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matric higher
secondary school,
arakkonam-3
NOTES OF LESSON FOR
PC CHEMISTRY
COMPLETED BY
P.R.SAGUNTHALA DEVI M.Sc., PGDCA,
Unit 3: Electrochemistry
Pattern
Part I
Choose the best Answer 100 X 1 = 100
56. In FeS crystal two out of three Fe2 ions may be converted
into Fe3+
17 BHARATHIDASANAR MATRIC HIGHER SECONDARY SCHOOL, ARAKKONAM _ 12th PC Chemistry
and the third one will go out from its lattice site such a
defect is
known as
a) Schottky defect b) Frenkel defect
c) Metal excess defect d) Metal deficiency defect
57. First order maximum occurs on a crystal at a glancing angle
of 300
when X-ray of wavelength 2A is used. Then the inter planar
distance
in the crystal is
a) b) 2 c) 0.5 d) 0.25
a) n = 2d sin b) n= c) nd = 2 sin d) n =
2d sin
65. Colloidal solutions are purified by
a) Electrodialysis b) Electro osmosis
c) Electrophoresis d) Electro filration
66. The zig-gag ceaseless movement of colloidal particles in the
dispersion medium is called
a) Tyndall effect b) Brownian movement
c) Osmosis d) Dialysis
67. The combination of the layers of charges around the sol
particle is
Called
a) Graham’s layer b) Brownian doubled layer
c) Tyndall layer d) Helmholtz double layer
68. Cheese in an example of
80. The solid that takes up gas, vapour or solute from a given
solution is
Called
1. Diamond is an example of
Solid with hydrogen bonding Covalent solid
Electrovalent solid Glass
9. In a solid lattice the cation has left a lattice site and is located at an
interstitial position, the lattice defect is .[AIIMS 1982, 199]
Interstitial defect Frenkel defect
Valency defect Schottky defect
16. Under which category iodine crystals are placed among the
following
Ionic crystal Molecular crystal
Metallic crystal Covalent crystal
17. Glass is
Supercooled liquid Amorphous solid
Crystalline solid Liquid crystal
20. How many space lattices are obtainable from the different crystal
systems . [MP PMT 1996; MP]
7 32
14 230
18. Pick out the statement which is not relevant in the discussion of
colloids . [KCET 2003]
Sodium aluminium silicate is Artificial rain is caused by
used in the softening of hard throwing electrified sand on the clouds
water from an aeroplane
Potash alum is used in
Deltas are formed at a place where
shaving rounds and as
the river pours its water into the sea
antiseptic in medicine
23. Lyophilic sols are more stable than lyophobic sols because . [NCERT
1982, 83]
The colloidal
particles have positive The colloidal particles are solvated
charge
There are strong electrostatic repulsions
The colloidal
between the negatively charged colloidal
particles have no charge
particles
30. For the adsorption of a gas on a solid, the plot of log (x/m) versus log
P is linear with slope equal to . [CBSE PMT 1994]
k n
log k 1/n
32. Colloidal solutions of metals like gold, silver and platinum are
generally prepared by using. [DPMT 1984]
Peptization Exchange of solvent
Bredig's arc method Oxidation method
35. Which among the following statement is false . [KCET (Med.) 200]
The adsorption may be Increase of pressure increases
monolayered or multilayered amount of adsorption
Particle size of adsorbent will Increase of temperature may
not affect the amount of adsorption decrease the amount of adsorption
42. In physical adsorption, the gas molecules are held on solid surface
by. [MP PET 1996; AI]
Chemical forces Gravitational forces
Electrostatic forces Vander Waal's forces
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17. Which one of the following statements is correct . [MP PET 1997]
The oxidation number of oxygen in KO₄ is
Sn2+ oxidises Fe3+
zero
The specific conductance of an electrolyte Zn/ZnSO₄ is a
solution decreases with increase in dilution reference electrode
unit-3; ELECTROCHEMISTRY
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7. The weight of AgNO3 (mol. mass= 170) present in 100 ml of its 0.25
M solution is:
10. 36 g water and 828 g ethyl alcohol form an ideal solution. The mole
fraction of water in it, is
1.0 0.4
0.7 0.1
12. The number of moles of solute per kg of a solvent is called its. [IIT
1985]
Molarity Molar fraction
Normality Molality
17. 171 g of cane sugar (C12 H22 o11 ) is dissolved in 1 litre of water.
