicon should have the following
nonstoichiometric compound on heating. number of valence electrons.
(1) 2 (2) 5 (3) 3 (4) 1

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