Professional Documents
Culture Documents
Review
h i g h l i g h t s g r a p h i c a l a b s t r a c t
sustainable development.
The strength and durability
performance of RAC are
comprehensively documented.
ITZ of RAC is porous, presence of
cracks and fissures are commonly Recycled aggregate concrete -
Review
found due to the residual mortar. Crushing process Microstructure
The deficiencies observed in RAC can
be significantly overcome by the
incorporation of mineral additives to
the concrete.
Recycled aggregate Hardened properties
a r t i c l e i n f o a b s t r a c t
Article history: The issues of sustainability are of prime concerns these days as we use large amount of natural resources
Received 24 March 2014 for producing materials such as concrete. Depletion of natural resources is one of such sustainability
Received in revised form 27 June 2014 issues which we need to address in an efficient manner. The recent trend in construction industry is to
Accepted 2 July 2014
use the alternative source of construction materials which can substitute the use of virgin materials in
order to reduce environmental impact in terms of energy consumption, pollution, waste disposal and
global warming. On the other hand, the waste generated from the demolition of old structure and con-
Keywords:
struction activity is a matter of concern all over the world. Thus, recycling and reuse of these wastes
Construction and demolition waste
Recycled aggregate
may reduce the usage of natural resources and it can also serve towards the demand of environment.
Recycled aggregate concrete The present paper gives a brief status of recycled aggregate concrete made out of recycled aggregate,
Strength summarizes and critically analyses some of the most important research findings over the past few years
Durability regarding the material aspects. It also attempts to elucidate the approaches for the better performances,
Interfacial transition zone identifies the gaps in the existing knowledge and underlines the reasons why this promising technology
Microstructure has not become widely accepted by the construction industry. The practical problems with application of
recycled aggregate in concrete are also discussed.
Ó 2014 Elsevier Ltd. All rights reserved.
http://dx.doi.org/10.1016/j.conbuildmat.2014.07.003
0950-0618/Ó 2014 Elsevier Ltd. All rights reserved.
502 M. Behera et al. / Construction and Building Materials 68 (2014) 501–516
Contents
1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 502
1.1. Essence of recycling of Construction & Demolition (C&D) wastes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 502
2. Recycled aggregate (RA). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 503
2.1. Recycling process . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 503
2.2. Physical and mechanical properties of recycled aggregate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 503
3. Recycled aggregate concrete (RAC) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 504
3.1. Properties of recycled aggregate concrete . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 504
3.1.1. Green state . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 504
3.1.2. Hardened properties. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 505
3.1.2.1. Compressive strength . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 506
3.1.2.2. Split tensile strength and flexural strength . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 507
3.1.2.3. Drying shrinkage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 507
3.1.2.4. Creep and modulus of elasticity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 508
3.1.2.5. Bond strength . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 509
3.2. Microstructure of recycled aggregate concrete . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 509
3.3. Techniques for improving properties of recycled aggregate concrete . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 510
3.3.1. Incorporation of mineral admixture . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 510
3.3.2. Impregnation of RA in cement slurry or other mineral admixture solution . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 511
3.3.3. Modifying mixing process . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 511
3.4. Durability properties . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 512
3.4.1. Techniques for improving durability properties . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 513
4. Summary and conclusion. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 513
5. Future aspects . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 514
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 514
Whereas Poon et al. [38] reported that RA extracted from crushing reaction, high alumina cement, silt, clay, sulphate, chloride and
of waste concrete consists of 65–70% natural coarse and fine aggre- increased quantity of dust particles [19,58,59]. Although the poten-
gate and 35–30% of cement paste by volume. tial for the use of RA has now been acknowledged, there are some
The amount of adhered mortar signifies strength characteristics factors which hinder the large use of RA in concrete as it affects the
of original concrete, effectiveness of crushing procedure, method of performance of concrete in terms of workability, strength and
crushing and the particle size of RA. There is always a reciprocal durability. Thus, some salient properties of RA such as particle size
relationship between this adhered mortar and the quality of RA. distribution, shape and size of aggregate, porosity, absorption,
The presence of attached mortar is greatly responsible for its toughness, hardness, strength and the impurity level, are necessar-
anomalously high water absorption capacity [39,43–47]. The por- ily to be assessed before its use in concrete. So, the above men-
ous nature of RA is responsible for the higher water absorption tioned inferior qualities and the weaknesses present in RA shown
capacity of RA as these pores allow to absorb more water [48]. in Fig. 3 hinders the use of RA in concrete and the lack of proper
The water absorption capacity of RA is 2–3 times higher than nat- specification also discourages the recycling technique.
