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Motivation
Hg0
Atmosphere
Mixed layer
Deep ocean
Radiation
HgIItotaq
kbio
krad
kd
Hg0aq HgIIaq HgPaq
krad
Changes in
kdark Chlorophyl conc.
mixed layer depth
Hgtotaq
Refs: Mason & Sullivan 1999, Kirk et al. 2008, Laurier et al. 2004, Sunderland et al. 2009
Results
Refs: Galathea expedition, Temme et al. 2003, Laurier et al. 2003 , Laurier et al. 2007, Lamborg et al. 1999, Environmental Canada 2003, EMEP 2005, Ebinghaus et al. 2002, Kellerhals
et al. 2003, Weiss-Penzias et al. 2003, Poissant et al 2005, Baker et al. 2002
Results
Fractions
0.08
0.06
1 2 3 4 5 6 7 8 9 10 11 12
Months
Kejimkujik
0.12
New Ocean simulation
Old Ocean simulation
Observations 95-02
0.1
Fractions
Mace Head
New Ocean R = 0.53*
0.08
Old Ocean R = -0.73**
Kejimkujik 0.06
New Ocean R = 0.74** 1 2 3 4 5 6 7 8 9 10 11 12
Months
Old Ocean R = 0.45 Delat
0.12
New Ocean simulation
Delta Old Ocean simulation
New Ocean R = 0.52 Observations 99-01
0.1
Old Ocean R = -0.15
Fractions
0.08
0.06
1 2 3 4 5 6 7 8 9 10 11 12
Months
Refs: Environmental Canada 2003, Ebinghaus et al. 2002, Baker et al. 2002
Conclusion
But…
Our netflux of Hg0 from the ocean is at the upper limits of earlier estimates
With current flux models it is not possible to explain the high concentrations of
Hg0aq in the mixed layers.
Acknowledgement
The Danish Expedition Foundation
Villum Kann Rasmussen Foundation
Knud Højgaards Foundation
Oticon Foundation
Andreassens & Hougaards Foundation
Nordea Foundation
Carlsbergs Mindelegat
Electric Power Research Institute
Britt Tang Soerensen
Matthew Johnson (University of Copenhagen)