Professional Documents
Culture Documents
, 427±435
University of Ghent
In order to study the influence of existing cracks in concrete structures on the carbonation and chloride penetration,
small-scale experiments were carried out on mortar prisms. Six different mortar compositions were investigated,
stored in five different environmental conditions. At regular times, the carbonation and chloride penetration of
cracked and uncracked specimens were examined experimentally. On the basis of the experimental results, a
tentative formula is established, quantifying the influence of the cracks as a function of crack width and crack
length. The statistical variation of the influence factor can be modelled by means of a log-normal distribution.
Notation
ëM
CL factor describing statistical variation of ãM
CL
A constant depending on diffusion resistance of
material
ACA constant depending on carbon diffusion resis-
Introduction
tance of material
ACL constant depending on chloride ion diffusion The durability of concrete structures is a very impor-
resistance of material tant issue in actual concrete research. Especially, con-
d crack depth crete structures in a marine environment seem to be
d0 1 mm prone to durability problems because of the presence of
t time chlorides, leading to an important number of corrosion
w crack width problems. Furthermore, concrete structures in a marine
w0 1 mm environment often tend to be rather massive, such as
X carbonation depth quay walls, locks and concrete armour units on break-
ãCA crack influence factor for carbonation waters. The service life of these massive concrete struc-
ãMCA crack influence factor based on maximum tures can severely be reduced because of early-age
values for carbonation thermal cracking due to the heat of hydration, in com-
ãCL crack influence factor for chloride penetration bination with subsequent acceleration of degradation
ãM
CL crack influence factor based on maximum owing to, for example, carbonation, chloride and sulfate
values for chloride penetration diffusion and frost.
ëCA factor describing statistical variation of ãCA At the Magnel Laboratory for Concrete Research,
ëM
CA factor describing statistical variation of ãM
CA University of Ghent, several research programmes have
ëCL factor describing statistical variation of ãCL been conducted concerning massive concrete armour
units for breakwaters, dealing especially with thermal
stresses due to the heat of hydration. A new simulation
Magnel Laboratory for Concrete Research, Department of Structur-
method for early-age concrete thermal cracking has been
al Engineering, University of Ghent, Technologiepark-Zwijnaarde 9,
developed, based entirely on the degree of hydration,
B-9052 Ghent, Belgium. 1
including basic creep behaviour and basic shrinkage.
(MCR 780) Paper received 28 April 1999; last revised 3 August The work reported in this paper is a result of a
1999; accepted 25 August 1999 recently started durability evaluation project concerning
427
Downloaded by [ Mr Michel Di Tommaso] on [25/08/17]. Copyright © ICE Publishing, all rights reserved.
De Schutter
possibly cracked massive concrete structures in a mar- the notches contained more cement than the surface of
ine environment. By means of some selected experi- a real crack in a concrete element. The effect of this
ments, the influence of existing thermal cracks on the difference will be studied in a subsequent experimental
further degradation of the concrete structure is exam- programme.
ined. The main purpose of the entire project is a prob- Six different mortar compositions were investigated,
abilistic formulation of the service life of marine as given in Table 1. CEM I 42.5 R is a rapid-hardening
concrete structures taking into account possible early- Portland cement, CEM III/B 32.5 HSR LA is a high-
age thermal cracking due to the heat of hydration, and sulfate-resisting blastfurnace slag cement with a limited
considering the interaction between different degrada- alkali content, and CEM V/A 32.5 is a composite ce-
tion mechanisms. ment made of Portland clinker, blastfurnace slag and
fly ash. In some series, fly ash or silica fume was
added. Owing to practical limitations, only one water±
cement ratio (0´50) was considered. STD sand was
Durability of cracked concrete structures
used, as prescribed for traditional mortar tests. Six dif-
It is important to note that the parameters controlling ferent combinations of crack width and crack depth
strength are not completely identical to those control- were considered, as given in Table 2. Zero crack width
ling durability. Especially, the condition of the outer and depth means that no crack is present.
concrete layer, the concrete cover, will be a main con- During the first 28 days the mortar specimens were
trolling factor in the rate of deterioration. The occur- stored under water. At the age of 28 days an epoxy
rence of small cracks in the skin of the concrete will coating was applied to all surfaces, except on the sur-
not always jeopardize the durability of the material. face containing the crack. In this way the coated sur-
However, under certain conditions, an extensive growth faces were protected from carbon and chloride
of this cracking can favour reinforcement corrosion, a penetration. Starting from 28 days, the specimens were
2
very frequent type of pathology in concrete structures. stored in different conditions as given in Table 3. Five
Although a consensus exists about the fact that a different treatments were considered: a 10% CO2 en-
cracked concrete cover zone is harmful to the durability vironment, a 3´5% NaCl solution and combinations of
3,4
of reinforced concrete structures, no quantification of CO2 environment, NaCl solution and water.
