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absorbing ability, in the range of 96% to 97% and a low thermal emittance, in the order of 10%,
and can be produced with high capacity in industrial scale. A reactive gas in an amount of 1 to
50 cm 3 /min kW, preferably 10 cm 3 /min kW, distributed in the coating zone provides that the
metal layer deposed onto the receiving material partly oxidizes during the deposition, whereby a
layer is obtained that comprises a grain mixture of metallic material and metal oxide, whereby
40% to 80%, preferably about 50%, of metallic material is embedded into the metal oxide
closest to the receiving material. The metallic material is successively decreased to about zero
at the surface of the layer by increasing the addition of oxygen at the end of the coating zone.
The metal is selected from the group consisting of nickel, chromium, cobalt, molybdenum, or the
similar, or a mixture thereof, preferably a nickel-chromium-alloy where the ratio of chromium is 4
to 30%, preferably about 20%, and the grain size is <0.005 mm, preferably 0.001 mm.
Each tube contains a sealed cooper pipe (heat pipe). The pipe is
then attached to a black copper fin that fills the tube (absorber
plate). Protruding from the top of each tube is a metal tip
attached to the sealed pipe (condenser). These tubes are
mounted, the metal tips up, into a heat exchanger (manifold). As
the sun shines on the black surface of the fin, the alcohol is
heated and hot vapor rises to the top of the pipe. Water, or
glycol, flows through the manifold and picks up the heat from the
tubes. The heated liquid circulates through another heat
exchanger and gives off its heat to water that is stored in a solar
storage tank. A Thermomax system is simple to install and easy
to expand.
Memotron In the newly developed Memotron tube the maximum working
temperature is controlled by means of a memory metal spring
which is positioned inside the heat-pipe's condenser.
The sputtering is a physical manufacturing process that involves coating a substratum with
metal particles. The manufacturing process takes place in a high vacuum chamber and the
coating process involves three stages, stabilizing layer coating, semi-conductor layer coating
(radiation absorbent layer) and anti-refection layer coating, as shown in the following diagram.
In the vacuum chamber three target plates are installed above the copper fin. By creating a
high-tension field between the targets and the copper fin and a magnetic field parallel to the
target plates, positive helium ion release titanium atoms from the target plate. The atoms strike
the copper fin and because of high kinetic energy of the atoms they
attach themselves to the top of the copper fin. During the process this
copper fin passes three targets plates.
First, a stabilizing layer of pure titanium is laid on the copper fin. This
layer gives the surface of the copper fin long-term stability. Secondly,
the titanium atoms react with oxygen to form an absorbent layer of
titanium oxide (TINOx) on the first layer.
Contents
1. Conversion to Work
2. Domestic Water Heating
3. Refrigeration
4. Upgrading by Reversed Absorption
5. Thermodynamics of Solar Radiation
6. Upper Limits to the Conversion of Solar Energy
Conversion to Work
Heat from a solar collector may be used to drive a heat engine operating in a cycle to produce
work. A heat engine may be used for such applications as water pumping and generating
electricity.
where Ain is the area of the incident solar radiation and Aabs is the area of the absorber. (The
other symbols are the same as in the other lecture notes.) The quantity Ain/Aabs is called the
concentration ratio. High concentration ratios are obtained by making Ain the area of a system
of mirrors designed to concentrate the solar radiation received onto a small absorber of area
Aabs. Heat losses from the absorber are reduced by the smaller size of the absorber.
Consequently, high concentration ratios give high collector temperatures. The stagnation
temperature Tmax is given by:
For example, if the optical efficiency is gamma = 0.8, the incident solar irradiation is qin =
800W/m2, the ambient temperature is Ta = 30°C, and the heat loss coefficient is U = 10W/m2K,
then a concentration ratio Ain/Aabs = 1 (no concentration) gives T max = 94°C, and a concentration
ratio Ain/Aabs = 10 gives Tmax = 670°C.
