Equipo 4, Fisicoqímica IV

Cruz Rodríguez Yanine, Hernández Martínez Jesús Alberto, Hernández Sánchez Saul, Limón Solano
Francisco Alejandro, Luna García Angelica.

Disolución C𝐒𝟐 en acetona

Inciso a), b)

Tabla de datos para la mezcla binaria ideal

Pcs2* Pacet*
512.3 343.8

xi xii pcs2 pacet pt

0 1 0 343.8 343.8
0.0624 0.9376 31.96752 322.34688 354.3144
0.067 0.933 34.3241 320.7654 355.0895
0.0711 0.9289 36.42453 319.35582 355.78035
0.1212 0.8788 62.09076 302.13144 364.2222
0.133 0.867 68.1359 298.0746 366.2105
0.1857 0.8143 95.13411 279.95634 375.09045
0.1991 0.8009 101.99893 275.34942 377.34835
0.2085 0.7915 106.81455 272.1177 378.93225
0.2761 0.7239 141.44603 248.87682 390.32285
0.2869 0.7131 146.97887 245.16378 392.14265
0.3502 0.6498 179.40746 223.40124 402.8087
0.3551 0.6449 181.91773 221.71662 403.63435
0.4058 0.5942 207.89134 204.28596 412.1773
0.4141 0.5859 212.14343 201.43242 413.57585
0.4474 0.5526 229.20302 189.98388 419.1869
0.453 0.547 232.0719 188.0586 420.1305
0.4933 0.5067 252.71759 174.20346 426.92105
0.4974 0.5026 254.81802 172.79388 427.6119
0.5702 0.4298 292.11346 147.76524 439.8787
0.573 0.427 293.5479 146.8026 440.3505
0.6124 0.3876 313.73252 133.25688 446.9894
0.6146 0.3854 314.85958 132.50052 447.3601
0.6161 0.3839 315.62803 131.98482 447.61285
0.6713 0.3287 343.90699 113.00706 456.91405
0.6713 0.3287 343.90699 113.00706 456.91405
0.722 0.278 369.8806 95.5764 465.457
0.7197 0.2803 368.70231 96.36714 465.06945
0.828 0.172 424.1844 59.1336 483.318
0.9191 0.0809 470.85493 27.81342 498.66835
0.9242 0.0758 473.46766 26.06004 499.5277
0.935 0.065 479.0005 22.347 501.3475
0.9407 0.0593 481.92061 20.38734 502.30795
0.9549 0.0451 489.19527 15.50538 504.70065
0.962 0.038 492.8326 13.0644 505.897
0.9692 0.0308 496.52116 10.58904 507.1102
1 0 512.3 0 512.3

Diagrama P vs XCS2, comportamiento de una mezcla binaria ideal y real

650 Ptotal
600

550
*
500 PCS
2

450

400
*
Presion/torr

350 Pacetona

300

250
Pacetona
200
PCS2
150

100

50

0
0.0 0.2 0.4 0.6 0.8 1.0
XCS2
Inciso c) y e)

KCS2 real Kacetona real

1628 1773.04794

xi PCS2 Raoult Pacet Raoult Pacet Henry PCS2 Henry

0 0 343.8 1628 0
0.0624 31.96752 322.34688 1526.4128 110.638191
0.067 34.3241 320.7654 1518.924 118.794212
0.0711 36.42453 319.35582 1512.2492 126.063709
0.1212 62.09076 302.13144 1430.6864 214.89341
0.133 68.1359 298.0746 1411.476 235.815376
0.1857 95.13411 279.95634 1325.6804 329.255002
0.1991 101.99893 275.34942 1303.8652 353.013845
0.2085 106.81455 272.1177 1288.562 369.680495
0.2761 141.44603 248.87682 1178.5092 489.538536
0.2869 146.97887 245.16378 1160.9268 508.687454
0.3502 179.40746 223.40124 1057.8744 620.921389
0.3551 181.91773 221.71662 1049.8972 629.609323
0.4058 207.89134 204.28596 967.3576 719.502854
0.4141 212.14343 201.43242 953.8452 734.219152
0.4474 229.20302 189.98388 899.6328 793.261648
0.453 232.0719 188.0586 890.516 803.190717
0.4933 252.71759 174.20346 824.9076 874.644549
0.4974 254.81802 172.79388 818.2328 881.914045
0.5702 292.11346 147.76524 699.7144 1010.99194
0.573 293.5479 146.8026 695.156 1015.95647
0.6124 313.73252 133.25688 631.0128 1085.81456
0.6146 314.85958 132.50052 627.4312 1089.71526
0.6161 315.62803 131.98482 624.9892 1092.37484
0.6713 343.90699 113.00706 535.1236 1190.24708
0.6713 343.90699 113.00706 535.1236 1190.24708
0.722 369.8806 95.5764 452.584 1280.14061
0.7197 368.70231 96.36714 456.3284 1276.0626
0.828 424.1844 59.1336 280.016 1468.08369
0.9191 470.85493 27.81342 131.7052 1629.60836
0.9242 473.46766 26.06004 123.4024 1638.65091
0.935 479.0005 22.347 105.82 1657.79982
0.9407 481.92061 20.38734 96.5404 1667.9062
0.9549 489.19527 15.50538 73.4228 1693.08348
0.962 492.8326 13.0644 61.864 1705.67212
0.9692 496.52116 10.58904 50.1424 1718.43806
1 512.3 0 0 1773.04794

Diagrama P vs XCS2, comportamiento de una mezcla binaria ideal y real

650 Ptotal

600
550 *
PCS
500 2

450
400
*
Pacetona
Presion/torr

350
300
250
Pacetona
200
PCS2
150
100
50
0
0.0 0.2 0.4 0.6 0.8 1.0
XCS2
Inciso d)

ideal