CHEMCAD 6.1.

3 Page
1

Job Name: PlantaBiodiesel Date: 08/13/2018 Time: 09:49:52

Triacylglycerol is a copy of Triolein Component ID # 2251 in CHEMCAD

Database.

CHEMCAD 6.1.3 Page

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Job Name: PlantaBiodiesel Date: 08/13/2018 Time: 09:49:52

FLOWSHEET SUMMARY

Equipment Label Stream Numbers

1 MIXE 103 101 -3

2 PUMP 3 -4
3 MIXE 4 8 -5
4 SCDS 7 -13 -9
5 PUMP 13 -8
6 PUMP 9 -10
7 HTXR 10 -11
8 EXTR 12 11 -17 -14
9 CSEP 17 -22 -23
10 PUMP 1 -2
11 HTXR 2 -6
12 EREA 15 -7
13 MIXE 6 5 -15
14 SCDS 22 -27 -29 -21
15 MIXE 14 23 19 -18
16 EREA 18 -20
17 CSEP 20 -16 -32
18 SCDS 16 -30 -24

Stream Connections

Stream Equipment Stream Equipment Stream Equipment

From To From To From To
1 10 11 7 8 21 14
2 10 11 12 8 22 9 14
3 1 2 13 4 5 23 9 15
4 2 3 14 8 15 24 18
5 3 13 15 13 12 27 14
6 11 13 16 17 18 29 14
7 12 4 17 8 9 30 18
8 5 3 18 15 16 32 17
9 4 6 19 15 101 1
10 6 7 20 16 17 103 1
Calculation mode : Sequential
Flash algorithm : Normal

Equipment Calculation Sequence

1 2 10 11 3 13 12 4 5 6 7 8 9 14 15 16 17 18

Equipment Recycle Sequence

3 13 12 4 5

Recycle Cut Streams

8

Recycle Convergence Method: Direct Substitution

CHEMCAD 6.1.3 Page

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Job Name: PlantaBiodiesel Date: 08/13/2018 Time: 09:49:52

Max. loop iterations 125

Recycle Convergence Tolerance

Flow rate 1.000E-003

Temperature 1.000E-003
Pressure 1.000E-003
Enthalpy 1.000E-003
Vapor frac. 1.000E-003

Recycle calculation has converged.

Column 18, stage 3 has two liquid phases.

CHEMCAD 6.1.3 Page
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Job Name: PlantaBiodiesel Date: 08/13/2018 Time: 09:49:58

Overall Mass Balance kmol/h kg/h

Input Output Input Output
FAME 0.000 3.380 0.000 1002.082
Glycerol 0.000 1.127 0.000 103.753
Methanol 3.658 0.278 117.200 8.907
Calcium Oxide 0.000 0.000 0.000 0.000
Calcium Sulfate 0.000 0.000 0.000 0.000
Phosphoric Acid 1.306 1.278 128.000 125.262
TriNa Phosphate 0.000 0.028 0.000 4.581
OIL 1.186 0.059 1050.000 52.480
Sulfuric Acid 0.000 0.000 0.000 0.000
Water 0.611 0.694 11.000 12.510
Sodium Hydroxide 0.250 0.166 10.000 6.647

Total 7.010 7.010 1316.200 1316.224

CHEMCAD 6.1.3 Page

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Job Name: PlantaBiodiesel Date: 08/13/2018 Time: 09:49:58

COMPONENTS
ID # Name Formula
1 8003 FAME C19H36O2
2 268 Glycerol C3H8O3
3 117 Methanol CH4O
4 930 Calcium Oxide CaO
5 931 Calcium Sulfate CaO4S
6 474 Phosphoric Acid H3O4P
7 985 TriNa Phosphate Na3O4P
8 8001 OIL C57H104O6
9 431 Sulfuric Acid H2O4S
10 62 Water H2O
11 429 Sodium Hydroxide NaOH

User/Pool Components Data Source

1 8003 FAME in User Components
8 8001 OIL in User Components

THERMODYNAMICS

K-value model : NRTL

No correction for vapor fugacity
Enthalpy model : Latent Heat
Liquid density : Library

Equip # 8 K-value : MUNF

Equip # 8 local water/hydrocarbon immiscible.
Equip # 8 local vapor/liquid/liquid/solid option.
Equip # 14 K-value : MUNF
Equip # 14 local water/hydrocarbon immiscible.
Equip # 14 local vapor/liquid/liquid/solid option.
Equip # 17 K-value : MUNF
Equip # 17 local water/hydrocarbon immiscible.
Equip # 17 local vapor/liquid/liquid/solid option.
Equip # 18 K-value : MUNF
Equip # 18 local water/hydrocarbon immiscible.
Equip # 18 local vapor/liquid/liquid/solid option.
Std vapor rate reference temperature is 0 C.
Atmospheric pressure is 101.3250 kPa.

NRTL Parameters: Tij = Aij + Bij/T + Cij * Ln(T) + Dij * T (T Deg K)

I J Bij Bji Alpha Aij Aji Cij Cji Dij

Dji
 2 3 -272.39 712.39 0.301 0.00 0.00 0.00 0.00 0.00
0.00
2 10 -274.35 258.11 1.011 0.00 0.00 0.00 0.00 0.00
0.00
3 10 -24.49 307.17 0.300 0.00 0.00 0.00 0.00 0.00
0.00
9 10 -1894.25 -1228.66 0.243 0.00 0.00 0.00 0.00 0.00
0.00

Warning : BIP matrix is less than 50 % full.