The available mechanical power from the thermal power output of the collector that would be
obtained using a Carnot cycle is Qout(1 - Ta/T), where the temperatures are absolute
temperatures.
where Tmax depends on the design of the collector and on the solar radiation input q in. Now,
given F', gamma, eta2, Ta, and Tmax, we can find the maximum efficiency obtainable, and the
optimum operating temperature Topt from the condition d(eta)/dT = 0. This occurs at the
optimum temperature
Topt = sqrt[TmaxTa],
eta = etac.eta1.
For example, putting F' = 0.9, gamma = 0.8, eta2 = 0.6, Ta = 30°C = 303K, we get the
efficiencies etamax for different degrees of concentration shown in Table 1. Very low overall
efficiencies are obtained unless operating temperatures greater than 500°C are used.
Expensive concentrating systems are needed to reach these high temperatures, so commercial
viability is difficult.
eta1 = Qr/Qout.
The available mechanical power in the heat extracted from the collector is
Qout(1 - Ta/T).
The mechanical power that would be needed to operate a reversible heat pump delivering heat
Qr to the reservoir at temperature Tr from ambient temperature Ta is
Qr(1 - Ta/Tr).
Therefore, the second law efficiency eta2, defined as the mechanical power needed for heating
divided by the available mechanical power, is given by
Collector efficiency increases as T max increases, but acceptable efficiencies at the temperatures
50°C to 60°C needed for domestic hot water systems are obtainable with flat-plate collectors.
Concentrating collectors producing heat at temperatures T considerably greater than T r give low
second law efficiencies, and are uneconomical because of their high cost. The use of gas or oil
burning at high flame temperatures for producing domestic hot water is also an inefficient waste
of available energy.
These considerations show why domestic flat-plate solar water heaters are commercially
successful.
Refrigeration
We can use thermal solar energy to produce refrigeration by converting solar heat into
mechanical power and using this power to drive a compression refrigerator. However, high
collector temperatures are needed to generate the mechanical power with acceptable efficiency.
Consequently, it is better to use an absorption refrigerator.
1. The use of solar heat to drive off the refrigerant as a vapor from the liquid absorbent at
the collector temperature T.
2. The condensation of the refrigerant, and the rejection of the heat of condensation at
ambient temperature Ta.
3. The evaporation of the refrigerant at the refrigeration temperature Tf with the extraction
of heat from the refrigeration load.
4. The reabsorption of the refrigerant, and the rejection of the heat of adsorption at
ambient temperature Ta.
Let Qout be the solar heating power at temperature T; let Qf be the refrigeration rate at
temperature Tf; and let Qa be the heat rejection rate at temperature T a. By the first law of
thermodynamics, since energy is conserved,
Qout + Qf = Qa.
By the second law of thermodynamics, since the entropy change in the cycle is zero,
(Qout/T) + (Qf/Tf) = Qa/Ta.
In real systems the actual refrigeration rate Qf' is less than ideal. We define the first law
efficiency
eta1 = Qf'/Qout,
The collector temperature T required for operating an absorption refrigerator is such that T - Ta
is slightly greater than Tc - Tf. For example, if Tf = -10°C and Ta = 30°C, then T must be slightly
greater than 80°C. This temperature can be obtained with flat-plate collectors.
The ideal cooling ratio in this example is 0.93. In practice a first law efficiency of 0.6 might be
obtained. In the latter case the second law efficiency becomes 0.64. If the solar collector
efficiency etac is 0.5, then the overall performance of the collector and absorption refrigerator is
eta = etac.eta1 = 0.3.
It is possible in principle to collect solar heat and raise the temperature of the thermal output by
means of an absorption system working in reverse. Some of the heat collected must be
sacrificed, but it is possible to reach temperatures beyond the collector stagnation temperature
Tmax. It is interesting to study the method, even though the absorption system may be expensive
compared with the cost of high temperature collectors.
The cycle (Fig. 2.) is similar to that of a solar absorption refrigeration system, except that the
working temperatures are higher.