The molarity of the solution is
10. For purification of alumina, the modern processes most useful when
(i) the impurity present is a lot of iron oxides and (ii) the impurity
present is a lot of silica, are
For (i) Hall's process; for (ii) For (i) Serpeck's process; for (ii)
Baeyer's process Baeyer's process
For (i) Hall's process; for (ii) For (i) Baeyer's process; for (ii)
Serpeck's process Serpeck's process
13. Which of the following is the correct statement for red lead. [AIIMS
2000]
It is an active form of lead It decomposes into Pb and CO₂
Its molecular formula is Pb₂O₃ It decomposes into PbO and O₂
19. Which of the following alkaline earth metals shows some properties
similar to aluminium. [BHU 1983]
Be Sr
Ca Ba
22. Which of the following statement about LiCl and is correct. [CEE
2002]
LiCl has higher melting point LiCl would ionize in water more
than NaCl than NaCl
LiCl dissolves in water Fused LiCl would be less
whereas NaCl does not conducting than fused NaCl
24. The property of the alkaline earth metals that increases with their
atomic number is. [BHU 2001]
Ionisation energy Solubility of their sulphates
Electronegativity Solubility of their hydroxides
37. Which of the following does not illustrate the anomalous properties
of lithium. [MP PET 1993]
The melting point and
Li forms a nitride Li₃N unlike
boiling point of Li are
group I metals
comparatively high
The ion of Li and its compounds are
Li is much softer than the
more heavily hydrated than those of
other group I metals
the rest of the group
39. The strongest reducing agent of the alkali metal is. [CPMT 1999;
Pb.C]
Li K
Na Cs
40. Which one of the following is the strongest base. [Pb. PMT 1998]
Be(OH)₂ Al(OH)₂
Mg(OH)₂ Si(OH)₂
42. The hardest substance amongst the following is. [Kerala PMT 2004]
Be₂C Titanium
Graphite B₄C
48. The most electropositive amongst the alkaline earth metals is. [MP
PMT 1993]
Beryllium Calcium
Magnesium Barium
4. Which of the following has the maximum number of unpaired d-electrons. [BIT 19
CBSE ]
Zn Ni3+
Fe2+ Cu+
7. Which of the following is not true for transition metals. [MP PET 1993]
They are malleable and They crystallize with body centred cubic and
ductile hexagonal close-packed structures only
They have high boiling and They show variable oxidation states although not
melting points always
10. Transition metals are often paramagnetic owing to. [Bihar CEE 1992]
Their high M.P. and The presence of one or more unpaired electrons
B.P. in the system
The presence of vacant Their being less electropositive than the elements
orbitals of groups I-A and II-A
13. The metal ion which does not form coloured compound is.
Chromium Zinc
Manganese Iron
14. Platinum, palladium, iridium etc., are called noble metals because. [NCERT 1975
CPM]
They are shining lustrous and pleasi
Alfred Noble discovered them
look at
They are inert towards many common
They are found in active state
reagents
15. Mercury is the only metal which is liquid at 0⁰ C This is due to its. [CBSE PMT 1
Very high ionisation energy and weak metallic bond High atomic weight
Low ionisation potential High vapour pressu
17. The transitional metal which form green compound in +3 oxidation state and yell
orange compound in +6 oxidation state is
Fe Cr
Ni Co
19. All those elements belong to f - block whose atomic numbers are
58 to 71 Both (a) and (b)
90 to 103 None
20. In the first transition series, the highest B.P. and M.P. is of
Cr Ni
V Fe
25. Acidified potassium dichromate is treated with hydrogen sulphide. In the reaction
oxidation number of chromium. [MP PET 1996]
Increases from + 3 to + 6 Remains unchanged
Decreases from +6 to +3 Decreases from +6 to +2
33. Zinc and mercury do not show variable valency like d-block elements because. [R
2000; MP P]
They are soft They have only two electrons in the outermost sub
Their d- shells are complete Their d-shells are incomplete
34. In acidic medium one mole of MnO₄ - accepts how many moles of electrons in a re
process ?. [MP PET/PMT 1998]
1 5
3 6
39. Mercury is transported in metal containers made of. [DPMT 1982; CPMT]
Silver Iron
Lead Aluminium
40. Which statement is true about the transitional elements. [MP PMT 1995]
They are highly reactive They have low M.P.
They show variable oxidation states They are highly electropositive
42. Transitional elements exhibit variable valencies because they release electrons fro
following orbits.[MP PET/PMT 1988]
ns orbit (n - 1)d and ns orbits
ns and np orbits (n - 1)d orbit
43. In which of the following ionic radii of chromium would be smallest. [MP PET 19
K₂CrO₄ CrCl₃
CrO₂ CrF₂
45. The equivalent weight of potassium permanganate for acid solution is. [MP PET 1
158 52.16
31.6 79
49. The hardness of Cr is due to ...... and metallic lusture is due to .......
Covalent bond, metallic bond Metallic bond, covalent bond
Covalent bond, hydrogen bond Metallic bond, hydrogen bond
a) (CH3)3CBr
b) CH3CH2CH2F
c) CH2 = CHCH2Br
a) 1-Bromo-4-sec. butyl-2-methylbenzene.
b) Bromoform
c) 1-Chlorobutane
d) 1-Chloro-4-ethylcyclohexane
e) 1-Bromo-4-sec-butyl-2-methylbenzene
g) 1−Bromo−1−chloro−1, 2, 2−trifluoroethane
Nature of bond when halogen atom is attached to the main atom.
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Write the isomers for C5H11Cl.
Identify all the possible monochloro structural isomers expected to
be formed on free radical monochlorination of (CH3)2CHCH2CH3.
Method of preparation of haloalkanes:
a) By electrophilic substitution
b) Sandmeyer’s reaction
c) From Alkenes
Show the finkelstein’s reaction?
a) Density
b) Melting Point
c) Solubility
d) Boiling Point
Haloalkanes react with KCN to form alkyl cyanides as main
product while AgCN forms isocyanides as the chief product. Explain.
What are polar protic solvents? Give examples.
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Differentiate between inversion and racemisation?
What do you mean by chiral and achiral atom? Differentiate with
an example.
Explain enantiomer and retention with an example?
How is elimination different from substitution? Show with a
example?
Explain why NO2 group do not show effect at meta position?
Explain:
a) Fridel-Craft Reaction
b) Sulphonation
d) Nitration
Although chlorine is an electron withdrawing group, yet it is ortho-
, para- directing in electrophilic aromatic substitution reactions. Why?
Give the uses of:
a) Chloroform
b) Carbon tetrachloride
c) DDT
What are ambident nucleophile? Explain with an example.
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Grignard reagents should be prepared under anhydrous
conditions?
Write the structure for following:
B. evaporation
C. deposition
D. sublimation
Answer: A.
2) Which of the following parts of the sun is easily visible only during a
total solar eclipse?
A. core
B. photosphere
C. sunspots
D. corona
Answer: D.
Answer: A.
Answer : B.
B. Magnetic reversals
Answer : A.
B. Se
C. I
D. Ga
Answer : D.
Answer : B.
B. ornithophily
C. entomophily
D. anemophily
Answer : B.
B. lion
C. man
D. jaguar
Answer : A.
B. decreases slightly
Answer : B.
1) Which prefix is often used with scientific terms to indicate that
something is the same, equal or constant?
A. iso
B. mega
C. meta
D. quasi
Answer : A.
B. morphology
D. cryogenics
Answer : D.
B. oncology
C. paleontogy
D. pathology
Answer : A.
Answer : D.
B. ductile
C. extractive
D. tactile
Answer : B.
B. urinary bladder
C. pancreas
D. lung
Answer : B.
B. Shark teeth
C. Oyster Shells
D. Whale bones
Answer : C.
B. decreases
Answer : A.
C. bacteria
D. seed
Answer : A.
B. segregate particles
D. model fractals
Answer : B.
1) Widespread resistance of malarial parasite to drugs like chloroquine
has prompted attempts to develop a malarial vaccine to combat malaria.
Why is it difficult to develop an effective malaria vaccine?
A. Malaria is caused by several species of Plasmodium.
Answer : A.
B. 2 and 4 only
C. 1, 3 and 4 only
D. 1, 2, 3 and 4
Answer : C.
B. 2, 3 and 4 only
C. 1 and 4 only
D. 1, 2, 3 and 4
Answer : D.
B. Oxygen
C. Fluorine
D. Chlorine
Answer : D.
Answer : A.
6) A married couple adopted a male child. A few years later, twin boys
were born to them. The blood group of the couple is AB positive and O
negative. The blood group of the three sons is A positive, B positive, and
O positive. The blood group of the adopted son is
A. O positive
B. A positive
C. B positive
Answer : A.
7) A new optical disc format known as the Blu-ray Disc (BD) is becoming
popular. In what way is it different from the traditional DVD?
1. DVD supports standard Definition video while BD supports High
definition Video.
2. Compared to a DVD, the BD format has several times more storage
capacity.
B. 1 and 2 only
C. 2 and 3 only
D. 1, 2 and 3
Answer : B.
D. Indian gazelle
Answer : B.
Answer : D.
B. 2 only
C. 1 and 3 only
D. 1, 2 and 3
Answer : D.
1) Vacuoles are bound by a definite membrane in plant cells called
A. Plasma membrane
B. Tonoplast
C. Cell wall
Answer : B.
B. Venus
C. Saturn
D. Neptune
Answer : C.
B. Tower
C. Hour
D. Cock
Answer : C.
B. Mars
C. Jupiter
D. Saturn
Answer : D.
5) The theory which advocates that living beings can arise only from
other living beings is termed
A. Bio-genesis
C. Catastrophism
D. Cosmozoic
Answer : A.
B. 9 & 16 respectively
C. 16 & 16 respectively
D. 9 & 9 respectively
Answer : A.
B. Centrosomes
D. Lysosomes
Answer : C.
B. Sea snake
C. Krait
D. Python
Answer : D.
9) The use of which of the following devices has given the modern
biologist a better insight into the internal structure of cells
A. Super Computer
B. Electron microscope
C. Spectrophotometer
D. Ultracentrifuge
Answer : B.
10) The two diseases that most often kill AIDS victims are
1.Kaposi's sarcoma
2.Lymphangioma
3.Pneumocystis carinii pneumonia
4.Systemic Lupus erythromatosus
A. 1 and 2
B. 2 and 3
C. 1 and 3
D. 3 and 4
Answer : C.
B. the earth comes in the between the sun and the moon
Answer : C.
B. Nephron
C. Granulocyte
D. Reticulocyte
B. Soil erosion
C. Soil creep
D. Silting of soil
Answer : B.
B. a NOR circuit
C. an OR circuit
D. a high-pass filter
Answer : C.
B. Decreases
C. Remains unaltered
D. Drops sharply
Answer : C.
B. Cat
C. Dog
D. Rabbit
Answer : A.
B. Nitric oxide
D. Nitrogen pentoxide
Answer : D.
B. Bony fish
C. Shark
D. Mammal
Answer : D.
B. Secant scale
C. Mercalli scale
D. Beaufort scale
Answer : A.
B. Diamond
C. Quartz
D. gold
Answer : A.
1) The general direct flow of summer monsoon in India is
A. From South to North
Answer : B.
B. Carbon monoxide
C. Nitrous oxide
D. Nitrogen peroxide
Answer : A.
Answer : B.
B. Intestine
C. Throat
Answer : C.
B. Kyoto Protocol
C. Montreal Protocol
Answer : B.
B. Spermatozoan
B. Dispersion of light
C. Reflection of light
D. Refraction of light
Answer : B.
B. Cat
C. Snake
D. Bat
Answer : D.
C. Heart
D. Kidney
Answer : A.
B. A homogeneous mixture
C. A heterogeneous mixture
D. An inorganic compound
Answer : A.
1) Spinach leaves are rich source of
A. Vitamin A
B. Iron
C. Carotene
D. Vitamin E
Answer: B.
B. Fungus
C. Virus
D. Algae
Answer : C.
3) Silk is produced by
A. Egg of silkworm
B. Pupa of silkworm
C. Larva of silkworm
D. Insect itself
Answer : C.
B. Gasoline
C. LPG
D. Distilled water
Answer : D.
B. A
C. O
D. B
Answer : C.
Answer : C.
Answer : C.
A. Only 1
B. Only 2
C. Both 1 & 2
D. Neither 1 nor 2
Answer : D.
B. Only 2
C. Both 1 & 2
D. Neither 1 nor 2
Answer : C.
B. Space technology
C. Missile technology
D. Communication technology
Answer : D.
1) Who gave the first evidence of the Big- Bang theory?
A. Edwin Hubble
B. Albert Einstein
C. S. Chandrasekhar
D. Stephen Hawking
Answer : A.
Answer : B.
B. Microwaves
C. Optical fibres
D. Radiowaves
Answer : B.
4) Which one of the following types of waves are used in a night vision
apparatus?
A. Radio waves
B. Microwaves
C. Infra-red waves
Answer : C.
Answer : A.
B. Mars
C. Saturn
D. Venus
Answer : A.
B. Mercuric oxide
C. Graphite
D. Nitroglycerine
Answer : D.
B. Radium
C. Thorium
D. Cadmium
Answer : D.
Answer : D.
B. Soybean
C. Fish flesh
D. Red meat
Answer : B.
1) Which one of the following glands produces the Growth Hormone
(Somatotropin)?
A. Adrenal
B. Pancreas
C. Pituitary
D. Thyroid
Answer : A.
B. Vitamin C
C. Vitamin D
D. Vitamin K
Answer : B.
B. Nitrogen
C. Carbon Dioxide
D. Oxygen
Answer : B.
B. Green light
C. Red light
D. Yellow light
Answer : C.
B. Malaria
C. Filariasis
D. Goitre
Answer : A.
B. Wax candle
D. Torch
Answer : A.
Answer : D.
B. Jupiter
C. Venus
D. Mercury
Answer : D.
Answer : D.
B. Jute
C. Coir
D. Rayon
Answer : B.
157 BHARATHIDASANAR MATRIC HIGHER SECONDARY SCHOOL, ARAKKONAM _ 12th PC Chemistry
1) Which acid is produced when milk gets sour?
A. Tartaric acid
B. Butyric acid
C. Lactic acid
D. Acetic acid
Answer : C.
B. Cholera
C. Dengu
D. Influenza
Answer : B.
B. Linseed
D. Mustard
Answer : A.
B. Citric acid
C. Tartaric acid
D. Formic acid
Answer : D.
B. 1.0 litre
C. 1.11 litre
D. 1.5 litre
Answer : C.
6) What would be the best choice for window material to keep the
outside heat away?
A. Single-pane glass
Answer : D.
Answer : C.
160 BHARATHIDASANAR MATRIC HIGHER SECONDARY SCHOOL, ARAKKONAM _ 12th PC Chemistry
8) Washing soda is the common name for
A. Calcium carbonate
B. Calcium bicarbonate
C. Sodium carbonate
D. Sodium bicarbonate
Answer : C.
B. chitin
C. DNA
D. hemoglobin
Answer : A.
10) The persons working in textile factories such as carpet weavers are
exposed to which of the following occupational disease?
A. Asbestosis
C. Silicosis
D. Siderosis
Answer : B.
B. Angle of declination
C. Angle of inclination
Answer : B.
B. Fluorine-containing compounds
C. Nitrogen-containing compounds
D. Sulphur-containing compounds
Answer : D.
3) Mist is caused by
A. Dry ice
Answer : C.
4) In the human body, Cowper’s glands form a part of which one of the
following?
A. Digestive system
B. Endocrine system
D. Nervous system
Answer : C.
B. 70-75
C. 80-97
D. 82-87
Answer : A.
B. humidity
C. temperature
Answer : D.
B. Molten rock
C. Water
D. Flexible rock
Answer : C.
B. Mushroom
C. Carrot
D. Cabbage
Answer : B.
165 BHARATHIDASANAR MATRIC HIGHER SECONDARY SCHOOL, ARAKKONAM _ 12th PC Chemistry
9) Which colour of heat radiation represents the highest temperature?
A. Blood red
B. Dark cherry
C. Salmon
D. White
Answer : D.
B. Silica
C. Graphite
D. Nickel
Answer : C.
1) What does airbag, used for safety of car driver, contain?
A. Sodium bicarbonate
B. Sodium azide
C. Sodium nitrite
166 BHARATHIDASANAR MATRIC HIGHER SECONDARY SCHOOL, ARAKKONAM _ 12th PC Chemistry
D. Sodium peroxide
Answer : B.
C. The Equator
Answer : D.
B. UO2
C. UF6
D. U metal
4) The time taken by the Sun to revolve around the center of our galaxy
is
A. 50 mn years
B. 100 mn years
C. 250 mn years
D. 365 mn years
Answer : C.
B. 2 and 3 only
C. 2, 3 and 4 only
D. 1, 2, 3 and 4
B. Sodium carbonate
C. Sodium hydroxide
D. Calcium carbonate
Answer : A.
Answer : C.
B. Calcium hydroxide
C. Sodium hydroxide
D. Calcium sulphate
Answer : A.
A. 1 only
B. 2 only
C. Both 1 and 2
D. Neither 1 nor 2
Answer : C.
B. 2 only
C. Both 1 and 2
D. Neither 1 nor 2
Answer : C.
1) Consider the following:
1. Carbon dioxide
2. Oxides of Nitrogen
3. Oxides of Sulphur
Which of the above is/are the emission/emissions from coal combustion
at thermal power plants?
A. 1 only
B. 2 and 3 only
C. 1 and 3 only
D. 1, 2 and 3
Answer : D.
B. 3 only
C. 2 and 3 only
D. 1, 2 and 3
Answer : C.
B. Convex lens
C. Cylindrical lens
Answer : D.
C. Polycythemia
D. Leucopenia
Answer : B.
5) Given below are the names of four energy crops. Which one of them
can be cultivated for ethanol?
A. Jatropha
B. Maize
C. Pongania
D. Sunflower
Answer : B.
Answer : A.
7) Radioactivity is measured by
A. Geiger-Muller counter
B. Polarimeter
C. Calorimeter
D. Colorimeter
Answer : A.
D. They activate certain genes in the cells of the body and help
delay the ageing
Answer : C.
B. 1, 3 and 4 only
C. 2 and 4 only
D. 1, 2, 3 and 4
Answer : A.
C. The mangrove trees are tall with dense canopies and serve as an
excellent shelter during a cyclone or tsunami
Answer : D.
1) The Himalayan Range is very rich in species diversity. Which one
among the following is the most appropriate reason for this
phenomenon?