CHEMCAD 6.1.3 Page

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Job Name: PlantaBiodiesel Date: 08/13/2018 Time: 09:49:58

EQUIPMENT SUMMARIES

Mixer Summary

Equip. No. 1 3 13 15
Name
Output Pressure kPa 400.0000 400.0000

Pump Summary

Equip. No. 2 5 6 10
Name
Output pressure kPa 400.0000 400.0000 110.0000
400.0000
Efficiency 1.0000 1.0000 1.0000
1.0000
Calculated power MJ/h 0.0461 0.0505 0.1128
0.3468
Calculated Pout kPa 400.0000 400.0000 110.0000
400.0000
Head m 36.9551 49.2726 9.7636
33.6513
Vol. flow rate m3/h 0.1537 0.1327 1.4090
1.1550
Mass flow rate kg/h 127.2000 104.3603 1177.2235
1050.0000

Scds Rigorous Distillation Summary

Equip. No. 4 14 18
Name
No. of stages 5 10 4
1st feed stage 4 2 3
Condenser type 0 1 0
Condenser mode 1 1 1
Condenser spec 2.0000 4.0000 2.0000
Reboiler mode 2 12 3
Reboiler spec. 500.0000 0.0100 112.0000
Reboiler comp i 0 1 0
Colm press drop kPa 10.0000 10.0000 10.0000
Est. dist. rate 2.4806 0.3290 0.8604
(kmol/h)
Est. reflux rate 4.9597 1.7207
(kmol/h)
Est. T top C 28.3192 198.0000 38.7681
Est. T bottom C 70.4472 410.0000 112.0000
Est. T 2 C 106.2260 77.2762
Eff. top stage 0.6000 0.6000 0.6000
Eff. last stage 0.7000 0.7000 0.7000
Top pressure kPa 20.0000 10.0000 40.0000
Calc Cond duty MJ/h -369.2586 -528.3622 -87.1489
Calc Reblr duty MJ/h 500.0000 970.3721 100.8082
Side 1 stage no. 0 1 0
Side 1 spec. 990.0000
Side product 1 mode 0 -3 0
Iterations 0 200 0
Initial flag 6 1 1
Calc Reflux mole 6.5121 1.2705 1.3726
(kmol/h)
CHEMCAD 6.1.3 Page
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Job Name: PlantaBiodiesel Date: 08/13/2018 Time: 09:49:58

EQUIPMENT SUMMARIES

Calc Reflux ratio 2.0000 4.0000 2.0000

Calc Reflux mass kg/h 208.7206 377.4134 30.7049
Optimization flag 1 0 1
Calc. tolerance 2.4650e-007 1.1967e-007 1.1446e-008

Heat Exchanger Summary

Equip. No. 7 11
Name
1st Stream T Out C 60.0000 60.0000
Calc Ht Duty MJ/h -139.6627 64.4271
LMTD Corr Factor 1.0000 1.0000
1st Stream Pout kPa 110.0000 400.0000

Extractor Summary

Equip. No. 8
Name
No. of Stages: 4
1st feed stage 1
2nd feed stage 4
P Top kPa 110.0000

Component Separator Summary

Equip. No. 9 17
Name
Pressure Out kPa 110.0000
Top Temp Spec 60.0000
Bottom Temp Spec 60.0000
Split Basis 1 0
Split Destination 1 1
Heat duty MJ/h 1.6092
Component No. 6 1.0000
Component No. 7 1.0000
Component No. 12 1.0000

Equilibrium Reactor Summary

Equip. No. 12 16
Name
Thermal mode 2 2
Temperature C 60.0000 60.0000
Heat duty MJ/h 428.3279 32.8698
Reaction phase 2 0
No of Reactions 1 1
Temp Units 3 3
CHEMCAD 6.1.3 Page
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Job Name: PlantaBiodiesel Date: 08/13/2018 Time: 09:49:58

EQUIPMENT SUMMARIES

Press Units 5 5
Heat of Rxn Units 4 5
Molar Flow Units 1 1
Calc IG Ht of Rxn -10.2239 -3.1139
(MJ/h)
Edit Reaction No. 1 0
Calc Liq H of Rxn 397.7417 26.0910
(MJ/h)

Reaction Stoichiometrics and Parameters for unit no. 12

Reaction no. 1
Base component 8
Frac.conversion 0.9500
8
-1.0000
 3
-3.0000
1
3.0000
2
1.0000

Reaction Stoichiometrics and Parameters for unit no. 16

Reaction no. 1
Base component 11
Frac.conversion 0.9300
11
-3.0000
6
-1.0000
7
1.0000
10
3.0000

CHEMCAD 6.1.3 Page

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Job Name: PlantaBiodiesel Date: 08/13/2018 Time: 09:49:58