ural aggregate and it may range up to 12% for coarse and fine RA
[34,37,38,49]. Poon et al. [38] in their study mentioned that it
may vary up to 15%. The water absorption capacity of RA is more 3. Recycled aggregate concrete (RAC)
for smaller particle size; since greater is the specific surface area
so greater is the mortar content [35]. Water absorption capacity The use of RA in concrete has generated interest in civil
of RA varies depending on the amount of cement paste attached engineering construction regarding sustainable development as it
to the surface of the aggregate particles [50]. According to the rec- is the means of achieving more environment friendly concrete.
ommendation by some international committee, coarse RA having Concrete made up of RA in terms of fine or coarse or both, pro-
water absorption capacity more than 7% and fine aggregate more cessed from C&D waste either as a partial or 100% replacement
than 13% is not desirable to be used in concrete [51]. The water of conventional natural aggregates is known as RAC. RAC mainly
absorption capacity of RA also reflects the water absorption of consists of three phases such as the aggregate phase, mortar phase
RAC. The density and specific gravity of the attached mortar is and the interfacial transition zones between the coarse aggregate
quite less and accounts for the low specific gravity, bulk density and the matrix and the adhered mortar as another matrix. Fig. 4a
and SSD density of RA [19,41,44–46,52,53,47]. Limbachiya et al. and b shows the schematic diagrams of natural aggregate concrete
[54], from the experimental investigation concluded that the rela- and RAC respectively, showing the basic difference of matrix in
tive density of RA or surface saturated density (SSD) is approxi- between two concrete. These three phases are responsible for lim-
mately 7–9% lower than that of natural aggregate. The porosity iting the properties of RAC. So it needs more attention regarding
of RA also determines its specific gravity consequently the density the performance of concrete when RA is to be used in concrete.
[15]. In practice, RA is obtained from different types of construction
RA is generally poorly graded due to its poor particle size and demolished structure as a result the properties of these RA
distribution [47]. It may be too coarse or too fine as a result of obtained from various sources also vary from structure to struc-
the processing and crushing through various types of crushers. ture. Since the early 1980s, European countries have endeavored
The quantity of finer fractions in RA is more. It has an old interfa- to use RAs for new concrete structures. A diversified study on
cial transition zone (ITZ) due to the presence of the old adhered RAC demonstrates the feasibility of the use of RA in concrete and
mortar or cement paste surrounding it. This is weak in nature it can be an alternative source to natural aggregate that has been
because of the presence of minute pores in the clinging mortar, explained later.
continuous cracks and fissures developed inside the aggregate in
consequence to the crushing process [55,56]. These basic features 3.1. Properties of recycled aggregate concrete
of RA are presented schematically in a pictorial format in Fig. 3.
It has rough surface texture and irregular shape, mostly rounded 3.1.1. Green state
in nature due to the wrapped mortar. RA is having inferior Fresh properties of concrete such as workability and wet
mechanical properties such as low crushing strength, low impact density are greatly affected by a number of factors such as w/c
resistance and low abrasion resistance than natural aggregate ratio; the characteristics of the constituent materials of concrete,
[19,53,54,57]. It may be contaminated with organic impurity such especially the aggregate i.e. type of aggregate, maximum size of
as textiles, fabrics, polymeric materials [15] and inorganic impuri- aggregate, water absorption of aggregate etc. Workability of con-
ties due to the internal chemical reaction such as alkali aggregate crete also gets affected by other physical parameters of aggregate
Old mortar
Matrix
Cracks
(a) (b)
Fig. 4. Difference between matrixes of (a) natural aggregate concrete and (b) recycle aggregate concrete.