this phenomenon is found in the literature. For a global At regular times (8, 12, 16, . . . weeks) the carbona-
evaluation of the durability of concrete structures and a tion and the chloride penetration were examined experi-
reliable service life prediction, a good knowledge of
the effect of cracks is definitely needed. By means of
experiments on small mortar prisms in different en- Table 2. Combinations of crack width and crack depth
vironmental conditions, a first attempt has been made Crack depth: Crack width: mm
to quantify the influence of cracks in concrete struc- mm
tures on carbonation and chloride penetration. 0 0´2 0´3 0´5
0 X
5 X X X
10 X X
Experimental programme
In the experimental programme carbonation and
chloride penetration tests were performed on mortar Table 3. Treatments
specimens of size 40 mm 3 40 mm 3 160 mm, pro- Code Treatment
vided with different sizes of artificial cracks with a A Permanent 10% CO2 environment
width up to 0´5 mm and a depth up to 10 mm. The B Permanent 3´5% NaCl solution
specimens were made using traditional mortar moulds. C Cycle 1 week 10% CO2 environment/1 week 3´5% NaCl
The cracks were realized as notches by means of the solution
D Cycle 1 week 10% CO2 environment/1 week water
positioning and removal afterwards of thin copper
E Cycle 1 week water/1 week 3´5% NaCl solution
sheets inside the specimens. As a result the surface of
Downloaded by [ Mr Michel Di Tommaso] on [25/08/17]. Copyright © ICE Publishing, all rights reserved.
Influence of cracks in concrete structures
mentally. At each time, two slices of thickness 1 cm penetration depth in treatment B is given in Fig. 5 for
were sawn from each mortar specimen. The first slice the uncracked specimens and in Fig. 6 for the speci-
was sprayed with a phenolphthalein solution in order to mens with a crack width of 0´2 mm and crack depth of
5
determine the carbonated zone. The second slice was 5 mm.
sprayed with a 0´1 N aqueous solution of silver nitrate The carbonation of mortar and concrete can be con-
in order to determine the depth of penetration of chlor- sidered as a Fickian diffusion problem8 governed by
ide ions. For a discussion of the accuracy of the silver the equation
6
nitrate solution method, see Otsuki et al. According to p
6 XA t (1)
Otsuki et al. the (soluble) chloride ion concentration
at the colour change border is recognized to be of the in which X is the carbonation depth, t is the exposure
order of 0´15% by weight of cement. This value is not time, and A is a constant depending on the diffusion
a threshold value of chloride above which corrosion resistance of the material. Assuming as a first approxi-
would be regarded as taking place. The silver nitrate mation that capillary absorption can be neglected, the
solution method consequently does not indicate chloride penetration can also be considered to be dif-
whether corrosion would occur or not, but merely fusion controlled. Equation (1) is valid for a homo-
serves as a quick tool to compare chloride penetration geneous material. A cracked material is not
in different circumstances, e.g. cracked and uncracked. homogeneous, providing preferential channels for the
As the onset of corrosion itself is not the subject of this diffusion of gases and fluids. However, as a first ap-
7
paper, reference is made to the literature. proximation, equation (1) can still be considered in
After sawing the two slices, the remaining mortar order to quantify the influence of the existing cracks on
specimen was covered again with the carbon- and carbonation and chloride penetration. In a further re-
chloride-resisting epoxy coating (except for the search project, a more detailed simulation procedure
`cracked' surface) and the treatment according to Table will be worked out, evaluating the approximations
3 was continued. made in this section.
On the basis of the experimentally obtained carbona-
tion depths and chloride penetration profiles, the con-
stant A can be estimated by means of regression
Experimental results analysis for each combination of mortar composition,
treatment and crack size. The results for the carbona-
At the age of 28 days the density, strength and water tion, indicated by ACA, are given in Table 5. The results
absorption of the different mortar compositions were for the chloride penetration, indicated by ACL, are given
determined. The results are given in Table 4. The ab- in Table 6. Owing to an erroneous application of the
sorption results were obtained by immersion of the protective epoxy layer on some uncracked reference
specimens in water until saturation. No significant dif- specimens, some A values could not be determined,
ferences were noticed between the different composi- leaving some blank fields in Tables 5 and 6. The
tions. erroneous application of the protective epoxy layer also
For each specimen the carbonation depth and the explains the fact that in Fig. 5 some curves decrease
chloride penetration were determined as described with time.
above. Fig. 1 shows some carbonation profiles for ser-
ies 1, whereas Fig. 2 shows some chloride penetration
profiles for series 2. For an initial quantification of the
effect of the cracks, the mean carbonation and chloride
Quantification of the influence of cracks
penetration depths were calculated from the measured
profiles. As an example, the mean carbonation depth The influence of the cracks on the carbonation and
for the different mortar compositions tested in treat- chloride penetration can be quantified by looking at the
ment A is given in Fig. 3 for the uncracked specimens, ratio between the A value for uncracked prisms and the
and in Fig. 4 for the specimens with a crack width of A value for the cracked prisms. This ratio is called the
0´5 mm and crack depth of 10 mm. The mean chloride crack influence factor and is denoted by the symbol ã,
Downloaded by [ Mr Michel Di Tommaso] on [25/08/17]. Copyright © ICE Publishing, all rights reserved.
