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etanol 46.

0684
heptano 100.21 densidad densidad
frasco etanol vol heptano vol n liq t burbuja n vapor etanol heptano
1 0 40 1.389 80 1.389 0.7866 0.68
2 2 38 1.388 64 1.3775 0.7866 0.68
3 4 36 1.3856 63 1.3775 0.7866 0.68
4 7 33 1.3835 62 1.3765 0.7866 0.68
5 10 30 1.381 61 1.3775 0.7866 0.68
6 20 20 1.3726 60 1.377 0.7866 0.68
7 25 15 1.3675 62 1.375 0.7866 0.68
8 30 10 1.3656 65 1.3755 0.7866 0.68
9 35 5 1.363 66 1.3745 0.7866 0.68
10 38 2 1.3614 69 1.3709 0.7866 0.68
11 40 0 1.3605 69 1.3605 0.7866 0.68
y
masa masa moles moles etanol heptano etanol
etanol heptano ni etanol ni heptano n total x1 x2 y1
0 27.2 0 0.2714 0.2714 0.0000 1.0000 0.0000
1.5732 25.84 0.03414922 0.2579 0.2920 0.1169 0.8831 0.5642
3.1464 24.48 0.06829844 0.2443 0.3126 0.2185 0.7815 0.5642
5.5062 22.44 0.11952228 0.2239 0.3435 0.3480 0.6520 0.6000
7.866 20.4 0.17074611 0.2036 0.3743 0.4562 0.5438 0.5642
15.732 13.6 0.34149222 0.1357 0.4772 0.7156 0.2844 0.5823
19.665 10.2 0.42686527 0.1018 0.5287 0.8075 0.1925 0.6511
23.598 6.8 0.51223832 0.0679 0.5801 0.8830 0.1170 0.6344
27.531 3.4 0.59761138 0.0339 0.6315 0.9463 0.0537 0.6674
29.8908 1.36 0.64883521 0.0136 0.6624 0.9795 0.0205 0.7747
31.464 0 0.68298443 0.0000 0.6830 1.0000 0.0000 0.9828

0 0
1 1 heptano
etanol

ρ=m/V m=ρ*V m = n * Mm n = m / Mm xi = n i / n T
-698.73 1888.5 -1275
heptano etanol ETANOL HEPTANO yi calculada
y2 psaturacion YI GAMMA exp YI GAMMA exp etanol heptano
1.0000 108.794702 57.086575 0 0.7167674401
0.4358 56.1058411 32.6036977 6.7054920653 0.6859147444
0.4358 53.7023682 31.4150441 3.7496411824 0.8097301073
0.4000 51.3864919 30.261652 2.6164534864 0.9309794174
0.4358 49.1556382 29.1427467 1.9621963783 1.2712012217
0.4177 47.0072875 28.0575632 1.3498382976 2.4365833133
0.3489 51.3864919 30.261652 1.2236556909 2.7499586845
0.3656 58.5995395 33.8283971 0.9560776003 4.1589307731
0.3326 61.1861482 35.089936 0.8989096527 7.8896628752
0.2253 69.53113 39.1036717 0.8869900331 12.3340460735
0.0172 69.53113 39.1036717 1.1022229588 0

a b c P ATM Kpa
13.8622 2910.26 216.432 585 77.9805
16.8958 3795.17 230.918

Psist*yi = γi*xi*Pisat
nT = n 1 + n 2 y1 = a(nvap)2 + b(nvap) + c γi = (Psist*yi) / (xi*Pisat)
lnγ1 = A*x22lnγ2 = A*x12
Etanol (C2H6O) Heptano (C7H16) Psistema (mm Hg)Psistema (KPa)
A A 585 77.9936
16.8958 13.8622
B B
3795.17 2910.26
C C en mm Hg
230.918 216.432

x1 etanol x2 heptano y1 etanol y2 heptano TB (°C)