such as surface texture, aggregate size, and shape of aggregate. In aggregate and matrix. So, it results in the higher water absorption
case of RAC, the slump loss is more than natural aggregate concrete capacity that will affect the workability of the mix. Even with tech-
and it is difficult to meet the required workability [60–63]. Being nical and environmental advantages, the wide spread use of RA
porous in nature, it requires more water than conventional con- may be limited due to its influence on the workability of the
crete to obtain the same workability [64]. Tabsh and Abdelfatah concrete, which turns out to be smaller when compared with the
[65] in their study concluded that RAC demands 10% extra water conventional concrete [61,63,70–73]. From literature, it has also
to achieve the same slump when RA is used instead of natural been found that the slump loss of RAC can be overcome by the
aggregate. Even if keeping w/c ratio constant; aggregate type and incorporation of some mineral admixtures, chemical admixture
the quantity of RCA can also affect the slump of RAC mixes [66]. or super plasticizers or by adding extra water corresponding to
Moreover, concrete made from RA, generally has a harsher and the absorption of aggregates [49]. By the use of super plasticizers,
granular texture due to the adhered mortar which causes a higher water demand of aggregate can be compensated to maintain the
water demand and more energy for compaction due to inter desired workability [23]. According to Saravana Kumar and Dhi-
particle friction [24,45,67,68]. Similarly Sagoe-Crentsil et al. [47] nakaran [74], the water demand could be reduced by 12.5% by
identified that commercially produced RA showed better workabil- the use of RAs admixed with fly ash (20%) and superplasticizer
ity performance than laboratory produced RA as it produces com- than that of without fly ash and super plasticizers.
paratively smoother aggregate. The angular shaped aggregate also Similarly the bulk density of green RAC is significantly lower
demands more water than rounded shape [69]. As the size of RA than natural aggregate concrete due to low density RA
decreases, water demand increases due to more adhered mortar [34,75,76]. The lower density is also a consequence of the lower
quantity. This higher water demand leads to difficulties in control- specific gravity of the RA.
ling the properties of fresh concrete and consequently influences
the strength and durability properties of hardened concrete [64].
If coarse RA is used in dry condition, then the workability of con- 3.1.2. Hardened properties
crete gets hampered to a great extent depending upon the quantity The hardened properties of RAC include the mechanical proper-
of RA used. The loss in workability or slump in RAC is quite prom- ties such as compressive strength, split tensile strength, flexural
inent at higher percentage replacement especially when it strength, modulus of elasticity, creep, and bond strength. These
exceeded 50% [49]. properties of concrete depend upon many parameters such as w/
RA absorbs free water from the mixture during mixing process c ratio of mix, engineering and physical properties of RA to be used
due to its reduced water content in adhered mortar phase of aggre- in concrete and the microstructure. From the literature, it has been
gate, which causes high water demand of mix to maintain the same observed that, RA are less resistant to mechanical action due to its
workability. In order to compensate the low workability problem poor bond between old mortar and the RA, presence of transverse
with RA, some researchers have adopted some novel procedures cracks and fissures in RA during recycling processes and the pres-
by using presoaked aggregate instead of using dried one [24]. ence of weak porous mortar around RA. The potentially inferior
The presoaked aggregates are used in surface saturated dry (SSD) mechanical properties of RAC raise concerns regarding the proper