STREAM PROPERTIES

Stream No. 1 2 3
4
Name Aceite JC Rec.
Metanol
- - Overall - -
Molar flow kmol/h 1.1859 1.1859 3.9077
3.9077
Mass flow kg/h 1050.0000 1050.0000 127.2000
127.2000
Temp C 25.0000 25.1956 25.0000
25.1479
Pres kPa 100.0000 400.0000 100.0000
400.0000
Vapor mole fraction 0.0000 0.0000 0.0000
0.0000
Enth MJ/h -2944.5 -2944.1 -1075.9 -
1075.9
Tc C 1366.8500 1366.8500 479.0534
479.0534
Pc kPa 470.0018 470.0018 20383.5516
20383.5516
Std. sp gr. wtr = 1 0.916 0.916 0.839
0.839
Std. sp gr. air = 1 30.572 30.572 1.124
1.124
Degree API 23.0481 23.0481 37.0991
37.0991
Average mol wt 885.4321 885.4321 32.5510
32.5510
Actual dens kg/m3 909.0721 908.9376 827.8019
827.6571
Actual vol m3/h 1.1550 1.1552 0.1537
0.1537
Std liq m3/h 1.1468 1.1468 0.1516
0.1516
Std vap 0 C m3/h 26.5795 26.5795 87.5862
87.5862
- - Liquid only - -
Molar flow kmol/h 1.1859 1.1859 3.9077
3.9077
Mass flow kg/h 1050.0000 1050.0000 127.2000
127.2000
Average mol wt 885.4321 885.4321 32.5510
32.5510
Actual dens kg/m3 909.0721 908.9376 827.8019
827.6571
Actual vol m3/h 1.1550 1.1552 0.1537
0.1537
Std liq m3/h 1.1468 1.1468 0.1516
0.1516
Std vap 0 C m3/h 26.5795 26.5795 87.5862
87.5862
Cp kJ/kg-K 1.6881 1.6893 2.4486
2.4493
Z factor 0.1027 0.4103 0.0021
0.0085
Visc N-s/m2 0.06914 0.06900 0.0009451
0.0009448
Th cond W/m-K 0.1713 0.1713 0.2039
0.2039
Surf. tens. N/m 0.0343 0.0343 0.0261
0.0261
CHEMCAD 6.1.3 Page
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Job Name: PlantaBiodiesel Date: 08/13/2018 Time: 09:49:58

STREAM PROPERTIES

Stream No. 5 6 7
8
Name Rec.
Metanol
- - Overall - -
Molar flow kmol/h 7.1638 1.1859 8.3497
3.2561
Mass flow kg/h 231.5624 1050.0000 1281.5837
104.3603
Temp C 26.6940 60.0000 60.0000
28.5103
Pres kPa 400.0000 400.0000 400.0000
400.0000
Vapor mole fraction 0.0000 0.0000 0.0000
0.0000
Enth MJ/h -1853.1 -2879.7 -4304.4 -
777.21
Tc C 372.8368 1366.8500 531.4811
239.7320
Pc kPa 15409.8997 470.0018 10770.3878
8127.4870
Std. sp gr. wtr = 1 0.821 0.916 0.899
0.801
Std. sp gr. air = 1 1.116 30.572 5.300
1.107
Degree API 40.7653 23.0481 25.9257
45.2339
Average mol wt 32.3238 885.4321 153.4885
32.0511
Actual dens kg/m3 808.5017 885.0321 863.4870
786.2413
Actual vol m3/h 0.2864 1.1864 1.4842
0.1327
Std liq m3/h 0.2819 1.1468 1.4258
0.1303
Std vap 0 C m3/h 160.5678 26.5795 187.1473
72.9801
- - Liquid only - -
Molar flow kmol/h 7.1638 1.1859 8.3497
3.2561
Mass flow kg/h 231.5624 1050.0000 1281.5837
104.3603
Average mol wt 32.3238 885.4321 153.4885
32.0511
Actual dens kg/m3 808.5017 885.0320 863.4870
786.2413
Actual vol m3/h 0.2864 1.1864 1.4842
0.1327
Std liq m3/h 0.2819 1.1468 1.4258
0.1303
Std vap 0 C m3/h 160.5678 26.5795 187.1473
72.9801
Cp kJ/kg-K 2.4959 1.8335 2.2116
2.5529
Z factor 0.0085 0.3683 0.0358
0.0086
Visc N-s/m2 0.0007154 0.01834 0.002178
0.0005151
Th cond W/m-K 0.2016 0.1713 0.1121
0.1989
Surf. tens. N/m 0.0241 0.0318 0.0293
0.0219
CHEMCAD 6.1.3 Page
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Job Name: PlantaBiodiesel Date: 08/13/2018 Time: 09:49:58
STREAM PROPERTIES

Stream No. 9 10 11
12
Name
Agua
- - Overall - -
Molar flow kmol/h 5.0936 5.0936 5.0936
0.6106
Mass flow kg/h 1177.2235 1177.2235 1177.2235
11.0000
Temp C 112.6573 112.6983 60.0000
25.0000
Pres kPa 30.0000 110.0000 110.0000
110.0000
Vapor mole fraction 0.0000 0.0000 0.0000
0.0000
Enth MJ/h -3396.4 -3396.3 -3536.0 -
174.45
Tc C 558.5255 558.5255 558.5255
374.2000
Pc kPa 1807.2858 1807.2858 1807.2858
22118.2302
Std. sp gr. wtr = 1 0.909 0.909 0.909
1.000
Std. sp gr. air = 1 7.980 7.980 7.980
0.622
Degree API 24.2140 24.2140 24.2140
10.0000
Average mol wt 231.1160 231.1160 231.1160
18.0150
Actual dens kg/m3 835.5281 835.4969 874.6787
996.7087
Actual vol m3/h 1.4090 1.4090 1.3459
0.0110
Std liq m3/h 1.2955 1.2955 1.2955
0.0110
Std vap 0 C m3/h 114.1672 114.1672 114.1672
13.6858
- - Liquid only - -
Molar flow kmol/h 5.0936 5.0936 5.0936
0.6106
Mass flow kg/h 1177.2235 1177.2235 1177.2235
11.0000
Average mol wt 231.1160 231.1160 231.1160
18.0150
Actual dens kg/m3 835.5281 835.4969 874.6787
996.7087
Actual vol m3/h 1.4090 1.4090 1.3459
0.0110
Std liq m3/h 1.2955 1.2955 1.2955
0.0110
Std vap 0 C m3/h 114.1672 114.1672 114.1672
13.6858
Cp kJ/kg-K 2.3398 2.3395 2.1609
4.1851
Z factor 0.0035 0.0128 0.0144
0.0011
Visc N-s/m2 0.001987 0.001987 0.006851
0.0009228
Th cond W/m-K 0.0991 0.0991 0.1061
0.6062
Surf. tens. N/m 0.0261 0.0261 0.0305
0.0721
CHEMCAD 6.1.3 Page
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Job Name: PlantaBiodiesel Date: 08/13/2018 Time: 09:49:59

STREAM PROPERTIES

Stream No. 13 14 15
16
Name
- - Overall - -
Molar flow kmol/h 3.2561 1.8372 8.3497
1.8372
Mass flow kg/h 104.3603 121.5967 1281.5623
119.7539
Temp C 28.3209 60.0000 52.0615
60.0000
Pres kPa 20.0000 110.0000 400.0000
100.0000
Vapor mole fraction 0.0000 0.0000 0.0000
0.0000
Enth MJ/h -777.26 -981.17 -4732.8 -
937.38
Tc C 239.7320 635.9130 1176.8496
541.8162
Pc kPa 8127.4870 16905.6502 74950.9093
17880.8783
Std. sp gr. wtr = 1 0.801 1.218 0.897
1.202
Std. sp gr. air = 1 1.107 2.285 5.299
2.251
Degree API 45.2339 -15.3200 26.2494 -
13.7960
Average mol wt 32.0511 66.1849 153.4860
65.1818
Actual dens kg/m3 786.4243 1185.8419 868.9339
1170.4972
Actual vol m3/h 0.1327 0.1025 1.4749
0.1023
Std liq m3/h 0.1303 0.0998 1.4287
0.0996
Std vap 0 C m3/h 72.9801 41.1790 187.1473
41.1790
- - Liquid only - -
Molar flow kmol/h 3.2561 1.8372 8.3497
1.8372
Mass flow kg/h 104.3603 121.5967 1281.5623
119.7539
Average mol wt 32.0511 66.1849 153.4860
65.1818
Actual dens kg/m3 786.4243 1185.8419 868.9339
1170.4972
Actual vol m3/h 0.1327 0.1025 1.4749
0.1023
Std liq m3/h 0.1303 0.0998 1.4287
0.0996
Std vap 0 C m3/h 72.9801 41.1790 187.1473
41.1790
Cp kJ/kg-K 2.5519 2.6643 1.9574
2.7154
Z factor 0.0004 0.0028 0.0631
0.0024
Visc N-s/m2 0.0005154 0.01600 0.0008861
0.01143
Th cond W/m-K 0.1990 0.3014 0.1757
0.3039
Surf. tens. N/m 0.0220 0.0587 0.0300
0.0559
CHEMCAD 6.1.3 Page
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Job Name: PlantaBiodiesel Date: 08/13/2018 Time: 09:50:00

