

Why use an automatic titration?

 Accuracy of results

 Quality and safety

 Productivity

 Economy
 What does CRISON offer?
CRISON covers all stages of the titration:

 Manual titration with optical indicator: Dispensing Burette 1S, Multi-

Burettes 2S and Multi-Burette 4S.

 Semi-automated titration: PH-BURETTE 24 1S and 2S.

 Automated titrators: TitroMatic “Universal” and “Specific” versions.

 Why CRISON titrators?

 More than 25 years of experience in design and manufacturing of

automated titrators.

 Well-defined offers. The instrument ‘s code includes practically all

necessary accessories.

 Exceptional performance - price ratio.

 Cheap maintenance due to the excellent price of the spare parts.

 Why CRISON titrators?
 The instruments are with comprehensible programming and user-guide
displays.

 Do not require long customer training for their use.

Small size instruments, do nor require a lot of space in the laboratory.

 The customer can perform on his own the titrator´s maintenance and
exchange the fungible parts.

 Clear User’s Manuals

 CRISON Dispensing Burettes

3 versions according to number of syringes:

Burette 1S
Multi-Burette 2S
Multi-Burette 4S

Depending on version the Multi-Burette 2S

and Multi-Burette 4S include 1 or 2
integrated peristaltic pumps.
 Dispensing burettes
Two RS232 interfaces. Can be linked to the
Universal TitroMatic for sample preparation
 Connection for automatically controlled stirrer
 Connection for external keypads
 Self-test program for burette calibration

(ISO 8655). Auto-adjustment.

 Applications:
Solution & mixture preparation
Repetitive reagent dispensing
FIA and SIA techniques
 Dispensing burettes
 Burette 1S - 5 dispensing modes

 Burette 2S-4S - 6 dispensing modes

 The Multi-Burettes allow working with
syringes with the same or different volume.
 Possibility for simultaneous dispensing of
equal or different volumes with more then 1
syringe.
 Semi-automated titrator: PH-BURETTE 24
3 instruments in 1
 A high-performance pH-meter
 A burette of high resolution (1 µl)
 Semi-automated end point titrator.

Versions:
 With 1 syringe, PH-BURETTE 24 1S
 With 2 syringes, PH-BURETTE 24 2S.
2 independent working stands.
2 independent sensor inputs.
PH-BURETTE 24 1S
PH-BURETTE 24 2S
 PH-BURETTE 24
As a pH-meter

 2 measuring modes: by stability or in continuous

 Calibration with 1, 2 or 3 buffer solutions
 Special calibration at any pH value
 Direct display of the measuring duration
 PH-BURETTE 24
As a burette

 3 dispensing modes: manual, repetitive and sequential

 Programmable dispensed volume from 1 µl to 999 ml
 Automatic syringe loading
 PH-BURETTE 24
As a titrator

 Once the programmed end point is reached the dispensing automatically

stops.
 Introduction of a calculating factor for result obtaining in the desired
units.
 Two titration modes: manual and sequential.
 PH-BURETTE 24

Features

 Direct and automatic control over the stirring.

 Two RS232C interfaces. One for printer or PC connection. The other
for linking other CRISON instruments (up to 10 burettes and Samplers)
 Connection for external keyboard: 3 keys mouse or PC keyboard.

 Reagent, user and sample identification.

 Specific program for burette volume calibration in accordance with

UNE-EN ISO 8355.
 PH-BURETTE 24
Applications:
 Total acidity in foodstuffs
 Kjeldahl titration
 Chlorides determination
 SO2 determination in wine
 pH measurement and regulation
 pH STAT
 Solution preparation
 Enzyme preparation
 etc, etc ...
 Automated titrators: TitroMatic

Presented in 2 groups:

 Universal automatic titrators

 Specific automatic titrators, Analysers

 General features
 Self-test programme, for calibrating the burette in the user’s own
laboratory.

 Two RS 232 C interfaces: one bi-directional to printer or PC. Another

for connection to any CRISON automatic sample changer or balance.

 Possibility to connect 2 TitroMatic to the same Automatic Sample

Changer.

 Supplied with EC Declaration of Conformity as per directive EMC

89/336/EC, and specifications certificate.
 Analysis according to GLP
 Easy programming in your own language.

 pH calibration with criteria for rejecting electrodes in poor condition. Re-

calibration warning once the programmed time is exceeded.