condition. When RA was used in SSD condition, an increase in ini- assessment of the properties of RA before its use. In addition to
tial slump has been observed with the increasing amount of RA. this, the response of RAC towards mechanical action will also
This is associated with the high absorption capacity of RA leading depend upon the level of replacement by RA, w/c ratio and the
to larger amount of initial free water [62,47]. Sometimes this moisture condition of the RA [13,47]. In RAC, w/c ratio also plays
may lead to bleeding of concrete [62], as a result the w/c ratio of a very important role as it depends on many factors such as water
the matrix can be slightly increased. But later on, the workability absorption of RA, free moisture content of aggregate, and quantity
declines. The initial moisture state of RA also affects the fresh prop- of adhered mortar. Despite that the wide variation in results of RAC
erties of RAC. The initial moisture state of RA mainly depends on may be due to the variation in w/c ratio and the variability in the
the type of dried condition of aggregate such as air dried, oven quality of RA also. The most important conclusion drawn from
dried or SSD condition. Again, the water absorption capacity of numerous studies is that the cement mortar adhered to the aggre-
RA increases with the increase in strength of parent concrete they gate surface influences the performance of RAC, basically the
are derived from. Higher the strength of parent concrete, more is strength characteristics. In the recent past, researchers have
the quantity adhered mortar due to strong bond between worked on different hardened properties of RAC which revealed
506 M. Behera et al. / Construction and Building Materials 68 (2014) 501–516
adjustments to the paste content and to the w/c ratio with the aid
of super plasticizers [20]. However, the drawbacks of RAC from
3.1.2.2. Split tensile strength and flexural strength. The other poten- RA content
tially inferior mechanical property of RAC is the split tensile
Fig. 7. Variation in 28-days split tensile strength w.r.t RA replacement percentage
strength which exhibits similar behavior as compressive strength by various researchers (1) Rao et al. 2011: w/c-0.43 [12], (2) Xiao et al. [97], (3)
with the increase in RA quantity. Several past investigations on Etxeberria et al. [24], (4) (5) (6) Kou et al.: TKOS, TKOL, KTS respectively [92], (7)
RAC showed that the effect of RA content on split tensile strength Elhakam et al.: w/c-0.45 [21], (8) Kou et al.: w/c-0.45 [77], (9) Kou et al.: w/c-0.55
is less than that on compressive strength. Some authors in their [77], (10) Elhakam et al.: w/c-0.60 [21].
RAC [77]. Drying shrinkage characteristics of RAC can be explained in RAC was found to be reversed by the use of RA derived from high
with the higher water absorption characteristics and highly porous strength concrete. It can be attributed to the higher water absorp-
nature of RA. Additionally the old mortar adhered to RA surface tion rate of RA, obtained from high strength concrete, which
contributes to increase in volume of total paste content which reduces the effective w/c ratio of the matrix. However, it was also
contributes more to the shrinkage of cement paste than natural found from their study that the creep development in RAC was
aggregate concrete [6,17,22,56,77]. A number of experimental only 20% lower than conventional concrete after a period of 1 year
investigations revealed that the shrinkage and creep of RAC is quite [13]. The potential drawbacks associated with the creep strain
higher than conventional concrete due to the higher water absorp- development in RAC can be reduced with the use of fly ash as a par-
tion of RA. Sanchez de Juan et al. [46] from their experimental tial replacement of cement or as addition to cement [55,77].