STREAM PROPERTIES

Stream No. 17 18 19
20
Name H3PO4
- - Overall - -
Molar flow kmol/h 3.8670 3.1434 1.3062
3.1434
Mass flow kg/h 1066.6267 249.5967 128.0000
249.5967
Temp C 59.2899 46.8034 25.0000
60.0000
Pres kPa 110.0000 100.0000 100.0000
100.0000
Vapor mole fraction 0.0000 0.0000 0.0000
0.0000
Enth MJ/h -2729.3 -2734.8 -1753.6 -
2701.9
Tc C 549.2203 702.1514 756.8500
719.2718
Pc kPa 2168.6718 11930.2821 5070.0002
16159.3059
Std. sp gr. wtr = 1 0.884 1.471 1.834
1.479
Std. sp gr. air = 1 9.524 2.742 3.384
2.742
Degree API 28.5744 -35.3337 -54.3462 -
35.8432
Average mol wt 275.8264 79.4030 97.9950
79.4030
Actual dens kg/m3 850.7234 1461.3059 1869.8256
1458.6916
Actual vol m3/h 1.2538 0.1708 0.0685
0.1711
Std liq m3/h 1.2066 0.1696 0.0698
0.1687
Std vap 0 C m3/h 86.6741 70.4554 29.2765
70.4554
- - Liquid only - -
Molar flow kmol/h 3.8670 3.1434 1.3062
3.1434
Mass flow kg/h 1066.6267 249.5967 128.0000
249.5967
Average mol wt 275.8264 79.4030 97.9950
79.4030
Actual dens kg/m3 850.7234 1461.3059 1869.8256
1458.6916
Actual vol m3/h 1.2538 0.1708 0.0685
0.1711
Std liq m3/h 1.2066 0.1696 0.0698
0.1687
Std vap 0 C m3/h 86.6741 70.4554 29.2765
70.4554
Cp kJ/kg-K 2.1222 2.0592 1.4793
2.0998
Z factor 0.0178 0.0040 0.0064
0.0048
Visc N-s/m2 0.003053 0.04200 0.1969
0.01985
Th cond W/m-K 0.0994 0.3514 0.4256
0.3576
Surf. tens. N/m 0.0290 0.0623 0.0684
0.0587
CHEMCAD 6.1.3 Page
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Job Name: PlantaBiodiesel Date: 08/13/2018 Time: 09:50:01

STREAM PROPERTIES

Stream No. 21 22 23
24
Name Biodiesel
Glicerol
- - Overall - -
Molar flow kmol/h 3.3328 3.8670 0.0000
1.1509
Mass flow kg/h 990.0000 1066.6267 0.0000
104.4015
Temp C 208.5413 60.0000 0.0000
112.0000
Pres kPa 10.0000 110.0000 0.0000
50.0000
Vapor mole fraction 0.0000 0.0000 0.0000
0.0000
Enth MJ/h -2007.1 -2727.7 0.00000 -
738.25
Tc C 494.1927 549.2203 0.0000
583.8587
Pc kPa 1334.2832 2168.6718 0.0000
7763.9181
Std. sp gr. wtr = 1 0.879 0.884 0.000
1.264
Std. sp gr. air = 1 10.256 9.524 0.000
3.132
Degree API 29.4308 28.5744 0.0000 -
19.5895
Average mol wt 297.0473 275.8264 0.0000
90.7119
Actual dens kg/m3 731.3575 850.2114 0.0000
1198.2923
Actual vol m3/h 1.3536 1.2545 0.0000
0.0871
Std liq m3/h 1.1259 1.2066 0.0000
0.0826
Std vap 0 C m3/h 74.7002 86.6741 0.0000
25.7961
- - Liquid only - -
Molar flow kmol/h 3.3328 3.8670
1.1509
Mass flow kg/h 990.0000 1066.6267
104.4015
Average mol wt 297.0473 275.8264
90.7119
Actual dens kg/m3 731.3575 850.2114
1198.2923
Actual vol m3/h 1.3536 1.2545
0.0871
Std liq m3/h 1.1259 1.2066
0.0826
Std vap 0 C m3/h 74.7002 86.6741
25.7961
Cp kJ/kg-K 2.5989 2.1244
2.8619
Z factor 0.0013 0.0178
0.0014
Visc N-s/m2 0.0002995 0.003007
0.009281
Th cond W/m-K 0.0762 0.0993
0.3019
Surf. tens. N/m 0.0168 0.0289
0.0559
CHEMCAD 6.1.3 Page
15

Job Name: PlantaBiodiesel Date: 08/13/2018 Time: 09:50:03

STREAM PROPERTIES

Stream No. 27 29 30
32
Name MeOH y Agua Aceite n.c. MeOH y Agua
Na3PO4
- - Overall - -
Molar flow kmol/h 0.3176 0.2166 0.6863
1.3062
Mass flow kg/h 21.1272 55.5001 15.3525
129.8427
Temp C 208.5413 541.8837 38.7445
60.0000
Pres kPa 10.0000 20.0000 40.0000
100.0000
Vapor mole fraction 1.000 0.0000 0.0000
0.0000
Enth MJ/h -86.995 -191.59 -185.47 -
1764.5
Tc C 449.2871 1543.8147 313.1539
856.1044
Pc kPa 32877.1648 -40771.1196 13305.5107
6697.0676
Std. sp gr. wtr = 1 0.890 0.974 0.901
1.879
Std. sp gr. air = 1 2.297 8.848 0.772
3.432
Degree API 27.4300 13.7339 25.6014 -
56.1773
Average mol wt 66.5136 256.2527 22.3694
99.4058
Actual dens kg/m3 0.1663 596.9613 883.4552
1887.2587
Actual vol m3/h 127.0240 0.0930 0.0174
0.0688
Std liq m3/h 0.0237 0.0570 0.0170
0.0691
Std vap 0 C m3/h 7.1194 4.8544 15.3828
29.2765
- - Vapor only - -
Molar flow kmol/h 0.3176
Mass flow kg/h 21.1272
Average mol wt 66.5136
Actual dens kg/m3 0.1663
Actual vol m3/h 127.0240
Std liq m3/h 0.0237
Std vap 0 C m3/h 7.1194
Cp kJ/kg-K 2.1061
Z factor 0.9987
Visc N-s/m2 1.112e-005
Th cond W/m-K 0.0211
- - Liquid only - -
Molar flow kmol/h 0.2166 0.6863
1.3062
Mass flow kg/h 55.5001 15.3525
129.8427
Average mol wt 256.2527 22.3694
99.4058
Actual dens kg/m3 596.9613 883.4552
1887.2588
Actual vol m3/h 0.0930 0.0174
0.0688
Std liq m3/h 0.0570 0.0170
0.0691
Std vap 0 C m3/h 4.8544 15.3828
29.2765
Cp kJ/kg-K 3.1287 3.4867
1.5321
Z factor 0.0023 0.0005
0.0080
Visc N-s/m2 0.001260 0.0006092
0.04313
Th cond W/m-K 0.1709 0.3522
0.4538
Surf. tens. N/m 0.0319 0.0399
0.0632
CHEMCAD 6.1.3 Page
16

Job Name: PlantaBiodiesel Date: 08/13/2018 Time: 09:50:03

STREAM PROPERTIES

Stream No. 101 103

Name Metanol NaOH
- - Overall - -
Molar flow kmol/h 3.6577 0.2500
Mass flow kg/h 117.2000 10.0000
Temp C 25.0000 25.0000
Pres kPa 100.0000 100.0000
Vapor mole fraction 0.0000 0.0000
Enth MJ/h -874.02 -201.89
Tc C 239.4900 2546.8500
Pc kPa 8097.0001 25331.0099
Std. sp gr. wtr = 1 0.801 1.934
Std. sp gr. air = 1 1.106 1.381
Degree API 45.2429 -58.3469
Average mol wt 32.0420 39.9970
Actual dens kg/m3 789.5790 1913.3401
Actual vol m3/h 0.1484 0.0052
Std liq m3/h 0.1464 0.0052
Std vap 0 C m3/h 81.9824 5.6038
- - Liquid only - -
Molar flow kmol/h 3.6577 0.2500
Mass flow kg/h 117.2000 10.0000
Average mol wt 32.0420 39.9970
Actual dens kg/m3 789.5790 1913.3401
Actual vol m3/h 0.1484 0.0052
Std liq m3/h 0.1464 0.0052
Std vap 0 C m3/h 81.9824 5.6038
Cp kJ/kg-K 2.5317 1.4720
Z factor 0.0022 0.0033
Visc N-s/m2 0.0005380 3.590
Th cond W/m-K 0.1999 0.3633
Surf. tens. N/m 0.0222 0.5241

CHEMCAD 6.1.3 Page

17

Job Name: PlantaBiodiesel Date: 08/13/2018 Time: 09:50:03

FLOW SUMMARIES

Stream No. 1 2 3
4
Stream Name Aceite JC Rec.
Metanol
Temp C 25.0000 25.1956 25.0000
25.1479
Pres kPa 100.0000 400.0000 100.0000
400.0000
Enth MJ/h -2944.5 -2944.1 -1075.9 -
1075.9
Vapor mole fraction 0.00000 0.00000 0.00000
0.00000
Total kmol/h 1.1859 1.1859 3.9077
3.9077
Flowrates in kmol/h
FAME 0.0000 0.0000 0.0000
0.0000
Glycerol 0.0000 0.0000 0.0000
0.0000
Methanol 0.0000 0.0000 3.6577
3.6577
Calcium Oxide 0.0000 0.0000 0.0000
0.0000
Calcium Sulfate 0.0000 0.0000 0.0000
0.0000
Phosphoric Acid 0.0000 0.0000 0.0000
0.0000
TriNa Phosphate 0.0000 0.0000 0.0000
0.0000
OIL 1.1859 1.1859 0.0000
0.0000
Sulfuric Acid 0.0000 0.0000 0.0000
0.0000
Water 0.0000 0.0000 0.0000
0.0000
Sodium Hydroxide 0.0000 0.0000 0.2500
0.2500
Stream No. 5 6 7
8
Stream Name Rec.
Metanol
Temp C 26.6940 60.0000 60.0000
28.5103
Pres kPa 400.0000 400.0000 400.0000
400.0000
Enth MJ/h -1853.1 -2879.7 -4304.4 -
777.21
Vapor mole fraction 0.00000 0.00000 0.00000
0.00000
Total kmol/h 7.1638 1.1859 8.3497
3.2561
Flowrates in kmol/h
FAME 0.0000 0.0000 3.3798
0.0000
Glycerol 0.0001 0.0000 1.1267
0.0001
Methanol 6.9137 0.0000 3.5339
3.2559
Calcium Oxide 0.0000 0.0000 0.0000
0.0000
Calcium Sulfate 0.0000 0.0000 0.0000
0.0000
Phosphoric Acid 0.0000 0.0000 0.0000
0.0000
TriNa Phosphate 0.0000 0.0000 0.0000
0.0000
OIL 0.0000 1.1859 0.0593
0.0000
Sulfuric Acid 0.0000 0.0000 0.0000
0.0000
Water 0.0000 0.0000 0.0000
0.0000
Sodium Hydroxide 0.2500 0.0000 0.2500
0.0000

CHEMCAD 6.1.3 Page

18

Job Name: PlantaBiodiesel Date: 08/13/2018 Time: 09:50:03

FLOW SUMMARIES

Stream No. 9 10 11
12
Stream Name
Agua
Temp C 112.6573 112.6983 60.0000
25.0000
Pres kPa 30.0000 110.0000 110.0000
110.0000
Enth MJ/h -3396.4 -3396.3 -3536.0 -
174.45
Vapor mole fraction 0.00000 0.00000 0.00000
0.00000
Total kmol/h 5.0936 5.0936 5.0936
0.6106
Flowrates in kmol/h
FAME 3.3798 3.3798 3.3798
0.0000
Glycerol 1.1266 1.1266 1.1266
0.0000
Methanol 0.2780 0.2780 0.2780
0.0000
Calcium Oxide 0.0000 0.0000 0.0000
0.0000
Calcium Sulfate 0.0000 0.0000 0.0000
0.0000
Phosphoric Acid 0.0000 0.0000 0.0000
0.0000
TriNa Phosphate 0.0000 0.0000 0.0000
0.0000
OIL 0.0593 0.0593 0.0593
0.0000
Sulfuric Acid 0.0000 0.0000 0.0000
0.0000
Water 0.0000 0.0000 0.0000
0.6106
Sodium Hydroxide 0.2500 0.2500 0.2500
0.0000

Stream No. 13 14 15
16
Stream Name
Temp C 28.3209 60.0000 52.0615
60.0000
Pres kPa 20.0000 110.0000 400.0000
100.0000
Enth MJ/h -777.26 -981.17 -4732.8 -
937.38
Vapor mole fraction 0.00000 0.00000 0.00000
0.00000
Total kmol/h 3.2561 1.8372 8.3497
1.8372
Flowrates in kmol/h
FAME 0.0000 0.0000 0.0000
0.0000
Glycerol 0.0001 1.1266 0.0001
1.1266
Methanol 3.2559 0.2179 6.9137
0.2179
Calcium Oxide 0.0000 0.0000 0.0000
0.0000
Calcium Sulfate 0.0000 0.0000 0.0000
0.0000
Phosphoric Acid 0.0000 0.0000 0.0000
0.0000
TriNa Phosphate 0.0000 0.0000 0.0000
0.0000
OIL 0.0000 0.0000 1.1859
0.0000
Sulfuric Acid 0.0000 0.0000 0.0000
0.0000
Water 0.0000 0.4026 0.0000
0.4865
Sodium Hydroxide 0.0000 0.0901 0.2500
0.0063

CHEMCAD 6.1.3 Page

19

Job Name: PlantaBiodiesel Date: 08/13/2018 Time: 09:50:03

FLOW SUMMARIES

Stream No. 17 18 19
20
Stream Name H3PO4
Temp C 59.2899 46.8034 25.0000
60.0000
Pres kPa 110.0000 100.0000 100.0000
100.0000
Enth MJ/h -2729.3 -2734.8 -1753.6 -
2701.9
Vapor mole fraction 0.00000 0.00000 0.00000
0.00000
Total kmol/h 3.8670 3.1434 1.3062
3.1434
Flowrates in kmol/h
FAME 3.3798 0.0000 0.0000
0.0000
Glycerol 0.0000 1.1266 0.0000
1.1266
Methanol 0.0601 0.2179 0.0000
0.2179
Calcium Oxide 0.0000 0.0000 0.0000
0.0000
Calcium Sulfate 0.0000 0.0000 0.0000
0.0000
Phosphoric Acid 0.0000 1.3062 1.3062
1.2782
TriNa Phosphate 0.0000 0.0000 0.0000
0.0279
OIL 0.0593 0.0000 0.0000
0.0000
Sulfuric Acid 0.0000 0.0000 0.0000
0.0000
Water 0.2080 0.4026 0.0000
0.4865
Sodium Hydroxide 0.1599 0.0901 0.0000
0.0063

Stream No. 21 22 23
24
Stream Name Biodiesel
Glicerol
Temp C 208.5413 60.0000 60.0000
112.0000
Pres kPa 10.0000 110.0000 110.0000
50.0000
Enth MJ/h -2007.1 -2727.7 0.00000 -
738.25
Vapor mole fraction 0.00000 0.00000 0.00000
0.00000
Total kmol/h 3.3328 3.8670 0.0000
1.1509
Flowrates in kmol/h
FAME 3.3257 3.3798 0.0000
0.0000
Glycerol 0.0000 0.0000 0.0000
1.1265
Methanol 0.0011 0.0601 0.0000
0.0055
Calcium Oxide 0.0000 0.0000 0.0000
0.0000
Calcium Sulfate 0.0000 0.0000 0.0000
0.0000
Phosphoric Acid 0.0000 0.0000 0.0000
0.0000
TriNa Phosphate 0.0000 0.0000 0.0000
0.0000
OIL 0.0044 0.0593 0.0000
0.0000
Sulfuric Acid 0.0000 0.0000 0.0000
0.0000
Water 0.0016 0.2080 0.0000
0.0126
Sodium Hydroxide 0.0000 0.1599 0.0000
0.0063