De Schutter
40 40
No crack Crack width 0.2 mm
Crack depth 5 mm
Carbonation depth: mm
Carbonation depth: mm
28w 28w
30 20w 30 20w
16w 16w
12w 12w
20 8w
20 8w
10 10
0 0
220 210 0 10 20 220 210 0 10 20
Distance from crack: mm Distance from crack: mm
40 40
Crack width 0.3 mm Crack width 0.3 mm
Crack depth 5 mm Crack depth 10 mm
Carbonation depth: mm
Carbonation depth: mm
28w 28w
30 20w 30 20w
16w 16w
12w 12w
20 20 8w
8w
10 10
0 0
220 210 0 10 20 220 210 0 10 20
Distance from crack: mm Distance from crack: mm
40 40
Crack width 0.5 mm Crack width 0.5 mm
Crack depth 5 mm Crack depth 10 mm
Carbonation depth: mm
Carbonation depth: mm
28w 28w
30 20w 30 20w
16w 16w
12w 12w
20 8w
20 8w
10 10
0 0
220 210 0 10 20 220 210 0 10 20
Distance from crack: mm Distance from crack: mm
Downloaded by [ Mr Michel Di Tommaso] on [25/08/17]. Copyright © ICE Publishing, all rights reserved.
Influence of cracks in concrete structures
40 40
No crack 28w
Crack width 0.2 mm 28w
Chloride penetration: mm
Chloride penetration: mm
20w
Crack depth 5 mm 20w
30 30
16w 16w
12w 12w
8w 8w
20 20
10 10
0 0
220 210 0 10 20 220 210 0 10 20
Distance from crack: mm Distance from crack: mm
40 40
Crack width 0.3 mm 28w Crack width 0.3 mm 28w
Chloride penetration: mm
Chloride penetration: mm
10 10
0 0
220 210 0 10 20 220 210 0 10 20
Distance from crack: mm Distance from crack: mm
40 40
Crack width 0.5 mm 28w
Crack width 0.5 mm 28w
Chloride penetration: mm
Chloride penetration: mm
10 10
0 0
220 210 0 10 20 220 210 0 10 20
Distance from crack: mm Distance from crack: mm
30
25 CEM I 42.5 R
Mean carbonation depth: mm
0
0 10 20 30
Exposure time: weeks
Downloaded by [ Mr Michel Di Tommaso] on [25/08/17]. Copyright © ICE Publishing, all rights reserved.
De Schutter
30
25 CEM I 42.5 R
0
0 10 20 30
Exposure time: weeks
Fig. 4. Mean carbonation depth for treatment A, crack width 0´5 mm, crack depth 10 mm
20
Mean chloride penetration: mm
CEM I 42.5 R
15
CEM III/B 32.5 HSR LA
0
0 10 20 30
Exposure time: weeks
20
Mean chloride penetration: mm
CEM I 42.5 R
15
CEM III/B 32.5 HSR LA
0
0 10 20 30
Exposure time: weeks
Fig. 6. Mean chloride penetration for treatment B, crack width 0´2 mm, crack depth 5 mm
Statistical variation
steel as a function of the crack width, ranging between
0´1 mm and 0´3 mm. This is in good agreement with The statistical variation of the crack influence factor
equation (3) when considering crack widths ranging can be described by adding a factor ë to equations (3)
from 0´1 mm to 0´3 mm. and (4):
432 Magazine of Concrete Research, 1999, 51, No. 6
Downloaded by [ Mr Michel Di Tommaso] on [25/08/17]. Copyright © ICE Publishing, all rights reserved.
Influence of cracks in concrete structures
Downloaded by [ Mr Michel Di Tommaso] on [25/08/17]. Copyright © ICE Publishing, all rights reserved.
De Schutter
10 10
1.5
1.8
1.4
8 8
1.3 1.6
Crack depth: mm
Crack depth: mm
6 6
1.2 1.4
4 4
Crack influence
Crack influence
factor based on
factor
maximum values
2 2
1.1 1.2
0 0
0 0.1 0 .2 0.3 0.4 0.5 0 0.1 0.2 0.3 0.4 0.5
Crack width: mm Crack width: mm
Fig. 7. Crack influence factor for carbonation Fig. 9. Crack influence factor based on maximum values for
carbonation
10
2
1.8 10
8
2.6
1.6 8
Crack depth: mm
2.2
Crack depth: mm
1.4 6
4
" 0:4676 0:1020 # Fig. 10. Crack influence factor based on maximum values for
: d w chloride penetration
ãM
CL ëM
CL exp 0 3976 (8)
d0 w0
Downloaded by [ Mr Michel Di Tommaso] on [25/08/17]. Copyright © ICE Publishing, all rights reserved.
Influence of cracks in concrete structures
Downloaded by [ Mr Michel Di Tommaso] on [25/08/17]. Copyright © ICE Publishing, all rights reserved.