 The standardisations results are automatically stored in the programmes.

 Statistic calculations in standardisations and sample analysis.

 User, program and reagent identification.

 Data Logger, the last 50 data.

 “Universal” TitroMatic, versions
 TitroMatic 1S with 1 syringe of 10 ml

 TitroMatic 1S 2B with 1 syringe of 10 ml and 2 peristaltic pumps

 TitroMatic 2S with 2 syringes of 10 ml

 TitroMatic 2S 2B with 2 syringes of 10 ml and 2 peristaltic pumps

Included accessories: magnetic stirrer, sensor support, electrode cable and set
of buffers and electrolyte solutions. The electrode must be ordered separately.
 Universal TitroMatic, features
 Syringes:
TitroMatic 2S: 2 titrant reagents ready for use at any moment.

 Peristaltic pumps:
For auxiliary reagent dispensing
For automatic sample levelling

 Electrode, A.T.C. and stirrer connections:

The TitroMatic 2S are double instruments:
2 sensors connections
2 working place
2 stirrers
 TitroMatic Main Menu
TITRATE: Performing of the titration programs.

MEASURE: pH-meter, pH or mV measurements.

CALIBRATE: Calibration in 1, 2 or 3 points.

MANUAL ACTUATION: Loading and cleaning of syringes and pumps.

PROGRAMMING: 5 programs per syringe. Select among Calculated

Equivalence Point, Defined Equivalence Point and Manual titration.

DISPLAY DATA: Data Logger of the last 55 results.

SYSTEM: GLP options, Data Output, Balance or Sampler configuration.

 Titration modes
 DEP, Defined End Point: The instruments adds titrant reagent until a
programmed pH/mV value is reached. The titrant addition is carried out
in continuous, adjusting the dispensing flow as a function of the end point
distance.

 CEP, Calculated Equivalence Point: The instrument follows the

potential (pH) variation of the sample during the titration, locating the
equivalence point of the reaction.

 Manual titration: The instrument presents on the display the potential

(pH) variation of the sample due to the manual addition of the titrant
reagent.
 Specific TitroMatic, Analyzers, features
 Automated titrators with programs adapted to perform specific analysis.
 Suitable instruments for the laboratories which perform these analysis

in routine way requiring high productivity.

 Presented as complete configurations with all accessories and sensors

necessary to perform the analysis.

 They allow the maximum automation of the process and optimum

analysis duration.
 Reliable and precise results with minimum intervention of the user.
 Specific TitroMatic, versions
Foodstaff
 pH, total acidity and formol number
 Chlorides (Morh method)
 Chlorides in meat (Carpentier-Volhard method)
 pH, acidity and chlorides in foodstuffs (Mohr method)
 Determination of nitrogen, according to Kjeldahl method
 Reducing sugar

Water
 COD
 pH, conductivity and alkalinity (p and m points)
 Specific TitroMatic, versions
Oenology
 pH and total acidity

 SO2

 pH, total acidity and SO2

 Reducing sugar

pH STAT

Karl Fischer, volumetric titrations

 TitroMatic Karl Fischer, versions

 TitroMaticKF 1S, 1 syringe.

The most economic.

TitroMatic KF 1S-2B, 1 syringe and 2 integrated pumps.

The most sold. Complete automation of reagents handling.

TitroMatic KF 2S-2B, 2 syringes and 2 integrated pumps.

Two titrant reagents ready to use or one reagent and water volume
standard in use straightway.
(Main customer - petro-chemical industry).
 Why CRISON TitroMatic KF?
 Very easy to use, dedicated instrument with intuitive keypad and user-
guide messages. Experience in Spain: auto-installed by the customers.

 Adaptable to all KF reagents on the market (without pirydine).

 Automatic and periodic elimination of the bubbles formed in the reagent

circuit.

 High analysis speed.

 Reasonable price. Exceptional performance.

 How does the TitroMatic Karl Fischer work?
1. Dispensation of the solvent
2. Medium neutralization
3. Automatic drift control
4. Standardization of the titrant reagent
5. Titrating the sample
6. The results
7. Next sample, empting the vessel or rest cycle
 Accessories
 External PC key board

 Printer

 Communication with PC
TiCom
CRISON Capture
 Automatic sample changers

Sampler 15
 Automatic sample changers

Sampler 20
 Automatic sample changers

Sampler 45