Fig. 2. A reversed absorption heat upgrader.
The solar heating power Qout at temperature T is used partly to provide the heat of generation
Qout,1 and partly to provide the heat of evaporation Qout,2. Thus Qout = Qout,1 + Qout,2. The
condensation of the refrigerant occurs at ambient temperature T a accompanied by the rejection
of latent heat Qa. The reabsorption of the refrigerant vapor produces heat Q r rejected to a
reservoir at temperature Tr.
By the first law we have Qout = Qr + Qa, and by the second law we have Qout/T = (Qr/Tr) +
(Qa/Ta). Eliminating Qa, we obtain the ideal heating ratio
As an example, suppose that Ta = 30°C, T = 80°C, and Tr = 140°C. Then the ideal heating ratio
is 0.53. The actual heating ratio would be less than this.
P = (1/3)alpha.T4,
U/V = alpha.T4,
S/V =(4/3)alpha.T3.
The pressure P, the internal energy per unit volume U/V, and the entropy per unit volume S/V
are functions of temperature T only.
We are interested in the available mechanical power extractable from solar radiation. This is
given by the availability potential A defined by
A = U + PaV - TaS,
where Pa and Ta are the pressure and temperature of the environment. The difference A f - Ai
between a final and an initial state is the maximum available work from a closed thermodynamic
system. For radiation we have
Since the entropy remains unchanged we have S2 = S1, so that (T2/T1)3 = V1/V2, and the
temperature decreases. The total energy alpha.T4V also decreases because work is done by
the radiation pressure during the expansion.
Isolated radiation can (in theory) be expanded irreversibly into a second radiation-free volume
whose walls are perfect mirrors without doing work by removing a partition separating the two
volumes. If there is no black particle of matter present, the spectrum remains the same, but the
radiation occupies a larger volume. Consequently, it is no longer blackbody radiation because
its spectrum and energy density do not correspond. As a result we cannot define a temperature
for it.
(T2/T1)4 = V1/V2.
S2/S1 = T2/T1.
Now imagine blackbody radiation escaping from a radiation enclosure through a pinhole into
empty space. Its energy and entropy per unit solid angle do not change with distance because
the rays can be reflected back to their source by an ideal spherical mirror. Since the ratio S/U
per unit solid angle does not change, the temperature of the radiation does not change.
Extraterrestrial solar radiation is similar to radial blackbody radiation from a source at 5800K
after traveling a distance 150 million kilometers. Taking the temperature of the terrestrial
environment as 300K we obtain the availability potential per unit volume A/V = 0.93U/V. This
explains why focusing direct solar radiation gives high temperatures and high first law
thermodynamic efficiencies. Corrections are needed for the apparent size of the sun's disk, and
for the attenuation of the radiation by the atmosphere.
If solar radiation is made diffuse by reflection at an ideally white surface, the spectrum remains
unchanged but the radiation can no longer be focused. A pencil of solar radiation let into a
hollow cavity with white diffusely reflecting walls still has the same energy and spectrum, but the
energy density per unit solid angle has decreased and the entropy has increased. The effect is
the same as if the radiation had been expanded without doing work. After the establishment of
thermodynamic equilibrium with the help of a black particle of matter, the temperature is
lowered and the entropy is further increased. It has been shown that the temperature of solar
radiation after complete diffuse reflection is 1350K. In this case the availability potential is given
by A/V = 0.70U/V. This is of interest as the theoretical upper limit to the energy available for
photosynthesis in plants.
This is of academic interest only; but we may bear it in mind when considering the imaginary
device shown in Fig. 3, which is potentially capable of achieving a high efficiency. It consists of
an ideal compound parabolic concentrator that focuses direct solar radiation into a cavity whose
walls are reflecting except for a blackbody receiver at a temperature Tout. The black receiver
transfers heat to a reversible engine to produce work and reject heat at ambient temperature.
