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OBJECTIVE:
To analyze and determine the paint chips layers from different cars using stereomicroscope and
ATR-FTIR.
PROCEDURES:
Part A
Part B
Part A
Observation
Details of car Proton Saga Magma Proton Wira 2007 Ford laser
Saloon 1989 1.3s 4 door
WCA 4200
Number of 4 3 9
layers
Color of Silver, white, yellow, silver Pink, red, brown Red, yellow, brown, dark red,
layers brick red, black, white, brick
red, dark brown
Part B
1. Proton Saga
Result
Library spectra
2. Proton Wira
Result
Library spectra
3. Ford
Result
Library spectra
DISCUSSION:
Based on the experiment that had been conducted in which about three different cars
were being used as samples for the paint chip analysis under the stereomicroscope and an ATR-
FTIR microscope. Generally, automotive paint was one of the most commonly experienced kinds
of paint evidence which involved in hit-and-run accidents and also any serious crimes involving
vehicles. The automotive paint usually functioned in protecting or coloring the surface of the
vehicles whereby, the finishing automotive process consists of four separate coatings in which
each of the layers was a mixture of different components such as pretreatment, primer, topcoat
and clear coat.
Therefore, in pretreatment process, zinc electroplating was used to apply to the steel body
of the vehicle in order to prevent any rusting process occurred and it will become more easier for
the forensic paint analyst if there was presence of zinc during the elemental analysis as it may
come from this coating. The next coating which was primer, often called as an epoxy resin with
corrosion-resistant pigments. The primer color itself was coordinated with the final color of
vehicle as to minimize the contrast and bleed-through. This coating was usually finished with a
powder which can smooth the surface of the metal and also provides good adhesion for the next
coating. As for the third coating which called as topcoat or basecoat, it was generally formed
from different additives such as a single color layer, a multilayer coat or a metallic color coat.
These topcoat coatings have characteristics of water-based chemistries in order to provide a
healthier atmosphere for the factory workers and environment due to no longer used of any
heavy metal such as lead. The last coatings which called as clear coats that comprises of
unpigmented coatings which able to improve gloss and durability of the coatings of vehicle.
Apart from that, the samples were also being analyzed under the ATR-FTIR microscope.
Theoretically, ATR-FTIR was known as Attenuated Total Reflection which operated when the
infrared beam comes into contact with the paint chip samples by measuring any changes that
occur in an internally reflected infrared beam. The infrared (IR) beam was directed with a high
refractive index at certain angle onto an optically dense crystal. The internal reflectance will
form an evanescent wave which extended beyond the surface of the crystal into the sample.
Furthermore, the attenuated beam returned back to the crystal and then directed to the detector in
IR spectrometer which records as interferogram signal and used to generate the IR spectrum.
The results obtained showed different observations for each of the cars that are being
used which included Proton Saga, Proton Wira and Ford. As in part A whereby the paint chips
samples was observed under the stereomicroscope formed several layers depending on the type
of the cars. Firstly, in Proton Saga of Magma Saloon 1989 model with plate number of WCA
4200 formed about 4 layers with color of silver, white, yellow and silver. While for Proton Wira
2007 with 1.3s 4 door model formed 3 layers which comprised of pink, red and brown color and
as for Ford laser, the formation of 9 layers which were red, yellow, brown, dark red, brick red,
black, white, brick red and also dark brown in the paint chip sample. This may be due to the type
of cars being produced whereby Proton Saga and Wira have a cheaper price as it were made in
Malaysia as compared to the car made in America, Ford laser with such a higher price as the
number of coatings increased.
Next, in the ATR-FTIR in which the samples spectra were being observed in the range of
500 to 4000cm-1 in order to detect any functional groups that may present in the organic
compound of the paint chip. Therefore, the spectral resolution used during the analysis was 2cm-1
with 16 times scanning until the acquisition time ended. In this instrument where there was
presence of library spectra in the database such that it can compare the IR spectrum of the
unknown sample with the reference sample. The result of the IR spectrum for Proton Saga
showed the presence of alkane group (C-H) at 2800-2950cm-1 and carbonyl group (C=O) at
1650-1750cm-1 in range. While in Proton Wira, the IR spectrum have presence of a bonded (O-
H) group and also free (O-H) group with the range of 3200-3400cm-1 and 3600-3700cm-1
respectively. Besides that, at the range of 1650-1750cm-1 the carbonyl group was present and
also alkane group (C-H) at the range 2800-2950cm-1. Lastly, the Ford paint chip also showed
similar functional group which included of alkane and carbonyl group at the same range such as
at 2800-2950cm-1 and 1650-1750cm-1 respectively.
The functional group of the compounds present in the samples can be identified and
compared with the spectra library of ATR-FTIR as reference. For instance, the library spectra for
Proton saga showed presence of several compounds such as ethyl-1-phenylpropylamine, b-
Methylphenethylamine-2-phenylpropylamine and N (-1- Phenylcyclohexyl) ethylamine which
may indicate the presence of alkane (C-H) and also carbonyl (C=O) group. Next, in Proton Wira
in which the free O-H group present may come from the library spectra of Duro Outdoor fixture
adhesive that was used as one of the elements for synthetic rubber while the Diphenoxylate HCL
in KBr and painter ‘s masking tape were from the alkane and also carbonyl group. The Ford
which consisted of O-H bonded and carbonyl (C=O) group may come from the diphenoxylate,
polystyrene acrylonitrile and pseudoephedrine of the library spectra. The library spectra can be
used as comparison as to identify the compounds that may present in the paint chip samples of
each of the cars.
CONCLUSION:
In a conclusion, the paint chip layers of each car were different as these cars may be
made or manufactured differently whereby, it can be identified morphologically and
spectroscopically by using stereomicroscope and also ATR-FTIR instrument.
QUESTIONS: