13.

50 An incinerator produces a dry exit gas of the following orsat composition measured at 60⁰F
and 30 inches of Hg absolute : 4% CO2, 26% CO, 2% CH4, 16% H2 and 52% N2. A dry natural gas of
the following (orsat) composition : 80.5% CH4, 17.8% C2H6 and 1.7% N2 is used at the rate of
1200ft3/min at 60⁰F and 30 inches of Hg absolute to burn the incineration off gas with air. The
final products of combustions analyze on a dry basis : 12.2% CO2, 0.7% CO, 2.4% O2, and 84.7%
N2.
Calculate (a) the rate of flow in ft3/min of the incinerator exit gas at 60⁰F and 30 inches of Hg
absolute on a dry basis and (b) the rate of air flow in ft3/min, dry at 80⁰F and 29.6 inches of Hg
absolute

 Pada aliran A

𝑃𝑉 = 𝑛𝑅𝑇
𝑖𝑛𝐻𝑔 𝑓𝑡 3
30 𝑖𝑛𝐻𝑔 𝑥 1200𝑓𝑡 3 = 𝑛 𝑥 21.9 𝑥 519.67 °𝑅
𝑙𝑏𝑚𝑜𝑙 °𝑅
36000 = 𝑛 11380.773
𝑛 = 3.1632 𝑙𝑏 𝑚𝑜𝑙

 CH4 : 0.805 x 3.1632 lb mol = 2.5464 lb mol

 C2H6 : 0.178 x 3.1632 lb mol = 0.56305 lb mol
 N2 : 0.017 x 3.1632 lb mol = 0.0538 lb mol
Reaksi 1 : CH4 + 2 O2 = CO2 + H2O
O2 bereaksi : 2 ( 2.5464 + 0.02 F ) = ( 5.0928 + 0.04 F ) lb mol
Reaksi 2 : 2 CO + O2 = 2 CO2
O2 bereaksi : 0.5 ( 0.26 F ) = 0.13 F lb mol
Reaksi 3 : C2H6 + 3.5 O2 = 2 CO2 + 3 H2O
O2 bereaksi : 0.56305 x 3.5 = 1.970675 lb mol
Reaksi 4 : H2 + 0.5 O2 = H2O
O2 bereaksi : 0.5 x 0.16 F = 0.08 F lb mol
O2 bereaksi : Reaksi 1 + Reaksi 2 + Reaksi 3 + Reaksi 4
: ( 5.0928 + 0.04 F ) + 0.13 F + 1.970675 + 0.08 F
: 7.063475 + 0.25 F
Aliran B
O2 excess : 0.2 ( 7.063475 + 0.25 F ) = 1.412695 + 0.05 F lb mol
Total O2 : 7.063475 + 0.25 F + 1.412695 + 0.05 F = 8.47617 + 0.3 F
N2 : ( 79/21 ) x ( 8.47617 + 0.3 F ) = 31.8865 + 1.1286 F
Total Aliran di A : ( 8.47617 + 0.3 F ) + ( 31.8865 + 1.1286 F ) = 40.36267 + 1.4286 F

NERACA MASSA ELEMEN

IN=OUT

C : ( 0.04 + 0.26 + 0.02 ) F + ( 0.805 + ( 2 x 0.178 )) x 3.1632 = 0 + ( 0.122 + 0.007 ) P

0.32 F + 3.6725 = 0.129 P

3.6725 = 0.129P – 0,32F (1)

H2 : ( 2x 0.02 + 0.16 ) F + ( 2 x 0.805 + 3 x 0.178 ) x 3.1632 = R + 0

0.2 F + 6.7819 = R

6.7819 = R – 0.2 F (2)

O : ( 2x 0.04 + 0.26 ) F + ( 8.47617 + 0.3 F ) = R + ( 2 x 0.122 + 0.007 + ( 2 x 0.024)) P

8.47617 = R + 0.299 P – 0.64 F (3)

N2 : 0.52 F + ( 0.017 ) x 3.1632 + ( 31.8865 + 1.1286 F ) = 0.847 P

0.52 F + 0.0538 + 31.8865 + 1.1286 F = 0.847 P

31.9403 = 0.847 P – 1.6486 F (4)

Lakukan Eliminasi

 1 dan 4
31.9403 = 0.847 P – 1.6486 F x 0.129
3.6725 = 0.129P – 0,32F x 0.847

4.1203 = 0.1093 P – 0.2127 F

3.1106 = 0.1093 P – 0.27104 F

1.0097 = 0,05834 F

F = 17.3072 lb mol

 PERSAMAAN 1
3.6725 = 0.129 P – 0,32 F
3.6725 = 0.129 P – 0.32 ( 17.3072 )
P = 71.4016 lb mol
 PERSAMAAN 2
6.7819 = R – 0.2 F
6.7819 = R – 0.2 ( 17.3072 )
10.2433 = R

Suhu 60 ⁰F = 60 + 459,67 = 519,67 ⁰R ( Rankine )

Suhu 80 ⁰F = 80 + 459,67 = 539,67 ⁰R ( Rankine )

a.) Aliran F dalam ft3/min ( V )

𝑃𝑉 = 𝑛𝑅𝑇
𝑖𝑛𝐻𝑔𝑓𝑡 3
30 𝑖𝑛𝐻𝑔 𝑥 𝑉 = 17.3072 𝑙𝑏 𝑚𝑜𝑙 𝑥 21.9 𝑙𝑏𝑚𝑜𝑙 °𝑅 x 519.67 ⁰R

30 𝑉 = 196969.314
𝑉 = 6565.6483 𝑓𝑡 3

b.) Aliran B ( udara )

40.36267 + 1.4286 F = 40.36267 + 1.4286 ( 17.3072 ) = 65.0877 lb mol
𝑃𝑉 = 𝑛𝑅𝑇
𝑖𝑛𝐻𝑔 𝑓𝑡 3
30 𝑖𝑛𝐻𝑔 𝑥 𝑉 = 65.0877 𝑙𝑏 𝑚𝑜𝑙 𝑥 21.9 𝑥 519.67 °𝑅
𝑙𝑏 𝑚𝑜𝑙 °𝑅
3
𝑉 = 24691.6113 𝑓𝑡
 𝑃1𝑉1 𝑃2𝑉2
=
𝑇1 𝑇2
30𝑖𝑛𝐻𝑔 𝑥 24691.6113 𝑓𝑡 3 29.6 𝑖𝑛𝐻𝑔 𝑥 𝑉2
=
519,67 ⁰R 539,67 ⁰R
399759.656 𝑓𝑡 3 = 15382.232 𝑉2
𝑉2 = 25994.7189 𝑓𝑡 3
Jadi, volume udara pada 80 ⁰F dan 29.6 inHg yaitu 25994.7189 ft3