The ideal efficiency of the heat engine is (1 - Ta/T). The cavity is designed so that it exchanges
radiation only with the disk of the sun, which is at a temperature T s. The efficiency of collection
is therefore 1 - (T/Ts)4. Accordingly, the overall efficiency of the system is
If Ts = 5800K and Ta = 300K, then the efficiency has a maximum eta = 0.85 at an operating
temperature T = 2480K. This is the theoretical limit for the conversion of extraterrestrial solar
radiation into mechanical work.
It is arguable that, because solar energy is theoretically a very high temperature resource, we
should try to harness it at this very high temperature for efficient conversion. We should then
use the waste heat for low temperature purposes instead of downgrading the solar energy with
low temperature collectors at the start. Such considerations might be important if solar energy
were to be used for many purposes on a large scale.
TECHNICAL SPECIFICATIONS
Directory
A. General Information
1. Product description
2. Product Use
3. Manufacturer's Experience
B. Glazing System
1. General Description
2. Optical Performance
3. Structural Performance
4. Thermal Performance
5. Fire Behavior
6. Durability
C. Absorber System
1. General Description
2. Optical Performance
3. Thermal Performance
4. Mechanical Integrity
5. Durability
D. Insulation
1. General Description
2. Thermal Performance
3. Fire Behavior
4. Durability
E. Collector Assembly
1. General Description
2. Collector Container
3. Moisture Control
4. System Sealant and Gaskets
F. Installation
1. Handling and Transportation
2. Mounting Procedure
3. Collector Interconnection
4. System Connection
5. Start-up Tests
G. Operation
1. Method of Operation and Control
2. Pressure Drop vs Collector Flow
3. Recommended Flow Rate
4. Maximum Operating Pressure
5. Recommended Operating Pressure
6. Maximum Operating Temperature
7. Stagnation Temperature
8. Recommended Heat Transfer Fluids
H. Maintenance and Warranty
1. Cleaning and Maintenance
2. Manufacturer Servicing
3. Availability of Parts
4. Replacement of Parts
5. Warranty
I. Durability
1. Operating Experience
2. Accelerated Aging Tests
J. Collector Efficiency
1. General Description
2. Test Conditions
3. Time Constant
4. Efficiency
5. Incident Angle Modifier
6. FSEC Standard Day Tests
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A. General Information
1.1 Options
1.3 Weight:
Residential and commercial domestic hot water, process hot water, space heating, pool
heating
None.
3.1 Background
3.2 Production:
3.3 Projects:
Mount Saint Vincent Motherhouse, Halifax, Nova Scotia, Canada. Largest SDHW
system in Canada. Collector type and number: 224 - G32 Collector area: 675 m2 (7,265
ft2) 1.75 GJ/m2 /year (154 MBtus/ft2 /year)
Top of the Mountain Apartments, Halifax, Nova Scotia, Canada. Collector type and
number: 49 - G32; 49 - G40 Collector area: 328 m2 (3,531 ft2) 1.78 GJ/m2 /year (156
MBtus/ft2 /year)
Somerset Place Apartments, Halifax, Nova Scotia, Canada Collector type and number:
120 - G32 Collector area: 356 m2 (3,332 ft2) 2.10 GJ/m2 /year (185 MBtus/ft2 /year)
Thermo Dynamics Ltd. has installed thousands of solar residential domestic hot water
and pool heating systems.
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B. Glazing System
Solite
All glazing is tempered with swiped edges and has a shallow stipple pattern to reduce
specular reflectance.
1.4 Thickness:
3.18 mm (1/8")
1.5 Spacing:
1.6 Weight:
1.7 Appearance:
Translucent; the inner surface is embossed with a stipple pattern which produces a
frosted effect.
Visible light 89.8% ASTM E424-71A Ultra violet light 51% ISO 9050 Solar light/energy
89.5% ASTM E424-71A
2.2 Energy Transmission:
Solar spectrum (0-3 micrometres) 89.5% Infrared spectrum (>3 micrometres) No data
available
1.525
Design Pressure is 2.87 kPa (.416 psi) for 1/8 inch glass with a design factor of 2.5.