CHEMCAD 6.1.3 Page

20

Job Name: PlantaBiodiesel Date: 08/13/2018 Time: 09:50:03

FLOW SUMMARIES

Stream No. 27 29 30
32
Stream Name MeOH y Agua Aceite n.c. MeOH y Agua
Na3PO4
Temp C 208.5413 541.8837 38.7445
60.0000
Pres kPa 10.0000 20.0000 40.0000
100.0000
Enth MJ/h -86.995 -191.59 -185.47 -
1764.5
Vapor mole fraction 1.0000 0.00000 0.00000
0.00000
Total kmol/h 0.3176 0.2166 0.6863
1.3062
Flowrates in kmol/h
FAME 0.0522 0.0019 0.0000
0.0000
Glycerol 0.0000 0.0000 0.0001
0.0000
Methanol 0.0590 0.0000 0.2123
0.0000
Calcium Oxide 0.0000 0.0000 0.0000
0.0000
Calcium Sulfate 0.0000 0.0000 0.0000
0.0000
Phosphoric Acid 0.0000 0.0000 0.0000
1.2782
TriNa Phosphate 0.0000 0.0000 0.0000
0.0279
OIL 0.0001 0.0548 0.0000
0.0000
Sulfuric Acid 0.0000 0.0000 0.0000
0.0000
Water 0.2064 0.0000 0.4739
0.0000
Sodium Hydroxide 0.0000 0.1599 0.0000
0.0000

Stream No. 101 103

Stream Name Metanol NaOH
Temp C 25.0000 25.0000
Pres kPa 100.0000 100.0000
Enth MJ/h -874.02 -201.89
Vapor mole fraction 0.00000 0.00000
Total kmol/h 3.6577 0.2500
Flowrates in kmol/h
FAME 0.0000 0.0000
Glycerol 0.0000 0.0000
Methanol 3.6577 0.0000
Calcium Oxide 0.0000 0.0000
Calcium Sulfate 0.0000 0.0000
Phosphoric Acid 0.0000 0.0000
TriNa Phosphate 0.0000 0.0000
OIL 0.0000 0.0000
Sulfuric Acid 0.0000 0.0000
Water 0.0000 0.0000
Sodium Hydroxide 0.0000 0.2500

CHEMCAD 6.1.3 Page

21
Job Name: PlantaBiodiesel Date: 08/13/2018 Time: 09:50:03
DISTILLATION PROFILE

Unit type : SCDS Unit name: Eqp # 4

* Net Flows *
Temp Pres Liquid Vapor Feeds Product
Duties
Stg C kPa kmol/h kmol/h kmol/h kmol/h MJ/h
1 28.3 20.00 6.51 3.26 -
369.3
2 28.3 20.00 6.50 9.77
3 31.4 23.33 6.42 9.75
4 43.0 26.67 12.95 9.67 8.35
5 112.7 30.00 7.85 5.09
500

Mole Reflux ratio 2.000

Total liquid entering stage 4 at 42.469 C, 13.609 kmol/h.

CHEMCAD 6.1.3 Page
22

Job Name: PlantaBiodiesel Date: 08/13/2018 Time: 09:50:03

EXTRACTOR PROFILE

Unit type : EXTR Unit name: Eqp # 8

* Net Flows *
Temp Pres Heavy Light Feeds Product Duties
Stg C kPa kmol/h kmol/h kmol/h kmol/h MJ/h
1 59.3 110.00 0.66 0.61 3.87
2 60.0 110.00 0.67 3.92
3 60.0 110.00 0.58 3.93
4 60.0 110.00 3.84 5.09 1.84

CHEMCAD 6.1.3 Page

23

Job Name: PlantaBiodiesel Date: 08/13/2018 Time: 09:50:03

DISTILLATION PROFILE

Unit type : SCDS Unit name: Eqp # 14

* Net Flows *
Temp Pres Liquid Vapor Feeds Product
Duties
Stg C kPa kmol/h kmol/h kmol/h kmol/h MJ/h
1 208.5 10.00 1.27 0.32 -
528.4
 3.33 side
pr
2 255.2 10.00 11.48 4.92 3.87
3 261.7 11.25 11.92 11.26
4 265.1 12.50 11.98 11.70
5 268.2 13.75 11.98 11.76
6 271.1 15.00 11.86 11.77
7 274.0 16.25 11.46 11.64
8 277.0 17.50 10.36 11.25
9 282.3 18.75 2.94 10.14
10 541.9 20.00 2.73 0.22
970.4

Mole Reflux ratio 4.000

Total liquid entering stage 2 at 101.888 C, 5.138 kmol/h.

CHEMCAD 6.1.3 Page
24

Job Name: PlantaBiodiesel Date: 08/13/2018 Time: 09:50:03

DISTILLATION PROFILE

Unit type : SCDS Unit name: Eqp # 18

* Net Flows *
Temp Pres Liquid Vapor Feeds Product
Duties
Stg C kPa kmol/h kmol/h kmol/h kmol/h MJ/h
1 38.7 40.00 1.37 0.69 -
87.15
2 62.3 40.00 1.35 2.06
3 75.2 45.00 3.25 2.03 1.84
4 112.0 50.00 2.10 1.15
100.8

Mole Reflux ratio 2.000

Total liquid entering stage 3 at 60.545 C, 3.184 kmol/h.