investigation reported that the shrinkage value lied in between Modulus of elasticity is another important mechanical property
15% and 60%. Domingo-Cabo et al. [89] reported that shrinkage which signifies the stiffness of concrete. Modulus of elasticity of
in RAC was 20% higher with a substitution level of 50% and this concrete gets affected by so many parameters such as porosity of
reached up to 70% with 100% RA after a period of 180 days. They aggregate and matrix, dense nature of aggregate and the transition
also identified that RAC showed a shrinkage value equivalent to zone characteristics. This is because the aggregate’s porosity and
conventional concrete at lower substitution level (20%) at early density determines the stiffness of bulk matrix. Substitution of nat-
age. Some researchers stated that the increase in drying shrinkage ural aggregate by RA also affects the modulus of elasticity. How-
can be up to 50% [37,61,89]. However, Sagoe-Crentsil et al. [47] ever, RA content has more has pronounced effect on the modulus
revealed that the drying shrinkage of RAC was about 25% higher of elasticity than that of compressive strength due to its porous
than that of natural aggregate concrete. Whereas Limbachiya nature, low density and weak bond between old ITZ and new ITZ
et al. [17] stated that RA has no major effect on the drying shrink- due to presence more capillary voids and cracks. Like compressive
age up to 30% replacement and after that it increases significantly strength, similar trend has also been observed for modulus of elas-
with the increase in RA content. The variation of drying shrinkage ticity with degree of substitution of RA. Modulus of elasticity of
of RAC (100% RA) with respect to natural aggregate concrete RAC decreases considerably than normal concrete and it reduces
reported by some researchers is shown in Fig. 9. From the figure with the increase in degree of substitution of RA [12,13,64]. Varia-
it is prominent that drying shrinkage of RAC with 100% RA is prom- tion of results of modulus of elasticity as reported by various
inently higher than conventional concrete. The short comings of researchers with natural aggregate and RA (100%) are presented
RAC due to the use of RA such as drying shrinkage, creep can be in Fig. 10. It is found that the modulus of elasticity of RAC with
minimized by incorporating fly ash whether as addition or replace- 100% RA can be lowered up to 45% than that of natural aggregate
ment [56,77,114]. Zhu and Wu [78,95] reported that the drying concrete [12,13,43,44,52,61,78,96,97]. However, Kheder and Al-
shrinkage of RAC can be minimized with the use of fly ash and Windawi [98] reported that it was lowered by 20–25% and Bairagi
super plasticizer in concrete. The reduction in creep of RAC due et al. [70] from their study mentioned that it was reduced by 39%.
to the addition of fly ash attributes to the reduction in w/c of the Despite that Tpocu et al. [75] reported that the reduction was up to
mix and the dilution effect of fly ash particles [56]. 80% at complete replacement by RA. From the failure pattern of
RAC, it is found that RAC behaves in a more brittle manner than
3.1.2.4. Creep and modulus of elasticity. A series of investigations on the conventional concrete. Limbachiya et al. [6] reported that the
deformation characteristics of the RAC specimens revealed that the lower values of elastic modulus of RAC may attribute to strength
creep increases with the increase in content of RA. This is due to characteristics of RA and its inferior quality compared to the natu-
the increased volume of total mortar content in case of RAC as ral aggregate. Despite that Xiao et al. [78,83] reported that the
compared to the conventional concrete. Creep of concrete is also decrease in elastic modulus is due to the old adhered mortar to
directly proportional to the content of the paste or mortar present the surface of RA which is comparatively of low elastic moduli than
in concrete as drying shrinkage. In RAC, the residual mortar of RA the aggregate. RA has adverse influence both on longitudinal and
contributes towards more mortar content which results in consid- transverse modulus of elasticity [99]. The reduced elastic moduli
erable higher creep. Some researchers from their investigations of RA is particularly responsible for the increase in the peak strain
reported that the creep of RAC can be increased up to 50% than that and ultimate strain of RAC [99] which leads to large deformation.
of conventional concrete [37,89]. Furthermore, Domingo-Cabo Limbachiya et al. [6] in their empirical studies also concluded that
et al. [89] concluded that the creep deformation was more than with the use of 100% RA, approximately 35% reduction in modulus
50% at 100% use of RA. On the other hand, Ajdukiewicz et al. [13] of elasticity was observed. Similarly, Corinaldesi [100] reported
suggested that the general tendency of the development of creep that 15% less elastic modulus could be achieved by using only
Drying shrinkage (micro strain)
35 0% RA 100% RA
Modulus of Elasticity (GPa)
30
25
20
15
10
0
1 2 3 4 5
Fig. 9. Influence of RA on Drying Shrinkage (1) Kou et al. [56], (2) Limbachiya et al.
[84], (3) Limbachiya et al. C20 [6], (4) Limbachiya et al. C30 [6], (5) Limbachiya et al. Fig. 10. Variation in modulus of elasticity (28-days) w.r.t RA replacement by
C35 [6], (6) Limbachiya et al. GEN3 [17], (7) Limbachiya et al. RC30 [17], (8) different researchers (1) Etxeberria et al. [24], (2) Rao et al. [12], (3) Xiao et al. [97],
Limbachiya et al. RC35 [17]. (4) Kou et al. [92], (5) Li et al. [52].
