Ser GG-RO-1105 Please check total printed pages before start:- 8 Roll No. : ORE sees CUMULATIVE EXAMINATION - 2014-15 SUBJECT - XI CLASS - CHEMISTRY Time : 3 Hrs. > General Instructions: a) All the questions are compulsory. b) There are 26 questions in total. c) Questions 1 to 5 are very short answer type questions and carry one mark each. d) Questions 6 to 10 carry two marks each e) Questions 11 to 22 carry three marks each. f) Questions 23 is value based question carrying four marks. g) Questions 24 to 26 carry five marks each. h) ‘There is no overall choice. However, an internal choice has been provided in one question of two marks, one question of three marks and all three questions in five marks each. You have to attempt only one of the choices in such questions. i) Use of calculators is not permitted. However, you may use log tables if necessary. [PT.0.]GG-RO-1105 2 Q1. Find out oxidation state of S in H,SO, 1 02. Give an example of intramolecular hydrogen bonding 1 axe Which of the following species will have the largest and “smallest size?Mg, Mg’, Al, Ale* 1 Q4. The vander Waals constants for two gases are as follows GAS a (atom L? mol?) b (L moi") x 1.39 0.0391 ¥ 3.59 0.0427 Which of them is more easily liquifiable? 1 Q5. For the reaction 2Cl(g) Cl,(g), what will be the signs of AH and 4S? 1 Qé. What will be the mass of one 'C atom in g? 2 Q7/ Write electronic configuration of Cu (at. no. 29) and Nitrogen 7 ig ig ~ (at. no. 7). Indicate the no. of unpaired electron in each OR Which is more stable Fe* or Fe** and why? 2 Qs Give electronic structure of Protium, Deuterium and Tritium What is common in them? Out of these which is radioactive? 2 Q% Explain the structure of carbonate ion in terms of Resonance 2 QJ6. Assign the position of the element having outer electronic configuration- (a) ns*np* for n=4 [P.1.0.]3 GG-RO-1105 (b) (n-1)d@ns? for n=5 2 ,O11. Balance the equation; ————MnO, + Fe** Mn2* + Fe®+ (acidic medium) 3 Q12.A compound contains 4.07% of Hydrogen, 24.27% of Carbon and 71.65% of Chlorine. Its. molecular mass is 98.96. What are its Empirical and Molecular formulae? 3 as ‘n' moles of a gas, write Vander Waal’s gas equation. Q13. hp) A sample of a gas was found to occupy a volume of 900 cm® at 27°C. Calculate the temperature at which it will occupy a volume of 300 em’, provided the pressure is kept constant. 3 014. (ay Commercially available conc. HCl is 38% HCl by mass.What is the molarity of this solution? (given=the density is 1.10gm/L (6) What volume of conc.HCl is required to make 1.00L of 0.10M HCI? 3 Q15.Assign reason for the following. a (a) Cl has more negative electron gain enthalpy than F. __——(b) First ionisation enthalpy of N is higher than O. 2) Size of anion is greater than its corresponding atom.3 Q16.(a) Write the equilibrium constant expression for the following reaction. CaCO,(s)+theat ___, CaO(s) + CO,(g) [P.T.0.] ee