Tensile strength is 152 MPa (22,000 psi) with a 2.5 safety factor.
Glazing can withstand 542 J (400 ft-lb) soft-body impact, 3 to 5 times stronger than
annealed glass.
Uniform load testing was conducted at the National Solar Test Facility in May1986 as
part of CSA-378. Positive load: 1.5 kPa (0.22 psi) Negative load: 1.9 kPa (0.28 psi)
No data available
6.0 Durability:
Glass is chemically inert to most chemical solvents and staining agents, and is resistant
to surface weathering, ultraviolet and thermal degradation, and moisture damage.
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C. Absorber System
1.0 General Description:
The absorber consists of eight parallel aluminum fins with integral copper riser tubes,
which are bonded to and completely surrounded by the aluminum by means of high-
pressure cold-rolling process. The absorber coating is Anodic-Cobalt selective surface
or black paint selective surface. The riser/header connection has two parts, a short
copper nipple brazed to the header with the absorber fin soldered to the copper nipple.
None.
1.4 Dimensions:
Tube diameter: rhombic shape with an open area of about 120 mm2 (0.19 in2 )
Tube spacing: 143 mm (5.63")
Header diameter: 22.2 or 28.6 mm (3/4" or 1") nominal
Absorber thickness: 0.5 mm (0.02")
Coating thickness: no data available.
Good thermal transfer due to the high conductivity of aluminum and the bond between
the aluminum fins and copper tubes.
To allow for thermal expansion, the absorber is free to float within the collector
container. EPDM gaskets prevent contact between the copper headers and the
aluminum container.
No data available.
The collector has completed 30-day stagnation testing at The National Solar Test
Facility (NSTF), Mississauga, Canada, with no sign of degradation or loss in
performance.
5.0 Durability:
The absorber and the selective surface are not affected by normal aqueous solutions.
Stagnation testing has shown no thermal degradation.
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D. Insulation
Collectors are insulated around the sides and back with fiberglass board. Complies with
ASTM-C-612 Classes 1 and 2.
1.3 Density:
1.4 Thickness:
Side: 25 mm (1")
Back: 25 mm (1")
No data available
Fiberglas AF530 is inherently fire safe. ULC Flame Spread rating of 15. (compared to
untreated Red Oak as 100 - test method ULC S-102)
4.0 Durability:
No changes should occur to the insulation when subjected to chemicals normally
encountered in use conditions. No thermal degradation has been found after prolonged
stagnation testing. Moisture adsorption is less than 0.2% by volume, 96 hours at 49°C
(120°F) and 95% R.H. Inorganic therefore does not breed or promote bacteria and
fungus. Essentially odorless.
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E. Collector Assembly
The collector is assembled in four stages. First, the collector frame and backing sheet
are assembled. Second, the back and side insulation are installed. Third, the tested
absorber assembly is inserted, and finally, the glazing, seal and cap are installed.
1.1 Container:
1.2 Insulation:
The pre-assembled absorber is fitted into the insulated container with the inlet and
outlet connection pipes protruding through the sides. A high-temperature EPDM gasket
is then fitted onto the pipes and locked into the aluminum frame. The absorber is free to
expand or contract inside the container.
The pre-cut glass is cleaned and fitted onto the retainer ledge in the collector container
with a high-temperature continuous EPDM gasket. A removable aluminum cap stripping
is then secured to the container with black oxide coated stainless steel screws.
Collector container sides are fabricated from aluminum extrusions with an integral
mounting channel. The bottom is an aluminum sheet which fits into a slot in the frame
and is pop-riveted to the sides.