M. Behera et al. / Construction and Building Materials 68 (2014) 501–516 509
30% RA. The incorporation of RA into concrete reduces the stiffness secondary C–S–H gel formation. In their study they reported that
of concrete and increases the brittleness as a result modulus of the bond strength was more for RAC for both plain and deformed
elasticity decreases [40]. bar than conventional concrete and it was 6% and 15% higher than
So, from the results obtained from various research works, it conventional concrete in the absence and presence of fly ash
can be well summarized that the influence of content of RA on respectively. So it can be summarized that bar profile has more
shrinkage, creep and especially on the modulus of elasticity is sig- influence on bond strength than the RA replacement.
nificantly higher than other strength properties [40,101]. Basically
the strength properties of RAC have an inverse relationship with
RA content. Despite that all these properties depend more or less 3.2. Microstructure of recycled aggregate concrete
on the w/c ratio of RAC and the variability in properties of
aggregate. The microstructure of RAC is a very different and complicated
structure than that of conventional concrete especially in the inter-
facial transition zone (ITZ). Unlike normal concrete, it has two ITZs,
3.1.2.5. Bond strength. While considerable results are available on one is new ITZ lies between RA and new matrix and another is old
the other strength properties of RAC, relatively few information ITZ lies between RA and old adhered mortar [59] which is shown in
is reported on the bond strength between matrix and steel Fig. 12c. So the mechanical performance of RAC is a consequence of
reinforcement. Some of the experimental investigations revealed dual performance of both the ITZs as ITZ significantly influence the
that the influence of RA and its quantity on the bond strength is strength property. Many studies have revealed that the ITZ of RAC
quite smaller than other mechanical properties. RA content does is very weak in nature [38,77,107]. This ITZ forms the weakest link
not have much influence on the bonding between concrete and and strength limiting phase in RAC as it acts like a wall between
reinforcing bar. However, the factors which contribute to the bond the matrix phase and the coarse aggregate phase in concrete
strength are type of rebar and rebar surface profile in case of RAC [59,88,108] and acts as a barrier to transfer the load as the cracks
[102]. From literature, it has been observed that the bond strength form first near the ITZ. It acts like a gradual transition zone whose
may reduce up to 10% at a replacement level up to 100% [13,102]. thickness is associated with degree of hydration and the adhered
Xiao et al. [103,104] studied the bond behavior of RAC with differ- mortar content of RA. In many studies, it is reported that for nor-
ent types rebar by pull out test and reported that the bond strength mal cement concrete the thickness of ITZ may range up to 50 lm
decreased by 12% and 6% at 50% and 100% replacement level of RA around the aggregate. It consists of less unhydrated particles,
than natural aggregate concrete respectively for plain rebar. And highly porous and greater concentration of Ca(OH)2 and ettringite.
for deformed bar it was quite similar to each other irrespective Moreover, from SEM analysis it is found that the ITZ of RAC is com-
of different level of replacement. The possible reason might be that posed of many minute intrinsic pores, cracks and fissures [59].
in case of deformed bar, the bond is due to mechanical anchorage Poon et al. [38] investigated the microstructure of ITZ through
and friction, whereas in case of plain bar, it is due to the bonding SEM analysis and reported that the ITZ of RAC consists of loose
between the rebar and concrete [22,104]. The influence of the and porous hydrates which are granular in nature. Thomas et al.
bar profile on bond strength development in between rebar and [76] studied the surface morphology of RAC through SEM which
concrete is shown in Fig. 11. However, Zuhud [105] in his study is shown in Fig. 12a, and observed that it is composed of loosely
reported that the bond strength between deformed bar and con- adhered mortar. The porous nature of ITZ causes the reduced elas-
crete increased with the increase in RA content. It was up to tic modulus and lower strength in that particular area relative to
32.4% and 46.1% more than conventional concrete for a replace- the surrounded mortar matrix [109–111]. Due to its poor micro-
ment percentage of 30.0% and 60.0% respectively. The increase in structure, the stiffness of the concrete may be low, which does
bond strength attributed to the increase in friction due to rough not withstand the stress transfer across this.