0 1 0 1 71.7470905

xi yi experimental

nliq etanol x1 heptano x2 etanol y1 heptano y2 TB experimental (°C)

nvap
1.389 1.389 0 1 0 1 80
1.388 1.3775 0.1169463 0.8830537 0.56420794 0.43579206 64
1.3856 1.3775 0.21849528 0.78150472 0.56420794 0.43579206 63
1.3835 1.3765 0.34800283 0.65199717 0.60001036 0.39998964 62
1.381 1.3775 0.45615181 0.54384819 0.56420794 0.43579206 61
1.3726 1.377 0.71560573 0.28439427 0.58228383 0.41771617 60
1.3675 1.375 0.8074606 0.1925394 0.65109375 0.34890625 62
1.3656 1.3755 0.88302364 0.11697636 0.63441532 0.36558468 65
1.363 1.3745 0.94627618 0.05372382 0.66742282 0.33257718 66
1.3614 1.3709 0.97951183 0.02048817 0.77467885 0.22532115 69
1.3605 1.3605 1 0 0.98279452 0.01720548 69

ETANOL HEPTANO
P SAT P SAT
108.794702 57.086575
56.1058411 32.6036977
53.7023682 31.4150441
51.3864919 30.261652
49.1556382 29.1427467
#REF! #REF!
47.0072875 28.0575632
51.3864919 30.261652
58.5995395 33.8283971
61.1861482 35.089936
69.53113 39.1036717
69.53113 39.1036717
ETANOL HEPTANO Psistema (mm Hg)Psistema (KPa)
P SAT P SAT 585 77.9936
77.9936 43.0951477

γi experimental gamma lnγi experimental gamma

x1*x22
x1*(1-x1)2
P1sat (KPa) P2sat (KPa) etanol γ1 heptano γ2 etanol lnγ1 heptano lnγ2

108.794702 57.086575 0 0.71676744 0 0.33300384 0


56.1058411 32.6036977 6.70549207 0.68591474 1.9029269 0.37700194 0.09119283
53.7023682 31.4150441 3.74964118 0.80973011 1.32166015 0.21105429 0.13344591
51.3864919 30.261652 2.61645349 0.93097942 0.96181977 0.07151811 0.14793611
49.1556382 29.1427467 1.96219638 1.27120122 0.67406445 0.2399623 0.13491641
47.0072875 28.0575632 1.3498383 2.43658331 0.29998481 0.89059678 0.05787826
51.3864919 30.261652 1.22365569 2.74995868 0.20184285 1.01158589 0.02993371
58.5995395 33.8283971 0.9560776 4.15893077 0.0449162 1.42525802 0.01208283
61.1861482 35.089936 0.89890965 7.88966288 0.10657275 2.06555341 0.00273119
69.53113 39.1036717 0.88699003 12.3340461 0.11992153 2.51236341 0.00041116
69.53113 39.1036717 1.10222296 0 0.09732901 0 0
y = GE/RTx1x22
G /RT
E
x = x1/x2 y = (x1lnγ1 + x2lnγ2) / (x1*x22)
x1lnγ1 + x2lnγ2 x*y
x1lnγ1 + (1-x1)lnγ2 x = x1/(1-x1) y = (x1lnγ1 + (1-x1)lnγ2) / (x1*(1-
x1)2

0 0 0 0
-0.786180808 0.1324339588 -8.6210810698 -1.1417239
-1.1548040678 0.2795828019 -8.6537239071 -2.4194324
-1.7333882432 0.5337489855 -11.717140821 -6.254012
-0.9561398484 0.8387484058 -7.0869054437 -5.9441306
-0.8945569966 2.5162452175 -15.4558366036 -38.890675
-1.2899337178 4.1937420291 -43.0930076793 -180.72096
-2.6985332973 7.5487356524 -223.3362540644 -1685.9063
-2.0796725512 17.6137165223 -761.4532487178 -13412.022
-2.0585897321 47.8086591319 -5006.726517738 -239364.88
0 0 0 0

81.4656127053 -6086.1437160448 -254698.18

m=
x2 N

0 1
0.01753875 2
0.07816654 3
0.28488798 4
0.70349889 5
6.33148999 6
17.5874722 7
56.9834099 8
310.24301 9
2285.66789 10
0 11

2677.89736
gráfico 1 n1 vs x1
1.2000

1.0000
f(x) = - 698.7344527782x^2 + 1888.4983836924x - 1274.9930493906
R² = 0.9943700032

0.8000
x1 experimental

0.6000

0.4000

0.2000

0.0000
1.355 1.36 1.365 1.37 1.375 1.38 1.385 1.39 1.395

n1 liquida
gráfico 2 x1,y1 vs t burbuja
84

80
temperatura de burbuja

76

72

68

64

60
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000 1.2000

x1 y1
grafica x1 vs y1
1.2000

1.0000

0.8000

0.6000

0.4000

0.2000

0.0000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000 1.2000