2.1 Materials:
Extruded framework is aluminum 6061-T6 alloy. The back sheet is aluminum utility
grade sheet with a thickness of 0.51 mm (.020")
2.2 Finish:
Inlet and outlet pipes are sealed with high-temperature round EPDM gaskets. The
continuous glazing gasket is a U-shaped EPDM neoprene. Silicone caulking is used for
the container corner sealant.
Header and glazing gasket: ethylene propylene diene monomer rubber (EPDM)
Caulking: silicone rubber
EPDM gasket has a tensile strength of 13800 kPa (2000 psi). Sealants and gaskets do
not corrode other collector materials.
no data available.
no data available.
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F. Installation
1.1 Packaging:
Collector mounting channel allows precise spacing between collectors. Two adjacent
collectors can be fastened to the sub-structure using bolts positioned anywhere along
the bolt track in the collector frame.
3.0 Collector Interconnection:
Piping connections are sweat-soldered to the ends of the collector arrays using
standard plumbing fittings.
G. Operation
Collectors can be used in closed or open loop systems with water or antifreeze.
National Solar Test Facility Date: September 14, 1990 Fluid: water
Below 200 kPa (30 psi) for drainback systems and 135-270 kPa (20-40 psi) for closed
loop systems.
300°C (570°F)
Propylene glycol USP, food grade antifreeze solution for closed loop systems, and
water for drainback and seasonal pool systems. The use of inhibited glycols is not
recommended. DO NOT use ethylene glycol.
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A trouble-shooting guide to help the home-owner maintain and service the equipment is
included in the installation manual. All service and repair is readily available from the
manufacturer or distributor.
The glazing may be replaced in the installed system without removing the collector from
the array by removing the screws holding the glazing cap stripping. Total replacement
time is a maximum of fifteen minutes and requires only a screw driver. Sensors are
clamped on outlet piping using screw-type pipe clamps. Replacement time is
approximately ten minutes. If the recommended installation procedures are followed,
one collector may be replaced in the array without removing another collector.
Collectors are connected together with a standard copper couplings (mechanical or
soldered).
5.0 Warranty:
The solar collector absorber is warranted for a period of ten years. Repair allowances
may also apply. The manufacturer may repair or replace the absorber as required at his
discretion.
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I. Durability
The collector has been subjected to 30 day plus high temperature (204°C;400°F)
stagnation tests at the Canadian National Solar Test Facility with no evidence of
deterioration (CSA F-378). One year of stagnation at DSET laboratories in Arizona were
also conducted in 1982 with no sign of deterioration.
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J. Collector Efficiency
Tested in accordance with SRCC (Solar Rating and Certification Corporation) Standard
OG100-81 with reference ANSI/ASHRAE Standard 93-86. Thermal efficiency is
calculated as recommended in ASHRAE 93-86.
Model: G32
Glazing: low-iron tempered Solite
Absorber material: aluminum fin and tube
Absorber coating: Anodic­Cobalt
Insulation: fiberglass Gross area: 2.96 m2 (31.9 ft2)
Aperture area: 2.78 m2 (30.0 ft2)
Absorber area: 2.87 m2 (30.9 ft2)
1.4 Comments:
The time constant and thermal efficiency test were determined in the solar simulator.
Incident angle modifier was determined from outdoor testing.
Water
4.0 Efficiency:
Efficiency curve is based on gross collector area, and was determined using the indoor solar
simulator. First order efficiency equation:
K(ta) = 1 - 0.154(1/cosq - 1)
The following standard day tests were performed by The Florida Solar Energy Center,
(FSEC).
Standard day: 5045 W·hr/m2.
Energy collected per collector per day:
Clear day: 35.3 MJ/d (33.5 MBtu/d)
Mildly Cloudy: 27.7 MJ/d (26.3 MBtu/d)
Cloudy Day: 9.12 MJ/d (8.65 MBtu/d)
The G Series Collectors described by this brochure, when properly installed and maintained,
meet the minimum standards established by the SRCC, (Solar Rating & Certification
Corporation). This certification does not imply endorsement or warranty of this product by
SRCC.