surface of RA and deformed bar. Similarly, Xiao et al. [104] from Khalaf and DeVenny [15] concluded that the pores and cracks
their study also reported that the bond strength of RAC with present on the surface and inside the RA respectively may vary
100% RA found to be more than conventional concrete. The higher in size. Hence the cement paste cannot penetrate into these pores
bond strength of RAC is due to the internal curing effect of RAC due due to more viscous whereas water can easily penetrate. It may
to more hydration of cement paste by the use of SSD aggregates result a poor bond between old ITZ and new ITZ. In addition to this,
which could be attributed to the improved contact zone between some amount of fine flake-like and whisker-like crystals were also
RA and matrix by the use of SSD aggregates [106]. Valeria et al. found in the voids of ITZ. Some studies on the ITZ of natural aggre-
[20] studied the influence of fly ash on the bond strength of RAC gate concrete have revealed that, the formation of large flat
and concluded that the bond strength increased with the Ca(OH)2 crystal perpendicular to the surface of aggregate grain
incorporation of fly ash. The improvement in strength can be results in the formation of a highly porous structure in the ITZ
explained through the pore structure improvement due to due to accumulation of water film in vicinity to aggregate surface.
Fig. 13a. Filled cracks in RA by two stage mixing approach [59]. Fig. 13d. Without surface treatment (on surface) [107].
Fig. 13b. Unfilled cracks in RA by normal mixing approach [59]. Fig. 13e. Surface microstructure of RA with fly ash [107].
Table 1
Different approaches adopted for the improvement of properties of RAC.
approaches tried by different researchers along with the above permeation [55,56]. In addition to this, microstructure of ITZ also
mentioned approaches and their beneficial effects have been sum- plays a significant role as it strongly depends on the nature of
marized in Table 1. aggregate, its porosity and its water absorption characteristics.
These can be easily understood from the following SEM images However, microstructure of RAC is porous in nature due to the
obtained from different sources as given below. Figs. 13a and 13b presence of old adhesive mortar around the RA, high water absorp-
show the influence of two stage mixing approach on filling the tion characteristics of RA, which also contributes towards the per-
cracks and fissures present on the surface of RA. Similarly meability characteristics of RAC. This porous ITZ has a large
Figs. 13c–13f represents the surface microstructure of RAC which influence on permeation characteristics of concrete, especially if
has been densified by the pozzolanic reaction of fly ash. Fig. 13f the individual ITZ regions are connected with each other across
represents surface improvement of RA filled with silica fume. the three dimensional microstructure. Apart from this, permeabil-
ity of RAC also depends upon the w/c ratio [77] and curing period
3.4. Durability properties [55]. So, more is the curing duration, denser is the microstructure
due to more hydration; hence better is the durability performance
Generally durability performance of concrete is a measure of [55]. Thus, porosity of RA is the controlling factor for better dura-
permeation characteristics of concrete, as well as integrity of con- bility performance of RAC. So it needs special treatment to block
crete against aggressive agents in the environment like sulphate, the open path for foreign agents. On the other hand, one of the
chlorides, acids, carbon dioxide, oxygen, etc. Investigations of the major difficulties with RA is the variability in their properties
RAC have revealed that, the durability performance of RAC is due to processing, composition, contents and proportions largely
poorer than conventional concrete. The poor durability perfor- linked to the original source of debris, which consequently results
mance of RAC is associated with the inferior quality of RA due to in the variability of concrete properties.
the presence of numerous cracks and fissures and pores present From literature, it has been observed that the permeability of
inside the aggregate, thus making it more susceptible towards concrete can be measured through different methods such as
M. Behera et al. / Construction and Building Materials 68 (2014) 501–516 513
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