A. It has high rainfall that supports luxuriant vegetative growth
Answer : B.
Answer : A.
3) The formation of ozone hole in the Antarctic region has been a cause
of concern. What could be the reason for the formation of this hole?
A. Presence of prominent tropospheric turbulence; and inflow of
chlorofluorocarbons
Answer : B.
B. 2 only
C. Both 1 and 2
D. Neither 1 nor 2
Answer : C.
Answer : B.
B. 2 and 3 only
C. 1 and 3 only
D. 1, 2 and 3
Answer : C.
D. Prairie land
Answer : C.
B. African elephant
C. Giraffe
D. White tiger
Answer : B.
Answer : A.
Answer : C.
1) Nitrous oxide, commonly called laughing gas, has been a matter of
concern to environmentalists recently because:
A. it is thought to cause cancer at low concentrations.
C. it is a greenhouse gas.
Answer : C.
B. entomophily
C. anemophily
D. ornithophily
C. nuclear medicine.
Answer : A.
B. cobalt-60
C. iodine-131
D. plutonium-238
Answer : A.
B. silver bullets
C. markers
D. dyes
Answer : A.
B. mercury
C. helium
D. water
Answer : D.
7) Which of the following materials is used along with iron ore and
limestone to produce iron in a modern blast furnace?
A. coke
B. cementite
D. bauxite
Answer : A.
B. toxicology
C. phrenology
D. ergonomics
Answer : B.
B. 20 to 20,000 Hertz
Answer : B.
B. hygrometer
C. anemometer
D. barometer
Answer : B.
1) Plants get their nitrogen from
A. rain
B. the soil
C. the air
D. the bedrock
Answer : B.
B. aluminum
C. mercury
D. sulfur
Answer : B.
B. a centimeter
C. a dekameter
D. a terameter
Answer : D.
C. temperature
D. surface tension
Answer : B.
B. carbon
C. nickel
D. silicon
Answer : B.
B. magnesium
C. copper
Answer : A.
B. unburned hydrocarbons
C. nitrous oxide
D. sulfur dioxide
Answer : D.
B. particulate formation
C. thermal pollution
D. noise pollution
9) Biomass energy is
A. formed through photosynthesis
Answer : A.
B. 32 degrees Fahrenheit
C. 72 degrees Fahrenheit
D. 97 degrees Fahrenheit
Answer : C.
3. When aniline is treated with sodium nitrite and hydrochloric acid at 0oC, it
gives. [Orissa JEE 2003]
Phenol and N2 Hydrazo compound
Diazonium salt No reaction takes place
6. Ethylamine can be prepared by the action of bromine and caustic potash on. [CPM
1994]
Acetamide Formamide
Propionamide Methyl cyanide
7. The amine formed from an amide by means of bromine and alkali has
Same number of C atoms as that of amide One more C atom than that of am
One less C atom than that of amide Two more C atoms than that of am
9. The diazonium salts are the reaction products in presence of excess of mineral acid
nitrous acid and .[MP PET 2002]
Primary aliphatic amine Primary aromatic amine
Secondary aromatic amine Tertiary aliphatic amine
10. For the preparation of p-nitroiodobenzene from p-nitroaniline, the best method is
. [Orissa JEE 2005]
NANO2 HCL followed by KI LiAlH4 followed by I2
NANO2 HCL followed by CuCN naBH4 followed by I2
15. Amides may be converted into amines by reaction named after . [CPMT 1974; MP
Perkin Hoffmann
17. Which of the following would be most reactive towards nitration. [AMU 2000;
UPSEA]
Benzene Toluene
Nitro benzene Chloro benzene
19. Which of the following reacts with chloroform and a base to form phenyl
isocyanide . [AFMC 1997]
Aniline Benzene
Phenol Nitrobenzene
23. Number of isomeric primary amines obtained from C4H11N are. [DPMT 2005]
3 5
4 6